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1. 发明申请

WO2019063128A1 VERFAHREN UND VORRICHTUNG ZUR REDUKTION VON METALLOXIDEN 审中-公开
公开(公告)号：WO2019063128A1
公开(公告)日：2019-04-04
申请号：PCT/EP2018/025246
申请日：2018-09-26
申请人： LINDE AKTIENGESELLSCHAFT
发明人： SCHWARZHUBER, Josef , GROB, Sascha , HEINZEL, Albrecht , HASELSTEINER, Thomas , PLEINTINGER, Stefan
IPC分类号： C21B5/06 , C21B13/00 , C01B3/36 , C01B3/38
CPC分类号： C01B3/36 , C01B3/382 , C01B3/386 , C01B2203/06 , C01B2203/0838 , C01B2203/0877 , C01B2203/1235 , C01B2203/1241 , C01B2203/1258 , C21B13/0026 , C21B13/0073 , C21B2100/22 , C21B2100/24 , C21B2100/62
摘要： Die Erfindung betrifft ein Verfahren sowie eine Vorrichtung zur Gewinnung eines Metalls (12), bei dem ein Oxid (11) des Metalls in einer Reduktionszone (R) mit einem Reduktionsgas (10) in Kontakt gebracht wird, zu dessen Erzeugung ein kohlenwasserstoffhaltiger Einsatz (6) mit einem Oxidationsmittel (5) im Reaktionsraum (T) einer Vergasungseinrichtung (P) durch Partialoxidation bei einem Druck, der weniger als 2bar über dem Betriebsdruck in der Reduktionszone (R) liegt, zu einem Kohlenmonoxid und Wasserstoff enthaltenden Syntheserohgas (8) umgesetzt wird. Kennzeichnend hierbei ist, dass der kohlenwasserstoffhaltige Einsatz (6) und/oder das Oxidationsmittel (5) stromaufwärts der Vergasungseinrichtung (P) durch Zuführung von bei der Reduktion des Metalloxids abfallender Wärme vorgewärmt werden.

2. 发明申请

WO2016016257A1 INTEGRATED SCT-CPO/POX PROCESS FOR PRODUCING SYNTHESIS GAS 审中-公开
标题翻译：综合SCT-CPO / POX生产合成气的方法
公开(公告)号：WO2016016257A1
公开(公告)日：2016-02-04
申请号：PCT/EP2015/067300
申请日：2015-07-28
申请人： ENI S.P.A.
发明人： BASINI, Luca Eugenio
IPC分类号： C01B3/38 , C01B3/36
CPC分类号： C01B3/386 , C01B3/36 , C01B3/382 , C01B2203/0255 , C01B2203/0261 , C01B2203/061 , C01B2203/062 , C01B2203/0844 , C01B2203/1211 , C01B2203/1241 , C01B2203/1247 , C01B2203/141 , C01B2203/142 , Y02P20/125
摘要： The present invention relates to an integrated process for producing synthesis gas from carbonaceous compounds, liquid feedstock, gaseous feedstock, or combinations thereof which comprises the step of conducting in parallel one stage of short contact time catalytic partial oxidation (SCT-CPO) and a stage of non-catalytic partial oxidation (POx).
摘要翻译：本发明涉及一种从碳质化合物，液体原料，气态原料或其组合产生合成气的综合方法，其包括以下步骤：将短时间接触时间催化部分氧化（SCT-CPO）和阶段的非催化部分氧化（POx）。

3. 发明申请

WO2016016253A1 INTEGRATED SHORT CONTACT TIME CATALYTIC PARTIAL OXIDATION/GAS HEATED REFORMING PROCESS FOR THE PRODUCTION OF SYNTHESIS GAS 审中-公开
标题翻译：一体化短接触时间催化部分氧化/气体加热改造方法生产合成气
公开(公告)号：WO2016016253A1
公开(公告)日：2016-02-04
申请号：PCT/EP2015/067292
申请日：2015-07-28
申请人： ENI S.P.A.
发明人： BASINI, Luca Eugenio
IPC分类号： C01B3/38
CPC分类号： C01B3/382 , C01B3/386 , C01B2203/0233 , C01B2203/0261 , C01B2203/061 , C01B2203/062 , C01B2203/0844 , C01B2203/1211 , C01B2203/1241 , C01B2203/1247 , C01B2203/1258 , C01B2203/1264 , C01B2203/141 , C01B2203/142 , Y02P20/125
摘要： This invention relates to an integrated process for the production of synthesis gas comprising the following stages: a) dividing a gaseous hydrocarbon stream, preferably comprising natural gas and/or refinery gas, into a first and a second stream, b) mixing the said second stream with a stream containing oxygen, water vapour and possibly CO 2 , and possibly a third stream containing liquid and/or gaseous compounds in which the said gaseous compounds are selected from hydrocarbons other than natural gas and/or refinery gas, or from those compounds which also derive from biomass, and in which the said liquid compounds are selected from hydrocarbons or compounds of various nature deriving from biomass, or mixtures thereof, c)causing the mixture obtainedin (b) to react in a short contact time Catalytic Partial Oxidation section to form a first synthesis gas, d) causing the first gaseous stream, preferably selected from natural gas and/or refinery gas, to react with steam in a Gas Heated Reforming section to produce a second synthesis gas, and convectively heating the Gas Heated Reforming reactor with the first synthesis gas obtained in the short contact time Catalytic Partial Oxidation section.
摘要翻译：本发明涉及一种用于生产合成气的综合方法，包括以下阶段：a）将优选包含天然气和/或炼油厂气体的气态烃流分成第一和第二流，b）将所述第二具有含有氧气，水蒸气和可能的CO 2的物流，以及可能的含有液体和/或气体化合物的第三物流，其中所述气态化合物选自天然气和/或炼油厂气体以外的烃，或者其中还衍生自生物质，其中所述液体化合物选自烃或衍生自生物质的各种性质的化合物或其混合物，c）使得（b）中获得的混合物在短时间接触时间催化部分氧化部分反应形成第一合成气体，d）使得优选选自天然气和/或炼厂气体的第一气流与气体反应器中的蒸汽反应以产生第二合成气，并用气体加热重整反应器与在短接触时间催化部分氧化部分获得的第一合成气进行对流加热。

4. 发明申请

WO2015069836A4 GASEOUS FUEL CPOX REFORMERS AND METHODS OF CPOX REFORMING 审中-公开
标题翻译：气体燃料CPOX重整器和CPOX重整方法
公开(公告)号：WO2015069836A4
公开(公告)日：2015-10-15
申请号：PCT/US2014064239
申请日：2014-11-06
申请人： WATT FUEL CELL CORP
发明人： FINNERTY CAINE M , DEWALD PAUL
IPC分类号： B01J12/00 , B01J4/00 , B01J19/00 , B01J19/24 , C01B3/32 , C01B3/38 , C01B3/40 , H01M8/06 , H01M8/24
CPC分类号： H01M8/0618 , B01J4/001 , B01J4/002 , B01J4/005 , B01J12/007 , B01J19/2425 , B01J2219/00006 , B01J2219/00058 , B01J2219/0006 , B01J2219/00069 , B01J2219/00135 , B01J2219/00159 , B01J2219/002 , B01J2219/00213 , B01J2219/00234 , B01J2219/00238 , B01J2219/2401 , C01B3/323 , C01B3/386 , C01B2203/0261 , C01B2203/1035 , C01B2203/1223 , C01B2203/1229 , C01B2203/1235 , C01B2203/1241 , C01B2203/1247 , C01B2203/141 , C01B2203/16 , C01B2203/1604
摘要： A gaseous fuel catalytic partial oxidation (CPOX) reformer can include a plurality or an array of spaced-apart CPOX reactor units (408), each reactor unit including an elongate tube having a wall with internal and external surfaces, the wall enclosing an open gaseous flow passageway with at least a portion of the wall having CPOX catalyst disposed therein and/or comprising its structure. The catalyst-containing wall structure and open gaseous flow passageway enclosed thereby define a gaseous phase CPOX reaction zone (409), the catalyst-containing wall section being gas-permeable to allow gaseous CPOX reaction mixture to diffuse therein and hydrogen- rich product reformate to diffuse therefrom. At least the exterior surface of a CPOX reaction zone of a CPOX reactor unit can include a hydrogen barrier. The gaseous fuel CPOX reformer also can include one or more igniters, and a source of gaseous reformable fuel.
摘要翻译：气态燃料催化部分氧化（CPOX）重整器可以包括多个或一排间隔开的CPOX反应器单元（408），每个反应器单元包括细长管，该细长管具有带内表面和外表面的壁，壁包围开放的气体其中至少一部分壁具有置于其中的CPOX催化剂和/或包含其结构。由此封闭的含催化剂的壁结构和敞开的气流通道限定了气相CPOX反应区（409），含催化剂的壁部分是透气的以允许气态CPOX反应混合物在其中扩散，并且将富含氢的产物重整产物从那里扩散。至少CPOX反应器单元的CPOX反应区的外表面可以包括氢阻挡层。气体燃料CPOX重整器还可以包括一个或多个点火器和气体可重整燃料源。

5. 发明申请

WO2015130764A1 METHOD FOR OPTIMIZING DOWN FIRED REFORMING FURNACES 审中-公开
标题翻译：优化下火炉改造炉的方法
公开(公告)号：WO2015130764A1
公开(公告)日：2015-09-03
申请号：PCT/US2015/017492
申请日：2015-02-25
申请人： HONEYWELL INTERNATIONAL INC.
发明人： MARTIN, Richard Ray , MARTIN, Matthew
IPC分类号： C01B3/38 , F23D14/60 , F27B3/20
CPC分类号： C01B3/384 , C01B3/386 , C01B2203/0233 , C01B2203/0255 , C01B2203/0816 , C01B2203/1241
摘要： A method of optimizing steam methane reforming in a multiple cell, down-fired furnace. The method includes the steps of introducing hydrocarbons and steam to a plurality of catalyst filled process tubes, combusting gases through a plurality of center cell down-fired burners at a burner discharge velocity of V m/s, and a mass flow rate of 1 kg/s, combusting gases through outer cell down-fired burners at a burner discharge velocity of 1.5V - 2V m/s and a mass flow rate of 0.5 - 0.65 kg/s, and finally discharging combustion products from the outer cell down-fired burners and the center cell down-fired burners at a substantially uniform momentum.
摘要翻译：一种优化多池，下燃炉中蒸汽甲烷重整的方法。该方法包括以下步骤：将碳氢化合物和蒸汽引入到多个催化剂填充的处理管中，通过多个中心单元向下燃烧的燃烧器以V m / s的燃烧器排出速度和1kg的质量流量燃烧气体 / s，以1.5V-2V m / s的燃烧器排出速度和0.5-0.66kg / s的质量流量通过外部单元向下燃烧的燃烧器燃烧气体，并且最终从外部单元向下燃烧的燃烧产物燃烧器和中心单元向下燃烧的燃烧器具有基本均匀的动量。

6. 发明申请

WO2015069621A3 REFORMER WITH PEROVSKITE AS STRUCTURAL COMPONENT THEREOF 审中-公开
标题翻译：改性剂作为其结构组分的PEROVSKITE
公开(公告)号：WO2015069621A3
公开(公告)日：2015-07-23
申请号：PCT/US2014063817
申请日：2014-11-04
申请人： WATT FUEL CELL CORP
发明人： FINNERTY CAINE M , DEWALD PAUL
IPC分类号： B01J12/00 , B01J19/24 , C01B3/38 , H01M8/24
CPC分类号： C01B3/40 , B01J7/00 , B01J12/007 , B01J19/2415 , B01J19/2425 , B01J19/2475 , B01J23/26 , B01J23/34 , B01J23/63 , B01J23/6522 , B01J23/83 , B01J35/04 , B01J2219/00157 , C01B3/386 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/1005 , C01B2203/1041 , C01B2203/1047 , C01B2203/1052 , C01B2203/1058 , C01B2203/1064 , H01M8/004 , H01M8/0618 , H01M8/0625 , H01M8/0668 , H01M8/12 , H01M2008/1293 , Y02P20/52
摘要： [0078] A reformer includes at least one reformer reactor unit (300) having a space-confining wall with external (307) and internal surfaces (306), at least a section of the wall and space confined thereby defining a reforming reaction zone (311), an inlet end (301) and associated inlet (302) for admission of flow of gaseous reforming reactant to the reforming reaction zone (311), an outlet end (303) and associated outlet (304) for outflow of hydrogen-rich reformate produced in the reforming reaction zone (311), at least that section of the wall (305) corresponding to the reforming reaction zone comprising perovskite as a structural component thereof, such wall section being gas-permeable to allow gaseous reforming reactant to diffuse therein and hydrogen-rich reformate to diffuse therefrom.
摘要翻译：重整器包括至少一个重整器反应器单元（300），其具有具有外部（307）和内表面（306）的空间限制壁，所述壁和空间的至少一部分由此限定重整反应区（ 311），入口端（301）和相关联的入口（302），用于允许气态重整反应物流入重整反应区（311），出口端（303）和相关联的出口（304）用于富氢富集在重整反应区（311）中产生的重整产物至少是与包含钙钛矿作为其结构成分的重整反应区对应的壁（305）的该部分，该壁部分是气体可渗透的，以允许气态重整反应物在其中扩散和富氢重整产物。

7. 发明申请

WO2015069836A2 GASEOUS FUEL CPOX REFORMERS AND METHODS OF CPOX REFORMING 审中-公开
标题翻译：气体燃料CPOX改造和CPOX改造方法
公开(公告)号：WO2015069836A2
公开(公告)日：2015-05-14
申请号：PCT/US2014/064239
申请日：2014-11-06
申请人： WATT FUEL CELL CORP.
发明人： FINNERTY, Caine, M. , DEWALD, Paul
IPC分类号： H01M8/06 , B01J19/24 , C01B3/32
CPC分类号： H01M8/0618 , B01J4/001 , B01J4/002 , B01J4/005 , B01J12/007 , B01J19/2425 , B01J2219/00006 , B01J2219/00058 , B01J2219/0006 , B01J2219/00069 , B01J2219/00135 , B01J2219/00159 , B01J2219/002 , B01J2219/00213 , B01J2219/00234 , B01J2219/00238 , B01J2219/2401 , C01B3/323 , C01B3/386 , C01B2203/0261 , C01B2203/1035 , C01B2203/1223 , C01B2203/1229 , C01B2203/1235 , C01B2203/1241 , C01B2203/1247 , C01B2203/141 , C01B2203/16 , C01B2203/1604
摘要： A gaseous fuel catalytic partial oxidation (CPOX) reformer can include a plurality or an array of spaced-apart CPOX reactor units, each reactor unit including an elongate tube having a wall with internal and external surfaces, the wall enclosing an open gaseous flow passageway with at least a portion of the wall having CPOX catalyst disposed therein and/or comprising its structure. The catalyst-containing wall structure and open gaseous flow passageway enclosed thereby define a gaseous phase CPOX reaction zone, the catalyst-containing wall section being gas-permeable to allow gaseous CPOX reaction mixture to diffuse therein and hydrogen-rich product reformate to diffuse therefrom. At least the exterior surface of a CPOX reaction zone of a CPOX reactor unit can include a hydrogen barrier. The gaseous fuel CPOX reformer also can include one or more igniters, and a source of gaseous reformable fuel.
摘要翻译：气态燃料催化部分氧化（CPOX）重整器可以包括多个或一组间隔开的CPOX反应器单元，每个反应器单元包括具有内壁和外表面的壁的细长管，该壁包围开放的气流通道，所述壁的至少一部分具有设置在其中的CPOX催化剂和/或包含其结构。含有催化剂的壁结构和封闭的气态流动通道限定了气相CPOX反应区，含催化剂的壁段是气体可渗透的，以允许气态CPOX反应混合物在其中扩散，富氢产物重整产物从其扩散。至少CPOX反应器单元的CPOX反应区的外表面可以包括氢气屏障。气态燃料CPOX重整器还可以包括一个或多个点火器和气体可重整燃料源。

8. 发明申请

WO2015069762A2 CHEMICAL REACTOR WITH MANIFOLD FOR MANAGEMENT OF A FLOW OF GASEOUS REACTION MEDIUM THERETO 审中-公开
标题翻译：用于管理气体反应介质流量的化学反应器
公开(公告)号：WO2015069762A2
公开(公告)日：2015-05-14
申请号：PCT/US2014/064116
申请日：2014-11-05
申请人： WATT FUEL CELL CORP.
发明人： FINNERTY, Caine, M. , DEWALD, Paul
IPC分类号： C01B3/32 , H01M8/06 , B01J19/00
CPC分类号： C01B3/386 , B01J4/001 , B01J4/002 , B01J4/005 , B01J7/00 , B01J8/0285 , B01J8/065 , B01J8/067 , B01J8/1836 , B01J8/24 , B01J12/005 , B01J12/007 , B01J19/0013 , B01J19/0093 , B01J19/2415 , B01J19/2445 , B01J2208/00389 , B01J2208/00902 , B01J2208/00911 , B01J2219/00006 , B01J2219/00058 , B01J2219/00063 , B01J2219/00069 , B01J2219/00117 , B01J2219/00132 , B01J2219/00135 , B01J2219/00155 , B01J2219/00157 , B01J2219/00159 , B01J2219/002 , B01J2219/00213 , B01J2219/00234 , B01J2219/00585 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0844 , C01B2203/085 , C01B2203/1223 , C01B2203/1229 , C01B2203/1235 , C01B2203/1241 , C01B2203/1247 , C01B2203/141
摘要： A chemical reactor includes a manifold for management of a flow of gaseous reaction medium thereto.
摘要翻译：化学反应器包括用于管理气态反应介质流的歧管。

9. 发明申请

WO2015069754A2 LIQUID FUEL CPOX REFORMER AND FUEL CELL SYSTEMS, AND METHODS OF PRODUCING ELECTRICITY 审中-公开
标题翻译：液体燃料CPOX改造器和燃料电池系统，以及生产电力的方法
公开(公告)号：WO2015069754A2
公开(公告)日：2015-05-14
申请号：PCT/US2014/064107
申请日：2014-11-05
申请人： WATT FUEL CELL CORP
发明人： FINNERTY, Caine, M. , DEWALD, Paul
IPC分类号： H01M8/06
CPC分类号： H01M8/0631 , B01J4/001 , B01J4/002 , B01J4/005 , B01J12/007 , B01J19/2425 , B01J2219/00006 , B01J2219/00058 , B01J2219/0006 , B01J2219/00069 , B01J2219/00135 , B01J2219/00159 , B01J2219/002 , B01J2219/00213 , B01J2219/00234 , B01J2219/00238 , C01B3/323 , C01B3/386 , C01B2203/0261 , C01B2203/0283 , C01B2203/0405 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/1633 , C01B2203/169 , H01M8/04037 , H01M8/04302 , H01M8/04328 , H01M8/04335 , H01M8/04373 , H01M8/04388 , H01M8/04395 , H01M8/04798 , H01M8/0618
摘要： Integrated liquid fuel catalytic partial oxidation (CPOX) reformer and fuel cell systems can include a plurality or an array of spaced-apart CPOX reactor units, each reactor unit including an elongate tube having a gas-permeable wall with internal and external surfaces, the wall enclosing an open gaseous flow passageway with at least a portion of the wall having CPOX catalyst disposed therein and/or comprising its structure. The catalyst-containing wall structure and open gaseous flow passageway enclosed thereby define a gaseous phase CPOX reaction zone, the catalyst-containing wall section being gas-permeable to allow gaseous CPOX reaction mixture to diffuse therein and hydrogen rich product reformate to diffuse therefrom. The liquid fuel CPOX reformer also can include a vaporizer, one or more igniters, and a source of liquid reformable fuel. The hydrogen-rich reformate can be converted to electricity within a fuel cell unit integrated with the liquid fuel CPOX reactor unit.
摘要翻译：集成的液体燃料催化部分氧化（CPOX）重整器和燃料电池系统可以包括多个或一组间隔开的CPOX反应器单元，每个反应器单元包括具有内部和外部表面的透气壁的细长管，封闭开放的气态流动通道，其中至少一部分具有CPOX催化剂的壁设置在其中和/或包括其结构。含有催化剂的壁结构和封闭的气态流动通道限定了气相CPOX反应区，含催化剂的壁段是透气的，以允许气态CPOX反应混合物在其中扩散，富氢产物重整产物从其扩散。液体燃料CPOX重整器还可以包括蒸发器，一个或多个点火器和液体可重整燃料源。富氢重整产物可以在与液体燃料CPOX反应器单元集成的燃料电池单元内转化为电。

10. 发明申请

WO2015069621A2 REFORMER WITH PEROVSKITE AS STRUCTURAL COMPONENT THEREOF 审中-公开
标题翻译：改性剂作为其结构组分的PEROVSKITE
公开(公告)号：WO2015069621A2
公开(公告)日：2015-05-14
申请号：PCT/US2014/063817
申请日：2014-11-04
申请人： WATT FUEL CELL CORP.
发明人： FINNERTY, Caine, M. , DEWALD, Paul
IPC分类号： C01B3/32 , H01M8/06 , B01J19/00
CPC分类号： C01B3/40 , B01J7/00 , B01J12/007 , B01J19/2415 , B01J19/2425 , B01J19/2475 , B01J23/26 , B01J23/34 , B01J23/63 , B01J23/6522 , B01J23/83 , B01J35/04 , B01J2219/00157 , C01B3/386 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/1005 , C01B2203/1041 , C01B2203/1047 , C01B2203/1052 , C01B2203/1058 , C01B2203/1064 , H01M8/004 , H01M8/0618 , H01M8/0625 , H01M8/0668 , H01M8/12 , H01M2008/1293 , Y02P20/52
摘要： A reformer includes at least one reformer reactor unit having a space-confining wall with external and internal surfaces, at feast a section of the wail and space confined thereby defining a reforming reaction zone, an inlet end and associated inlet for admission of a flow of gaseous reforming reactant to the reforming reaction zone, an outlet end and associated outlet for outflow of hydrogen-rich reformate produced in the reforming reaction zone, at least that section of the wall corresponding to the reforming reaction zone comprising perovskite as a structural component thereof, such wall section being gas-permeable to allow gaseous reforming reactant to diffuse therein and hydrogen-rich reformate to diffuse therefrom.
摘要翻译：重整器包括至少一个重整器反应器单元，其具有具有外部和内部表面的空间限制的壁，并且节约了一部分壁和限制的空间，从而限定了重整反应区，入口端和相关联的入口，重整反应区的气态重整反应物，在重整反应区中产生的富氢重整产物流出的出口端和相关出口，至少该对应于包含钙钛矿作为其结构组分的重整反应区的壁的该部分，这种壁部分是气体可渗透的，以允许气态重整反应物在其中扩散，并且富氢重整产物从其扩散。

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