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    • 1. 发明申请
    • FIELD EFFECT ELEMENTS
    • 场效应元素
    • WO2009013291A2
    • 2009-01-29
    • PCT/EP2008/059598
    • 2008-07-22
    • BASF SEHENNIG, IngolfDÖTZ, FlorianECKERLE, PeterPARASHKOV, RadoslavKASTLER, MarcelVAIDYANATHAN, Subramanian
    • HENNIG, IngolfDÖTZ, FlorianECKERLE, PeterPARASHKOV, RadoslavKASTLER, MarcelVAIDYANATHAN, Subramanian
    • H01L51/30
    • H01L51/052H01L51/0529
    • A field effect element comprising: a source electrode (6) and a drain-electrode (7), a semiconducting layer (2) comprising a semiconducting compound being in contact with the source electrode (6) and the drain electrode (7), - a gate electrode (5), and a dielectric layer (3) comprising one or more compounds selected from hygroscopic organic compounds and/or from nanoparticulate inorganic compounds being arranged between the semiconducting layer (2) and the gate electrode (5), wherein said hygroscopic organic compounds have a water absorption capability of more than 1.2 % by weight, and a hydrophobic insulating layer (4) being arranged between the gate electrode (5) and the dielectric layer (3) preventing diffusion of water into the one or more hygroscopic compounds of the dielectric layer during the time of use of the field effect element, said hydrophobic insulating layer (4) having a water absorption capability of less than 1.2 % by weight, the semiconducting layer (2), the dielectric layer (3) or the hydrophobic insulating layer (4), or a combination thereof, being disposable from a liquid; and a process for producting the same.
    • 一种场效应元件,包括:源极(6)和漏电极(7);包含与源电极(6)和漏电极(7)接触的半导体化合物的半导体层(2) 栅电极(5)和包含一种或多种选自吸湿有机化合物和/或从纳米颗粒无机化合物组成的化合物的电介质层(3),其布置在半导电层(2)和栅电极(5)之间,其中所述 吸湿性有机化合物具有大于1.2重量%的吸水能力,并且在栅电极(5)和电介质层(3)之间布置疏水绝缘层(4),防止水扩散到一个或多个吸湿性 在场效应元件使用期间介电层的化合物,所述疏水绝缘层(4)的吸水能力小于1.2%(重量),半导体层(2),介电层 c层(3)或疏水绝缘层(4),或其组合,其是从液体中一次性的; 以及产品的制造过程。
    • 8. 发明申请
    • DITHIENOPHTHALIMIDE SEMICONDUCTOR POLYMERS
    • 二苯基二胺半导体聚合物
    • WO2013004730A1
    • 2013-01-10
    • PCT/EP2012/062996
    • 2012-07-04
    • BASF SENOGUCHI, HiroyoshiDÖTZ, FlorianMISHRA, Ashok, KumarVAIDYANATHAN, SubramanianMINH-TIEN, Mai
    • NOGUCHI, HiroyoshiDÖTZ, FlorianMISHRA, Ashok, KumarVAIDYANATHAN, SubramanianMINH-TIEN, Mai
    • C08G61/12C09K11/00H01B1/00H01L51/00
    • H01L51/0036C08G61/126C08G2261/124C08G2261/1412C08G2261/3223C08G2261/3327C08G2261/344C08G2261/364C08G2261/92H01L51/0043H01L51/0558Y02E10/549
    • The invention concerns apolymer of the formula (I): wherein: M1 is an optionally substituted dithienophthalimide formula (II): wherein: X is N or C-R, wherein R is H or a C 1 -C 40 alkyl group, R 1 , at each occurrence, is independently selected from H, a C 1-40 alkyl group, a C 2-40 alkenyl group, a C 1-40 haloalkyl group, and a monocyclicor polycyclic moiety, wherein: each of the C 1-40 alkyl group, the C 2-40 alkenyl group, and the C 1-40 haloalkyl group can be optionally substituted with 1-10 substituents independently selected from a halogen, CN, -NO 2 , OH, NH 2 , -NH(C 1-20 alkyl), N(C 1-20 alkyl) 2 , -S(O) 2 OH, -CHO, -C(O)-C 1-20 alkyl, -C(O)OH, -C(O)-OC 1-20 alkyl, -C(O)NH 2 , -C(O)NH-C 1-20 alkyl, -C(O)N(C 1-20 alkyl) 2 , -OC 1-20 alkyl, -SiH 3 , -SiH(C 1-20 alkyl) 2 , -SiH 2 (C 1-20 alkyl), and -Si(C 1-20 alkyl) 3 ; and the monocyclic or polycyclic moiety can be covalently bonded to the imide nitrogen via an optional linker, and can be optionally substituted with 1-5 substituentsindependently selected from a halogen, oxo, -CN, -NO 2 , OH, =C(CN) 2 , -NH 2 , -NH(C 1-20 alkyl), N(C 1-20 alkyl) 2 , -S(O) 2 OH,-CHO, -C(O)OH, -C(O)-C 1-20 alkyl, -C(O)-OC 1-20 alkyl, -C(O)NH 2 , -C(O)NH-C 1-20 alkyl, -C(O)N(C 1-20 alkyl) 2 , -SiH 3 , -SiH(C 1-20 alkyl) 2 , -SiH 2 (C 1-20 alkyl), -Si(C 1-20 alkyl) 3 ,-O-C 1-20 alkyl, -O-C 1-20 alkenyl, -O-C 1-20 haloalkyl, C 1-20 alkyl, C 1-20 alkenyl, C 1-20 haloalkyl, C 7-20 arylalkyl, C 6-20 aryloxy and C 7-20 arylcarbonyl. M 2 is a repeating unit comprising one or more cyclic moieties; and n is an integer between 2 and 5,000.
    • 本发明涉及式(I)的聚合物:其中:M1是任选取代的二噻吩邻苯二甲酰亚胺式(II):其中:X是N或CR,其中R是H或C 1 -C 40烷基, 独立地选自H,C 1-4烷基,C 2-40链烯基,C 1-40卤代烷基和单环多环部分,其中:C 1-4烷基,C 2-40链烯基 ,C 1-4卤代烷基可以任选地被1-10个独立地选自卤素,CN,-NO 2,OH,NH 2,-NH(C 1-20烷基),N(C 1-20烷基) -S(O)2 OH,-CHO,-C(O)-C 1-20烷基,-C(O)OH,-C(O)-OC 1-20烷基,-C(O)NH 2,-C )NH-C 1-20烷基,-C(O)N(C 1-20烷基)2,-OC 1-20烷基,-SiH 3,-SiH(C 1-20烷基)2,-SiH 2(C 1-20烷基) 和-Si(C 1-20烷基)3; 并且单环或多环部分可以经由任选的接头共价键合到酰亚胺氮上,并且可以任选被1-5个取代基取代,所述取代基独立地选自卤素,氧代,-CN,-NO 2,OH,= C(CN)2 ,-NH 2,-NH(C 1-20烷基),N(C 1-20烷基)2,-S(O)2 OH,-CHO,-C(O)OH,-C(O) -C(O)-OC 1-20烷基,-C(O)NH 2,-C(O)NH-C 1-20烷基,-C(O)N(C 1-20烷基)2,-SiH 3,-SiH C 1-20烷基)2,-SiH 2(C 1-20烷基),-Si(C 1-20烷基)3,-O-C 1-20烷基,-O-C 1-20烯基,-O-C 1-20卤代烷基, C 1-20烷基,C 1-20烯基,C 1-20卤代烷基,C 7-20芳基烷基,C 6-20芳氧基和C 7-20芳基羰基。 M2是包含一个或多个环状部分的重复单元; n为2〜5,000的整数。