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1. 发明申请

WO2009026209A2 TOTAL ORGANIC CARBON (TOC) REDUCTION IN BRINE VIA CHLORINOLYSIS 审中-公开
标题翻译：通过氯化裂解降解盐水中的总有机碳（TOC）
公开(公告)号：WO2009026209A2
公开(公告)日：2009-02-26
申请号：PCT/US2008/073446
申请日：2008-08-18
申请人： DOW GLOBAL TECHNOLOGIES INC. , CHAUDHARY, Sunil, K. , HOOK, Bruce , CHRISTENSON, Chris , CHAUVEL, Jean , WEST, David , GLUCK, Steve , LUME PEREIRA, Celio , LENGYEL, Istvan , KOESTER, Frank
发明人： CHAUDHARY, Sunil, K. , HOOK, Bruce , CHRISTENSON, Chris , CHAUVEL, Jean , WEST, David , GLUCK, Steve , LUME PEREIRA, Celio , LENGYEL, Istvan , KOESTER, Frank
IPC分类号： C01D3/14 , C01B11/06
CPC分类号： C01D3/14 , C01B11/062 , C01D3/16
摘要： A plurality of stages is employed to reduce the total organic carbon (TOC) content of a brine by-product stream to produce a recyclable brine stream having a TOC content of less than about 10 ppm. In a first stage treatment, a brine by-product stream may be subjected to chlorinolysis at a temperature of less than about 125 0C to obtain a chlorinolysis product having a TOC content of less than about 100 ppm, which may be treated in a second stage with activated carbon to obtain a TOC content of less than about 10 ppm. The chlorinolysis may be a reaction with sodium hypochlorite, which may be produced in situ by treatment of the brine by-product stream with chlorine gas and sodium hydroxide. The brine by-product stream may contain a high amount of difficult to remove glycerin, such as a brine by-product stream from the production of epichlorohydrin from glycerin.
摘要翻译：采用多个阶段来减少盐水副产物流的总有机碳（TOC）含量，以产生TOC含量小于约10ppm的可再循环的盐水流。在第一阶段处理中，盐水副产物流可以在低于约125℃的温度下进行氯解，以获得TOC含量小于约100ppm的氯解产物，其可以在第二阶段与活性炭混合以获得小于约10ppm的TOC含量。氯解可以是与次氯酸钠的反应，次氯酸钠可以通过用氯气和氢氧化钠处理盐水副产物流原位产生。盐水副产物流可能含有大量难以除去的甘油，例如来自甘油生产表氯醇的盐水副产物流。

2. 发明申请

WO2009026208A2 BRINE PURIFICATION 审中-公开
标题翻译：净水
公开(公告)号：WO2009026208A2
公开(公告)日：2009-02-26
申请号：PCT/US2008/073444
申请日：2008-08-18
申请人： DOW GLOBAL TECHNOLOGIES INC. , HOOK, Bruce , TIRTOWIDJOJO, Dan , KOESTER, Frank , CHAUDHARY, Sunil , MEHTA, Anil , CHAUVEL, Jean , CHRISTENSON, Chris , FRANK, Timothy , LUME PEREIRA, Celio , GLUCK, Steve , LORD, Glenn , WEST, David , LUNDSTROEM, Christine , HORN, Annett , LENGYEL, Istvan
发明人： HOOK, Bruce , TIRTOWIDJOJO, Dan , KOESTER, Frank , CHAUDHARY, Sunil , MEHTA, Anil , CHAUVEL, Jean , CHRISTENSON, Chris , FRANK, Timothy , LUME PEREIRA, Celio , GLUCK, Steve , LORD, Glenn , WEST, David , LUNDSTROEM, Christine , HORN, Annett , LENGYEL, Istvan
IPC分类号： C01D3/14 , C02F1/461 , B01D9/00
CPC分类号： C02F9/00 , B01D9/0031 , B01D9/004 , C01D3/14 , C01D3/16 , C02F1/265 , C02F1/283 , C02F1/4674 , C02F1/72 , C02F3/02 , C02F3/34 , C02F2101/30 , C02F2209/02 , C02F2209/06 , C02F2209/20 , C25B1/46 , C25B15/08 , Y02W10/15
摘要： Processes and apparatus for reducing organic content of brine which is useful in industrial processes.
摘要翻译：用于减少工业过程中有用的盐水有机含量的方法和设备。

3. 发明申请

WO2017034949A1 A METHOD FOR PRODUCING HYDROCARBONS BY OXIDATIVE COUPLING OF METHANE WITH A HEAVY DILUENT 审中-公开
标题翻译：通过甲烷氧化偶联生产氢氧化碳的方法
公开(公告)号：WO2017034949A1
公开(公告)日：2017-03-02
申请号：PCT/US2016/047707
申请日：2016-08-19
申请人： SABIC GLOBAL TECHNOLOGIES, B.V. , SARSANI, Vidya Sagar Reddy , WEST, David , LENGYEL, Istvan
发明人： SARSANI, Vidya Sagar Reddy , WEST, David , LENGYEL, Istvan
IPC分类号： C07C2/84 , C07C11/04
CPC分类号： C07C2/84 , Y02P20/582 , C07C11/04
摘要： A method for producing C 2 hydrocarbons comprising (a) introducing a reactant mixture to a reactor comprising a catalyst, wherein the reactant mixture comprises CH 4 /O 2 and a heavy diluent, and wherein the reactant mixture is characterized by a bulk CH 4 /O 2 molar ratio; (b) allowing the reactant mixture to contact a surface of the catalyst and react via an oxidative coupling of CH 4 (OCM) reaction to form a product mixture, wherein the reactant mixture is characterized by a local CH 4 /O 2 molar ratio on the catalyst surface, wherein the local CH 4 /O 2 molar ratio is greater than the bulk CH 4 /O 2 molar ratio, wherein the product mixture comprises C 2 hydrocarbons, and wherein a selectivity to C 2 hydrocarbons is increased by at least about 1% when compared to a selectivity of an otherwise similar OCM reaction conducted in the absence of the heavy diluent; and (c) recovering the product mixture from the reactor.
摘要翻译：一种制备C 2烃的方法，包括（a）将反应混合物引入到包含催化剂的反应器中，其中反应物混合物包含CH 4 / O 2和重稀释剂，并且其中反应混合物的特征在于体积CH 4 / O 2摩尔比; （b）允许反应物混合物与催化剂的表面接触并通过CH 4（OCM）反应的氧化偶合反应以形成产物混合物，其中反应混合物的特征在于催化剂表面上的局部CH 4 / O 2摩尔比，其中所述局部CH 4 / O 2摩尔比大于本体CH 4 / O 2摩尔比，其中所述产物混合物包含C 2烃，并且其中与C 2烃的选择性相比，对C 2烃的选择性增加至少约1％否则在没有重稀释剂的情况下进行相似的OCM反应; 和（c）从反应器中回收产物混合物。

4. 发明申请

WO2016209508A1 A METHOD FOR PRODUCING HIGHER VALUE HYDROCARBONS BY ISOTHERMAL OXIDATIVE COUPLING OF METHANE 审中-公开
标题翻译：通过甲烷等温氧化偶联生产高价烃的方法
公开(公告)号：WO2016209508A1
公开(公告)日：2016-12-29
申请号：PCT/US2016/034126
申请日：2016-05-25
申请人： SABIC GLOBAL TECHNOLOGIES, B.V. , SARSANI, Vidya Sagar Reddy , WEST, David , MAMEDOV, Aghaddin , LIANG, Wugeng , LOWREY, James , LENGYEL, Istvan
发明人： SARSANI, Vidya Sagar Reddy , WEST, David , MAMEDOV, Aghaddin , LIANG, Wugeng , LOWREY, James , LENGYEL, Istvan
IPC分类号： C01B3/26 , C07C2/84 , C07C11/04
CPC分类号： C07C2/84 , C01B3/386 , C01B3/506 , C01B2203/0261 , C01B2203/046 , C01B2203/1041 , C01B2203/1082 , C07C2521/08 , C07C2523/04 , C07C2523/30 , C07C2523/34 , Y02P20/582 , C07C11/04 , C07C11/06
摘要： A method for producing olefins comprising (a) introducing to an isothermal reactor a reactant mixture comprising CH 4 and O 2 , wherein the reactor comprises a catalyst bed comprising a catalyst, wherein a catalyst bed temperature is 750-1,000°C, and wherein the reactor has a residence time of 1-100 ms; (b) wherein isothermal conditions minimize hot spots in the bed, thereby decreasing deep oxidation reactions; (c) allowing the reactant mixture to contact the catalyst and react via oxidative coupling of CH 4 reaction to form a product mixture comprising C 2+ hydrocarbons (olefins and paraffins; C 2 hydrocarbons and C 3 hydrocarbons) and synthesis gas (H 2 and CO), wherein the product mixture has an olefin/paraffin molar ratio of from 0.5:1 to 20:1, and wherein the product mixture has a H 2 /CO molar ratio of from 0.2:1 to 2.5:1; (d) recovering the product mixture from the reactor; and (e) recovering C 2 hydrocarbons and/or synthesis gas from the product mixture.
摘要翻译：一种制备烯烃的方法，包括（a）向等温反应器中引入包含CH 4和O 2的反应物混合物，其中所述反应器包括催化剂床，所述催化剂床包含催化剂床，其中催化剂床温度为750-1,000℃，并且其中所述反应器具有停留时间为1-100 ms; （b）其中等温条件使床中的热点最小化，从而减少深的氧化反应; （c）允许反应物混合物与催化剂接触并通过CH 4反应的氧化偶联反应以形成包含C 2 +烃（烯烃和链烷烃; C 2烃和C 3烃）和合成气（H 2和CO）的产物混合物，其中产物混合物的烯烃/石蜡摩尔比为0.5:1至20:1，其中产物混合物的H 2 / CO摩尔比为0.2:1至2.5:1; （d）从反应器回收产物混合物; 和（e）从产物混合物回收C 2烃和/或合成气。

5. 发明申请

WO2018026501A1 OXIDATIVE COUPLING OF METHANE PROCESS WITH ENHANCED SELECTIVITY TO C2+ HYDROCARBONS BY ADDITION OF H2O IN THE FEED 审中-公开
标题翻译：加入水中H2O促进C2 +烃选择性甲烷工艺的氧化偶联
公开(公告)号：WO2018026501A1
公开(公告)日：2018-02-08
申请号：PCT/US2017/042376
申请日：2017-07-17
申请人： SABIC GLOBAL TECHNOLOGIES, B.V. , SARSANI, Vidya Sagar Reddy , LENGYEL, Istvan , WEST, David
发明人： SARSANI, Vidya Sagar Reddy , LENGYEL, Istvan , WEST, David
IPC分类号： C07C2/84 , C07C9/06 , C07C11/04
CPC分类号： C07C2/84 , C07C11/04 , C07C2523/02 , C07C2523/10 , C07C2523/30 , C07C2523/34 , C07C9/06
摘要： A process for producing olefins comprising introducing to a reactor a reactant mixture comprising methane, oxygen, and water, wherein the reactor comprises a catalyst, and wherein water is present in the reactant mixture from 0.5 mol% to 20 mol%; allowing the reactant mixture to contact the catalyst and react via an OCM reaction to form a product mixture comprising C 2 + hydrocarbons, unreacted methane, and byproducts; wherein C 2 + hydrocarbons comprise olefins and paraffins; and wherein the process is characterized by a productivity, a C 2 + selectivity, or both that is increased when compared to a productivity, a C 2 + selectivity, or both, respectively, of an otherwise similar process conducted (i) with a reactant mixture comprising methane and oxygen and (ii) without water present in the reactant mixture from 0.5 mol% to 20 mol%; recovering the product mixture from the reactor; recovering C 2 + hydrocarbons from the product mixture; and recovering olefins from C 2 + hydrocarbons.
摘要翻译：一种生产烯烃的方法，其包括向反应器中引入包含甲烷，氧气和水的反应物混合物，其中所述反应器包含催化剂，并且其中反应物混合物中水的存在量为0.5摩尔％至 20摩尔％; 使反应物混合物接触催化剂并经由OCM反应反应以形成包含C 2 +烃，未反应的甲烷和副产物的产物混合物; 其中C≤2+烃包含烯烃和链烷烃; 并且其中所述方法的特征在于与生产力，C 2 + / 2选择性或两者相比增加的生产力，C 2 +选择性或两者，（i）与包含甲烷和氧的反应物混合物和（ii）反应物混合物中不存在0.5摩尔％至20摩尔％的水; 从反应器中回收产物混合物; 从产物混合物中回收C 2 +烃; 并从C 2 +烃中回收烯烃。

6. 发明申请

WO2016200504A1 LOW INLET TEMPERATURE FOR OXIDATIVE COUPLING OF METHANE 审中-公开
标题翻译：用于甲烷氧化偶联的低入口温度
公开(公告)号：WO2016200504A1
公开(公告)日：2016-12-15
申请号：PCT/US2016/030384
申请日：2016-05-02
申请人： SABIC GLOBAL TECHNOLOGIES B.V. , LIANG, Wugeng , SARSANI, Sagar , WEST, David , LOWREY, James , MAMEDOV, Aghaddin , LENGYEL, Istvan
发明人： LIANG, Wugeng , SARSANI, Sagar , WEST, David , LOWREY, James , MAMEDOV, Aghaddin , LENGYEL, Istvan
IPC分类号： C07C2/84 , C07C7/20 , C07C9/04 , C07C9/06 , C07C11/04 , C10L3/12 , B01J23/34 , B01J23/30 , B01J23/10 , B01J32/00
CPC分类号： C07C2/84 , B01J19/245 , B01J21/08 , B01J23/10 , B01J23/34 , B01J35/0006 , B01J35/002 , B01J37/0236 , B01J2219/00074 , B01J2219/24 , C07C2521/08 , C07C2523/04 , C07C2523/10 , C07C2523/30 , C07C2523/34 , Y02P20/52 , C07C11/04 , C07C11/06 , C07C11/08
摘要： Disclosed is a process for producing C 2 + hydrocarbons, and systems for implementing the process, that includes providing a reactant feed that includes methane and an oxygen containing gas to a first reaction zone, wherein the temperature of the reactant feed is less than 700 °C, contacting the reactant feed with a first catalyst capable of catalyzing an oxidative coupling of methane reaction (OCM) to produce a first product stream that includes C2+ hydrocarbons and heat, and contacting the first product stream with a second catalyst capable of catalyzing an OCM reaction to produce a second product stream that includes C 2 + hydrocarbons, wherein the produced heat is at least partially used to heat the first product stream prior to or during contact with the second catalyst, wherein the amount of C 2 + hydrocarbons in the second product stream is greater than the amount of C 2 + hydrocarbons in the first product stream.
摘要翻译：公开了一种生产C2 +烃的方法，以及用于实施该方法的系统，其包括向第一反应区提供包括甲烷和含氧气体的反应物进料，其中反应物进料的温度低于700℃，使反应物进料与能够催化甲烷反应（OCM）的氧化偶联的第一催化剂接触以产生包含C2 +烃和热的第一产物流，并使第一产物流与能够催化OCM反应的第二催化剂接触产生包括C2 +烃的第二产物流，其中所产生的热至少部分地用于在与第二催化剂接触之前或期间加热第一产物流，其中第二产物流中的C2 +烃的量大于第一产物流中的C2 +烃的量。

7. 发明申请

WO2018047032A3 PROCESS FOR SELECTIVE CONVERSION OF HYDROCARBONS TO C2 FRACTION AND SYNGAS COMPOSITION 审中-公开
公开(公告)号：WO2018047032A3
公开(公告)日：2018-03-15
申请号：PCT/IB2017/055120
申请日：2017-08-24
申请人： SABIC GLOBAL TECHNOLOGIES B.V. , SANKARANARAYANAN, Krishnan , GAUTAM, Pankaj S. , MAMEDOV, Aghaddin , PANNALA, Sreekanth , NAIR, Balamurali , LENGYEL, Istvan , WEST, David
发明人： SANKARANARAYANAN, Krishnan , GAUTAM, Pankaj S. , MAMEDOV, Aghaddin , PANNALA, Sreekanth , NAIR, Balamurali , LENGYEL, Istvan , WEST, David
IPC分类号： C10G5/00
摘要： Embodiments of the invention include processes for the production of C 2 hydrocarbons (C 2 H 2 and/or C 2 H 4 ) in an energy and carbon efficient process.

8. 发明申请

WO2018047032A2 PROCESS FOR SELECTIVE CONVERSION OF HYDROCARBONS TO C2 FRACTION AND SYNGAS COMPOSITION 审中-公开
标题翻译：选择性地将烃转化为C2馏分和合成气组分的方法
公开(公告)号：WO2018047032A2
公开(公告)日：2018-03-15
申请号：PCT/IB2017/055120
申请日：2017-08-24
申请人： SABIC GLOBAL TECHNOLOGIES B.V. , SANKARANARAYANAN, Krishnan , GAUTAM, Pankaj S. , MAMEDOV, Aghaddin , PANNALA, Sreekanth , NAIR, Balamurali , LENGYEL, Istvan , WEST, David
发明人： SANKARANARAYANAN, Krishnan , GAUTAM, Pankaj S. , MAMEDOV, Aghaddin , PANNALA, Sreekanth , NAIR, Balamurali , LENGYEL, Istvan , WEST, David
CPC分类号： C07C2/78 , C01B3/36 , C01B2203/025 , C01B2203/0415 , C01B2203/043 , C01B2203/046 , C01B2203/0475 , C01B2203/061 , C01B2203/062 , C01B2203/1235 , C01B2203/1241 , C07C4/04 , C07C5/08 , C07C2521/06 , C07C2523/44 , C07C11/04 , C07C11/24
摘要： Embodiments of the invention include processes for the production of C 2 hydrocarbons (C 2 H 2 and/or C 2 H 4 ) in an energy and carbon efficient process.
摘要翻译：本发明的实施方案包括用于生产C 2烃（C 2 H 2和/或C 2 H 5）的方法，在低碳和高能效的过程中。

9. 发明申请

WO2017074582A1 CATALYSTS PREPARED FROM NANOSTRUCTURES OF MNO2 AND WO3 FOR OXIDATIVE COUPLING OF METHANE 审中-公开
标题翻译：用MNO2和WO3纳米结构制备的催化剂用于甲烷氧化偶联
公开(公告)号：WO2017074582A1
公开(公告)日：2017-05-04
申请号：PCT/US2016/051623
申请日：2016-09-14
申请人： SABIC GLOBAL TECHNOLOGIES, B.V. , LIANG, Wugeng , SARSANI, Vidya Sagar Reddy , WEST, David , MAMEDOV, Aghaddin , LOWREY, James , LENGYEL, Istvan
发明人： LIANG, Wugeng , SARSANI, Vidya Sagar Reddy , WEST, David , MAMEDOV, Aghaddin , LOWREY, James , LENGYEL, Istvan
IPC分类号： B01J37/03 , B01J37/04 , B01J37/10 , B01J21/08 , B01J23/34 , B01J35/00 , B01J35/02 , C07C2/00
CPC分类号： B01J21/08 , B01J23/34 , B01J35/0013 , B01J35/023 , B01J35/026 , B01J37/033 , B01J37/04 , B01J37/10 , C07C2/84 , C07C2521/08 , C07C2523/04 , C07C2523/30 , C07C2523/34 , C10G50/00 , C07C9/06 , C07C9/10 , C07C9/14 , C07C11/02
摘要： Disclosed is a process to prepare a [MnNaW]O n /SiO 2 catalyst using manganese oxide (MnO 2 ) and tungsten oxide (WO 3 ) nanostructures. Also disclosed are methods and systems using the aforementioned catalyst having higher methane conversion and C 2 to C 4 selectivity compared to similar catalysts not prepared with MnO 2 and WO 3 nanostructures.
摘要翻译：公开了使用氧化锰（MnO 2 / sub）制备[MnNaW] O n / SiO 2催化剂的方法）和氧化钨（WO 3）纳米结构。还公开了使用上述催化剂的方法和系统，其与未用MnO 2 / sub制备的类似催化剂相比具有较高的甲烷转化率和C 2至C 4选择性 >和WO 3纳米结构。

10. 发明申请

WO2017011496A2 SILVER PROMOTED CATALYSTS FOR OXIDATIVE COUPLING OF METHANE 审中-公开
标题翻译：用于甲烷氧化偶联的银助催化剂
公开(公告)号：WO2017011496A2
公开(公告)日：2017-01-19
申请号：PCT/US2016/041990
申请日：2016-07-13
申请人： SABIC GLOBAL TECHNOLOGIES, B.V. , LIANG, Wugeng , SARSANI, Vidya Sagar Reddy , WEST, David , PEREZ, Hector , MAMEDOV, Aghaddin , LENGYEL, Istvan , LOWREY, James
发明人： LIANG, Wugeng , SARSANI, Vidya Sagar Reddy , WEST, David , PEREZ, Hector , MAMEDOV, Aghaddin , LENGYEL, Istvan , LOWREY, James
IPC分类号： B01J23/00 , B01J23/66 , B01J23/68 , B01J37/08 , B01J37/02 , B01J35/00 , C07C2/84
CPC分类号： B01J23/688 , B01J23/002 , B01J23/66 , B01J35/0013 , B01J35/006 , B01J35/023 , B01J37/0205 , B01J37/0211 , B01J37/0236 , B01J37/088 , B01J2523/00 , C07C2/84 , C07C2521/08 , C07C2523/04 , C07C2523/10 , C07C2523/30 , C07C2523/34 , C07C2523/66 , C07C2523/68 , Y02P20/582 , B01J2523/18 , B01J2523/3706 , B01J2523/3712 , B01J2523/12 , B01J2523/69 , B01J2523/72 , C07C9/06
摘要： An oxidative coupling of methane (OCM) catalyst composition comprising one or more oxides doped with Ag; wherein one or more oxides comprises a single metal oxide, mixtures of single metal oxides, a mixed metal oxide, mixtures of mixed metal oxides, or combinations thereof; and wherein one or more oxides is not La2O3 alone. A method of making an OCM catalyst composition comprising calcining one or more oxides and/or oxide precursors to form one or more calcined oxides, wherein the one or more oxides comprises a single metal oxide, mixtures of single metal oxides, a mixed metal oxide, mixtures of mixed metal oxides, or combinations thereof, wherein the one or more oxides is not La2O3 alone, and wherein the oxide precursors comprise oxides, nitrates, carbonates, hydroxides, or combinations thereof; doping the one or more calcined oxides with Ag to form the OCM catalyst composition; and thermally treating the OCM catalyst composition.
摘要翻译：包含一种或多种掺杂有Ag的氧化物的甲烷（OCM）催化剂组合物的氧化偶联; 其中一种或多种氧化物包含单一金属氧化物，单一金属氧化物的混合物，混合金属氧化物，混合金属氧化物的混合物或其组合; 并且其中一种或多种氧化物不是单独的La 2 O 3。一种制造OCM催化剂组合物的方法，包括煅烧一种或多种氧化物和/或氧化物前体以形成一种或多种煅烧氧化物，其中所述一种或多种氧化物包括单一金属氧化物，单一金属氧化物的混合物，混合金属氧化物，混合金属氧化物的混合物或其组合，其中所述一种或多种氧化物单独不是La 2 O 3，并且其中所述氧化物前体包含氧化物，硝酸盐，碳酸盐，氢氧化物或其组合; 用Ag掺杂一种或多种煅烧氧化物以形成OCM催化剂组合物; 并热处理OCM催化剂组合物。

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