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1. 发明申请

WO2005021457A2 OPTICAL FIBER COATINGS 审中-公开
标题翻译：光纤涂层
公开(公告)号：WO2005021457A2
公开(公告)日：2005-03-10
申请号：PCT/EP2004/051851
申请日：2004-08-20
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , SITZMANN, Eugene Valentine , WOLF, Jean-Pierre , BRAMER, David , LOSAPIO, Greg
发明人： SITZMANN, Eugene Valentine , WOLF, Jean-Pierre , BRAMER, David , LOSAPIO, Greg
IPC分类号： C03C25/10
CPC分类号： C09D4/00 , C03C25/106 , C08F2/50 , C08F290/06 , C08F290/062 , C08F290/067
摘要： Optical fiber coating compositions which comprise at least one ethylenically unsaturated polymerizable compound and a photoinitiator blend, wherein the blend comprises (a) bis(2,4,6-trimethylbenzoyl)phenylphosphine oxide and (b) 2,4,6,-trimethylbenzoyl ethoxyphenylphosphine oxide in an (a):(b) weight:weight ratio of between about 1:10 and about 1:8; or (c) bis(2,4,6-trimethylbenzoA)phenylphosphine oxide, (d) 2,4,6,-trimethylbenzoylethoxyphenylphosphine oxide and (e) 2-hydroxy-2-methyl-1-phenyl-1-propanone in a (c):(d):(e) weight:weight:weight ratio between about 3:11:14 and about 4:1:16; or (f) bis(2,4,6-trimethylbenzoyl)phenylphosphine oxide and (g) 2-hydroxy-2-methyl-1-phenyl-1-propanone in a (f):(g) weight:weight ratio of between about 1:3 and about 1:5 exhibit fast photospeed, very low color and fast photobleaching. The photoinitiator blends have low volatility, high shelf life stability and high compatibility with resins and monomers. The photoinitiator blends are for example liquid and easy to use.
摘要翻译：包含至少一种烯键式不饱和可聚合化合物和光引发剂共混物的光学纤维涂料组合物，其中所述共混物包含（a）双（2,4,6-三甲基苯甲酰基）苯基氧化膦和（b）2 ，4,6-，-trimethylbenzoyl＆害羞; （a）：（b）重量比：约1:10至约1:8的重量比的乙氧基苯基氧化膦; 或（c）双（2,4,6-三甲基苯甲酰基）苯基氧化膦，（d）2,4,6-三甲基苯甲酰基乙氧基苯基氧化膦和（e）2-和2-羟基-2-甲基-1-苯基-1-丙酮在（c）：（d）:( e）重量：重量：约3:11:14和约4:1:16之间的重量比; 或（f）双（2,4,6-三甲基苯甲酰基）苯基氧化膦和（g）2-羟基-2-甲基-1-苯基-1-丙酮的（f）:( g）重量：约1：3和约1：5显示出快速的感光速度，非常低的颜色和快速的光漂白。光引发剂共混物具有低挥发性，高贮存期稳定性和与树脂和单体的高相容性。光引发剂混合物例如是液体并且易于使用。

2. 发明申请

WO2005070989A3 THERMALLY STABLE CATIONIC PHOTOCURABLE COMPOSITIONS 审中-公开
公开(公告)号：WO2005070989A3
公开(公告)日：2005-08-04
申请号：PCT/EP2005/050157
申请日：2005-01-17
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , WOLF, Jean-Pierre , ILG, Stephan , BIRBAUM, Jean-Luc , SITZMANN, Eugene Valentine , BRAMER, David , LOSAPIO, Greg
发明人： WOLF, Jean-Pierre , ILG, Stephan , BIRBAUM, Jean-Luc , SITZMANN, Eugene Valentine , BRAMER, David , LOSAPIO, Greg
IPC分类号： C08G59/18
摘要： Disclosed are cationic photocurable compositions with improved shelf life stability. The thermally stable compositions comprise at least one cationically polymerizable compound, for example an epoxy compound, at least one onium salt photoinitiator and at least one compound selected from the group consisting of the organic phosphorus stabilizers and the hindered nitroxyl stabilizers. Also disclosed is a cationic photoinitiator composition comprising at least one onium salt photoinitiator and at least one compound selected from the group consisting of the organic phosphorus stabilizers and the hindered nitroxyl stabilizers.

3. 发明申请

WO2005014605A1 PROCESS FOR PREPARING ACYLPHOSPHANES AND DERIVATIVES THEREOF 审中-公开
标题翻译：制备其中的酰亚胺及其衍生物的方法
公开(公告)号：WO2005014605A1
公开(公告)日：2005-02-17
申请号：PCT/EP2004/051427
申请日：2004-07-09
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , SOMMERLADE, Reinhard H. , BOULMAÂZ, Souâd , WOLF, Jean-Pierre , GEIER, Jens , GRÜTZMACHER, Hansjörg , SCHERER, Markus , SCHÖNBERG, Hartmut , STEIN, Daniel , MURER, Peter , BURKHARDT, Stephan
发明人： SOMMERLADE, Reinhard H. , BOULMAÂZ, Souâd , WOLF, Jean-Pierre , GEIER, Jens , GRÜTZMACHER, Hansjörg , SCHERER, Markus , SCHÖNBERG, Hartmut , STEIN, Daniel , MURER, Peter , BURKHARDT, Stephan
IPC分类号： C07F9/50
CPC分类号： C07F9/5036 , C07F9/5337
摘要： The present invention relates to a new, selective process for the preparation of mono- and bisacylphosphanes of formula (I) n and m are each independently of the other 1 or 2; R 1 , if n = 1, is e.g. phenyl R 1 , if n = 2, is e.g. C 1 -C 18 alkylene or phenylene; R 2 is e. g. C 1 -C 18 alkyl, phenyl or substituted phenyl; R 3 is e. g. C 1 -C 18 alkyl, by (1) reacting a phosphorous halide of formula Ila or a phosphorous halide oxide of formula (Ilb) or a phosphorous halide sulfide of formula (IIc) with an alkali metal in a solvent in the presence of a proton source; (2) subsequent reaction with m acid halides of formula (III) An oxidation step may follow to obtain mono- and bisacylphosphane oxides or mono-and bisacylphosphane sulfides.
摘要翻译：本发明涉及制备式（I）的单 - 和双酰基磷烷的新的选择性方法，n和m各自独立地为1或2; R1，如果n = 1，则为例如苯基R1，如果n = 2，是例如。 C1-C18亚烷基或亚苯基; R2是e。 G。 C 1 -C 18烷基，苯基或取代的苯基; R3是e。 G。通过（1）在溶剂中在质子源的存在下使式IIa的卤化磷或式（IIb）的卤化磷或式（IIc）的卤化磷化物与碱金属在碱性溶剂中反应; （2）随后与式（III）的酰卤反应可以进行氧化步骤以获得单酰基和双酰基氧化膦或单酰基和双酰基磷烷硫化物。

4. 发明申请

WO2005076074A2 FUNCTIONALIZED PHOTOINITIATORS 审中-公开
标题翻译：功能化光敏元件
公开(公告)号：WO2005076074A2
公开(公告)日：2005-08-18
申请号：PCT/EP2005/050276
申请日：2005-01-24
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , DIETLIKER, Kurt , HÜSLER, Rinaldo , BIRBAUM, Jean-Luc , WOLF, Jean-Pierre
发明人： DIETLIKER, Kurt , HÜSLER, Rinaldo , BIRBAUM, Jean-Luc , WOLF, Jean-Pierre
IPC分类号： G03F
CPC分类号： C08F2/50 , B33Y70/00 , G03F7/0007 , G03F7/001 , G03F7/0037 , G03F7/031
摘要： The invention relates to novel photoinitiators of formula (I) wherein each of the substituents is given the definition as set forth in the Specification and the claims. The photoinitiators can be used to prepare multifunctional photoinitiators.
摘要翻译：本发明涉及式（I）的新型光引发剂，其中每个取代基被给出如本说明书和权利要求书中所阐述的定义。光引发剂可用于制备多功能光引发剂。

5. 发明申请

WO2004037799A1 IMPROVEMENT IN THE STORAGE STABILITY OF PHOTOINITIATORS 审中-公开
标题翻译：光敏剂储存稳定性的改进
公开(公告)号：WO2004037799A1
公开(公告)日：2004-05-06
申请号：PCT/EP2003/050729
申请日：2003-10-17
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ULRICH, Thomas , BOLLE, Thomas , DIETLIKER, Kurt , WOLF, Jean-Pierre , FUCHS, André
发明人： ULRICH, Thomas , BOLLE, Thomas , DIETLIKER, Kurt , WOLF, Jean-Pierre , FUCHS, André
IPC分类号： C07D295/10
CPC分类号： C07D295/096 , B33Y70/00 , C07D295/112 , C08F2/50 , C09D11/101 , G03F7/0007 , G03F7/001 , G03F7/0037 , G03F7/031
摘要： Compounds of formula (I), wherein R 1 is hydrogen or alkyl; R 2 is C 1 -C 4 alkoxy or a morpholino radical; and R 3 is hydrogen or C 1 -C 4 alkoxy, are suitable for improving the solubility of specific photoinitiators in formulations and accordingly enhance the storage stability of formulations comprising a photoinitiator and compounds of formula (I).
摘要翻译：式（I）的化合物，其中R 1是氢或烷基; R2是C1-C4烷氧基或吗啉基; 并且R 3是氢或C 1 -C 4烷氧基适合于提高特定光引发剂在制剂中的溶解度，并因此提高包含光引发剂和式（I）化合物的制剂的储存稳定性。

6. 发明申请

WO2006056541A1 PROCESS FOR PREPARING ACYLPHOSPHANES AND DERIVATIVES THEREOF 审中-公开
标题翻译：制备其中的酰亚胺及其衍生物的方法
公开(公告)号：WO2006056541A1
公开(公告)日：2006-06-01
申请号：PCT/EP2005/055935
申请日：2005-11-14
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , MURER, Peter , WOLF, Jean-Pierre , BURKHARDT, Stephan , GRÜTZMACHER, Hansjörg , STEIN, Daniel , DIETLIKER, Kurt
发明人： MURER, Peter , WOLF, Jean-Pierre , BURKHARDT, Stephan , GRÜTZMACHER, Hansjörg , STEIN, Daniel , DIETLIKER, Kurt
IPC分类号： C07F9/50
CPC分类号： G03F7/029 , C07F9/5036 , C07F9/5337 , C07F9/5537 , C07F9/65515 , C07F9/6552
摘要： The invention relates to a process for the preparation of (bis)acylphosphanes of formula I, wherein n and m are each independently of the other 1 or 2; R1 if n = 1 , is e.g. unsubstituted or substituted C 1 -C 18 alkyl or C 2 -C 18 alkenyl, or phenyl, R1 if n = 2, is e.g. a divalent radical of the monovalent radical defined above; R2 is e.g. C 1 -C 18 alkyl, C 3 -C 12 cycloalkyl, C 2 -C 18 alkenyl, mesityl, phenyl, naphthyl; R3 is one of the radicals defined under R 1 ; the process comprises the steps a) contacting e.g. elemental phosphorous [P]∞, P(Hal) 3 with a reducing metal optionally in the presence of a catalyst or an activator in a solvent to obtain metal phosphides Me 3 P or Me' 3 P 2 , wherein Me is an alkali metal and Me' is an earth alkali metal or to obtain metal polyphosphides b) optionally adding a proton source, optionally in the presence of a catalyst or an activator to obtain metal dihydrogen phosphides MePH 2 ; c) subsequent acylation reaction with m acid halides of formula III or m carboxylic acid esters of formula IV or, in case that in formula I m = 1, with one carboxylic ester of formula IV followed by one acid halide of formula III or vice versa, wherein R is the residue of an alcohol and R 2 is as defined above; d) alkylation reaction subsequent reaction with an electrophilic agent R 1 Hal or other electrophilic agents to obtain the compounds of formula I. An oxidation step may follow to obtain mono- and bisacylphosphane oxides or mono- and bisacylphosphane sulfides, which are used as photoinitiators.
摘要翻译：本发明涉及制备式（I）的（双）酰基磷烷的方法，其中n和m各自独立地为1或2; 如果n = 1，则为R1。未取代或取代的C 1 -C 18烷基或C 2 -C 18链烯基，或苯基，R 1如 n = 2，例如上述定义的一价基团的二价基团; R2是例如 C 1 -C 18烷基，C 3 -C 12环烷基，C 2 -C 12 烯基，均三甲苯基，萘基，萘基， R 3是在R 1上定义的基团之一; 该方法包括以下步骤：a）元素磷[P] 8，P（Hal）3 3与还原金属任选地在催化剂或活化剂存在下在溶剂中反应，得到金属磷化物Me 3 或Me'3 P 2，其中Me是碱金属，Me'是碱土金属，或者获得金属多磷酸盐b）任选地加入质子源，任选地加入存在催化剂或活化剂以获得金属磷酸二氢盐MePH 2; c）随后与式III的酰基卤或式IV的羧酸酯的酰化反应，或在式I中m = 1的情况下，与一种式IV的羧酸酯接触，然后加入式III的酰卤，反之亦然其中R是醇的残基，R 2'如上所定义; d）烷基化反应随后与亲电子试剂R 1 Hal或其他亲电子试剂反应以获得式I化合物。可以进行氧化步骤以获得单酰基和双酰基氧化膦或单酰基和双酰基磷烷硫化物，它们用作光引发剂。

7. 发明申请

WO2004103580A1 STRONGLY ADHERENT SURFACE COATINGS 审中-公开
标题翻译：强力表面涂料
公开(公告)号：WO2004103580A1
公开(公告)日：2004-12-02
申请号：PCT/EP2004/050806
申请日：2004-05-14
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , WOLF, Jean-Pierre , KUNZ, Martin
发明人： WOLF, Jean-Pierre , KUNZ, Martin
IPC分类号： B05D3/14
CPC分类号： B05D3/06 , B05D3/067 , B05D3/068 , B05D3/08 , B05D3/142 , C07F9/5045 , C08F283/00 , C08F290/06 , C08F290/14 , Y10T428/12569
摘要： In a process for the production of a strongly adherent coating on an inorganic or organic substrate, wherein a), a low-temperature plasma treatment, a corona discharge treatment or a flame treatment is carried out on the inorganic or organic substrate, b) one or more photoinitiators or mixtures of photoinitiators with monomers or/and oligomers, containing at least one ethylenically unsaturated group, or solutions, suspensions or emulsions of the afore-mentioned substances, are applied to the inorganic or organic substrate, and optionally, c) using suitable methods those afore-mentioned substances are dried and/or are irradiated with electromagnetic waves, it proves advantageous to use compounds of formula (I), (II), (III) and/or (IV), IN-L-RG (I), IN-L-RG 1 -L 1 -H (II), IN-L-RG 1 -L 1 -IN 1 (III), IN-L-RG 1 -L 1 -RG 2 -L 2 -IN 1 (IV), wherein IN and IN 1 are each independently of the others a monacylphosphine, monoacylphosphine oxide or monoacylphosphine sulfide photoinitiator group; L 1 L 1 and L 2 are a single bond or a spacer group; RG is a monovalent radical having at least one ethylenically unsaturated C=C bond; and RG 1 and RG 2 are each independently of the other a divalent radical having at least one ethylenically unsaturated C=C bond.
摘要翻译：在无机或有机基底上制备强粘附涂层的方法中，其中a）在无机或有机基底上进行低温等离子体处理，电晕放电处理或火焰处理，b）一或更多的光引发剂或光引发剂与含有至少一个烯键式不饱和基团的单体或/和低聚物或上述物质的溶液，悬浮液或乳液的混合物施用于无机或有机底物，以及任选地，c）使用使用上述物质干燥和/或用电磁波照射的合适方法，证明使用式（I），（II），（III）和/或（IV）的化合物，IN-L-RG（ IN-L-RG1-L1-H（II），IN-L-RG1-L1-IN1（III），IN-L-RG1-L1-RG2-L2-IN1（IV）各自独立地为单酰基膦，单酰基氧化膦或单酰基膦硫化物光引发剂基团; L1 L1和L2是单键或间隔基; RG是具有至少一个烯属不饱和C = C键的一价基团; 并且RG1和RG2各自独立地为具有至少一个烯属不饱和C = C键的二价基团。

8. 发明申请

WO2007003507A1 SULPHONIUM SALT INITIATORS 审中-公开
标题翻译：硫酸钡发射器
公开(公告)号：WO2007003507A1
公开(公告)日：2007-01-11
申请号：PCT/EP2006/063378
申请日：2006-06-21
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , WOLF, Jean-Pierre , LATIKA, Attila , BIRBAUM, Jean-Luc , ILG, Stephan , HAYOZ, Pascal
发明人： WOLF, Jean-Pierre , LATIKA, Attila , BIRBAUM, Jean-Luc , ILG, Stephan , HAYOZ, Pascal
IPC分类号： C07C381/12 , G03F7/004 , G03F7/039
CPC分类号： C07D209/88 , B33Y70/00 , C07C309/06 , C07C381/12 , G03F7/0045 , G03F7/038 , Y10S430/122
摘要： Compounds of the formula (I), (II), (III), (IV) and wherein, R is hydrogen, C 1 -C 20 alkyl; C 2 -C 20 alkyl interrupted by one or more O; is -L-X-R 2 or - L-R 2 ; R 1 has ofr example one of the meanings as given for R; R 2 is a monovalent sensitizer or photoinitiator moiety; Ar 1 and Ar 2 for example independently of one another are phenyl substituted by C 1 -C 20 alkyl, halogen or OR 3 ; or are unsubstituted naphthyl, anthryl, phenanthryl or biphenylyl; or are naphthyl, anthryl, phenanthryl or biphenylyl substituted by C 1 -C 20 alkyl, OH or OR 3 ; or are -Ar 4 -A-Ar 3 ; Ar 3 is unsubstituted phenyl naphthyl, anthryl, phenanthryl or biphenylyl; or is phenyl, naphthyl, anthryl, phenanthryl or biphenylyl substituted by C 1 -C 20 alkyl, OR 3 or benzoyl; Ar 4 is phenylene, naphthylene, anthrylene or phenanthrylene; A is a direct bond, S, O or C 1 -C 20 alkylene; X is CO, C(O)O, OC(O), O, S or NR 3 ; L is C 1 -C 20 alkylene or C 2 -C 20 alkylene interrupted by one or more O; R 3 is C 1 -C 20 alkyl or C 1 -C 20 hydroxyalkyl; and Y is an anion, are suitable as photolatent acid generators.
摘要翻译：式（I），（II），（III），（IV）的化合物，其中R是氢，C 1 -C 20烷基; 被一个或多个O中断的C 2 -C 20烷基; 是-L-X-R 2或-L-R 2; R 1具有如R给出的含义之一; R 2 2是单价敏化剂或光引发剂部分; Ar 1和Ar 2，例如彼此独立地是被C 1 -C 20烷基取代的苯基，卤素或OR 3; 或未取代的萘基，蒽基，菲基或联苯基; 或被C 1 -C 20烷基，OH或OR 3取代的萘基，蒽基，菲基或联苯基; 或为-Ar 4 -Ar -Ar 3 N; Ar 3是未取代的苯基萘基，蒽基，菲基或联苯基; 或者是被C 1 -C 20烷基，OR 3或苯甲酰基取代的苯基，萘基，蒽基，菲基或联苯基。 Ar 4是亚苯基，亚萘基，亚蒽基或菲基; A是直接键合，S，O或C 1 -C 20亚烷基; X是CO，C（O）O，OC（O），O，S或NR 3。 L是被一个或多个O中断的C 1 -C 20亚烷基或C 2 -C 20 -C 20亚烷基; R 3是C 1 -C 20烷基或C 1 -C 20烷基或C 1 -C 20烷基或C 1 -C 20烷基，羟; 并且Y是阴离子，适合作为光潜酸产生剂。

9. 发明申请

WO2004104051A1 BIMOLECULAR PHOTOINITIATOR SYSTEMS 审中-公开
标题翻译：双分子光电子系统
公开(公告)号：WO2004104051A1
公开(公告)日：2004-12-02
申请号：PCT/EP2004/050817
申请日：2004-05-17
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , BIRBAUM, Jean-Luc , DIETLIKER, Kurt , FREIERMUTH, Beat , KUNZ, Martin , OKA, Hidetaka , WOLF, Jean-Pierre
发明人： BIRBAUM, Jean-Luc , DIETLIKER, Kurt , FREIERMUTH, Beat , KUNZ, Martin , OKA, Hidetaka , WOLF, Jean-Pierre
IPC分类号： C08F2/46
CPC分类号： G03F7/031 , C07D335/16 , C08F2/50 , C08K5/07 , C08K5/45
摘要： Photoinititator systems comprising (b1) at least one aromatic aldehyde; (b2) at least one tertiary amine compound and/or a quaternary ammonium salt of a tertiary amine compound; and (b3) optionally a sensitizer compound are suitable for the photo polymerization of ethylenically unsaturated monomeric or oligomeric polymerizable compounds; wherein the aromatic aldehyde is a compound of formula I (1), wherein R 1 and R 2 independently of each other are hydrogen, C 1 -C 4 alkyl, formyl, or OR 6 ; R 3 , R 4 and R 5 for example are hydrogen, C 1 -C l2 alkyl, C 3 -C 8 cycloalkyl, halogen, C 1 -C 8 alkanoyl, OR 6 , NR 7 R 8 , SR 9 , SOR 9 , SO 2 R 9 ; benzoyl; phenyl which optionally is substituted; or R 1 and R 3 together, or R 3 and R 5 together for example form a group b, g, h, k or p which is optionally substituted; provided that at least one of the residues R 3 , R 4 and R 5 is SR 9 , or that R 1 and R 3 together, or R 3 and R 5 together form a group a, b, c, d, e, f, g, h, j, k, m, n or o; R 6 for example is hydrogen, C 1 -C 18 alkyl or phenyl; R 7 and R 8 for examples are hydrogen or C 1 -C 12 alkyl; R 9 is for example hydrogen, C 1 -C 24 alkyl, phenyl which is optionally substituted; and R 10 is for example hydrogen, C 1 -C 12 alkyl or phenyl.
摘要翻译：光引发剂体系，其包含（b1）至少一种芳族醛; （b2）至少一种叔胺化合物和/或叔胺化合物的季铵盐; 和（b3）任选的敏化剂化合物适用于烯键式不饱和单体或低聚物可聚合化合物的光聚合; 其中芳族醛是式I（1）的化合物，其中R 1和R 2彼此独立地是氢，C 1 -C 4烷基，甲酰基或OR 6; R 3，R 4和R 5例如是氢，C 1 -C 12烷基，C 3 -C 8环烷基，卤素，C 1 -C 8烷酰基，OR 6，NR 7 R 8，SR 9，SOR 9，SO 2 R 9; 苯甲酰; 任选被取代的苯基; 或R 1和R 3一起，或R 3和R 5一起例如形成任选取代的基团b，g，h，k或p; 条件是残基R3，R4和R5中的至少一个为SR9，或者R1和R3一起或R3和R5一起形成a，b，c，d，e，f，g，h，j，k ，m，n或o; R6例如是氢，C1-C18烷基或苯基; R 7和R 8例如是氢或C 1 -C 12烷基; R 9为例如氢，C 1 -C 24烷基，任选被取代的苯基; 并且R 10例如是氢，C 1 -C 12烷基或苯基。

10. 发明申请

WO2003104245A1 MULTIMER FORMS OF MONO- AND BIS-ACYLPHOSPHINE OXIDES 审中-公开
标题翻译：单和双磷酰氧化物的多种形式
公开(公告)号：WO2003104245A1
公开(公告)日：2003-12-18
申请号：PCT/EP2003/005801
申请日：2003-06-03
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , WOLF, Jean-Pierre , HUG, Gebhard
发明人： WOLF, Jean-Pierre , HUG, Gebhard
IPC分类号： C07F9/53
CPC分类号： C07F9/28 , B33Y70/00 , C07F9/5337 , C07F9/65685 , C08F2/50 , G03F7/029
摘要： The invention relates to dimer and multimer forms of BAPO compounds of the formula (1) dimer and multimer forms of MAPO compounds of the formula (II) wherein R 1 , R 2 , and R 3 independently of one another are unsubstituted or substituted C 1 -C 12 alkyl, benzyl, C 1 -C 12 alkoxy, C 3 -C 6 cycloalkyl or C 5 -C 14 aryl; Q is a di-tri or tetravalent arylene residue; n is 1-4, m is 0-2, n+m is 2, 3 or 4, with the proviso, that R 1 and R 3 are different from each other. The invention further relates to a process for the preparation of dimer or multimer forms of BAPO compounds of the formula (I) and of dimer or multimer forms of MAPO compounds of the formula (II), characterized in the (n + m) equivalents of a dimetalated-phosphine R 1 P(M) 2 is reacted with one equivalent of a di-or polycarboxylic acid halogenide to form an intermediate of the formula III the intermediate is then reacted either with (n + m) equivalents of a further carboxylic acid halogenide (R 2 -CO-Hal) or with a halogenide R 3 -Hal, the reaction products are then oxidized to form phosphine oxides of the formula I or II.
摘要翻译：本发明涉及式（1）的二聚体和多聚体形式的二聚体和多聚体形式的式（II）的MAPO化合物，其中R 1，R 2和R 3彼此独立地是未取代的或取代的C 1 -C 12烷基，苄基，C 1 -C 12烷氧基，C 3 -C 6环烷基或C 5 -C 14芳基; Q是二价或四价的亚芳基; n为1-4，m为0-2，n + m为2,3或4，条件是R1和R3彼此不同。本发明还涉及制备式（I）的二聚体或多聚体形式的BAPO化合物和式（II）的MAPO化合物的二聚体或多聚体形式的方法，其特征在于（n + m）当量的二价膦化物R1P（M）2与一当量的二元或多元羧酸卤化物反应形成式Ⅲ的中间体，然后使中间体与（n + m）当量的另外的羧酸卤化物 R2-CO-Hal）或与卤化物R3-Hal反应，然后将反应产物氧化形成式I或II的氧化膦。

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