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1. 发明申请

WO2009045606A1 MULTI-METAL HYDROGENATION CATALYSTS 审中-公开
标题翻译：多金属氢化催化剂
公开(公告)号：WO2009045606A1
公开(公告)日：2009-04-09
申请号：PCT/US2008/070786
申请日：2008-07-22
申请人： BATTELLE MEMORIAL INSTITUTE , FRYE, John, G. , HOLLADAY, Johnathan, E. , MUZATKO, Danielle, S. , WHITE, James, F. , ZACHER, Alan, H.
发明人： FRYE, John, G. , HOLLADAY, Johnathan, E. , MUZATKO, Danielle, S. , WHITE, James, F. , ZACHER, Alan, H.
IPC分类号： B01J23/46 , B01J23/60 , B01J23/62 , B01J23/89 , C07C29/00
CPC分类号： B01J23/626 , B01J23/462 , B01J23/464 , B01J23/466 , B01J23/48 , B01J23/60 , B01J23/62 , B01J23/628 , B01J23/6447 , B01J23/656 , B01J23/80 , B01J23/85 , B01J23/889 , B01J23/89 , B01J23/8906 , B01J23/8926 , B01J23/8986 , B01J27/045 , B01J27/0576 , B01J37/18 , C07C29/60 , C07C31/205
摘要： A reduction catalyst having a first metal component comprising one of Co, Os, Fe, Re, Rh and Ru. The first metal component is present in the catalyst at from 0.5 percent to 20 percent, by weight. A second metal component differing from the first metal component present in the catalyst with the second metal component being selected from the group consisting of Fe, Mn, Ru, Os, Rh, Ir, Ni, Pd, Pt, Ag, Au, Zn, Co, Re, Cu, Pb, Cr, W, Mo, Sn, Nb, Cd, Te, V, Bi, Ga and Na. A hydrogenation catalyst comprising one or both of Ni and Co and one or more elements selected from the group consisting of Mn, Fe, Ag, Au, Mo and Rh.
摘要翻译：一种具有包含Co，Os，Fe，Re，Rh和Ru中的一种的第一金属组分的还原催化剂。催化剂中第一种金属组分以重量百分比为0.5％至20％存在。不同于催化剂中存在的第一金属组分的第二金属组分，其中第二金属组分选自Fe，Mn，Ru，Os，Rh，Ir，Ni，Pd，Pt，Ag，Au，Zn， Co，Re，Cu，Pb，Cr，W，Mo，Sn，Nb，Cd，Te，V，Bi，Ga及Na。包含Ni和Co中的一种或两种以及选自Mn，Fe，Ag，Au，Mo和Rh中的一种或多种元素的氢化催化剂。

2. 发明申请

WO2009029540A2 CHEMICAL PRODUCTION PROCESSES, SYSTEMS, AND CATALYST COMPOSITIONS 审中-公开
标题翻译：化学生产过程，系统和催化剂组合物
公开(公告)号：WO2009029540A2
公开(公告)日：2009-03-05
申请号：PCT/US2008/074090
申请日：2008-08-22
申请人： BATTELLE MEMORIAL INSTITUTE , PETERSON, Thomas, H. , HOLLADAY, Johnathan, E. , ZACHER, Alan, H. , GRAY, Michel, J. , WERPY, Todd, A. , WHITE, James, F.
发明人： PETERSON, Thomas, H. , HOLLADAY, Johnathan, E. , ZACHER, Alan, H. , GRAY, Michel, J. , WERPY, Todd, A. , WHITE, James, F.
IPC分类号： C07C45/52 , C07C47/22 , B01J27/16
CPC分类号： C07C45/52 , C07C49/17 , C07C47/22
摘要： Chemical production processes are provided that include exposing a reactant composition to a catalyst composition to form a product composition, with the reactant composition including a multihydric alcohol compound and the catalyst composition being effective to dehydrate at least a portion of the multihydric alcohol compound. Embodiments of the process provide that the reactant composition is exposed to the catalyst composition for less than about 0.25 seconds and/or that the catalyst is maintained at a temperature of from about 2800C to about 3200C. Processes utilizing a reactant composition including a multihydric alcohol compound and an inert compound are also provided.
摘要翻译：提供了化学生产方法，其包括将反应物组合物暴露于催化剂组合物以形成产物组合物，反应物组合物包含多元醇化合物，催化剂组合物有效地使至少一部分多元醇化合物脱水。该方法的实施方案提供反应物组合物暴露于催化剂组合物少于约0.25秒和/或催化剂保持在约2800℃至约3200℃的温度。还提供了利用包含多元醇化合物和惰性化合物的反应物组合物的方法。

3. 发明申请

WO2008019219A1 METHOD FOR CONVERSION OF CARBOHYDRATES IN IONIC LIQUIDS TO HYDROXYMETHYLFURFURAL 审中-公开
标题翻译：将离子液体中的碳酸氢盐转化为羟基甲基纤维素的方法
公开(公告)号：WO2008019219A1
公开(公告)日：2008-02-14
申请号：PCT/US2007/073947
申请日：2007-07-20
申请人： BATTELLE MEMORIAL INSTITUTE , ZHAO, Haibo , HOLLADAY, Johnathan, E. , ZHANG, Zongchao, C.
发明人： ZHAO, Haibo , HOLLADAY, Johnathan, E. , ZHANG, Zongchao, C.
IPC分类号： C07D307/46
CPC分类号： C07D307/46
摘要： Methods are described for converting carbohydrates including, e.g., monosaccharides, disaccharides, and polysaccharides in ionic liquids to value-added chemicals including furans, useful as chemical intermediates and/or feedstocks. Fructose is converted to 5-hydroxylmethylfurfural (HMF) in the presence of metal halide and acid catalysts. Glucose is effectively converted to HMF in the presence of chromium chloride catalysts. Yields of up to about 70% are achieved with low levels of impurities such as levulinic acid.
摘要翻译：描述了用于将离子液体中包括例如单糖，二糖和多糖的碳水化合物转化成包括用作化学中间体和/或原料的呋喃的增值化学品的方法。在金属卤化物和酸催化剂存在下，果糖被转化成5-羟甲基糠醛（HMF）。在氯化铬催化剂存在下，葡萄糖有效转化为HMF。通过低水平的杂质如乙酰丙酸实现高达约70％的产率。

4. 发明申请

WO2007106099A1 METHOD FOR THE PREPARATION OF ALPHA-BETA-UNSATURATED CARBONYL COMPOUNDS 审中-公开
标题翻译：制备阿尔法 - 不饱和碳化合物的方法
公开(公告)号：WO2007106099A1
公开(公告)日：2007-09-20
申请号：PCT/US2006/012696
申请日：2006-04-04
申请人： BATTELLE MEMORIAL INSTITUTE , CARGILL INCORPORATED , HOLLADAY, Johnathan, E. , ZACHER, Alan, H. , LILGA, Michael, A. , WHITE, James, F. , MUZATKO, Danielle, S. , ORTH, Rick, J. , TSOBANAKIS, Paraskevas , MENG, Xiangsheng , ABRAHAM, Timothy, W.
发明人： HOLLADAY, Johnathan, E. , ZACHER, Alan, H. , LILGA, Michael, A. , WHITE, James, F. , MUZATKO, Danielle, S. , ORTH, Rick, J. , TSOBANAKIS, Paraskevas , MENG, Xiangsheng , ABRAHAM, Timothy, W.
IPC分类号： C07C51/377 , C07C57/04
CPC分类号： C07C231/14 , C07C51/377 , Y02P20/127 , C07C57/04 , C07C233/09
摘要： A process is disclosed for conversion of ammonium salts of β-hydroxy carbonyl compounds forming useful conversion products including, e.g., α, β-unsaturated carbonyl compounds and/or ammonium salts of α, β-unsaturated carbonyl compounds recovered at a high molar yield. Conversion products find use, e.g., as feedstock and/or end-use chemicals.
摘要翻译：公开了用于转化形成有用转化产物的β-羟基羰基化合物的铵盐的方法，包括例如以高摩尔收率回收的β-不饱和羰基化合物和/或β-不饱和羰基化合物的铵盐。转化产物可用于例如原料和/或最终用途的化学品。

5. 发明申请

WO2007089510A2 METHODS FOR DEHYDRATION OF SUGARS 审中-公开
标题翻译：蔗糖脱水方法
公开(公告)号：WO2007089510A2
公开(公告)日：2007-08-09
申请号：PCT/US2007/001945
申请日：2007-01-24
申请人： BATTELLE MEMORIAL INSTITUTE , HOLLADAY, Johnathan, E. , HU, Jianli , ZHANG, Xinjie , WANG, Yong
发明人： HOLLADAY, Johnathan, E. , HU, Jianli , ZHANG, Xinjie , WANG, Yong
IPC分类号： C07D493/04 , C08G63/672 , C07H1/00
CPC分类号： C07D493/04
摘要： The invention includes a method of dehydration of a sugar using a dehydration catalyst and a co-catalyst within a reactor. A sugar is introduced and H 2 is flowed through the reactor at a pressure of less than or equal to about 300 psig to convert at least some of the sugar into an anhydrosugar product. The invention includes a process for producing isosorbide. A starting material comprising sorbitol is flowed into a reactor. H 2 is counter flowed through the reactor. The starting material is exposed to a catalyst in the presence of a co- catalyst which comprises at least one metal. The exposing is conducted at a hydrogen pressure of less than or equal to 300 psig within the reactor and the hydrogen removes at least some of any water present during the exposing and inhibits formation of colored byproducts.
摘要翻译：本发明包括使用反应器内的脱水催化剂和助催化剂使糖脱水的方法。引入糖并且H 2 O 2以小于或等于约300psig的压力流过反应器，以将至少一些糖转化为脱水糖产物。本发明包括一种生产异山梨醇的方法。将含有山梨糖醇的原料流入反应器。 H 2反向流过反应器。原料在包含至少一种金属的助催化剂存在下暴露于催化剂。暴露在反应器内以小于或等于300psig的氢气压力进行，并且氢去除暴露期间存在的任何水中的至少一些并且抑制着色副产物的形成。

6. 发明申请

WO2007089510A3 METHODS FOR DEHYDRATION OF SUGARS 审中-公开
标题翻译：蔗糖脱水方法
公开(公告)号：WO2007089510A3
公开(公告)日：2008-01-17
申请号：PCT/US2007001945
申请日：2007-01-24
申请人： BATTELLE MEMORIAL INSTITUTE , HOLLADAY JOHNATHAN E , HU JIANLI , ZHANG XINJIE , WANG YONG
发明人： HOLLADAY JOHNATHAN E , HU JIANLI , ZHANG XINJIE , WANG YONG
IPC分类号： C07D493/04 , C07H1/00 , C07H3/10 , C08G63/672
CPC分类号： C07D493/04
摘要： The invention includes a method of dehydration of a sugar using a dehydration catalyst and a co-catalyst within a reactor. A sugar is introduced and H 2 is flowed through the reactor at a pressure of less than or equal to about 300 psig to convert at least some of the sugar into an anhydrosugar product. The invention includes a process for producing isosorbide. A starting material comprising sorbitol is flowed into a reactor. H 2 is counter flowed through the reactor. The starting material is exposed to a catalyst in the presence of a co- catalyst which comprises at least one metal. The exposing is conducted at a hydrogen pressure of less than or equal to 300 psig within the reactor and the hydrogen removes at least some of any water present during the exposing and inhibits formation of colored byproducts.
摘要翻译：本发明包括使用反应器内的脱水催化剂和助催化剂使糖脱水的方法。引入糖，并且H 2 O 2以小于或等于约300psig的压力流过反应器，以将至少一些糖转化为脱水糖产物。本发明包括制备异山梨醇的方法。将含有山梨醇的原料流入反应器。 H 2反向流过反应器。在包含至少一种金属的助催化剂的存在下，将原料暴露于催化剂。暴露在反应器内在小于或等于300psig的氢气压力下进行，并且氢去除暴露期间存在的任何水中的至少一些，并且抑制着色副产物的形成。

7. 发明申请

WO2007106100A1 METHOD AND APPARATUS FOR CONVERSION OF β -HYDROXY CARBONYL COMPOUNDS 审中-公开
标题翻译：用于转化β-羟基碳化合物的方法和装置
公开(公告)号：WO2007106100A1
公开(公告)日：2007-09-20
申请号：PCT/US2006/012697
申请日：2006-04-04
申请人： BATTELLE MEMORIAL INSTITUTE , CARGILL, INCORPORATED , ZACHER, Alan, H. , HOLLADAY, Johnathan, E. , LILGA, Michael, A. , WHITE, James, F. , MUZATKO, Danielle, S. , ORTH, Rick, J. , TSOBANAKIS, Paraskevas , MENG, Xiangsheng , ABRAHAM, Timothy, W.
发明人： ZACHER, Alan, H. , HOLLADAY, Johnathan, E. , LILGA, Michael, A. , WHITE, James, F. , MUZATKO, Danielle, S. , ORTH, Rick, J. , TSOBANAKIS, Paraskevas , MENG, Xiangsheng , ABRAHAM, Timothy, W.
IPC分类号： C07C57/065 , C07C231/12
CPC分类号： C07C51/377 , C07C57/04
摘要： A process and apparatus are disclosed for conversion of β-hydroxy carbonyl compounds forming useful conversion products including, e.g., acrylic acid [CAS No. 79-10-7], acrylates, and acrylamide [CAS No. 79-06-01]. Conversion products find use, e.g., as feedstock and/or end-use chemicals.
摘要翻译：公开了用于转化形成有用转化产物的β-羟基羰基化合物的方法和装置，包括例如丙烯酸[CAS No.79-10-7]，丙烯酸酯和丙烯酰胺[CAS No.79-06-01]。转化产物可用作例如原料和/或最终用途的化学品。

8. 发明申请

WO2007089526A1 METHOD OF PERFORMING SUGAR DEHYDRATION AND CATALYST TREATMENT 审中-公开
标题翻译：执行糖脱水和催化处理的方法
公开(公告)号：WO2007089526A1
公开(公告)日：2007-08-09
申请号：PCT/US2007/001995
申请日：2007-01-25
申请人： BATTELLE MEMORIAL INSTITUTE , HU, Jianli , HOLLADAY, Johnathan, E. , ZHANG, Xinjie , WANG, Yong
发明人： HU, Jianli , HOLLADAY, Johnathan, E. , ZHANG, Xinjie , WANG, Yong
IPC分类号： C07H1/00
CPC分类号： C07H1/00
摘要： The invention includes a method of treating a solid acid catalyst. After exposing the catalyst to a mixture containing a sugar alcohol, the catalyst is washed with an organic solvent and is then exposed to a second reaction mixture. The invention includes a process for production of anhydrosugar alcohol. A solid acid catalyst is provided to convert sugar alcohol in a first sample to an anhydrosugar alcohol. The catalyst is then washed with an organic solvent and is subsequently utilized to expose a second sample. The invention includes a method for selective production of an anhydrosugar. A solid acid catalyst is provided within a reactor and anhydrosugar alcohol is formed by flowing a starting sugar alcohol into the reactor. The acid catalyst is then exposed to an organic solvent which allows a greater amount of additional anhydrosugar to be produced than would occur without exposing the acid catalyst to the organic solvent.
摘要翻译：本发明包括一种处理固体酸催化剂的方法。在将催化剂暴露于含有糖醇的混合物之后，将催化剂用有机溶剂洗涤，然后暴露于第二反应混合物。本发明包括生产脱水葡萄糖醇的方法。提供固体酸催化剂以将第一样品中的糖醇转化成脱水葡萄糖醇。然后将催化剂用有机溶剂洗涤，随后用于暴露第二个样品。本发明包括选择性生产脱水糖的方法。在反应器内提供固体酸催化剂，并通过将起始糖醇流入反应器而形成脱水葡萄糖醇。然后将酸催化剂暴露于有机溶剂，其允许比不会将酸催化剂暴露于有机溶剂的情况下产生更多量的额外的脱水糖。

9. 发明申请

WO2009129325A3 HYDROGENOLYSIS PROCESSES AND HYDROGENOLYSIS CATALYST PREPARATION METHODS 审中-公开
标题翻译：氢化方法和氢化催化剂制备方法
公开(公告)号：WO2009129325A3
公开(公告)日：2010-03-18
申请号：PCT/US2009040695
申请日：2009-04-15
申请人： BATTELLE MEMORIAL INSTITUTE , HOLLADAY JOHNATHAN E , WHITE JAMES F , PETERSON THOMAS H , FRYE JOHN G , MUZATKO DANIELLE S , BARE SIMON R , VASSILAKIS JAMES G , ROSIN RICHARD R
发明人： HOLLADAY JOHNATHAN E , WHITE JAMES F , PETERSON THOMAS H , FRYE JOHN G , MUZATKO DANIELLE S , BARE SIMON R , VASSILAKIS JAMES G , ROSIN RICHARD R
IPC分类号： B01J21/18 , B01J23/889 , B01J23/89 , B01J37/18 , C07C17/23
CPC分类号： B01J21/18 , B01J23/8896 , B01J23/8986 , B01J37/18
摘要： Hydrogenolysis processes are provided that can include providing a hydrogenolysis reactor having a catalyst therein. The catalyst can be exposed to a reducing agent in the absence of polyhydric alcohol compound while maintaining a temperature of the catalyst above 290°C. Hydrogenolysis processes can also include providing a passivated catalyst to within a reactor and exposing the catalyst to a reducing atmosphere while maintaining the catalyst at a temperature less than 210°C. Hydrogenolysis catalyst preparation methods are provided that can include exposing the catalyst to a first reducing atmosphere while maintaining the catalyst at a first temperature to reduce at least a portion of the catalyst. The method can also include passivating at least the portion of the catalyst and depassivating the portion of the catalyst in the presence of a second reducing atmosphere while maintaining the portion of the catalyst at a second temperature less than the first temperature.
摘要翻译：提供氢解方法，其可以包括提供其中具有催化剂的氢解反应器。催化剂可以在不存在多元醇化合物的情况下暴露于还原剂，同时将催化剂的温度保持在290℃以上。氢解方法还可以包括在反应器内提供钝化的催化剂，并将催化剂暴露于还原气氛，同时将催化剂保持在低于210℃的温度。提供了氢解催化剂制备方法，其可以包括将催化剂暴露于第一还原气氛，同时将催化剂保持在第一温度以减少至少一部分催化剂。该方法还可以包括钝化至少一部分催化剂，并且在第二还原气氛存在的情况下使催化剂的一部分钝化，同时保持催化剂的部分在低于第一温度的第二温度。

10. 发明申请

WO2004058708A1 PROCESS FOR PRODUCING N-METHYL SUCCINIMIDE 审中-公开
标题翻译：生产N-甲基磺酰胺的方法
公开(公告)号：WO2004058708A1
公开(公告)日：2004-07-15
申请号：PCT/US2003/040106
申请日：2003-12-16
申请人： BATTELLE MEMORIAL INSTITUTE , WERPY, Todd, A. , FRYE, John, G., Jr. , WHITE, James, F. , HOLLADAY, Johnathan, E. , ZACHER, Alan, H.
发明人： WERPY, Todd, A. , FRYE, John, G., Jr. , WHITE, James, F. , HOLLADAY, Johnathan, E. , ZACHER, Alan, H.
IPC分类号： C07D207/40
CPC分类号： C07D207/404 , C07D207/267
摘要： The invention includes methods of processing an initial di-carbonyl compound by conversion to a cyclic compound. The cyclic compound is reacted with an alkyating agent to form a derivative having an alkylated ring nitrogen. The invention encompasses a method of producing an N-alkyl product. Amonia content of a solution is adjusted to produce a ratio of ammonia to di-carboxylate compound of from about 1:1 to about 1.5:1. An alkylating agent is added and the initial compound is alkylated and cyclized. The invention includes methods of making N-methyl pyrrolidinone (NMP). Aqueous ammonia and succinate is introduced into a vessel and ammonia is adjusted to provide a ratio of ammonia to succinate of less than 2:1. A methylating agent is reacted with succinate at a temperature of from greater than 100 °C to about 400 °C to produce N-methyl succinimide which is purified and hydrogenated to form NMP.
摘要翻译：本发明包括通过转化为环状化合物来处理初始二羰基化合物的方法。环状化合物与烷基化剂反应形成具有烷基化环氮的衍生物。本发明包括生产N-烷基产物的方法。调节溶液的阿莫尼亚含量以产生约1：1至约1.5：1的氨与二羧酸酯化合物的比例。加入烷基化剂并将该初始化合物烷基化并环化。本发明包括制备N-甲基吡咯烷酮（NMP）的方法。将氨水和琥珀酸钠引入容器中，并调节氨以提供小于2:1的氨与琥珀酸的比例。甲基化剂与琥珀酸盐在大于100℃至约400℃的温度下反应，生成N-甲基琥珀酰亚胺，将其纯化并氢化形成NMP。

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