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    • 9. 发明申请
    • LITHOGRAPHIC PRINTING PLATE PRECURSORS WITH OLIGOMERIC OR POLYMERIC SENSITIZERS
    • 具有低分子或聚合物敏感剂的平版印刷机前驱体(LITHOGRAPHIC PRINTING PLATE PRECURSORS WITH OLIGOMERIC或POLYMERIC SENSITIZERS)
    • WO2006053689A1
    • 2006-05-26
    • PCT/EP2005/012136
    • 2005-11-11
    • KODAK POLYCHROME GRAPHICS GMBHSTREHMEL, BerndBAUMANN, HaraldDWARS, UdoPIETSCH, DetlefDRABER, AxelMURSAL, Michael
    • STREHMEL, BerndBAUMANN, HaraldDWARS, UdoPIETSCH, DetlefDRABER, AxelMURSAL, Michael
    • G03F7/031G03F7/029
    • G03F7/029G03F7/031Y10S430/116Y10S430/117Y10S430/121Y10S430/123Y10S430/127Y10S522/904Y10S522/913
    • Lithographic printing plate precursor comprising (a) a lithographic substrate with a hydrophilic surface and (b) a radiation-sensitive coating on the hydrophilic surface comprising (i) one or more types of monomers and/or oligomers and/or polymers, each comprising at least one ethylenically unsaturated group accessible to a freeradical polymerization, (ii) at least one sensitizer, and at least one coinitiator capable of forming free radicals together with the sensitizer (ii); characterized in that the at least one sensitizer is an oligomeric or polymeric compound comprising the following structural unit (Formula (I)), wherein π 1 is an aromatic or heteroaromatic unit or a combination of the two so that a conjugated n-system is present between the two groups Z in structure (I), each Z independently represents a heteroatom, each R 1 and R 2 is independently selected from a halogen atom, an alkyl, aryl, alkylaryl or aralkyl group, a group -NR 3 R 4 and a group -OR 5 , each R 3 , R 4 and R 5 is independently selected from an alkyl, aryl, alkylaryl and aralkyl group, a and b independently represent 0 or an integer from 1 to 4, n has a value of >1 and AS is an aliphatic spacer.
    • 该平版印刷版前体包括(a)具有亲水表面的平版印刷基材和(b)亲水表面上的辐射敏感涂层,其包含(i)一种或多种类型的单体和/或低聚物和/或聚合物, 至少一种可自由聚合的烯属不饱和基团,(ii)至少一种敏化剂,和至少一种能够与敏化剂(ii)一起形成自由基的共引发剂; 其特征在于,所述至少一种敏化剂是包含以下结构单元(式(I))的低聚或聚合化合物,其中p 1是芳族或杂芳族单元或两者的组合,使得 在结构(I)中的两个基团Z之间存在共轭n系,每个Z独立地表示杂原子,每个R 1和R 2独立地选自 卤素原子,烷基,芳基,烷基芳基或芳烷基,基团-NR 3 R 4和基团-OR 5,各R R 4,R 4和R 5独立地选自烷基,芳基,烷基芳基和芳烷基,a和b独立地表示0或 1〜4的整数,n的值为1,AS为脂肪族间隔物。
    • 10. 发明申请
    • RADIATION-SENSITIVE COMPOSITIONS AND IMAGEABLE ELEMENTS BASED THEREON
    • 基于此的辐射敏感组合物和可成像元素
    • WO2005054952A1
    • 2005-06-16
    • PCT/EP2004/013138
    • 2004-11-18
    • KODAK POLYCHROME GRAPHICS GMBHBAUMANN, HaraldDWARS, UdoFLUGEL, Michael
    • BAUMANN, HaraldDWARS, UdoFLUGEL, Michael
    • G03F7/031
    • G03F7/031Y10T428/31591
    • Radiation-sensitive composition comprising (a) at least one photopolymerizable compound with at least one ethylenically unsaturated group accessible to a free-radical polymerization, wherein the at least one photopolymerizable compound has a molecular weight of 3,000 or less and can be obtained by reacting a diisocyanate with (I) an ethylenically unsaturated compound with a hydroxy group, and at the same time (ii) a saturated organic compound with an NH group and an OH group, wherein the reactants are used in amounts according to the following condition: Number of moles of isocyanate groups ≤ number of moles of OH plus NH groups; (b) at least one sensitizer which absorbs radiation from the wavelength range of 250 to 450 nm of the electromagnetic spectrum and is selected from: dihydropyridines of formula (I) and oxazole derivatives of formula (II): (II) (c) at least one coinitiator capable of forming free radicals together with the sensitizer (b) and selected from 2,2’, 4,4’, 5’5-hexaarylbiimidazoles, compounds with at least one photolytically cleavable trihalogenmethyl group, diaryliodonium salts, triarylsulfonium salts and N-heterocyclic compounds with at least one nitrogen atom in the ring, having an oxy substituent at least one ring nitrogen atom, and mixtures of the above compounds; and (d) optionally one or more components selected from alkali-soluble binders, colorants, exposure indicators, plasticizers, chain transfer agents, leuco dyes, surfactants, inorganic fillers and thermopolymerization inhibitors; with the proviso that the radiation-sensitive composition does not comprise a metallocene.
    • 辐射敏感性组合物,其包含(a)至少一种可光聚合化合物与至少一种可自由基聚合的烯键式不饱和基团,其中所述至少一种可光聚合化合物的分子量为3,000以下,可以通过使 二异氰酸酯与(I)具有羟基的烯属不饱和化合物,同时(ii)具有NH基和OH基的饱和有机化合物,其中反应物的用量按照以下条件使用: 异氰酸酯基团的摩尔数= OH加NH基团的摩尔数; (b)至少一种吸收来自电磁波谱的波长范围为250至450nm的辐射的敏化剂,并选自:式(I)的二氢吡啶和式(II)的恶唑衍生物:(II)(c) 能够与敏化剂(b)一起形成自由基的至少一种共引发剂,并选自2,2',4,4',5,5'-六芳基联咪唑,具有至少一个可光解裂解的三卤代甲基的化合物,二芳基碘鎓盐,三芳基锍盐 和环中具有至少一个氮原子的N-杂环化合物,至少一个环氮原子具有氧取代基,以及上述化合物的混合物; 和(d)任选的一种或多种选自碱溶性粘合剂,着色剂,曝光指示剂,增塑剂,链转移剂,无色染料,表面活性剂,无机填料和热聚合抑制剂的组分; 条件是辐射敏感组合物不包含金属茂。