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1. 发明申请

WO2012094634A3 FUNCTIONALIZED CARBON MEMBRANES 审中-公开
标题翻译：功能性碳膜
公开(公告)号：WO2012094634A3
公开(公告)日：2012-11-01
申请号：PCT/US2012020545
申请日：2012-01-06
申请人： DUNE SCIENCES INC , MILLER JOHN M , TESHIMA JANET , HUTCHISON JAMES E
发明人： MILLER JOHN M , TESHIMA JANET , HUTCHISON JAMES E
IPC分类号： G01N1/28 , B82B1/00 , H01J37/26
CPC分类号： B05D1/185 , B05D3/044 , G01N1/2813 , H01J37/20 , H01J37/26
摘要： Embodiments provide electron-conducting, electron-transparent substrates that are chemically derivatized (e.g., functional ized) to enhance and facilitate the deposition of nanoscale materials thereupon, including both hard and soft nanoscale materials. In various embodiments, the substrates may include an electron- conducting mesh support, for example, a carbon, copper, nickel, molybdenum, beryllium, gold, silicon, GaAs, or oxide (e.g., SiO2, TiO2, ITO, or AI2O3) support, or a combination thereof, having one or more apertures. In various embodiments, the mesh support may be coated with an electron conducting, electron transparent carbon film membrane that has been chemically derivatized to promote adhesion and/or affinity for various materials, including hard inorganic materials and soft materials, such as polymers and biological molecules.
摘要翻译：实施例提供了化学衍生化（例如功能化）的电子传导的电子透明基底，以增强和促进纳米尺度材料的沉积，包括硬和软纳米尺度材料。在各种实施例中，基底可以包括电子传导网支撑体，例如碳，铜，镍，钼，铍，金，硅，GaAs或氧化物（例如，SiO 2，TiO 2，ITO或Al 2 O 3）载体，或其组合，具有一个或多个孔。在各种实施例中，网状支撑体可以涂覆有电子传导的电子透明碳膜膜，其被化学衍生化以促进对各种材料的粘合和/或亲和力，包括硬无机材料和软材料，例如聚合物和生物分子。

2. 发明申请

WO2010057114A3 FUNCTIONALIZED NANOPARTICLES AND METHODS OF FORMING AND USING SAME 审中-公开
标题翻译：功能化的纳米颗粒及其形成和使用方法
公开(公告)号：WO2010057114A3
公开(公告)日：2010-08-19
申请号：PCT/US2009064623
申请日：2009-11-16
申请人： DUNE SCIENCES INC , MILLER JOHN M , HUTCHISON JAMES E , SWEENEY SCOTT F
发明人： MILLER JOHN M , HUTCHISON JAMES E , SWEENEY SCOTT F
IPC分类号： D06M11/83 , D06M11/42 , D06M11/46 , D06M11/58 , D06M13/244 , D06M14/04
CPC分类号： D06M23/08 , D06M11/42 , D06M11/44 , D06M11/45 , D06M11/46 , D06M11/47 , D06M11/48 , D06M11/485 , D06M11/49 , D06M11/83 , Y10T442/2475 , Y10T442/2525 , Y10T442/2762 , Y10T442/277
摘要： Embodiments herein provide a nanoparticle, such as a metal nanoparticle, coupled to a linker molecule to form a nanoparticle-linker construct. In an embodiment, a nanoparticle-linker construct may be further bound to a substrate to take advantage of one or more properties of the nanoparticle. In an embodiment, a functionalized nanoparticle (a nanoparticle having a reactive functionality) may be bound to a linker to form a functionalized nanoparticle-linker construct which may in-turn be bound to a substrate.
摘要翻译：本文的实施方案提供了与连接分子偶联以形成纳米颗粒 - 连接体构建体的纳米颗粒，例如金属纳米颗粒。在一个实施方案中，纳米颗粒 - 接头构建体可以进一步与底物结合以利用纳米颗粒的一种或多种性质。在一个实施方案中，功能化纳米颗粒（具有反应性官能团的纳米颗粒）可以结合到接头以形成官能化的纳米颗粒 - 连接体构建体，其可以依次结合到底物上。

3. 发明申请

WO2006127675A2 NANOPARTICLES AND METHOD TO CONTROL NANOPARTICLE SPACING 审中-公开
标题翻译：纳米颗粒和控制纳米颗粒间隔的方法
公开(公告)号：WO2006127675A2
公开(公告)日：2006-11-30
申请号：PCT/US2006019861
申请日：2006-05-22
申请人： STATE OF OREGON ACTING BY & TH , HUTCHISON JAMES E , WOEHRLE GERD H , WARNER MARVIN G , BROWN LEIF O
发明人： HUTCHISON JAMES E , WOEHRLE GERD H , WARNER MARVIN G , BROWN LEIF O
IPC分类号： G06K9/40
CPC分类号： C07H21/00 , B22F1/0081 , B22F2998/00 , B82Y10/00 , B22F1/0018
摘要： Disclosed herein are novel nanoparticles, particularly metal nanoparticles, such as gold nanoparticles. According to one embodiment of a method disclosed herein nanoparticles are functionalized via ligand exchange reactions. Also disclosed is a method for controlling nanoparticle spacing to produce nanoparticle arrays having defined spacing. Such nanoparticles and arrays thereof are particularly useful in nanoelectronics, nanophotonics, catalysis, sensors, and biotaggents.
摘要翻译：本文公开了新型纳米颗粒，特别是金纳米颗粒，例如金纳米颗粒。根据本文公开的方法的一个实施方案，纳米颗粒通过配体交换反应进行官能化。还公开了一种用于控制纳米颗粒间距以产生具有限定间隔的纳米颗粒阵列的方法。这种纳米颗粒及其阵列在纳米电子学，纳米光子学，催化，传感器和生物分子中特别有用。

4. 发明申请

WO2006127736A2 SILICON SUBSTRATES WITH THERMAL OXIDE WINDOWS FOR TRANSMISSION ELECTRON MICROSCOPY 审中-公开
标题翻译：带传感电子显微镜的氧化硅窗的硅基板
公开(公告)号：WO2006127736A2
公开(公告)日：2006-11-30
申请号：PCT/US2006019971
申请日：2006-05-23
申请人： OREGON STATE , HUTCHISON JAMES E , KEARNS GREGORY J
发明人： HUTCHISON JAMES E , KEARNS GREGORY J
IPC分类号： G06K9/00
CPC分类号： H01J37/20 , Y10T428/24331
摘要： Silicon grids with electron-transparent SiO 2 windows for use as substrates for high-resolution transmission electron microscopy of chemically-modified SiO 2 surfaces are fabricated by forming an oxide layer on a silicon substrate. An aperture is defined in the silicon substrate by etching the substrate to the oxide layer. A single substrate can include a plurality of apertures that are in respective frame regions that are defined by one or more channels in the substrate. Tabs are provided to secure the frame regions to the substrate, and the tabs are readily broken to obtain a particular frame region. Conductive or other features can be defined on the oxide layers prior to separation of the frame regions from the substrate.
摘要翻译：具有电子透明SiO 2窗的硅栅，用作化学改性SiO 2表面的高分辨率透射电子显微镜的基板，通过在硅衬底。通过将衬底蚀刻到氧化物层，在硅衬底中限定孔。单个基板可以包括在由基板中的一个或多个通道限定的相应框架区域中的多个孔。提供凸片以将框架区域固定到基板，并且突片容易断裂以获得特定的框架区域。在将框架区域与衬底分离之前，可以在氧化物层上限定导电或其它特征。

5. 发明申请

WO2009035727A3 TEM GRIDS FOR DETERMINATION OF STRUCTURE-PROPERTY RELATIONSHIPS IN NANOTECHNOLOGY 审中-公开
标题翻译：用于确定纳米技术结构与性质关系的TEM网格
公开(公告)号：WO2009035727A3
公开(公告)日：2009-04-30
申请号：PCT/US2008064152
申请日：2008-05-19
申请人： OREGON STATE , HUTCHISON JAMES E , KEARNS GREGORY J
发明人： HUTCHISON JAMES E , KEARNS GREGORY J
IPC分类号： H01L21/44
CPC分类号： H01J37/20 , G01N1/32 , H01J37/26 , H01J2237/2826 , Y10S977/954 , Y10T428/24331
摘要： Silicon grids with electron-transparent SiO2 windows for use as substrates for high-resolution transmission electron microscopy of chemically-modified SiO2 surfaces are fabricated by forming an oxide layer on a silicon substrate. An aperture is defined in the silicon substrate by etching the substrate to the oxide layer. A single substrate can include a plurality of apertures that are in respective frame regions that are defined by one or more channels in the substrate. Structural or chemical functionalizations can be provided, and surface interactions observed via TEM.
摘要翻译：通过在硅衬底上形成氧化层来制造具有电子透明SiO 2窗口的硅栅，用作化学改性SiO 2表面的高分辨率透射电子显微镜的衬底。通过将衬底蚀刻到氧化物层，在硅衬底中限定孔。单个基板可以包括在由基板中的一个或多个通道限定的相应框架区域中的多个孔。可以提供结构或化学官能化，通过TEM观察表面相互作用。

6. 发明申请

WO2006124769A2 METHOD FOR FUNCTIONALIZING SURFACES 审中-公开
标题翻译：功能化表面的方法
公开(公告)号：WO2006124769A2
公开(公告)日：2006-11-23
申请号：PCT/US2006018716
申请日：2006-05-12
申请人： OREGON STATE , HUTCHISON JAMES E , INMAN CHRISTINA E , KEARNS GREGORY J , GOTO SHUJI , FOSTER EVAN W
发明人： HUTCHISON JAMES E , INMAN CHRISTINA E , KEARNS GREGORY J , GOTO SHUJI , FOSTER EVAN W
IPC分类号： H01L29/739
CPC分类号： C23C28/00 , B82Y10/00 , C23C8/80 , C23C28/322 , C23C28/34 , C23C28/345 , H01L21/288 , H01L21/76838 , H01L29/66439 , Y10T428/25 , Y10T428/256 , Y10T428/31678
摘要： Disclosed is a method for the chemical modification of surfaces to form patterned nanoparticle arrays on the surfaces. Methods of producing arrays in predetermined patterns and electronic devices that incorporate such patterned arrays are also described.
摘要翻译：公开了一种用于化学改性表面以在表面上形成图案化纳米颗粒阵列的方法。还描述了以预定图案制造阵列的方法和结合了这种图案化阵列的电子装置。

7. 发明申请

WO2009035727A9 TEM GRIDS FOR DETERMINATION OF STRUCTURE-PROPERTY RELATIONSHIPS IN NANOTECHNOLOGY 审中-公开
标题翻译： TEM技术用于测定纳米技术中的结构 - 性能关系
公开(公告)号：WO2009035727A9
公开(公告)日：2009-06-25
申请号：PCT/US2008064152
申请日：2008-05-19
申请人： OREGON STATE , HUTCHISON JAMES E , KEARNS GREGORY J
发明人： HUTCHISON JAMES E , KEARNS GREGORY J
IPC分类号： H01L21/44
CPC分类号： H01J37/20 , G01N1/32 , H01J37/26 , H01J2237/2826 , Y10S977/954 , Y10T428/24331
摘要： Silicon grids with electron-transparent SiO2 windows for use as substrates for high-resolution transmission electron microscopy of chemically-modified SiO2 surfaces are fabricated by forming an oxide layer on a silicon substrate. An aperture is defined in the silicon substrate by etching the substrate to the oxide layer. A single substrate can include a plurality of apertures that are in respective frame regions that are defined by one or more channels in the substrate. Structural or chemical functionalizations can be provided, and surface interactions observed via TEM.
摘要翻译：通过在硅衬底上形成氧化层来制造具有电子透明SiO 2窗口的硅栅格用作化学改性SiO 2表面的高分辨率透射电子显微镜的衬底。通过将衬底蚀刻到氧化物层来在硅衬底中限定孔。单个衬底可以包括多个孔，这些孔位于由衬底中的一个或多个通道限定的相应框架区域中。可以提供结构或化学功能化，并通过TEM观察表面相互作用。

8. 发明申请

WO2008054338A3 NEW COMPOSITIONS OF AU-11 NANOPARTICLES AND THEIR OPTICAL PROPERTIES 审中-公开
标题翻译： AU-11纳米粒子的新组成及其光学性能
公开(公告)号：WO2008054338A3
公开(公告)日：2008-11-27
申请号：PCT/US2006019859
申请日：2006-05-22
申请人： OREGON STATE , HUTCHISON JAMES E , WOEHRLE GERD H
发明人： HUTCHISON JAMES E , WOEHRLE GERD H
IPC分类号： B82B1/00 , C01B17/00 , C22C5/02
CPC分类号： B22F1/0018 , B22F1/0059 , C22C5/02 , Y10S977/83
摘要： As demonstrated herein, the ligand exchange chemistry of phosphine- stabilized Au11 clusters with ?-functionalized thiols is a powerful synthetic method that provides convenient access to a diverse family of functionalized Au11 clusters. The general nature of the presented ligand exchange approach, in combination with the ease preparation, makes this approach of broad utility. The approach is general and shows the high tolerance for a wide variety of functional groups. Mechanistic studies provided conclusive evidence that the Aup core of the precursor particle remains intact during ligand exchange and showed that the ligand exchange of these particles follows a different pathway than for ligand exchanges of larger gold nanoparticles such as "Au1Oi(PPh3)2iCl5". Optical studies of the products show a strong dependence on the nature of the stabilizing thiol ligands.
摘要翻译：如本文所证明的，膦稳定化的Au11簇与β-官能化硫醇的配体交换化学是一种功能强大的合成方法，其提供了对功能化的Au11簇的多种家族的方便访问。所提出的配体交换方法的一般性质，与易于制备相结合，使得这种广泛用途的方法。该方法是一般性的，并且显示出对各种功能组的高度容忍度。机理研究提供了确切的证据，表明前体颗粒的Aup核心在配体交换期间保持完整，并且表明这些颗粒的配体交换遵循与比较大的金纳米颗粒如“Au 101（PPh 3）2iCl 5”的配体交换不同的途径。产物的光学研究显示强烈依赖于稳定巯基配体的性质。

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