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1. 发明申请

WO2007012611A1 NAPHTHALENE AMIDINE IMIDES 审中-公开
标题翻译：萘胺类胺
公开(公告)号：WO2007012611A1
公开(公告)日：2007-02-01
申请号：PCT/EP2006/064531
申请日：2006-07-21
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , LANGHALS, Heinz , JASCHKE, Harald , EHLIS, Thomas , WALLQUIST, Olof
发明人： LANGHALS, Heinz , JASCHKE, Harald , EHLIS, Thomas , WALLQUIST, Olof
IPC分类号： C09B57/00 , C09B57/08 , C09K11/06 , C07D471/08
CPC分类号： C09B5/62 , C07D471/04
摘要： Disclosed are naphthalinamidinimide of formula (I), wherein R 1 R 2 , R 3 , R 4 , R 5 and R6 independently from each other are hydrogen; or C 1 -C 37 alkyl; wherein - one to 10 of the CH 2 units of C 1 -C 37 alkyl independently from each may be substituted by carbonyl groups; oxygen atoms; sulphur atoms; selenium atoms; tellurium atoms; cis- or trans-CH=CH-groups; acetylenic C≡C- groups; 1 ,2-, 1 ,3- or 1 ,4-substituted phenyl radicals; 2,3-, 2,4-, 2,5-, 2,6-, 3,4- or 3,5-disubstituted pyridine radicals; 2,3- , 2,4-, 2,5- or 3,4-disubstituted thiophene radicals; 1 ,2-, 1 ,3-, 1 ,4-, 1 ,5-, 1 ,6-, 1 ,7-, 1 ,8-, 2,3-, 2,6- or 2,7-disubstituted 1 ,2-, 1 ,3-, 1 ,4-, 1 ,5-, 1 ,6-, 1 ,7-, 1 ,8-, 1 ,9-, 1 ,10-, 2,3-, 2,6-, 2,7-, 2,9-, 2,10- or 9,10-disubstituted anthracene radicals; wherein one or 2 CH-groups of the CH=CH- groups, the naphthalene radicals and the anthracene radicals may be substituted by nitrogen atoms; - up to 12 single hydrogen atoms of the CH 2 -groups independently from each other may be substituted at the same carbon atoms by fluorine; chlorine; bromine; or iodine; the cyano group; a linear alkyl chain with up to 18 carbon atoms; cis- or frans-CH=CH-groups; acetylenic C≡C-groups; 1 ,2-, 1 ,3- or 1 ,4-substituted phenyl radicals; 2,3-, 2,4-, 2,5-, 2,6-, 3,4- or 3,5- disubstituted pyridine radicals; 2,3-, 2,4-, 2,5- or 3,4-disubstituted thiophene radicals; 1 ,2-, 1 ,3-, 1 ,4-, 1 ,5-, 1 ,6-, 1 ,7-, 1 ,8-, 2,3-, 2,6- or 2,7-disubstituted naphthalene radicals; 1 ,2-, 1 ,3-, 1 ,4-, 1 ,5-, 1 ,6-, 1 ,7-, 1 ,8-, 1 ,9-, 1 ,10-, 2,3-, 2,6-, 2,7-, 2,9-, 2,10- or 9,10-disubstituted anthracene radicals; wherein up to 6 CH 2 - units in the alkyl chain independently from each other may be substituted by carbonyl groups, oxygen atoms, sulphur atoms, selenium atoms, tellurium atoms and up to 12 single hydrogen atoms of the CH 2 -groups of the alkyl radicals each independently from each other may also be substituted at the same C-atoms by fluorine, chlorine, bromine or iodine or cyano groups or linear alkyl chains with up to 18 carbon atoms, wherein one to 6 CH 2 -units independently from each other may be substituted by carbonyl groups, oxygen atoms, sulphur atoms, selenium atoms, tellurium atoms, cis- or frans-CH=CH-groups, wherein one CH-unit may also be substituted by a nitrogen atom, by acetylenic C≡C-groups, 1 ,2-, 1 ,3- or 1 ,4-substituted phenyl radicals, 2,3-, 2,4-, 2,5-, 2,6-, 3,4- or 3,5-disubstituted pyridine radicals, 2,3-, 2,4-, 2,5- or 3,4-disubstituted thiophene radicals, 1 ,2-, 1 ,3-, 1 ,4-, 1 ,5-, 1 ,6-, 1 ,7-, 1 ,8-, 2,3-, 2,6- or 2,7-disubstituierte naphthalene radicals, wherein one or two carbon atoms may be substituted by nitrogen atoms, by 1 ,2-, 1 ,3-, 1 ,4-, 1 ,5-, 1 ,6-, 1 ,7-, 1 ,8-, 1 ,9-, 1 ,10-, 2,3-, 2,6-, 2,7-, 2,9-, 2,10- or 9,10-di- substituierte anthracene radicals, wherein one or two carbon atoms may be substituted by nitrogen atoms; or instead of substituents the free valencies of the methine- or quarternary carbon atoms may be linked pairwise forming rings like cyclohexane rings; or are an amino radical, if R 1 and R 2 together with the carbon atoms C 1 and C 2 or R 3 and R 4 together with the carbon atoms C 3 and C 4 form a 6-membered radical; R 7 and R 8 , independently from each other are =0; or =NH-, if =NH- together with the nitrogen atom N 1 (for R 6 ) or together with the nitrogen atom N 2 (for R 7 ) forms a five-membered radical. The compounds are useful for different purposes, preferably as UV absorbers for cosmetic applications.
摘要翻译：公开了式（I）的萘胺亚胺，其中R 1 R 2，R 3，R 4，R 5和R6彼此独立地是氢; 或C 1 -C 13烷基; 其中 - 独立地各自独立地具有1至10个C 1 -C 3 - 烷基的CH 2 - 2个单元可以被羰基取代; 氧原子; 硫原子硒原子; 碲原子顺式或反式-CH = CH-基团; 炔属C = C-基团; 1,2或1-3或1,4-取代的苯基; 2,3-，2,4-，2,5-，2,6-，3,4-或3,5-二取代的吡啶基; 2,3-，2,4-，2,5-或3,4-二取代噻吩基; 1,2,1-，1,3-，1,1-，4-，1,5-，1,6-，1,7-，1,8-，2,3，2,6-或2,7-二取代 1,2-，1,3-，1-，4-，1,5-，1,6-，1,7-，1,8-，1,9-，1,10-，2,3-， 2,6-，2,7-，2,9-，2,10-或9,10-二取代的蒽基; 其中CH = CH-基团，萘基和蒽基团的一个或两个CH-基团可以被氮原子取代; - CH 2 - 2个基团多达12个单个氢原子彼此独立地可以被相同的碳原子被氟取代; 氯; 溴; 或碘; 氰基; 具有至多18个碳原子的直链烷基链; 顺式或反式-CH = CH-基团; 炔属C = C - 基; 1,2或1-3或1,4-取代的苯基; 2,3-，2,4-，2,5-，2,6-，3,4-或3,5-二取代吡啶基; 2,3-，2,4-，2,5-或3,4-二取代噻吩基; 1,2,1-，1,3-，1,1-，4-，1,5-，1,6-，1,7-，1,8-，2,3，2,6-或2,7-二取代萘基; 1,2-，1,3-，1-，4-，1,5-，1,6-，1,7-，1,8-，1,9-，1,10-，2,3-， 2,6-，2,7-，2,9-，2,10-或9,10-二取代的蒽基; 其中烷基链中多达6个CH 2 - 单元彼此独立地可被羰基，氧原子，硫原子，硒原子，碲原子和至多12个单氢原子取代烷基的CH 2 - 2个基团各自独立地也可以在相同的C原子上被氟，氯，溴或碘或氰基或具有至多18个碳的直链烷基链取代原子，其中一个至六个CH 2 - 彼此独立地可以被羰基，氧原子，硫原子，硒原子，碲原子，顺式或反式-CH = CH-基团取代其中一个CH-单元也可以被氮原子取代，被炔基C = C - 基，1,2-，1,3-或1,4-取代的苯基，2,3-，，2,5-，2,6-，3,4-或3,5-二取代的吡啶基，2,3-，2,4-，2,5-或3,4-二取代的噻吩基，1,2 - ，1,3 - ，1,4 - ，1,5 - ，1,6 - ，1-7 - ，1,8-，2,3 - ，2,6 - 或2,7-二枯基其中一个或两个碳原子可以被氮原子取代，其中一个或两个碳原子可以被1,2 - ，1,3 - ，1,4 - ，1-5 - ，1-6 - ，1-7 - 8-，1,9-，1,10-，2,3-，2,6-，2,7-，2,9-，2,10-或9,10-二取代的蒽基，其中一个或两个碳原子可以被氮原子取代; 或代替取代基，次甲基或季碳原子的自由价可以成对连接形成环如环己烷环; 或者如果R 1和R 2与碳原子C 1和C 2一起是氨基，或R 3和R 4与碳原子C 3和C 4连接形成6元基团 ; R 7和R 8彼此独立地为= 0; 或= NH-，如果= NH-与氮原子N 1（对于R 6）或与氮原子N 2一起，（R 7 7）形成五元基团。该化合物可用于不同的目的，优选用于化妆品应用的UV吸收剂。

2. 发明申请

WO2006003094A2 MEROCYANINE DERIVATIVES 审中-公开
公开(公告)号：WO2006003094A2
公开(公告)日：2006-01-12
申请号：PCT/EP2005/052850
申请日：2005-06-20
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , WAGNER, Barbara , BIENEWALD, Frank , WOLLEB, Heinz , WALLQUIST, Olof , HERZOG, Bernd , EHLIS, Thomas , HAASE, Jürg
发明人： WAGNER, Barbara , BIENEWALD, Frank , WOLLEB, Heinz , WALLQUIST, Olof , HERZOG, Bernd , EHLIS, Thomas , HAASE, Jürg
IPC分类号： A61K7/42
CPC分类号： A61K8/498 , A61K8/4913 , A61K8/494 , A61Q17/04
摘要： Disclosed is the use of merocyanine derivatives of formula (I), wherein Q is hydrogen; C 1 -C 22 alkyl; -OH; -OR 7 ; -NR 7 R 8 ; or -N=R 9 ; R 1 is hydrogen; C 1 -C 22 alkyl; -OR 7 , -SR 7 ; -NR 7 R 8 ; C 1 -C 22 alkyl; C 2 -C 12 alkenyl; C 2 -C 12 alkinyl; C 3 -C 12 cycloalkyl; C 3 -C 12 cycloalkenyl; C 7 -C 12 aralkyl; C 1 -C 12 heteroalkyl, C 2 -C 11 heteroaralkyl; C 6 -C 10 aryl; or C 1 -C 9 heteroaryl; R 4 is cyano; COR 7 , COOR 7 ; CONR 7 R 8 ; SO 2 (C 6 -C 12 )aryl; C 2 -C 12 alk-1-enyl; C 3 -C 12 cycloalk-1-enyl; C 2 -C 12 alk-1-inyl; C 2 -C 12 heteroalkyl; C 3 -C 5 heterocycloalkyl; C 6 -C 10 aryl; or C 1 -C 9 heteroaryl; R 5 is -COR 7 ; -COOR 7 ; -OR 7 ; -SR 7 , -NHR 7 , -NR 7 R 8 ; C 1 -C 22 alkyl; C 2 -C 12 alkenyl; C 2 -C 12 alkinyl; C 3 -C 12 cycloalkyl; C 3 -C 12 cycloalkenyl; C 7 -C 12 aralkyl; C 1 -C 12 alkylphenyl; C 1 -C 12 alkoxy-C 6 -C 10 aryl; C 1 -C 12 heteroalkyl; C 2 -C 11 heteroaralkyl; C 3 -C 12 cycloheteroalkyl; C 6 -C 10 aryl; C 1 - C 12 alkoxy-C 6 -C 10 aryl; or C 1 -C 9 heteroaryl; R 6 is hydrogen; C 1 -C 22 alkyl; C 1 -C 22 alkoxy; or COR 7 ; R 7 and R 8 independently from each other are hydrogen; C 1 -C 22 alkyl; C 2 -C 12 alkenyl; C 2 -C 12 alkinyl; C 3 -C 12 cycloalkyl; C 3 -C 12 cycloalkenyl; -(CH 2 ) t COOH; C 7 -C 12 aralkyl; C 1 -C 12 heteroalkyl; C 2 -C 11 heteroaralkyl; C 6 -C 10 aryl; C 1 -C 9 heteroaryl; Si-R 10 R 11 R 12 ; Si(OR 10 )(OR 11 )(OR 12 ); SiR 10 (OR 11 )(OR 12 ); SiR 10 R 11 (OR 12 ); -(CH 2 ) u -O-(CH 2 ) v -SiR 10 R 11 R 12 ; or a radical X-Sil; t, u and v, independently from each other are a number from 1 to 5; R 9 is a (C 1 -C 6 )alkylidene radical; R 10 , R 11 , R 12 independently form each other are C 1 -C 22 alkyl; X is a linker; Sil is a silane-, oligosiloxane- or polysiloxane radical; R 1 and R 2 , R 1 and Q, R 1 and R 6 , R 1 and T, R 2 and R 3 , R 2 and R 4 , R 2 and R 6 , R 2 and Q, R 4 and R 6 , R 4 and T, R 6 and Q, T and Q, each independently, are linked together, so that 1, 2, 3 or 4 carbocyclic or N, O and/or S-heterocyclic rings are formed, wherein each of them, independently from each other, may be condensed with an aromatic or heteroaromatic ring, and/or more N-, O- and/or S-heterocyclic rings, and each N atom in a N-heterocyclic ring may be substituted by C 1 -C 22 alkyl; n is a number from 1 to 4; wherein at least one of the radicals R 1 , R 6 or Q is different from hydrogen; if n = 1 T is -COR 5 ; -CN; C 6 -C 10 aryl; -NHR 5 ; or -SO 2 -(C 6 -C 12 )aryl; R 2 and R 3 independently from each other are C 1 -C 22 alkyl; hydroxy-C 1 -C 22 alkyl; C 2 -C 12 alkenyl; C 2 -C 12 alkinyl; C 3 -C 12 cycloalkyl, C 3 -C 12 cycloalkenyl; C 7 -C 12 aralkyl; C 1 -C 12 heteroalkyl; C 3 -C 12 cycloheteroalkyl; C 6 -C 10 aryl; C 1 -C 9 heteroaryl; or a radical of formula (II); p is a number from 5 to 100; q is a number from 1 to 5; s is a number from 0 to 4; if n = 2 R 2 and R 3 are each C 1 -C 5 alkylene; and simultaneously T is defined as for n = 1; or T is a bivalent radical of formula -NR 7 -V-NR 7 -, wherin V is phenylene; or C 1 -C 5 alkylene; R 7 is hydrogen; or C 1 -C 5 alkyl; and R 2 and R 3 simultaneously are defined as for n = 1; if n = 3 one of R 2 , R 3 or T is a trivalent radical; if n = 4 one of R 2 , R 3 or T is a tetravalent radical; for protecting of human hair and skin against the damaging effect of UV radiation.

3. 发明申请

WO2007128744A3 TRIAZINE DERIVATIVES 审中-公开
公开(公告)号：WO2007128744A3
公开(公告)日：2007-11-15
申请号：PCT/EP2007/054239
申请日：2007-05-02
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , EHLIS, Thomas , BORSOS, Elek
发明人： EHLIS, Thomas , BORSOS, Elek
IPC分类号： C07D251/52 , C07D251/70 , A61Q17/04
摘要： Disclosed are triazine derivatives of formula (1), wherein X 1 is a bivalent radical of formula (1a) -NR 9 -A-NR 9 -; (1b); or (1c) *-O-A-O-* A and A' independently from each other are unsubstituted or substituted, straight-chain or branched C 1 -C 12 alkylene, which is optionally interrupted by C 5 -C 12 cycloalkylene, N, O or S; C 5 -C 12 cycloalkylene; biphenylene; C 6 -C 10 arylene; or C 5 -C 10 arylene-(C 1 -C 12 alkylene); R 1 is a radical of formula (1d); (1e); (1f); (1g); or (1h); R 2 and R 3 independently from each other are hydrogen; C 1 -C 12 alkyl; OR 7 ; NR 7 R 8 ; C 6 -C 10 aryl; X 2 is O, or NH; W 1 is C 1 -C 20 alkyl; or a group Sp-Sil; Sp is a straight-chain or branched saturated or single or multiple unsaturated C 3 -C 12 hydrocarbon; Sil is a silane; an oligosiloxane; or a polysiloxane moiety; and R 4 , R 5 R 6 , R 7 , R 8 and R 9 independently from each other are hydrogen; C 1 -C 12 alkyl; or C 3 -C 12 cycloalkyl.

4. 发明申请

WO2007093513A1 AROMATIC SULPHONATE FLAME RETARDANT COMPOSITIONS 审中-公开
标题翻译：芳香磺化阻燃剂组合物
公开(公告)号：WO2007093513A1
公开(公告)日：2007-08-23
申请号：PCT/EP2007/051058
申请日：2007-02-05
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , BREINER, Christine , EHLIS, Thomas , HOCHBERG, Robert , KNIESEL, Simon
发明人： BREINER, Christine , EHLIS, Thomas , HOCHBERG, Robert , KNIESEL, Simon
IPC分类号： C08K5/42 , C08K5/00 , C08L69/00 , C08K5/3475 , C08K5/13 , C08K5/353
CPC分类号： C08K5/45 , C08K5/42 , C08L69/00 , C08L2666/18
摘要： The invention relates to flame retardant compositions, wherein salts of selected aromatic sulphonic acids are present in a polycarbonate substrate. The compositions attain the desirable V-0 rating, according to UL-94 (Underwriter's Laboratories Subject 94) and other excellent ratings in related test methods while preserving the excellent mechanical, chemical and thermal properties of polycarbonates, such as light transparency.
摘要翻译：本发明涉及阻燃组合物，其中选择的芳族磺酸的盐存在于聚碳酸酯底物中。根据UL-94（Underwriter's Laboratories Subject 94）和相关测试方法中的其它优异等级，组合物达到所需的V-0等级，同时保持聚碳酸酯的优异的机械，化学和热性能，例如光透明度。

5. 发明申请

WO2004006878A1 MEROCYANINE DERIVATIVES FOR COSMETIC USE 审中-公开
标题翻译：用于化妆品使用的MEROCANANINE衍生物
公开(公告)号：WO2004006878A1
公开(公告)日：2004-01-22
申请号：PCT/EP2003/006955
申请日：2003-07-01
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , WAGNER, Barbara , EHLIS, Thomas , EICHIN, Kai
发明人： WAGNER, Barbara , EHLIS, Thomas , EICHIN, Kai
IPC分类号： A61K7/42
CPC分类号： C07D239/54 , A61K8/4906 , A61Q17/04 , C07C255/30 , C07C255/31 , C07C2601/16 , C07D207/20 , C07D231/36 , C07D263/14 , C07D277/10 , C07D295/145 , C07D295/155 , C07D319/06
摘要： The use is described of merocyanine derivatives of formula (1), wherein R 1 and R 2 are each independently of the other hydrogen; C 1 -C 22 alkyl; cyclo-C 3 C 8 alkyl; or unsubstituted or C 1 -C 5 alkyl- or C 1 -C 5 alkoxy-substituted C 6 -C 20 aryl; orl; or R 1 and R 2 together with the nitrogen atom linking them form a -(CH 2 ) m - ring which is uninterrupted or. interrupted by -O- or by -NH-; R 3 is a cyano group; -COOR 5 ; -CONHR 5 ; -COR 5 ; or -SO 2 R 5 ; R 4 is a cyano group; -COOR 6 ; -CONHR 6 ; -COR 6 ; or -SO 2 R 6 ; R 5 and R 6 are each independently of the other C 1 -C 22 alkyl; or unsubstituted or C 1 -C 5 alkyl substituted C 6 -C 20 aryl; or R 3 and R 4 together or R 5 and R 6 together form a 5- to 7-membered, monocyclic, carbocyclic or heterocyclic ring; Z 1 , and Z 2 are each independently of the other a -(CH 2 ),- group which is uninterrupted or interrupted by -O-, -S-, or by -NR 7 -, and/or is unsubstituted or substituted by C, 1 -C 5 alkyl; R 7 is C 1 C 5 alkyl; I is from 1 to 4; m is from 1 to 7; n is from 1 to 4; when n = 2, R 1 , R 5 or R 6 is a bivalent alkyl group; or R 1 , and R 2 together with the 2 nitrogen atoms linking them form a -(CH 2 ) m - ring; when n = 3, R 1 , R 5 or R 6 is a trivalent alkyl group; when n = 4, R 1 , R 5 or R 6 is a tetravalent alkyl group; and R 1 , and R 2 in formula (1) are not simultaneously hydrogen, in protecting human and animal hair and skin from UV radiation.
摘要翻译：描述了式（1）的部花青衍生物，其中R 1和R 2各自独立地为氢; C1-C22烷基; 环C3C8alkyl; 或未取代的或C 1 -C 5烷基 - 或C 1 -C 5烷氧基取代的C 6 -C 20芳基; ORL; 或R 1和R 2与连接它们的氮原子一起形成不间断的 - （CH 2）m - 环。被-O-或-NH-中断; R3是氰基; -COOR5; -CONHR5; -COR5; 或-SO 2 R 5; R4是氰基; -COOR6; -CONHR6; -COR 6; 或-SO 2 R 6; R 5和R 6各自独立地为C 1 -C 22烷基; 或未取代的或C 1 -C 5烷基取代的C 6 -C 20芳基; 或R 3和R 4一起或R 5和R 6一起形成5-至7-元单环，碳环或杂环; Z 1和Z 2各自独立地为不间断或被-O - ， - S-或-NR 7 - 间隔的另一个 - （CH 2） - 基，和/或未取代或被C 1〜 C 5烷基; R7是C1C5烷基; 我是从1到4; m为1〜7; n为1至4; 当n = 2时，R 1，R 5或R 6为二价烷基; 或R 1和R 2与连接它们的2个氮原子一起形成 - （CH 2）m - 环; 当n = 3时，R 1，R 5或R 6为三价烷基; 当n = 4时，R 1，R 5或R 6为四价烷基; 式（1）中的R 1和R 2不同时为氢，以保护人和动物的头发和皮肤免受UV辐射。

6. 发明申请

WO2007071584A2 USE OF TRANSMISSION DYES 审中-公开
标题翻译：使用传染性染色体
公开(公告)号：WO2007071584A2
公开(公告)日：2007-06-28
申请号：PCT/EP2006/069519
申请日：2006-12-11
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , MÜLLER, Stefan , HAASE, Jürg , EHLIS, Thomas , KREYER, Gilbert , GIESINGER, Jochen , VOGT, Martin
发明人： MÜLLER, Stefan , HAASE, Jürg , EHLIS, Thomas , KREYER, Gilbert , GIESINGER, Jochen , VOGT, Martin
CPC分类号： C07D295/192 , A61K8/411 , A61K8/42 , A61K8/49 , A61K8/494 , A61K2800/43 , A61Q17/04
摘要： Disclosed is the use of an aqueous dispersion comprising (a) a micronized sparingly soluble organic compound which has a UV-Vis spectrum with a maximum from 380 to 420 nm; and (b) an anionic dispersing agent for protecting the human skin from browning and skin aging.
摘要翻译：公开了包含（a）微波化的微溶有机化合物的水分散体的使用，其具有最大值为380至420nm的UV-Vis光谱; 和（b）用于保护人体皮肤免于褐变和皮肤老化的阴离子分散剂。

7. 发明申请

WO2005058269A1 MEROCYANINE DERIVATIVES FOR COSMETIC USE 审中-公开
标题翻译：用于化妆品使用的MEROCANANINE衍生物
公开(公告)号：WO2005058269A1
公开(公告)日：2005-06-30
申请号：PCT/EP2004/053327
申请日：2004-12-08
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , WAGNER, Barbara , EHLIS, Thomas , MÜLLER, Stefan
发明人： WAGNER, Barbara , EHLIS, Thomas , MÜLLER, Stefan
IPC分类号： A61K7/42
CPC分类号： C07D295/116 , A61K8/41 , A61K8/44 , A61K8/46 , A61K8/494 , A61K8/81 , A61Q17/00 , A61Q17/02 , C07C225/20 , C07C229/46 , C07C255/31 , C07C317/48 , C07C2601/14 , C07C2601/16 , C07D295/155
摘要： Described are merocyanine derivatives of formula (1a) or (1b) wherein n and o are integers from 2 to 4 and aminocyclohexenone intermediates. They are used in protecting human and animal hair and skin from UV radiation.
摘要翻译：描述的是式（1a）或（1b）的部花青衍生物，其中n和o是2-4的整数和氨基环己烯酮中间体。它们用于保护人体和动物的毛发和皮肤免受紫外线辐射。

8. 发明申请

WO2004085412A2 SYMMETRICAL TRIAZINE DERIVATIVES 审中-公开
标题翻译：对称TRIAZINE衍生物
公开(公告)号：WO2004085412A2
公开(公告)日：2004-10-07
申请号：PCT/EP2004/050331
申请日：2004-03-19
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , EHLIS, Thomas , MÜLLER, Stefan , HAYOZ, Pascal
发明人： EHLIS, Thomas , MÜLLER, Stefan , HAYOZ, Pascal
IPC分类号： C07D251/24
CPC分类号： C07D251/24 , A61K8/4966 , A61Q17/04
摘要： Disclosed is the use of the compounds of formula wherein A is a radical of formula (1a) or (1b) R, R 1 and R 5 independently from each other are hydrogen; C 1 -C 18 alkyl; or C 6 -C 12 aryl; R 2 , R 3 and R 4 independently from each other are hydrogen; or a radical of formula wherein at least one of the radicals R 2 , R 3 and R 4 are a radical of formula (1c); R 6 , R 7 , R 8 , R 9 and R 10 independently from each other are hydrogen; hydroxy; C 1 -C 18 alkyl; C 1 -C 18 alkoxy;C 6 -C 12 aryl; C 6 -C 12 aryloxy; C 1 -C 18 alkylthio; carboxy; -COOM; C 1 -C 18 alkylcarboxyl; aminocarbonyl; or mono- or di-C 1 -C 18 alkylamino; M is an alkali metal ion; x is 1 or 2; and y is a number from 2 to 10; for the protection of human and animal hair and skin against the damaging effect of UV radiation. The compounds of formula (1) are high effective UV absorbers for cosmetic formulations aund can - depending on their physical properties - be used in micronized or soluble form.
摘要翻译：公开了下式化合物的用途其中A是式（1a）或（1b）的基团，R，R 1和R 5彼此独立地是氢; C1-C18烷基; 或C6-C12芳基; R2，R3和R4彼此独立地是氢; 或下式的基团，其中基团R 2，R 3和R 4中的至少一个为式（1c）的基团; R 6，R 7，R 8，R 9和R 10彼此独立地为氢; 羟基; C1-C18烷基; C1-C18烷氧基; C 6 -C 12芳基; C6-C12aryloxy; C1-C18alkylthio; 羧基; -COOM; C1-C18alkylcarboxyl; 羰基; 或单或二C1-C18烷基氨基; M是碱金属离子; x为1或2; y为2〜10的数; 用于保护人体和动物毛发和皮肤免受紫外线辐射的破坏作用。式（1）的化合物是用于化妆品制剂的高效紫外线吸收剂，可根据其物理性质 - 以微粉化或可溶形式使用。

9. 发明申请

WO2003086341A3 AMINOPHENYLBENZOTHIAZOLE COMPOUNDS 审中-公开
公开(公告)号：WO2003086341A3
公开(公告)日：2003-10-23
申请号：PCT/EP2003/003870
申请日：2003-04-14
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , WAGNER, Barbara , EHLIS, Thomas , MONGIAT, Sébastien , EICHIN, Kai
发明人： WAGNER, Barbara , EHLIS, Thomas , MONGIAT, Sébastien , EICHIN, Kai
IPC分类号： C07D277/66
摘要： The Use, as a UV filter, of a compound of formula (I), wherein R 1 and R 2 are each independently of the other hydrogen; unsubstituted or halo-, amino-, mono- or di-C 1 -C 5 alkylamino-, cyano- or C 1 -C 5 alkoxy-substituted C 1 -C 22 alkyl, C 5 -C 10 cycloalkyl, carboxy-C 1 -C 22 alkyl, carboxy-C 6 -C 10 aryl, C 6 -C 10 aryl, C 6 -C 10 aryl-C 1 -C 5 alkyl; carbamoyl; or sulfamoyl; or R 1 and R 2 , together with the nitrogen atom linking them, form a 5- to 7-membered heterocyclic radical; and R 3 is hydrogen; or C 1 -C 22 alkyl; and R 4 is hydrogen; hydroxy; C 1 -C 22 alkyl; or C 1 -C 22 alkoxy; is described. The compounds of formula (I) are suitable especially as UV filters in cosmetic preparations.

10. 发明申请

WO2003075875A1 UV ABSORBER COMPOSITIONS COMPRISING A HYDROXYPHENYLTRIAZINE COMPOUND 审中-公开
标题翻译：含有羟基苯乙烯化合物的紫外线吸收剂组合物
公开(公告)号：WO2003075875A1
公开(公告)日：2003-09-18
申请号：PCT/EP2003/002200
申请日：2003-03-04
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , HAASE, Jürg , EHLIS, Thomas , BORSOS, Elek , HÜGLIN, Dietmar , HERZOG, Bernd
发明人： HAASE, Jürg , EHLIS, Thomas , BORSOS, Elek , HÜGLIN, Dietmar , HERZOG, Bernd
IPC分类号： A61K7/42
CPC分类号： A61K8/4966 , A61Q17/04
摘要： UV absorber compositions are described, comprising (a) from 1 to 99 % by weight of a hydroxyphenyltriazine compound of formula (I) wherein R 1 , R 2 and R 3 are each independently of the others C 1 -C 18 alkyl; C 2 -C 10 ,alkenyl; or phenyl-C,-C 4 alkyl; R 4 is hydrogen; or C 1 -C 5 alkyl; and (b) from 99 to 1 % by weight of a further UV absorber selected from the group of (b) hydroxyphenyltriazines that are different from component (a), (b 2 ) benzotriazoles, (b 3 ) dibenzoylmethane derivatives and (b 4 ) camphor derivatives. The compositions are suitable as UV filters in cosmetic compositions.
摘要翻译：描述了紫外线吸收剂组合物，其包含（a）1至99重量％的式（I）的羟基苯基三嗪化合物，其中R 1，R 2和R 3各自独立地为C 1 -C 18烷基; C2-C10烯基; 或苯基-C 1 -C 4烷基; R4是氢; 或C 1 -C 5烷基; 和（b）99重量％至1重量％的另外的紫外线吸收剂，其选自（b）不同于组分（a），（b 2）苯并三唑，（b3）二苯甲酰甲烷衍生物和（b4）樟脑）的羟苯基三嗪衍生物。该组合物适用于化妆品组合物中的UV过滤器。

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