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    • 2. 发明申请
    • METAL NANOSTRUCTURED NETWORKS AND TRANSPARENT CONDUCTIVE MATERIAL
    • 金属纳米结构网络和透明导电材料
    • WO2013192437A3
    • 2014-03-13
    • PCT/US2013046866
    • 2013-06-20
    • C3NANO INC
    • VIRKAR AJAYLI YING-SYIYANG XIQIANGLEMIEUX MELBURNE C
    • H01B5/14
    • C09D11/037C09D11/322C09D11/52G06F3/041G06F2203/04103H01B1/02H01L31/022466H01L31/1884Y02E10/50
    • Metal nanowires, such as silver nanowires coated on a substrate were fused together to form fused metal nanowire networks that have greatly improved conductivity while maintaining good transparency. Materials formed from the fused metal nanowire networks described herein can have a transparency to visible light of at least about 85% and a sheet resistance of no more than about 100 Olims/square or a transparency to visible light of at least about 90% and a sheet resistance of no more than about 250 Olims/square. In addition to maintaining good transparency, the materials formed from the sintered metal nanowire networks can have a haze of no more than 0.5. The method of forming such a fused metal nanowire networks are disclosed that involves exposure of metal nanowires to various fusing agents on a short timescale. The resulting sintered network can have a core-shell structure in which metal halide forms the shell. Additionally, effective methods are described for forming patterned structure with areas of sintered metal nanowire network with high conductivity and areas of un-sintered metal nanowires with low conductivity. The corresponding patterned films are also described. When formed into a film, materials comprising the metal nanowire network demonstrate low sheet resistance while maintaining desirably high levels of optical transparency with low haze, making them suitable for transparent electrode, touch sensors, and other electronic/optical device formation.
    • 将金属纳米线如涂覆在基材上的银纳米线熔合在一起形成熔融金属纳米线网络,其极大地改善导电性,同时保持良好的透明度。 由本文所述的熔融金属纳米线网络形成的材料可以具有至少约85%的可见光和不超过约100奥立兴/平方米的薄层电阻或至少约90%的可见光透明度的透明度,以及 表面电阻不超过约250欧姆/平方。 除了保持良好的透明度之外,由烧结金属纳米线网络形成的材料可以具有不超过0.5的雾度。 公开了形成这种熔融金属纳米线网络的方法,其包括在短时间尺度上将金属纳米线暴露于各种熔合剂。 所得到的烧结网络可以具有其中金属卤化物形成壳的核 - 壳结构。 另外,描述了用于形成具有导电性高的烧结金属纳米线网络区域和具有低导电性的未烧结金属纳米线区域的图案化结构的有效方法。 还描述了相应的图案化膜。 当形成膜时,包含金属纳米线网络的材料表现出低的薄层电阻,同时保持理想的高水平的具有低雾度的光学透明度,使得它们适合于透明电极,触摸传感器和其他电子/光学器件形成。
    • 4. 发明申请
    • TRANSPARENT CONDUCTIVE COATINGS BASED ON METAL NANOWIRES
    • 基于金属纳米线的透明导电涂料
    • WO2015077145A3
    • 2015-10-08
    • PCT/US2014065685
    • 2014-11-14
    • C3NANO INC
    • YANG XIQIANGLI YING-SYIHUANG YUNG-YUSCULLY CHRISTOPHER SMORRIS CLIFFORD MVIRKAR AJAY
    • H05K1/02
    • C09D11/52C09D11/08C09D11/10C09D11/38H05K1/097H05K3/105H05K3/1283H05K2201/0108H05K2201/026
    • Polymer binders, e.g., crosslinked polymer binders, have been found to be an effective film component in creating high quality transparent electrically conductive coatings or films comprising metal nanostructured networks. The metal nanowire films can be effectively patterned and the patterning can be performed with a high degree of optical similarity between the distinct patterned regions. Metal nanostructured networks are formed through the fusing of the metal nanowires to form conductive networks. Methods for patterning include, for example, using crosslinking radiation to pattern crosslinking of the polymer binder. The application of a fusing solution to the patterned film can result in low resistance areas and electrically resistive areas. After fusing the network can provide desirable low sheet resistances while maintaining good optical transparency and low haze. A polymer overcoat can further stabilize conductive films and provide desirable optical effects. The patterned films can be useful in devices, such as touch sensors.
    • 已经发现,聚合物粘合剂,例如交联聚合物粘合剂,是产生高质量透明导电涂层或包含金属纳米结构网络的膜的有效膜组分。 可以有效地构图金属纳米线膜,并且可以在不同的图案化区域之间以高度的光学相似性进行图案化。 通过金属纳米线的融合形成金属纳米结构网络以形成导电网络。 用于图案化的方法包括例如使用交联辐射来模制聚合物粘合剂的交联。 将融合溶液应用于图案化膜可导致低电阻区域和电阻区域。 在融合之后,网络可以提供期望的低薄层电阻,同时保持良好的光学透明度和低雾度。 聚合物外涂层可以进一步稳定导电膜并提供所需的光学效果。 图案化的膜可用于诸如触摸传感器的装置中。