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1. 发明申请

WO2013034642A1 CATALYTIC SYSTEM AND PROCESS FOR THE TOTAL HYDROCONVERSION OF HEAVY OILS 审中-公开
标题翻译：催化体系及重油总氢过程
公开(公告)号：WO2013034642A1
公开(公告)日：2013-03-14
申请号：PCT/EP2012/067412
申请日：2012-09-06
申请人： ENI S.P.A. , MOLINARI, Daniele , BELLUSSI, Giuseppe , LANDONI, Alberto , POLLESEL, Paolo
发明人： MOLINARI, Daniele , BELLUSSI, Giuseppe , LANDONI, Alberto , POLLESEL, Paolo
IPC分类号： B01J27/051 , B01J29/78 , C10G45/12
CPC分类号： B01J29/89 , B01J27/051 , B01J29/7876 , C10G45/12 , C10G47/16 , C10G65/12
摘要： A catalytic system characterized in that it comprises: a first catalyst, having a hydrogenating function, consisting of solid particles of which at least 95% by volume having an equivalent diameter smaller than 20 μm, containing one or more sulfides of metals of group VI and/or VIII B, possibly prepared starting from an oil- soluble precursor of the same; and a second catalyst, having a cracking function, consisting of solid particles of which at least 90% by volume having an equivalent diameter larger than 5 μm and smaller than 5 mm, containing an amorphous silico- aluminate and/or a crystalline silico-aluminate and/or an alumina, the equivalent average diameter of the solid particles of the second catalyst being greater than the equivalent average diameter of the solid particles of the first catalyst. Said catalytic system can be used in a process for the hydroconversion of heavy oils which comprises sending the heavy oil to a hydroprocessing step carried out in one or more slurry reactors, in the presence of hydrogen or a mixture of hydrogen and H 2 S, obtaining a stream of products in vapour or liquid-vapour phase, and extracting at the bottom, in continuous or discontinuous, a liquid stream containing non-converted products together with the two catalysts of said catalytic system, said liquid stream extracted then being separated into a clarified primary stream containing the first catalyst, which is at least partially recycled to the hydroprocessing step, and a stream rich in the second catalyst, which is regenerated in a regeneration step and at least partially recycled to the hydroprocessing step.
摘要翻译：一种催化体系，其特征在于它包括：具有氢化功能的第一催化剂，其由至少95体积％的当量直径小于20μm的固体颗粒组成，其含有一种或多种第VI族金属的硫化物，和 /或VIII B，可能从其油溶性前体开始制备; 和具有裂化功能的第二催化剂，其由固体颗粒组成，其中至少90体积％的当量直径大于5μm且小于5mm，其含有非晶硅铝酸盐和/或结晶硅铝酸盐和/或氧化铝，所述第二催化剂的固体颗粒的当量平均直径大于所述第一催化剂的固体颗粒的当量平均直径。所述催化体系可用于重油加氢转化的方法，其包括将重油送入在一种或多种淤浆反应器中，在氢气或氢气和H 2 S的混合物存在下进行的加氢处理步骤，获得流的蒸气或液相 - 蒸气相中的产物，并且连续或不连续地将含有未转化产物的液体物流与所述催化体系的两种催化剂一起萃取，然后将所述液体流分离成澄清的初级含有至少部分再循环到加氢处理步骤的第一催化剂的物流和富含第二催化剂的物流，其在再生步骤中再生并且至少部分地循环到加氢处理步骤。

2. 发明申请

WO2007028540A1 PROCESS FOR THE REOXIDATION, WITHOUT THE FORMATION OF NITROGEN OXIDES, OF FERROUS SOLUTIONS COMING FROM THE REMOVAL PROCESS IN CONTINUOUS OF HYDROGEN SULFIDE FROM GASEOUS STREAMS BY MEANS OF THE REDOX METHOD 审中-公开
标题翻译：在氧化还原过程中，无法形成氮氧化物，通过REDOX方法从连续流出的硫酸氢盐中除去过程中的有害溶剂
公开(公告)号：WO2007028540A1
公开(公告)日：2007-03-15
申请号：PCT/EP2006/008524
申请日：2006-08-31
申请人： ENI S.P.A. , BELLUSSI, Giuseppe , DE ANGELIS, Alberto , POLLESEL, Paolo , MILLI, Marcello
发明人： BELLUSSI, Giuseppe , DE ANGELIS, Alberto , POLLESEL, Paolo , MILLI, Marcello
IPC分类号： C10L3/10 , C01B17/05 , B01D53/14 , B01D53/52
CPC分类号： B01D53/1468 , B01D53/1418 , B01D53/1425 , B01D53/1493 , C01B17/05 , C10L3/10
摘要： Process for the reoxidation, without the formation of ni¬ trogen oxides, of ferrous solutions used in the removal process in continuous of hydrogen sulfide from gaseous streams containing them, comprising: a) putting a gas containing H∑S in contact with an oxidiz¬ ing acid aqueous solution of ferric nitrate and containing a heteropolyacid having rjedox properties; b) filtrating and separating the sulfur produced; c) reoxidizing the ferrous nitrate to ferric nitrate with air as such or enriched in oxygen at a pressure higher than atmospheric pressure; d) recycling the solution containing ferric nitrate and the heteropolyacid to the oxidation step (a); and e) discharging the air.
摘要翻译：包括：a）将含有H 2 S的气体与氧化物接触，用于在不含氧化物的情况下，再次氧化从含有它们的气流中连续除去硫化氢中的亚铁溶液，酸式硝酸铁水溶液，含有具有杂聚性质的杂多酸; b）过滤和分离产生的硫; c）将空气中的硝酸亚铁还原为硝酸铁，或在高于大气压的压力下富集氧气; d）将含有硝酸铁和杂多酸的溶液再循环到氧化步骤（a）中; 和e）排出空气。

3. 发明申请

WO2005014192A1 PROCESS FOR THE DISPOSAL OF SULFUR IN THE FORM OF COMPOUNDS LIQUID AT ROOM TEMPERATURE 审中-公开
标题翻译：化合物液体在室温下处理硫磺的方法
公开(公告)号：WO2005014192A1
公开(公告)日：2005-02-17
申请号：PCT/EP2004/007565
申请日：2004-07-06
申请人： ENI S.p.A. , ENITECNOLOGIE S.p.A. , DE ANGELIS, Alberto , POLLESEL, Paolo , BELLUSSI, Giuseppe , LOCKHART, Thomas, Paul
发明人： DE ANGELIS, Alberto , POLLESEL, Paolo , BELLUSSI, Giuseppe , LOCKHART, Thomas, Paul
IPC分类号： B09B1/00
CPC分类号： E21B41/0057 , B09B1/008 , B65G5/00
摘要： Process for the disposal of sulfur in the liquid state which comprises: a) transforming elemental sulfur into sulfanes having the general formula H 2 S n+1 , wherein n is a number from 1 to 7; b) optionally mixing elemental sulfur in powder form with the liquid sulfanes, up to such a concentration as to guarantee the pumpability of the mixture; c) injecting the sulfanes liquid at room temperature into geological formations having a temperature lower than 150°C.
摘要翻译：用于处理液态硫的方法，其包括：a）将元素硫转化为具有通式H 2 Sn + 1的硫烷，其中n为1至7的数; b）任选地将粉末形式的元素硫与液体硫烷混合，直至其浓度保证混合物的可泵送性; c）将室温下的硫烷液体注入温度低于150℃的地质构造中。

4. 发明申请

WO2010102653A1 PROCESS FOR THE ABATEMENT OF HYDROGEN SULPHIDE FROM COMPOSITIONS CONTAINING IT WITH SIMULTANEOUS PRODUCTION OF HYDROGEN 审中-公开
标题翻译：从含有同时生成氢的组合物中脱硫的方法
公开(公告)号：WO2010102653A1
公开(公告)日：2010-09-16
申请号：PCT/EP2009/001918
申请日：2009-03-13
申请人： ENI S.p.A. , BELLUSSI, Giuseppe , DE ANGELIS, Alberto , POLLESEL, Paolo , PEREGO, Carlo
发明人： BELLUSSI, Giuseppe , DE ANGELIS, Alberto , POLLESEL, Paolo , PEREGO, Carlo
IPC分类号： C01B3/38 , C01B17/50 , C01B31/26
CPC分类号： C01B3/38 , C01B17/508 , C01B32/72 , C01B2203/0227 , C01B2203/0405 , C01B2203/0415 , C01B2203/043 , C01B2203/0455 , C01B2203/0485 , C01B2203/06 , C01B2203/0811 , C01B2203/0894 , C01B2203/1041 , C01B2203/1047 , C01B2203/1241 , C01B2203/1258
摘要： Process for the abatement of hydrogen sulphide from compositions containing it with the contemporaneous production of hydrogen, comprising: a. treating hydrogen sulphide with methane (reforming) according to the endothermic reaction: 2 H 2 S + CH 4 = CS 2 + 4H 2 (1) b. cooling the reaction products and separating the carbon disulphide (CS 2 ); c. burning the carbon disulphide; d. feeding at least an aliquot of the hot gases from the combustion of carbon disulphide to the reforming step, as a heat source for maintaining the endothermic reaction (1). e. disposing of the cooled gases from the combustion of carbon disulphide.
摘要翻译：包括：a。同时生产氢气从含有它的组合物中减少硫化氢的方法。根据吸热反应用甲烷（重整）处理硫化氢：H2S + CH4 = CS2 + 4H2（1）b。冷却反应产物并分离二硫化碳（CS2）; C。燃烧二硫化碳; 天。将来自二硫化碳燃烧的热气体的至少一部分进料至重整步骤，作为用于保持吸热反应的热源（1）。即处理来自二硫化碳燃烧的冷却气体。

5. 发明申请

WO2010041113A1 PROCESS FOR THE DIRECT OXIDATION OF METHANE TO METHANOL BY MEANS OF NON-THERMAL PLASMA IN A REACTOR WITH THE GLIDING ARC IN TORNADO (GAT) TECHNOLOGY 审中-公开
标题翻译：通过TORNADO（GAT）技术在玻璃反应器中的非热等离子体将甲烷直接氧化成甲醇的方法
公开(公告)号：WO2010041113A1
公开(公告)日：2010-04-15
申请号：PCT/IB2009/007019
申请日：2009-09-25
申请人： ENI S.P.A. , BELLUSSI, Giuseppe , DE ANGELIS, Alberto , POLLESEL, Paolo
发明人： BELLUSSI, Giuseppe , DE ANGELIS, Alberto , POLLESEL, Paolo
IPC分类号： B01J19/08 , C07C29/50 , C07C31/04
CPC分类号： B01J19/2415 , B01J19/088 , B01J19/1812 , B01J2219/0809 , B01J2219/0815 , B01J2219/082 , B01J2219/083 , B01J2219/0832 , B01J2219/0841 , B01J2219/0869 , B01J2219/0883 , B01J2219/0894 , C07C29/50 , C07C31/04
摘要： The present invention relates to a process for the direct oxidation of methane to methanol in which the reaction is carried out in a gliding arc in tornado (GAT) reactor with the non-thermal plasma, also known as cold plasma, technology. Said process comprises the following phases: injecting into said GAT reactor in a tangential direction, alternatively one of the following gaseous mixtures comprising methane and pure oxygen, or methane and air, or methane and enriched air, injecting steam into said GAT reactor, generating non- thermal plasma by means of two electrodes positioned inside the GAT reactor, collecting the methanol produced, condensing it and separating it. The internal walls of the GAT reactor act as anode and an electrode is inserted in its interior which acts as cathode in spiral form coaxial to the reactor.
摘要翻译：本发明涉及一种将甲烷直接氧化成甲醇的方法，其中反应在具有非热等离子体（也称为冷等离子体）技术的龙卷风（GAT）反应器中的滑动弧中进行。所述方法包括以下阶段：沿切向方向注入所述GAT反应器，或者选择性地包括甲烷和纯氧，或甲烷和空气或甲烷和富集空气的下列气体混合物之一，将蒸汽注入所述GAT反应器中， - 通过位于GAT反应器内部的两个电极的热等离子体，收集产生的甲醇，冷凝并分离。 GAT反应器的内壁充当阳极，电极插入其内部，其作为与反应器同轴的螺旋形式的阴极。

6. 发明申请

WO2007028539A1 PROCESS FOR THE REMOVAL IN CONTINUOUS OF HYDROGEN SULFIDE FROM GASEOUS STREAMS 审中-公开
标题翻译：从气体条件下连续除去硫化氢的方法
公开(公告)号：WO2007028539A1
公开(公告)日：2007-03-15
申请号：PCT/EP2006/008523
申请日：2006-08-31
申请人： ENI S.P.A. , BELLUSSI, Giuseppe , DE ANGELIS, Alberto , POLLESEL, Paolo , MILLI, Marcello
发明人： BELLUSSI, Giuseppe , DE ANGELIS, Alberto , POLLESEL, Paolo , MILLI, Marcello
IPC分类号： C10L3/10 , C01B17/05 , B01D53/52 , B01D53/14
CPC分类号： B01D53/14 , B01D53/1418 , B01D53/1425 , B01D53/1468 , B01D53/1493 , C01B17/05 , C10L3/10
摘要： Process for the removal in continuous of hydrogen sulfide from gaseous streams containing it, comprising: a) putting a gas containing H 2 S in contact with an oxidizing acid aqueous solution of ferric nitrate and containing a heteropolyacid having redox properties; b) filtrating and separating the sulfur produced by the redox reaction; c) oxidizing the ferrous nitrate to ferric nitrate with air; d) recycling the solution containing ferric nitrate and heteropolyacid to the oxidation step (a) ; e) subjecting the gaseous stream leaving the oxidation reactor (c) to washing with the reduced solution; and f) discharging the gaseous stream.
摘要翻译：用于从含有它的气流中连续除去硫化氢的方法，包括：a）将含有H 2 S的气体与硝酸铁的氧化酸性水溶液接触并含有具有氧化还原的杂多酸性能; b）过滤和分离由氧化还原反应产生的硫; c）用空气将硝酸亚铁氧化成硝酸铁; d）将含有硝酸铁和杂多酸的溶液循环到氧化步骤（a）中; e）使离开氧化反应器（c）的气流经还原溶液洗涤; 和f）排出气流。

7. 发明申请

WO2005075351A2 PROCESS FOR THE REMOVAL OF HYDROGEN SULFIDE, BY MEANS OF ITS OXIDATION IN THE PRESENCE OF HETERO POLYACIDS 审中-公开
标题翻译：通过在异戊二烯存在下氧化还原硫化氢的方法
公开(公告)号：WO2005075351A2
公开(公告)日：2005-08-18
申请号：PCT/EP2005/000669
申请日：2005-01-20
申请人： ENI S.P.A. , ENITECNOLOGIE, S.P.A. , DE ANGELIS, Alberto , BELLUSSI, Giuseppe , POLLESEL, Paolo , ROMANO, Ugo , PEREGO, Carlo
发明人： DE ANGELIS, Alberto , BELLUSSI, Giuseppe , POLLESEL, Paolo , ROMANO, Ugo , PEREGO, Carlo
IPC分类号： C01B17/05
CPC分类号： B01D53/52 , B01D2257/304 , C01B17/05
摘要： Hydrogen sulfide is oxidized to sulfur by means of treatment with an aqueous acid solution containing trivalent iron and a hetero polyacid having formula (I): H n X V y M (12-y) O 40 ; or a sole hetero polyacid having formula (II): H n Me M 12 O 40 ; wherein the symbols X, M Me n and y are specified in the text. At the end of the oxidation, the solution is treated with gas containing oxygen to re-oxidize the reduced metal.
摘要翻译：通过用含有三价铁的含水酸溶液和式（I）的杂多酸处理将硫化氢氧化成硫：Hn X Vy M（12-y）O40; 或具有式（II）的单独的多元酸：Hn Me M12 O40; 其中符号X，M Me n和y在文中指定。在氧化结束时，用含氧的气体处理溶液以再还原还原的金属。

8. 发明申请

WO2004056943A1 PROCESS AND REACTOR FOR THE PRODUCTION OF OLEFINS BY THE STEAM CRACKING REACTION OF LIQUID HYDROCARBON FEEDS IN THE PRESENCE OF A CATALYST 审中-公开
标题翻译：通过催化剂存在下液体碳源的蒸汽破碎反应生产烯烃的方法和反应器
公开(公告)号：WO2004056943A1
公开(公告)日：2004-07-08
申请号：PCT/EP2003/014780
申请日：2003-12-11
申请人： POLIMERI EUROPA S.P.A. , ENITECNOLOGIE S.P.A. , ROMAGNOLI, Massimo , POLLESEL, Paolo , RIZZO, Caterina , BELLUSSI, Giuseppe , PEREGO, Carlo , CLERICI, Gabriele, Carlo, Ettore , GALIMBERTI, Francesca
发明人： ROMAGNOLI, Massimo , POLLESEL, Paolo , RIZZO, Caterina , BELLUSSI, Giuseppe , PEREGO, Carlo , CLERICI, Gabriele, Carlo, Ettore , GALIMBERTI, Francesca
IPC分类号： C10G11/00
CPC分类号： C10G9/14 , C10G11/00 , C10G11/10
摘要： A process for the production of light olefins by means of the steam cracking reaction of liquid hydrocarbon feeds, preferably selected from naphtha, kerosene, atmospheric gas oil, vacuum gas oil and oil residues, alone or mixed with each other, in the presence of a suitable catalyst, effected at a reaction temperature ranging from 700 to 850 °C, at a pressure ranging from 1.1 to 4.5 absolute Atm and for a contact time ranging from 0.02 to 0.3 sec, preferably from 0.05 to 0.15 sec, in a reactor comprising one or more cylindrical pipes, with the same or different section, consisting of a tubular core and a reaction zone whose transversal section is in the form of a circular crown, the ratio between the area of said circular crown and the circular section ranging from 0.35 to 0.99, preferably from 0.75 to 0.95.
摘要翻译：通过液体烃进料的蒸汽裂解反应生产轻质烯烃的方法，该方法优选选自石脑油，煤油，常压瓦斯油，减压瓦斯油和油残余物，单独或彼此混合，在合适的催化剂，在反应温度为700至850℃，压力范围为1.1至4.5，绝对的大气压下进行，接触时间为0.02至0.3秒，优选为0.05至0.15秒，或更多的具有相同或不同截面的圆柱形管，其由管状芯和横截面为圆形冠的形式的反应区组成，所述圆形冠部的面积与圆形截面之间的比率范围为0.35至 0.99，优选0.75至0.95。

9. 发明申请

WO2011039595A2 MIXED OXIDES OF TRANSITION METAL, HYDROTREATMENT CATALYSTS OBTAINED THEREFROM, AND PREPARATION PROCESS COMPRISING SOL -GEL PROCESSES 审中-公开
标题翻译：过渡金属的混合氧化物，其获得的加氢催化剂以及包含溶解过程的制备方法
公开(公告)号：WO2011039595A2
公开(公告)日：2011-04-07
申请号：PCT/IB2010/002392
申请日：2010-09-23
申请人： ENI S.P.A. , BELLUSSI, Giuseppe , CARATI, Angela , GAGLIARDI, Maria, Federica , ZANARDI, Stefano , MARELLA, Marcello , SCATTOLIN, Roberto , TOMASELLI, Michele
发明人： BELLUSSI, Giuseppe , CARATI, Angela , GAGLIARDI, Maria, Federica , ZANARDI, Stefano , MARELLA, Marcello , SCATTOLIN, Roberto , TOMASELLI, Michele
IPC分类号： B01J27/049 , B01J27/051 , B01J37/03 , B01J37/20 , B01J35/10
CPC分类号： B01J27/0515 , B01J23/002 , B01J23/883 , B01J23/8885 , B01J27/049 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J37/033 , B01J37/20 , B01J2523/00 , C10G45/08 , C10G2300/1044 , C10G2300/1062 , C10G2300/107 , C10G2300/1077 , C10G2300/202 , C10G2400/04 , C10G2400/06 , B01J2523/31 , B01J2523/68 , B01J2523/69 , B01J2523/845 , B01J2523/847 , B01J2523/41
摘要： New sulfided metal catalysts are described, containing a metal X selected from Ni, Co and mixtures thereof, a metal Y selected from Mo, W and mixtures thereof, an element Z selected from Si, Al and mixtures thereof, and possibly an organic residue, obtained by the sulfidation of mixed oxide precursors, also new, having general formula (A) X a Y b Z c O d . pC (A) possibly shaped without a binder, or by sulfidation of mixed oxides having formula (A), in shaped form with a binder, wherein X is selected from Ni, Co and mixtures thereof, Y is selected from Mo, W and mixtures thereof, Z is selected from Si, Al and mixtures thereof, 0 is oxygen, C is selected from: a nitrogenated compound N, an organic residue deriving from the partial calcination of the nitrogenated compound N, said nitrogenated compound N, when present, being selected from: a) an alkyl ammonium hydroxide having formula (I) R I R II R III R IV NOH ( I ) wherein the groups R I -R IV , the same or different, are aliphatic groups containing from 1 to 7 carbon atoms, b) an amine having formula (II) R 1 R 2 R 3 N (II) wherein R 1 is a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, and R 2 and R 3 , the same or different, are selected from H and a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, said alkyl being equal to or different from R 1 , a, b, c, d are the number of moles of the elements X, Y, Z, O, respectively, p is the weight percentage of C with respect to the total weight of the precursor having formula (A), a, b, c, d are higher than 0 a/b is higher than or equal to 0.3 and lower than or equal to 2, (a+b) /c is higher than or equal to 0.3 and lower than or equal to 10, preferably varying from 0.8 to 10 d = (2a+6b+Hc)/2 wherein H = 4 when Z = Si H = 3 when Z = Al and p is higher than or equal to 0 and lower than or equal to 40%. Said catalysts can be used as hydrotreating catalysts.
摘要翻译：描述了新的硫化金属催化剂，其含有选自Ni，Co及其混合物的金属X，选自Mo，W及其混合物的金属Y，选自Si，Al及其混合物的元素Z以及可能的有机残基，通过硫化混合氧化物前体获得，也是新的，具有通式（A）Xa Yb Zc Od。 pC（A）可以成形为没有粘合剂，或通过硫化具有式（A）的混合氧化物，成型为粘合剂，其中X选自Ni，Co及其混合物，Y选自Mo，W和混合物 Z选自Si，Al及其混合物，0为氧，C选自：氮化合物N，衍生自含氮化合物N的部分煅烧的有机残基，所述含氮化合物N当存在时为选自：a）具有式（I）RIRIIRIIIRIVNOH（I）的烷基氢氧化铵，其中基团RI-RIV相同或不同，是含有1至7个碳原子的脂族基团，b）具有式（II）的胺， R 1 R 2 R 3 N（II）其中R 1是含有4至12个碳原子的直链，支链或环状烷基，R 2和R 3相同或不同，选自H和直链，支链或环状的烷基，其含有4〜 12个碳原子，所述烷基等于或不同于R 1，a，b，c，d ar e分别是元素X，Y，Z，O的摩尔数，p是C相对于具有式（A）的前体的总重量的重量百分比，a，b，c，d高于（a + b）/ c高于或等于0.3且低于或等于10，优选从0.8至10d =（ 2a + 6b + Hc）/ 2，其中当Z = Al时，当Z = Si H = 3时，H = 4，p大于或等于0且小于或等于40％。所述催化剂可用作加氢处理催化剂。

10. 发明申请

WO2009149923A1 CATALYTIC SYSTEM AND PROCESS FOR THE HYDROCONVERSION OF HEAVY OIL PRODUCTS 审中-公开
标题翻译：催化体系和重油加氢工艺
公开(公告)号：WO2009149923A1
公开(公告)日：2009-12-17
申请号：PCT/EP2009/004193
申请日：2009-06-08
申请人： ENI S.P.A. , BELLUSSI, Giuseppe , RISPOLI, Giacomo , CARATI, Angela
发明人： BELLUSSI, Giuseppe , RISPOLI, Giacomo , CARATI, Angela
IPC分类号： B01J23/28 , B01J23/883 , B01J29/70 , C10G45/04
CPC分类号： C10G45/04 , B01J23/882 , B01J23/883 , B01J27/051 , B01J29/041 , B01J29/061 , B01J29/072 , B01J29/166 , B01J29/7007 , B01J29/7615 , B01J35/0006 , B01J37/20 , C10G45/08 , C10G45/12 , C10G45/46 , C10G45/50 , C10G45/54 , C10G47/20 , C10G2300/1003 , C10G2300/1011 , C10G2300/1033 , C10G2300/1074 , Y02P30/20
摘要： Catalytic system which can be used in processes for the hydroconversion of heavy oils by means of hydrotreatment in slurry phase, characterized in that it comprises: a catalyst, having the function of hydrogenating agent, containing MoS 2 or WS 2 or mixtures thereof in lamellar form or an oil-soluble precursor thereof; a co-catalyst, having nanometric or micronic particle- sizes, selected from cracking and/or denitrogenation catalysts. The co-catalyst preferably consists of zeolites having small-sized crystals and with a low aggregation degree between the primary particles, and/or oxides or sulfides or precursors of sulfides of Ni and/or Co in a mixture with Mo and/or W.
摘要翻译：催化体系，其可用于通过浆料相中的加氢处理加氢转化重油的方法，其特征在于其包含：具有包含MoS 2或WS 2的氢化剂或其混合物的层状功能的催化剂或其油溶性前体; 具有选自裂化和/或脱氮催化剂的纳米或微米粒径的助催化剂。助催化剂优选由具有小尺寸晶体并且在初级粒子之间具有低聚集度的沸石和/或与Mo和/或W的混合物中的Ni和/或Co的硫化物的硫化物或硫化物的前体组成。

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