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1. 发明申请

WO2011011492A2 DECARBOXYLATION CELL FOR PRODUCTION OF COUPLED RADICAL PRODUCTS 审中-公开
标题翻译：用于生产偶联产物的脱羧单元
公开(公告)号：WO2011011492A2
公开(公告)日：2011-01-27
申请号：PCT/US2010042715
申请日：2010-07-21
申请人： CERAMATEC INC , BHAVARAJU SAI , KARANJIKAR MUKUND , JOSHI ASHOK , HUNT JOEL , CHITTA PALLAVI
发明人： BHAVARAJU SAI , KARANJIKAR MUKUND , JOSHI ASHOK , HUNT JOEL , CHITTA PALLAVI
IPC分类号： C25B9/08 , C07C1/207 , C25B3/10
CPC分类号： C25B3/10 , C25B9/08
摘要： An electrolytic cell produces coupled radical products. The method involves obtaining a carboxylic acid material from biomass and converting it into an alkali metal salt. The alkali metal salt is then used in an anolyte as part of an electrolytic cell. The electrolytic cell may include an alkali ion conducting membrane (such as a NaSICON membrane). When the cell is operated, the alkali metal salt of the carboxylic acid decarboxylates and forms radicals. Such radicals are then bonded to other radicals, thereby producing a coupled radical product such as a hydrocarbon. The produced hydrocarbon may be, for example, saturated, unsaturated, branched, or unbranched, depending upon the starting material.
摘要翻译：电解池产生偶联的自由基产物。该方法包括从生物质获得羧酸物质并将其转化为碱金属盐。然后将碱金属盐用作阳极电解液作为电解池的一部分。电解池可以包括碱离子传导膜（例如NaSICON膜）。当电池操作时，羧酸的碱金属盐脱羧并形成自由基。然后将这些基团与其它基团键合，由此产生偶联的基团产物如烃。取决于起始原料，生成的烃可以是例如饱和的，不饱和的，支链的或非支链的。

2. 发明申请

WO2011011521A3 METHOD OF PRODUCING COUPLED RADICAL PRODUCTS 审中-公开
标题翻译：生产偶联产品的方法
公开(公告)号：WO2011011521A3
公开(公告)日：2011-05-05
申请号：PCT/US2010042756
申请日：2010-07-21
申请人： CERAMATEC INC , BHAVARAJU SAI , KARANJIKAR MUKUND , JOSHI ASHOK , HUNT DAVID , CHITTA PALLAVI
发明人： BHAVARAJU SAI , KARANJIKAR MUKUND , JOSHI ASHOK , HUNT DAVID , CHITTA PALLAVI
IPC分类号： C10K3/00 , C25B3/06
CPC分类号： C25B9/08 , C10G3/00 , C10G2300/1011 , C10G2300/44 , C25B3/10 , Y02P30/20
摘要： A method that produces coupled radical products. An alkali metal salt is used in an anolyte as part of an electrolytic cell. The electrolytic cell may include an alkali ion conducting membrane (such as a NaSICON membrane). When the cell is operated, the alkali metal salt of the carboxylic acid decarboxylates and forms radicals. Such radicals are then bonded to other radicals, thereby producing a coupled radical product such as a hydrocarbon.
摘要翻译：一种产生偶联产物的方法。在阳极电解液中使用碱金属盐作为电解池的一部分。电解池可以包括碱离子传导膜（例如NaSICON膜）。当电池操作时，羧酸的碱金属盐脱羧并形成自由基。然后将这些基团与其它基团键合，由此产生偶联的基团产物如烃。

3. 发明申请

WO2011011537A2 METHOD OF PRODUCING COUPLED RADICAL PRODUCTS FROM BIOMASS 审中-公开
标题翻译：从生物质生产耦合自由基产物的方法
公开(公告)号：WO2011011537A2
公开(公告)日：2011-01-27
申请号：PCT/US2010042780
申请日：2010-07-21
申请人： CERAMATEC INC , KARANJIKAR MUKUND , BHAVARAJU SAI , JOSHI ASHOK , CHITTA PALLAVI , HUNT DAVID
发明人： KARANJIKAR MUKUND , BHAVARAJU SAI , JOSHI ASHOK , CHITTA PALLAVI , HUNT DAVID
IPC分类号： C25B3/10 , C07C1/207 , C25B9/08
CPC分类号： C10G3/40 , C10G3/45 , C10G3/47 , C10G3/50 , C10G2300/1014 , C10G2300/1018 , C10G2300/44 , C10G2400/04 , C12P7/54 , C25B3/00 , C25B3/10 , C25B9/08 , Y02E50/343 , Y02P30/20
摘要： A method that produces coupled radical products from biomass. The method involves obtaining a lipid or carboxylic acid material from the biomass. This lipid material or carboxylic acid material is converted into an alkali metal salt. The alkali metal salt is then used in an anolyte as part of an electrolytic cell. The electrolytic cell may include an alkali ion conducting membrane (such as a NaSICON membrane). When the cell is operated, the alkali metal salt of the carboxylic acid decarboxylates and forms radicals. Such radicals are then bonded to other radicals, thereby producing a coupled radical product such as a hydrocarbon.
摘要翻译：一种从生物质产生偶联自由基产物的方法。该方法涉及从生物质获得脂质或羧酸材料。该脂质材料或羧酸材料被转化为碱金属盐。然后将碱金属盐用于阳极电解液中作为电解池的一部分。电解池可以包括碱离子传导膜（例如NaSICON膜）。当电池运行时，羧酸的碱金属盐脱羧并形成自由基。然后将这些基团键合到其他基团上，由此产生偶联的自由基产物如烃。

4. 发明申请

WO2011011521A2 METHOD OF PRODUCING COUPLED RADICAL PRODUCTS 审中-公开
标题翻译：生产偶联产品的方法
公开(公告)号：WO2011011521A2
公开(公告)日：2011-01-27
申请号：PCT/US2010042756
申请日：2010-07-21
申请人： CERAMATEC INC , BHAVARAJU SAI , KARANJIKAR MUKUND , JOSHI ASHOK , HUNT DAVID , CHITTA PALLAVI
发明人： BHAVARAJU SAI , KARANJIKAR MUKUND , JOSHI ASHOK , HUNT DAVID , CHITTA PALLAVI
IPC分类号： C10K3/00 , C25B3/06
CPC分类号： C25B9/08 , C10G3/00 , C10G2300/1011 , C10G2300/44 , C25B3/10 , Y02P30/20
摘要： A method that produces coupled radical products. An alkali metal salt is used in an anolyte as part of an electrolytic cell. The electrolytic cell may include an alkali ion conducting membrane (such as a NaSICON membrane). When the cell is operated, the alkali metal salt of the carboxylic acid decarboxylates and forms radicals. Such radicals are then bonded to other radicals, thereby producing a coupled radical product such as a hydrocarbon.
摘要翻译：一种产生耦合自由基产物的方法。碱金属盐在阳极电解液中用作电解槽的一部分。电解池可以包括碱离子传导膜（例如NaSICON膜）。当电池运行时，羧酸的碱金属盐脱羧并形成自由基。然后将这些基团键合到其他基团上，由此产生偶联的自由基产物如烃。

5. 发明申请

WO2012103135A3 PRODUCTION OF FUEL FROM CHEMICALS DERIVED FROM BIOMASS 审中-公开
标题翻译：由生物质衍生的化学品生产燃料
公开(公告)号：WO2012103135A3
公开(公告)日：2012-11-22
申请号：PCT/US2012022425
申请日：2012-01-24
申请人： CERAMATEC INC , BHAVARAJU SAI , KARANJIKAR MUKUND
发明人： BHAVARAJU SAI , KARANJIKAR MUKUND
IPC分类号： C10G3/00 , B09B3/00 , C08B37/00 , C10L1/16
CPC分类号： C25B9/08 , C07C51/00 , C07C51/09 , C07C51/41 , C07C51/412 , C10L1/02 , C25B3/00 , C25B3/02 , Y02E50/13 , Y02P30/20 , C07C59/185 , C07C53/126 , C07C59/125
摘要： Hydrocarbons may be formed from six carbon sugars. This process involves obtaining a quantity of a hexose sugar. The hexose sugar may be derived from biomass. The hexose sugar is reacted to form an alkali metal levulinate, an alkali metal valerate, an alkali metal 5-hydroxy pentanoate, or an alkali metal 5-alkoxy pentanoate. An anolyte is then prepared for use in a electrolytic cell. The anolyte contains the alkali metal levulinate, the alkali metal valerate, the alkali metal 5-hydroxy pentanoate, or the alkali metal 5-alkoxy pentanoate. The anolyte is then decarboxylated. This decarboxylating operates to decarboxylate the alkali metal levulinate, the alkali metal valerate, the alkali metal 5-hydroxy pentanoate, or the alkali metal 5-alkoxy pentanoate to form radicals, wherein the radicals react to form a hydrocarbon fuel compound.
摘要翻译：碳氢化合物可以由六种碳糖形成。这个过程涉及获得一定数量的己糖。己糖可以来源于生物质。己糖反应形成碱金属乙酰丙酸盐，碱金属戊酸盐，碱金属5-羟基戊酸盐或碱金属5-烷氧基戊酸盐。然后制备用于电解池的阳极电解液。阳极电解液含有碱金属乙酰丙酸盐，碱金属戊酸盐，碱金属5-羟基戊酸盐或碱金属5-烷氧基戊酸盐。然后将阳极电解液脱羧。该脱羧作用是使碱金属乙酰丙酸盐，碱金属戊酸盐，碱金属5-羟基戊酸盐或碱金属5-烷氧基戊酸盐脱羧生成自由基，其中自由基反应形成烃燃料化合物。

6. 发明申请

WO2011133906A3 ELECTROCHEMICAL SYNTHESIS OF ARYL-ALKYL SURFACTANT PRECURSOR 审中-公开
标题翻译： ARYL-ALKYL表面活性剂前体的电化学合成
公开(公告)号：WO2011133906A3
公开(公告)日：2012-04-05
申请号：PCT/US2011033636
申请日：2011-04-22
申请人： CERAMATEC INC , BHAVARAJU SAI , KARANJIKAR MUKUND
发明人： BHAVARAJU SAI , KARANJIKAR MUKUND
IPC分类号： C25B3/04 , C25B3/00
CPC分类号： C25B3/10 , C25B9/08 , Y02E60/366
摘要： An aryl-alkyl (R-Ar) hydrocarbon is prepared by an electrosynthesis process in an electrolytic cell (100) having an alkali ion conductive membrane (110) positioned between an anolyte compartment (112) configured with an anode (116) and a catholyte compartment (114) configured with a cathode (118). An anolyte solution (124) containing an alkali metal salt of an alkyl carboxylic acid (128) and an aryl compound (130) is introduced into the anolyte compartment (112). The aryl compound (130) may include an alkali metal salt of an aryl carboxylic acid, an arene (aromatic) hydrocarbon, or an aryl alkali metal adduct (Ar- M+). The anolyte solution (124) undergoes electrolytic decarboxylation to form an alkyl radical. The alkyl radical reacts with the aryl compound to produce the aryl-alkyl hydrocarbon.
摘要翻译：在具有位于阳极（116）的阳极电解液室（112）和阴极电解液（116）之间的碱金属离子传导膜（110）的电解槽（100）中，通过电合成工艺制备芳基 - 烷基（R-Ar）隔室（114）配置有阴极（118）。将含有烷基羧酸（128）和芳基化合物（130）的碱金属盐的阳极电解液（124）引入阳极电解液室（112）中。芳基化合物（130）可以包括芳基羧酸的碱金属盐，芳烃（芳族）烃或芳基碱金属加合物（Ar-M +）。阳极电解液（124）进行电解脱羧以形成烷基。烷基与芳基化合物反应生成芳基 - 烷基烃。

7. 发明申请

WO2012106468A2 NICKEL-METAL HYDRIDE/HYDROGEN HYBRID BATTERY USING ALKALI ION CONDUCTING SEPARATOR 审中-公开
标题翻译：使用碱性离子导体分离器的镍 - 金属氢化物/氢混杂电池
公开(公告)号：WO2012106468A2
公开(公告)日：2012-08-09
申请号：PCT/US2012023541
申请日：2012-02-01
申请人： CERAMATEC INC , JOSHI ASHOK , GORDON JOHN , BHAVARAJU SAI
发明人： JOSHI ASHOK , GORDON JOHN , BHAVARAJU SAI
IPC分类号： H01M12/06 , H01M2/14 , H01M10/39
CPC分类号： H01M2/1646 , H01M2/166 , H01M10/30 , H01M10/345 , H01M12/08 , Y02E60/124 , Y02E60/128
摘要： A nickel-metal hydride (hydrogen) hybrid storage battery comprising a positive electrode containing nickel hydroxide, a combination negative electrode containing a hydrogen storage alloy electrode and a reversible hydrogen electrode, an alkaline electrolyte, and an alkali conducting separator disposed between the positive electrode and the negative electrode. The alkali conducting separator may be a substantially non-porous ion conducting material wherein the alkali conducted is Na, K, or Li. A method of charging and discharging such a hybrid battery is also disclosed.
摘要翻译：一种镍氢（氢）混合蓄电池，包括含有氢氧化镍的正极，含有储氢合金电极和可逆氢电极的组合负极，碱性电解质以及设置在正极和负极之间的碱性导电分隔体负极。碱传导隔板可以是基本无孔的离子传导材料，其中传导的碱是Na，K或Li。还公开了一种对这种混合电池进行充电和放电的方法。

8. 发明申请

WO2012048280A3 ELECTROCHEMICAL SYSTEMS AND METHODS FOR OPERATING ELECTROCHEMICAL CELL WITH AN ACIDIC ANOLYTE 审中-公开
标题翻译：电化学系统和电化学电池操作方法
公开(公告)号：WO2012048280A3
公开(公告)日：2012-07-26
申请号：PCT/US2011055458
申请日：2011-10-07
申请人： CERAMATEC INC , BHAVARAJU SAI , JOSHI ASHOK
发明人： BHAVARAJU SAI , JOSHI ASHOK
IPC分类号： C25B9/08 , C25B1/24 , C25B13/04
CPC分类号： C25B9/08 , C02F1/4674 , C02F2001/46138 , C02F2001/46185 , C02F2101/101 , C02F2201/46115 , C02F2201/46135 , C02F2201/4618 , C02F2209/06 , C25B1/10 , C25B3/00 , C25B15/02 , C25B15/08 , Y02E60/366
摘要： An electrochemical cell (50) having a cation-conductive ceramic membrane (56) and an acidic anolyte. Generally, the cell (50) includes a catholyte compartment (54) and an anolyte compartment (52) that are separated by a cation-conductive membrane (56). While the catholyte compartment (54) houses a primary cathode (60), the anolyte compartment (52) houses an anode (58) and a secondary cathode (62). In some cases, a current is passed through the electrodes to cause the secondary cathode (62) to evolve hydrogen gas. In other cases, hydrogen peroxide is channeled between the secondary cathode (62) and the membrane (56) to form hydroxyl ions. In yet other cases, the cell (50) includes a diffusion membrane disposed between the secondary cathode (62) and the anode (58). In each of the aforementioned cases, the cell functions to maintain the pH of a fluid contacting the membrane (56) at an acceptably high level.
摘要翻译：具有阳离子导电陶瓷膜（56）和酸性阳极电解液的电化学电池（50）。通常，电池（50）包括由阳离子导电膜（56）分离的阴极电解液室（54）和阳极电解液室（52）。当阴极电解液隔室（54）容纳主阴极（60）时，阳极电解液室（52）容纳阳极（58）和次级阴极（62）。在一些情况下，电流通过电极以使次级阴极（62）放出氢气。在其他情况下，过氧化氢被引导在次级阴极（62）和膜（56）之间以形成羟基离子。在其他情况下，电池（50）包括设置在次级阴极（62）和阳极（58）之间的扩散膜。在上述每种情况下，电池用于将接触膜（56）的流体的pH保持在可接受的高水平。

9. 发明申请

WO2009097445A3 ZINC ANODE BATTERY USING ALKALI ION CONDUCTING SEPARATOR 审中-公开
标题翻译： ZINC阳极电池使用碱性离子导电分离器
公开(公告)号：WO2009097445A3
公开(公告)日：2009-10-15
申请号：PCT/US2009032458
申请日：2009-01-29
申请人： CERAMATEC INC , JOSHI ASHOK , GORDON JOHN , BHAVARAJU SAI
发明人： JOSHI ASHOK , GORDON JOHN , BHAVARAJU SAI
IPC分类号： H01M2/16 , H01M2/18 , H01M4/24 , H01M10/28 , H01M10/36
CPC分类号： H01M10/36 , C04B35/447 , C04B2235/3203 , C04B2235/3217 , C04B2235/3232 , H01M10/39
摘要： A zinc anode storage battery (50) comprising a first electrode (54) containing zinc or a zinc alloy, a second electrode (52) containing an oxidizing material capable of electrochemical reduction by zinc, an alkaline electrolyte, and a substantially non-porous, alkali-ion conducting separator (56) provided between the first electrode (54) and the second electrode (52). The alkali conducting separator (56) may be a solid alkali metal ion super ion conducting material, wherein the alkali metal is Na, K, or Li.
摘要翻译：一种锌阳极蓄电池（50），包括含有锌或锌合金的第一电极（54），含有能够通过锌电化学还原的氧化材料的第二电极（52），碱性电解质和基本上无孔的，设置在第一电极（54）和第二电极（52）之间的碱离子传导分离器（56）。碱性导电分离器（56）可以是固体碱金属离子超离子导电材料，其中碱金属是Na，K或Li。

10. 发明申请

WO2011123817A3 PRODUCTION OF ALKALI BICARBONATE AND ALKALI HYDROXIDE FROM ALKALI CARBONATE IN AN ELECTROLYTIC CELL 审中-公开
标题翻译：在电解槽中从碱式碳酸钙生产碱性二碳酸酯和碱金属氢氧化物
公开(公告)号：WO2011123817A3
公开(公告)日：2012-01-26
申请号：PCT/US2011030996
申请日：2011-04-01
申请人： CERAMATEC INC , PENDLETON JUSTIN , JOSHI ASHOK , BHAVARAJU SAI
发明人： PENDLETON JUSTIN , JOSHI ASHOK , BHAVARAJU SAI
IPC分类号： C25B1/18 , C01D7/10 , C07C29/70 , C07C31/28 , C25B3/00
CPC分类号： C25B1/14 , C25B1/16 , C25B3/04 , Y02P20/132
摘要： Alkali bicarbonate is synthesized in an electrolytic cell (100) from alkali carbonate. The electrolytic cell (100) includes an alkali ion conductive membrane (110) positioned between an anolyte compartment (112) configured with an anode (116) and a catholyte compartment (114) configured with a cathode (118). The alkali conductive membrane (110) selectively transports alkali ions (120) and prevents the transport of anions produced in the catholyte compartment. An aqueous alkali carbonate solution is introduced into the anolyte compartment (112) and electrolyzed at the anode (116) to produce carbon dioxide and/or hydrogen ions which react with alkali carbonate to produce alkali bicarbonate. The alkali bicarbonate is recovered by filtration or other separation techniques. When the catholyte solution includes water, pure alkali hydroxide is produced. When the catholyte solution includes methanol, pure alkali methoxide is produced.
摘要翻译：在碱金属碳酸盐的电解池（100）中合成碱金属碳酸氢盐。电解池（100）包括位于由阳极（116）构成的阳极电解液室（112）和配置有阴极（118）的阴极电解液室（114）之间的碱金属离子传导膜（110）。碱性导电膜（110）选择性地输送碱离子（120）并防止在阴极电解液室中产生的阴离子的运输。将碱金属碳酸盐水溶液引入阳极电解液室（112）中并在阳极（116）处电解以产生与碱金属碳酸盐反应产生碱式碳酸氢盐的二氧化碳和/或氢离子。通过过滤或其他分离技术回收碱金属碳酸氢盐。当阴极电解液包含水时，产生纯碱氢氧化物。当阴极电解液包含甲醇时，产生纯碱金属甲醇盐。

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