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    • 6. 发明申请
    • FABRIC RINSE COMPOSITION CONTAINING A CATIONIC UV ABSORBER
    • 含有阳离子紫外线吸收剂的织物组合物
    • WO2002088455A1
    • 2002-11-07
    • PCT/EP2002/003007
    • 2002-03-19
    • CIBA SPECIALTY CHEMICALS HOLDING INC.HOCHBERG, RobertROHWER, HaukeEHLIS, Thomas
    • HOCHBERG, RobertROHWER, HaukeEHLIS, Thomas
    • D06M13/358
    • C11D3/2072C08K5/19C08K5/3475C08K5/34928C11D1/62C11D3/0015C11D3/28C11D3/42D06M13/352D06M13/358D06M13/46D06M13/467D06P1/6426D06P1/66D06P5/06
    • Disclosed is a fabric rise composition comprising a) 0.1 to 10 % by weight of a UV absorber of formula (1), wherein U is a radical of a UV absorber selected from hydroxyphenyl-benztriazole, hydroxyphenyl-triazine and benzophenone; A direct bond; C 1 -C 6 alkylen; C 1 -C 6 alkyliden; or a group of formula (1a); Y direct bond; or the group -CO-; -COO-; -OOC-; -CO-N(R')-; -(R')N-CO-; -SO 2 -N(R')-; -R(R')N-SO 2 ; a group of formula (1b); (1c); (1d); or (1e); B direct bond; C 2 -C 6 alkylene or C 2 -C 6 alkylidene which is substituted by OH and which can be interrupted by -O- or by one or two N + X - (R') 2- ; or is a group of formula (1g), or (h); or the group (2) is a saturated or unsaturated mononuclear or trinuclear N-heterocyclic radical containing 1-4 N-atoms as ring members, at least one of which is quaternized; R 1 , R 2 and R 3 independently from each other are hydrogen; C 1 -C 8 alkyl; or C 1 -C 8 alkyl which is substituted by 1 -COOR'' group or by 1 to 3 OH groups, C 2 -C 8 hydroxyalkyl which is interrupted by one or more -O- groups, -(C 1 -C 8 )alkylene-COO - , -(C 1 -C 8 )alkylidene-COO - , -(C 2 -C 8 )alkylidene-SO 3 - each of which is substituted by one OH group; C 3 -C 5 alkenyl; C 5 -C 7 cycloalkyl; phenyl; tolyl; benzyl; or glycidyl; or R 1 together with R 2 and if appropriate with R 3 and together with the N + -atom to which they are attached, form a N-heterocyclic radical which can contain 1-3 N-atoms or one O-atom as ring members; R' is hydrogen; C 1 -C 4 alkyl or C 2 -C 3 hydroxyalkyl; R'' is hydrogen; or C 1 -C 4 alkyl and X - if not present in R 1 , R 2 or R 3 is a colourless organic or inorganic anion. B° is -(CH 2 ) m -; or one of the following groups: (3); (4); or (5); m and r are independently from each other 2 or 3; p is 1 to 6; n is 1 to 4; g is 0 or 1; with the proviso that A, Y and B are not the same time the direct bond; b) 5 to 25 % by weight, based on the total weight of the composition of a fabric softener agent; and c) water.
    • 公开了一种织物上升组合物,其包含a)0.1至10重量%的式(1)的UV吸收剂,其中U是选自羟苯基 - 苯并三唑,羟苯基 - 三嗪和二苯甲酮的UV吸收剂基团; 直接债券 C1-C6alkylen; C1-C6alkyliden; 或一组式(1a); Y直接债券 或基团-CO-; -COO-; -OOC-; -CO-N(R') - ; - (R')N-CO-; -SO 2 N(R') - ; -R(R')N-SO 2; 一组式(1b); (1C); (1D); 或(1e); B直接债券; 被OH取代的C2-C6亚烷基或C2-C6亚烷基,其可被-O-或一个或两个N +(R')2 - 间隔; 或者是式(1g)或(h)的基团; 或基团(2)是含有1-4个N原子作为环成员的饱和或不饱和单核或三核N-杂环基,其中至少一个被季铵化; R1,R2和R3彼此独立地是氢; C1-C8烷基; 或被1个-COOR'基团取代的C 1 -C 8烷基或1〜3个OH基团,被一个或多个-O-基团间隔的C 2 -C 8羟烷基, - (C 1 -C 8)亚烷基-CO 2 - - (C 1 -C 8)亚烷基-COO - , - (C 2 -C 8)亚烷基-SO 3 - ,每个被一个OH基团取代; C3-5烯基; C5-C7环烷基; 苯基; 甲苯; 苄基; 或缩水甘油基; 或R 1与R 2一起,如果合适,与R 3一起并与它们所连接的N +原子一起形成可以含有1-3个N原子或一个O原子作为环成员的N-杂环基团; R'是氢; C 1 -C 4烷基或C 2 -C 3羟烷基; R“是氢; 或C 1 -C 4烷基和X 1如果不存在于R 1中,R 2或R 3是无色有机或无机阴离子。 B DEG是 - (CH2)m-; 或以下组之一:(3); (4); 或(5); m和r彼此独立地为2或3; p为1〜6; n为1〜4; g为0或1; 条件是A,Y和B不是直接键的同一时间; b)5至25重量%,基于织物柔软剂的组合物的总重量; 和c)水。
    • 7. 发明申请
    • FABRIC RINSE COMPOSITION COMPRISING A TRIAZINE UV ABSORBER
    • 包含TRIAZINE紫外线吸收剂的织物组合物
    • WO2002079564A1
    • 2002-10-10
    • PCT/EP2002/003008
    • 2002-03-19
    • CIBA SPECIALTY CHEMICALS HOLDING INC.HOCHBERG, RobertROHWER, Hauke
    • HOCHBERG, RobertROHWER, Hauke
    • D06M13/358
    • D06M13/358C07D251/24C11D3/28C11D3/42D06L4/614D06L4/629D06L4/657D06M13/463
    • Disclosed is a fabric rinse composition comprising a) 0.1 to 10% by weight of a UV absorber selected from a hydroxyaryl-1, 3, 5- triazine of the formula (I), wherein R 1 is hydrogen; c 1 -c 4 -Alkoxy; or halogen; R 2 is mono-C 1 -C 4 alkylamino; a radical of the formula (I'); X is C 2 -C 4 alkylen; Y 1 , Y 2 independently from each other are C 1 -C 4 alkyl or C 1 -C 4 alkyl which is substituted by halogen, cyano hydroxy or C 1 -C 4 alkoxy; or Y 1 and Y 2 or Y 1 and Y 3 together with the nitrogen atom form a 5- to 7- membered heterocycle; Y 3 is hydrogene; C 1 -C 4 alkyl; C 3 -C 4 alkenyl; or C 1 -C 4 alkyl, C 3 -C 4 alkenyl which is substituted by cyano, hydroxy, C 1 -C 4 alkoxy, phenyl or C 1 -C 4 alkoxycarbonyl; or Y 1 , Y 2 and Y 3 together with the binding nitrogen atom form a pyrrolidine, piperidine or morpholine radical; A is the counter ion; b) 5 to 25% by weight, based on the total weight of the composition of a fabric care ingredient; and c) the remainder being substantially water.
    • 公开了一种织物漂洗组合物,其包含a)0.1至10重量%的选自式(I)的羟基芳基-1,3,5-三嗪的UV吸收剂,其中R 1是氢; C1-C4烷氧基; 或卤素; R2是单-C1-C4烷基氨基; 式(I')的基团; X是C 2 -C 4亚烷基; Y1,Y2彼此独立地是被卤素,氰基羟基或C1-C4烷氧基取代的C1-C4烷基或C1-C4烷基; 或Y1和Y2或Y1和Y3与氮原子一起形成5-至7-元杂环; Y3是氢原子; C 1 -C 4烷基; C3-C4烯基; 或C 1 -C 4烷基,被氰基,羟基,C 1 -C 4烷氧基,苯基或C 1 -C 4烷氧基羰基取代的C 3 -C 4烯基; 或Y1,Y2和Y3与结合氮原子一起形成吡咯烷,哌啶或吗啉基; A是抗衡离子; b)5至25重量%,基于织物护理成分的组合物的总重量; 和c)其余部分基本上是水。