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1. 发明申请

WO2011106048A3 PROCESSES AND SYSTEMS FOR THE PRODUCTION OF PROPYLENE GLYCOL FROM GLYCEROL 审中-公开
标题翻译：用于从甘油生产丙二醇的方法和系统
公开(公告)号：WO2011106048A3
公开(公告)日：2011-10-27
申请号：PCT/US2010057651
申请日：2010-11-22
申请人： BATTELLE MEMORIAL INSTITUTE , FRYE JOHN G , OBERG AARON A , ZACHER ALAN H
发明人： FRYE JOHN G , OBERG AARON A , ZACHER ALAN H
IPC分类号： C07C29/60 , C07C29/128 , C07C31/20
CPC分类号： C07C29/60 , C07C31/205
摘要： Processes and systems for converting glycerol to propylene glycol are disclosed. The glycerol feed is diluted with propylene glycol as the primary solvent, rather than water which is typically used. The diluted glycerol feed is sent to a reactor where the glycerol is converted to propylene glycol (as well as other byproducts) in the presence of a catalyst. The propylene glycol-containing product from the reactor is recycled as a solvent for the glycerol feed.
摘要翻译：公开了用于将甘油转化为丙二醇的方法和系统。用丙二醇作为主要溶剂稀释甘油进料，而不是通常使用的水。将稀释的甘油进料送入反应器，在该反应器中甘油在催化剂存在下转化为丙二醇（以及其它副产物）。来自反应器的含丙二醇的产物再循环作为甘油进料的溶剂。

2. 发明申请

WO03035593B1 HYDROGENOLYSIS OF 5-CARBON SUGARS AND ALCOHOLS 审中-公开
标题翻译： 5碳糖和醇的氢解
公开(公告)号：WO03035593B1
公开(公告)日：2003-11-13
申请号：PCT/US0233983
申请日：2002-10-23
申请人： BATTELLE MEMORIAL INSTITUTE , WERPY TODD A , FRYE JOHN G JR , ZACHER ALAN H , MILLER DENNIS J
发明人： WERPY TODD A , FRYE JOHN G JR , ZACHER ALAN H , MILLER DENNIS J
IPC分类号： B01J21/18 , B01J23/36 , B01J23/889 , C07C29/00 , C07C31/18
CPC分类号： C07C29/00 , B01J21/18 , B01J23/36 , B01J23/8896 , C07C29/149 , C07C29/60 , Y02P20/52 , C07C31/205 , C07C31/225 , C07C31/202
摘要： Methods and compositions for reactions of hydrogen over a Re-containing catalyst with compositions containing a 5-carbon sugar, sugar alcohol, or lactic acid are described. It has been surprisingly discovered that reaction with hydrogen over a Recontaining multimetallic catalyst restulted in superior conversion and selectively to desired products such as propylene glycol. A process for the synthesis of PG from lactate or lactic acid is also described.
摘要翻译：描述了在含Re的催化剂上与含有5碳糖，糖醇或乳酸的组合物反应氢的方法和组合物。已经令人惊讶地发现，通过复合多金属催化剂与氢的反应恢复了优异的转化率并选择性地转化为所需产物如丙二醇。还描述了从乳酸或乳酸合成PG的方法。

3. 发明申请

WO03035582B1 HYDROGENOLYSIS OF 6-CARBON SUGARS AND OTHER ORGANIC COMPOUNDS 审中-公开
标题翻译： 6-碳糖和其他有机化合物的氢解
公开(公告)号：WO03035582B1
公开(公告)日：2003-12-11
申请号：PCT/US0233982
申请日：2002-10-23
申请人： BATTELLE MEMORIAL INSTITUTE , UNIV MICHIGAN STATE , WERPY TODD A , FRYE JOHN G JR , ZACHER ALAN H , MILLER DENNIS J
发明人： WERPY TODD A , FRYE JOHN G JR , ZACHER ALAN H , MILLER DENNIS J
IPC分类号： C07C29/00 , C07B31/00
CPC分类号： C07C29/00 , B01J21/18 , B01J23/8896 , B01J37/0201 , B01J37/0205 , B01J37/0209 , B01J37/18 , C07C29/149 , C07C29/60 , Y02P20/52 , C07C31/205 , C07C31/225 , C07C31/202
摘要： Methods for hydrogenolysis are described which use a Re-containing multimetallic catalyst for hydrogenolysis of both C-O and C-C bonds. Methods and compositions for reactions of hydrogen over a Re-containing catalyst with compositions containing a 6-carbon sugar, sugar alcohol, or glycerol are described. It has been surprisingly discovered that reaction with hydrogen over a Re-containing multimetallic catalyst resulted in superior conversion and selectivity to desired products such as propylene glycol.
摘要翻译：描述了使用含Re多金属催化剂氢解C-O和C-C键的氢解方法。描述了用于在含有6碳糖，糖醇或甘油的组合物的含Re的催化剂上反应氢的方法和组合物。已经令人惊讶地发现，通过含Re的多金属催化剂与氢的反应导致对所需产物如丙二醇的优异的转化率和选择性。

4. 发明申请

WO2004058708B1 PROCESS FOR PRODUCING N-METHYL SUCCINIMIDE 审中-公开
标题翻译：生产N-甲基琥珀酰亚胺的方法
公开(公告)号：WO2004058708B1
公开(公告)日：2004-09-23
申请号：PCT/US0340106
申请日：2003-12-16
申请人： BATTELLE MEMORIAL INSTITUTE , WERPY TODD A , FRYE JOHN G JR , WHITE JAMES F , HOLLADAY JOHNATHAN E , ZACHER ALAN H
发明人： WERPY TODD A , FRYE JOHN G JR , WHITE JAMES F , HOLLADAY JOHNATHAN E , ZACHER ALAN H
IPC分类号： C07D207/40 , C07D207/404
CPC分类号： C07D207/404 , C07D207/267
摘要： The invention includes methods of processing an initial di-carbonyl compound by conversion to a cyclic compound. The cyclic compound is reacted with an alkyating agent to form a derivative having an alkylated ring nitrogen. The invention encompasses a method of producing an N-alkyl product. Amonia content of a solution is adjusted to produce a ratio of ammonia to di-carboxylate compound of from about 1:1 to about 1.5:1. An alkylating agent is added and the initial compound is alkylated and cyclized. The invention includes methods of making N-methyl pyrrolidinone (NMP). Aqueous ammonia and succinate is introduced into a vessel and ammonia is adjusted to provide a ratio of ammonia to succinate of less than 2:1. A methylating agent is reacted with succinate at a temperature of from greater than 100 °C to about 400 °C to produce N-methyl succinimide which is purified and hydrogenated to form NMP.
摘要翻译：本发明包括通过转化成环状化合物来处理初始二羰基化合物的方法。该环状化合物与烷基化剂反应形成具有烷基化环氮的衍生物。本发明包括生产N-烷基产物的方法。调节溶液的氨含量以产生约1:1至约1.5:1的氨与二羧酸盐化合物的比率。加入烷基化试剂并将初始化合物烷基化并环化。本发明包括制备N-甲基吡咯烷酮（NMP）的方法。将氨水和琥珀酸盐引入容器中并调节氨以提供小于2：1的氨与琥珀酸盐的比例。使甲基化剂与琥珀酸酯在大于100℃至约400℃的温度下反应以产生N-甲基琥珀酰亚胺，将其纯化并氢化以形成NMP。

5. 发明申请

WO2007146836B1 HYDROXYMETHYLFURFURAL REDUCTION METHODS AND METHODS OF PRODUCING FURANDIMETHANOL 审中-公开
标题翻译：羟丙基纤维素还原方法及其制备方法
公开(公告)号：WO2007146836B1
公开(公告)日：2008-03-06
申请号：PCT/US2007070802
申请日：2007-06-08
申请人： BATTELLE MEMORIAL INSTITUTE , LILGA MICHAEL A , HALLEN RICHARD T , WERPY TODD A , WHITE JAMES F , HOLLADAY JOHNATHAN E , FRYE JOHN G , ZACHER ALAN H
发明人： LILGA MICHAEL A , HALLEN RICHARD T , WERPY TODD A , WHITE JAMES F , HOLLADAY JOHNATHAN E , FRYE JOHN G , ZACHER ALAN H
IPC分类号： C07D307/12 , C07D307/40
CPC分类号： C07D307/12 , C07D307/40
摘要： A method of reducing hydroxymethylfurfural (HMF) where a starting material containing HMF in a solvent comprising water is provided. H 2 is provided into the reactor and the starting material is contacted with a catalyst containing at least one metal selected from Ni, Co, Cu, Pd, Pt, Ru, Ir, Re and Rh, at a temperature of less than or equal to 250°C. A method of hydrogenating HMF includes providing an aqueous solution containing HMF and fructose. H 2 and a hydrogenation catalyst are provided. The HMF is selectively hydrogenated relative to the fructose at a temperature at or above 30°C. A method of producing tetrahydofuran dimethanol (THFDM) includes providing a continuous flow reactor having first and second catalysts and providing a feed comprising HMF into the reactor. The feed is contacted with the first catalyst to produce furan dimethanol (FDM) which is contacted with the second catalyst to produce THFDM.
摘要翻译：提供一种还原羟甲基糠醛（HMF）的方法，其中含有HMF的原料在包含水的溶剂中。 H 2被提供到反应器中，起始材料与含有选自Ni，Co，Cu，Pd，Pt，Ru，Ir，Re和Rh中的至少一种金属的催化剂接触，温度小于或等于250℃。氢化HMF的方法包括提供含有HMF和果糖的水溶液。 H 2 H 2和氢化催化剂。在30℃或更高的温度下，HMF相对于果糖选择性氢化。制备四氢呋喃二甲醇（THFDM）的方法包括提供具有第一和第二催化剂的连续流动反应器，并向反应器中提供包含HMF的进料。进料与第一催化剂接触以产生与第二催化剂接触以产生THFDM的呋喃二甲醇（FDM）。

6. 发明申请

WO2009029535A2 CHEMICAL PRODUCTION PROCESSES, SYSTEMS, AND CATALYST COMPOSITIONS 审中-公开
标题翻译：化学生产过程，系统和催化剂组合物
公开(公告)号：WO2009029535A2
公开(公告)日：2009-03-05
申请号：PCT/US2008074079
申请日：2008-08-22
申请人： BATTELLE MEMORIAL INSTITUTE , PETERSON THOMAS H , WERPY TODD A , ZACHER ALAN H , GRAY MICHEL J , WHITE JAMES F
发明人： PETERSON THOMAS H , WERPY TODD A , ZACHER ALAN H , GRAY MICHEL J , WHITE JAMES F
IPC分类号： C07C45/52 , B01J8/00 , B01J27/185 , B01J27/186
CPC分类号： B01J27/186 , B01J8/025 , B01J23/96 , B01J27/1856 , B01J27/285 , B01J37/03 , B01J38/12 , B01J2208/00212 , B01J2208/00256 , B01J2219/00247 , C07C45/52 , Y02P20/584 , C07C47/22 , C07C49/17
摘要： Chemical production processes are provided that can include exposing a reactant composition to a catalyst composition to form a product composition. The reactant composition can include a multihydric alcohol compound and the product composition can include a carbonyl compound. The catalyst composition can include a metal effective to facilitate catalyst activation. Processes disclosed also include supplementing a dehydration catalyst with a promoter, and activating the supplemented catalyst in the presence of oxygen. Processes also include providing a supplemented dehydration catalyst to within a reactor, and exposing a multihydric alcohol compound to the dehydration catalyst, with the exposing forming coke within the reactor. Oxygen can be provided to the reactor to remove at least a portion of the coke.
摘要翻译：提供化学生产方法，其可以包括将反应物组合物暴露于催化剂组合物以形成产物组合物。反应物组合物可以包括多元醇化合物，并且产物组合物可以包括羰基化合物。催化剂组合物可以包括有效促进催化剂活化的金属。所公开的方法还包括用助催化剂补充脱水催化剂，并在氧的存在下活化补充的催化剂。方法还包括向反应器内部提供补充的脱水催化剂，并将多元醇化合物暴露于脱水催化剂中，同时在反应器内形成曝光的焦炭。可以将氧气提供给反应器以除去至少一部分焦炭。

7. 发明申请

WO2009099684A3 METHODS AND APPARATUS FOR CATALYTIC HYDROTHERMAL GASIFICATION OF BIOMASS 审中-公开
标题翻译：生物质催化水热气化方法与装置
公开(公告)号：WO2009099684A3
公开(公告)日：2010-01-21
申请号：PCT/US2009030099
申请日：2009-01-05
申请人： BATTELLE MEMORIAL INSTITUTE , ELLIOTT DOUGLAS C , BUTNER ROBERT SCOTT , NEUENSCHWANDER GARY G , ZACHER ALAN H , HART TODD R
发明人： ELLIOTT DOUGLAS C , BUTNER ROBERT SCOTT , NEUENSCHWANDER GARY G , ZACHER ALAN H , HART TODD R
IPC分类号： C10J3/78
CPC分类号： C10J3/78 , B01J21/18 , B01J23/462 , B01J23/75 , B01J23/78 , B09B3/00 , B09B3/0083 , C10B53/02 , C10J2300/0916 , C10J2300/0923 , C10J2300/0979 , C10L3/08 , C10L9/086 , Y02E50/14 , Y02P20/145 , Y02P20/52
摘要： Continuous processing ?f wet bi&upsi,-mass feedstock by catalytic hydrothermal gasification must address catalyst fouling and poisoning. One solution can involve heating (101) the wet bioraass with a h&egr,-atmg unit to a temperature sufficient for organic constituents in the feedstock to decompose, for precipitates of inorganic wastes to form, for preheating the wet feedstock in preparation for subsequent separation of sulfur contaminants, or combinations thereof. Treatment further includes separating (102) the precipitates out of the wet feedstock, removing sulfur contaminants (103), or both using a solids separation unit and a sulfur separation unit, respectiv ely. Having removed much of the inorganic wastes and the sulfur that can cause poisoning and fouling, the wet biomass feedstock can be exposed to the heterogeneous catalyst for gasification (104).
摘要翻译：连续加工，湿法生产，催化水热气化的原料必须解决催化剂污染和中毒问题。一种解决方案可以包括将湿式二氧化碳加热（101）到具有原料单元的温度足以使原料中的有机成分分解的温度，以形成无机废物的沉淀物，用于预热湿原料以备后续分离硫污染物或其组合。处理进一步包括从湿原料中分离（102）沉淀物，清除硫污染物（103）或使用固体分离单元和硫分离单元两者。除去大部分无机废物和可能引起中毒和结垢的硫，湿生物质原料可暴露于非均相催化剂进行气化（104）。

8. 发明申请

WO2009129256A8 PROCESSES AND SYSTEMS FOR PRODUCING PRODUCTS OF HYDROGENOLYSIS OF POLYHYDRIC ALCOHOLS 审中-公开
标题翻译：生产多元醇的氢化产物的方法和系统
公开(公告)号：WO2009129256A8
公开(公告)日：2014-10-16
申请号：PCT/US2009040551
申请日：2009-04-14
申请人： BATTELLE MEMORIAL INSTITUTE , HOLLADAY JOHNATHAN E , MUZATKO DANIELLE S , WHITE JAMES F , ZACHER ALAN H
发明人： HOLLADAY JOHNATHAN E , MUZATKO DANIELLE S , WHITE JAMES F , ZACHER ALAN H
IPC分类号： C07C29/60 , C07C31/20
CPC分类号： C07C29/132 , C07C29/60 , C07C31/205
摘要： Hydrogenolysis systems are provided that can include a reactor housing an Ru-comprising hydrogenolysis catalyst and wherein the contents of the reactor is maintained at a neutral or acidic pH. Reactant reservoirs within the system can include a polyhydric alcohol compound and a base, wherein a weight ratio of the base to the compound is less than 0.05. Systems also include the product reservoir comprising a hydrogenolyzed polyhydric alcohol compound and salts of organic acids, and wherein the moles of base are substantially equivalent to the moles of salts or organic acids. Processes are provided that can include an Ru-comprising catalyst within a mixture having a neutral or acidic pH. A weight ratio of the base to the compound can be between 0.01 and 0.05 during exposing.
摘要翻译：提供了氢解系统，其可以包括容纳含Ru的氢解催化剂的反应器，并且其中反应器的内容物保持在中性或酸性pH。系统内的反应物储存器可以包括多元醇化合物和碱，其中碱与化合物的重量比小于0.05。系统还包括包含氢解的多元醇化合物和有机酸的盐的产物储存器，其中碱的摩尔数基本上等于盐或有机酸的摩尔数。提供了可以在具有中性或酸性pH的混合物中包含含Ru的催化剂的方法。在曝光期间，碱与化合物的重量比可以在0.01和0.05之间。

9. 发明申请

WO2009029540A3 CHEMICAL PRODUCTION PROCESSES, SYSTEMS, AND CATALYST COMPOSITIONS 审中-公开
标题翻译：化学生产过程，体系和催化剂组合物
公开(公告)号：WO2009029540A3
公开(公告)日：2009-09-17
申请号：PCT/US2008074090
申请日：2008-08-22
申请人： BATTELLE MEMORIAL INSTITUTE , PETERSON THOMAS H , HOLLADAY JOHNATHAN E , ZACHER ALAN H , GRAY MICHEL J , WERPY TODD A , WHITE JAMES F
发明人： PETERSON THOMAS H , HOLLADAY JOHNATHAN E , ZACHER ALAN H , GRAY MICHEL J , WERPY TODD A , WHITE JAMES F
IPC分类号： C07C45/52 , B01J27/16 , C07C47/22
CPC分类号： C07C45/52 , C07C49/17 , C07C47/22
摘要： Chemical production processes are provided that include exposing a reactant composition to a catalyst composition to form a product composition, with the reactant composition including a multihydric alcohol compound and the catalyst composition being effective to dehydrate at least a portion of the multihydric alcohol compound. Embodiments of the process provide that the reactant composition is exposed to the catalyst composition for less than about 0.25 seconds and/or that the catalyst is maintained at a temperature of from about 2800C to about 3200C. Processes utilizing a reactant composition including a multihydric alcohol compound and an inert compound are also provided.
摘要翻译：提供化学生产方法，其包括将反应物组合物暴露于催化剂组合物以形成产物组合物，其中反应物组合物包含多元醇化合物并且催化剂组合物有效使至少一部分多元醇化合物脱水。该方法的实施方案规定反应物组合物暴露于催化剂组合物小于约0.25秒和/或催化剂保持在约280℃至约320℃的温度。还提供了利用包含多元醇化合物和惰性化合物的反应物组合物的方法。

10. 发明申请

WO2011075743A2 MULTIHYDRIC COMPOUND DEHYDRATION SYSTEMS, CATALYST COMPOSITIONS, AND METHODS 审中-公开
标题翻译：多水化合物脱水体系，催化剂组合物和方法
公开(公告)号：WO2011075743A2
公开(公告)日：2011-06-23
申请号：PCT/US2010061373
申请日：2010-12-20
申请人： BATTELLE MEMORIAL INSTITUTE , STROHM JAMES J , ZACHER ALAN H , GRAY MICHEL J , WHITE JAMES F , LEBARBIER VANESSA
发明人： STROHM JAMES J , ZACHER ALAN H , GRAY MICHEL J , WHITE JAMES F , LEBARBIER VANESSA
IPC分类号： B01J23/92
CPC分类号： C07C45/00 , B01J8/001 , B01J21/08 , B01J27/18 , B01J27/1806 , B01J27/1853 , B01J27/285 , B01J38/02 , B01J38/04 , B01J38/06 , B01J38/12 , C07C45/52 , Y02P20/584 , C07C47/22
摘要： The present disclosure relates to facilities, systems, methods and/or catalysts for use in chemical production. In particular, the disclosure provides innovations relating to dehydration of multihydric compounds such as glycerol to form acrolein. Some of these innovations include continuous reaction systems as well as system parameters that allow for long term production.
摘要翻译：本公开涉及用于化学生产的设施，系统，方法和/或催化剂。具体而言，本公开提供了涉及多羟基化合物例如甘油脱水以形成丙烯醛的创新。其中一些创新包括连续反应系统以及允许长期生产的系统参数。

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