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1. 发明申请

WO2010060555A1 PREPARATION OF ULTRA HIGH MOLECULAR MASS POLYETHYLENE AND ULTRA HIGH MOLECULAR MASS POLYETHYLENE HAVING IMPROVED CROSSLINK ABILITY PREPARED THEREBY 审中-公开
标题翻译：超高分子量聚乙烯的制备和超高分子量聚乙烯具有改进的交联能力
公开(公告)号：WO2010060555A1
公开(公告)日：2010-06-03
申请号：PCT/EP2009/008183
申请日：2009-11-18
申请人： BASELL POLYOLEFINE GMBH , MIHAN, Shahram , KOELLING, Lars , VOGT, Heinz , LILGE, Dieter , ENDERLE, Hans-Friedrich , NITZ, Hans-Jörg , LUKESOVA, Lenka
发明人： MIHAN, Shahram , KOELLING, Lars , VOGT, Heinz , LILGE, Dieter , ENDERLE, Hans-Friedrich , NITZ, Hans-Jörg , LUKESOVA, Lenka
IPC分类号： C08F10/02 , C08F4/24 , C08F4/02
CPC分类号： C08F10/02 , C08F110/02 , C08F4/24 , C08F4/025 , C08F2500/01 , C08F2500/17 , C08F2500/07 , C08F2500/24
摘要： The invention pertains to a method for the preparation of ultra high molecular mass polyethylene by polymerization in suspension or in gas phase in the presence of a chromium catalyst sitting on an alumosilicate support material. The chromium catalyst has been subjected to a fluorinating treatment and the polymerization is performed under low temperature conditions within a temperature range of from 50 to 100 °C. The invention pertains also to ultra heigh molecular mass polyethylene prepared by that method and having a density in the range of from 0.930 to 0.950 g/cm 3 .
摘要翻译：本发明涉及通过在坐在铝硅酸盐载体材料上的铬催化剂存在下在悬浮液或气相中聚合制备超高分子量聚乙烯的方法。铬催化剂已进行氟化处理，聚合反应在低温条件下在50〜100℃的温度范围内进行。本发明还涉及通过该方法制备并且具有在0.930-0.950g / cm3范围内的密度的超高分子量聚乙烯。

2. 发明申请

WO2010063432A1 PROCESS FOR THE POLYMERIZATION OF ETHYLENE, AND ETHYLENE POLYMERS HAVING BROAD MOLECULAR WEIGHT DISTRIBUTION AND LONG- CHAIN BRANCHING 审中-公开
标题翻译：乙烯聚合方法和具有宽分子量分布和长链分支的乙烯聚合物
公开(公告)号：WO2010063432A1
公开(公告)日：2010-06-10
申请号：PCT/EP2009/008513
申请日：2009-11-30
申请人： BASELL POLYOLEFINE GMBH , CIACCIA, Eleonora , VITTORIAS, Iakovos , MIHAN, Shahram , LUKESOVA, Lenka , LILGE, Dieter , HERRARA SALINAS, Maclovio , MEIER, Gerhardus , MANNEBACH, Gerd
发明人： CIACCIA, Eleonora , VITTORIAS, Iakovos , MIHAN, Shahram , LUKESOVA, Lenka , LILGE, Dieter , HERRARA SALINAS, Maclovio , MEIER, Gerhardus , MANNEBACH, Gerd
IPC分类号： C08F10/02 , C08F4/70 , C08F4/655
CPC分类号： C08F10/02 , C08F10/00 , C08F110/06 , C08F210/06 , C08F210/16 , C08F2410/04 , C08F4/6555 , C08F4/7042 , C08F210/14 , C08F2500/04 , C08F2500/12 , C08F2500/11 , C08F2500/10
摘要： New ethylene polymers having broad molecular weight distribution and long-chain branching, above all at high molecular weight fractions; the polymers have strain hardening equal or higher than 1.4 (at constant elongational rate of 0.5s -1 , at 150°C), branching index g' equal or lower than 0.9 (at Mw of 2⋅10 6 g/mol). The polymers are prepared by using a mixed catalyst system comprising a polymerization catalyst based on a late transition metal component having a tridentate ligand, and a Ziegler polymerization catalyst annealed at a temperature higher than 100°C, for a time of at least 10 minutes.
摘要翻译：新的乙烯聚合物具有宽分子量分布和长链支化，首先是高分子量级分; 聚合物具有等于或高于1.4的应变硬化（在150℃的恒定拉伸速率为0.5s -1，支化指数g'等于或低于0.9（Mw为2·10 6 g / mol）。通过使用包含基于具有三齿配体的后过渡金属组分的聚合催化剂和在高于100℃的温度下退火的齐格勒聚合催化剂至少10分钟的混合催化剂体系来制备聚合物。

3. 发明申请

WO2006114209A1 MOLDING COMPOSITION COMPRISING POLYETHYLENE FOR PREPARING FILMS AND PROCESS FOR PREPARING THE MOLDING COMPOSITION IN THE PRESENCE OF A MIXED CATALYST 审中-公开
标题翻译：包含聚乙烯的模塑组合物用于制备膜和在混合催化剂存在下制备模塑组合物的方法
公开(公告)号：WO2006114209A1
公开(公告)日：2006-11-02
申请号：PCT/EP2006/003474
申请日：2006-04-15
申请人： BASELL POLYOLEFINE GMBH , MIHAN, Shahram , LILGE, Dieter , KARER, Rainer , VOGT, Heinz , KIPKE, Jennifer
发明人： MIHAN, Shahram , LILGE, Dieter , KARER, Rainer , VOGT, Heinz , KIPKE, Jennifer
IPC分类号： C08F10/02 , C08F4/22 , C08F4/659
CPC分类号： C08J5/18 , C08F4/65912 , C08F4/65925 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08J2323/08 , C08L23/06 , C08L23/0815 , C08L2205/02 , C08L2314/04 , C08L2314/06 , Y02P20/52 , Y10T428/1352 , C08F4/69 , C08F4/025 , C08F4/65916 , C08L2666/06 , C08F2500/17 , C08F2500/12 , C08F2500/04 , C08F2500/26 , C08F2500/09 , C08F2500/18 , C08F210/14 , C08F4/6292 , C08F4/63904
摘要： Molding composition comprising polyethylene and having a density in the range from 0.915 to 0.955 g/cm 3 , an MI in the range from 0 to 3.5 g/10 min, an MFR in the range from 5 to 50, a polydispersity M w /M n in the range from 5 to 20, and a z-average moiar mass M z of less than 1 million g/mol, a process for preparing such a composition, a catalyst suitable for the preparation of the same, as well as films comprising this molding composition.
摘要翻译：包含聚乙烯的密度为0.915-0.955g / cm 3，MI为0-3.5g / 10min，MI为5至50的MFR的成型组合物，5至20范围内的多分散性M 1 / M N n N和小于1的z-平均摩尔质量M z z 制备这种组合物的方法，适用于其制备的催化剂以及包含该模塑组合物的薄膜。

4. 发明申请

WO2012152857A1 PROCESS FOR THE MANUFACTURE OF A MIXED CATALYST SYSTEM FOR THE COPOLYMERIZATION OF ETHYLENE WITH C1-C12 ALPHA-OLEFINS 审中-公开
标题翻译：用于乙烯与C 1 -C 12α-烯烃的共聚合的混合催化剂体系的制备方法
公开(公告)号：WO2012152857A1
公开(公告)日：2012-11-15
申请号：PCT/EP2012/058614
申请日：2012-05-10
申请人： BASELL POLYOLEFINE GMBH , RICHTER-LUKESOVA, Lenka , GALL, Barbara , MIHAN, Shahram , SCHIENDORFER, Michael
发明人： RICHTER-LUKESOVA, Lenka , GALL, Barbara , MIHAN, Shahram , SCHIENDORFER, Michael
IPC分类号： C08F210/16
CPC分类号： C08F210/16 , B01J31/1815 , B01J2231/12 , B01J2531/0241 , B01J2531/842 , C08F2410/04 , Y02P20/52 , C08F4/7042 , C08F4/6546 , C08F210/14 , C08F2500/12
摘要： A novel process for the manufacture of a mixed catalyst system by combining a Ziegler catalyst and a tridentate iron complex is described, which is characterized in that the reaction of a tridentate ligand with an iron compound is performed in an organic solvent containing less than 10 percent by weight, based on the total amount of the organic solvent, of electron donor compounds selected from the group consisting of ethers, aliphatic esters, aromatic esters, tertiary amines, amides, silanes, silazanes or orthoesters.
摘要翻译：描述了通过组合齐格勒催化剂和三齿铁络合物制备混合催化剂体系的新方法，其特征在于三齿配体与铁化合物的反应在含有少于10％基于有机溶剂的总量，选自醚，脂族酯，芳族酯，叔胺，酰胺，硅烷，硅氮烷或原酸酯的电子给体化合物。

5. 发明申请

WO2012084774A1 PROCESS FOR CONTROLLING THE RELATIVE ACTIVITY OF ACTIVE CENTERS OF CATALYST SYSTEMS COMPRISING AT LEAST ONE LATE TRANSITION METAL CATALYST COMPONENT AND AT LEAST ONE ZIEGLER CATALYST COMPONENT 审中-公开
标题翻译：用于控制包含至少一次过渡金属催化剂组分和至少一种齐格勒催化剂组分的催化剂体系的活性中心的相对活性的方法
公开(公告)号：WO2012084774A1
公开(公告)日：2012-06-28
申请号：PCT/EP2011/073178
申请日：2011-12-19
申请人： BASELL POLYOLEFINE GMBH , RICHTER-LUKESOVA, Lenka , SCHMITZ, Harald , MIHAN, Shahram , HERRERA SALINAS, Maclovio , MEIER, Gerhardus
发明人： RICHTER-LUKESOVA, Lenka , SCHMITZ, Harald , MIHAN, Shahram , HERRERA SALINAS, Maclovio , MEIER, Gerhardus
IPC分类号： C08F210/16
CPC分类号： C08F210/02 , C08F10/00 , C08F210/16 , C08F2400/02 , C08F2410/04 , C08F2/001 , C08F4/7042 , C08F210/14 , C08F2500/07 , C08F2500/10 , C08F2500/12
摘要： A method of controlling the polymer composition of an ethylene copolymer in a process for preparing ethylene copolymers by copolymerizing ethylene and at least one other olefin in the presence of a polymerization catalyst system comprising - at least one late transition metal catalyst component (A) having a tridentate ligand which bears at least two ortho, ortho'-disubstituted aryl radicals, - at least one Ziegler catalyst component (B), and - at least one activating compound (C) by varying the polymerization temperature, a process for copolymerizing ethylene and at least one other olefin in the presence of such a polymerization catalyst system comprising utilizing the controlling method, a method for altering the polymer composition of an ethylene copolymer obtained by copolymerizing ethylene and at least one other olefin in the presence of such a polymerization catalyst system by varying the polymerization temperature and a method for transitioning from one ethylene copolymer grade to another by using the method for altering the polymer composition.
摘要翻译：一种通过在聚合催化剂体系存在下共聚乙烯和至少一种其它烯烃来制备乙烯共聚物的方法中的乙烯共聚物的聚合物组合物的控制方法，所述聚合催化剂体系包含 - 至少一种后过渡金属催化剂组分（A）至少两个邻位，二取代的芳基的三齿配体， - 至少一种齐格勒催化剂组分（B）和 - 通过改变聚合温度的至少一种活化化合物（C），使乙烯和在这种聚合催化剂体系的存在下，至少一种其它的烯烃包括利用该控制方法，改变通过在这样的聚合催化剂体系存在下使乙烯与至少一种其它烯烃共聚获得的乙烯共聚物的聚合物组成的方法改变聚合温度和从一种乙烯共聚物级t转变的方法另一种是通过使用改变聚合物组成的方法。

6. 发明申请

WO2011089017A1 ULTRA-HIGH MOLECULAR WEIGHT POLYETHYLENE 审中-公开
标题翻译：超高分子量聚乙烯
公开(公告)号：WO2011089017A1
公开(公告)日：2011-07-28
申请号：PCT/EP2011/000282
申请日：2011-01-24
申请人： BASELL POLYOLEFINE GMBH , LUKESOVA, Lenka , KÖLLING, Lars , MIHAN, Shahram
发明人： LUKESOVA, Lenka , KÖLLING, Lars , MIHAN, Shahram
IPC分类号： C08F110/02
CPC分类号： C08F10/00 , C08F4/52 , C08F4/58 , C08F4/6392 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F4/76 , C08F110/02 , C08F2420/01 , C08F2500/01 , C08F2500/12 , C08F4/63904 , C08F2500/24
摘要： A novel UHMW polyethylene material, which is displaying excellent abrasion resistance amongst other properties, is devised.
摘要翻译：设计了一种新型UHMW聚乙烯材料，其具有优异的耐磨性等特性。

7. 发明申请

WO2011089000A1 PROCESS FOR THE PREPARATION OF ETHYLENE COPOLYMER COMPOSITIONS IN THE PRESENCE OF AN OLIGOMERIZATION CATALYST 审中-公开
标题翻译：在低级催化剂存在下制备乙烯共聚物组合物的方法
公开(公告)号：WO2011089000A1
公开(公告)日：2011-07-28
申请号：PCT/EP2011/000212
申请日：2011-01-20
申请人： BASELL POLYOLEFINE GMBH , SCHUHEN, Katrin , LUKESOVA, Lenka , MIHAN, Shahram
发明人： SCHUHEN, Katrin , LUKESOVA, Lenka , MIHAN, Shahram
IPC分类号： C08F110/02 , C08F210/16
CPC分类号： C08F110/02 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F10/00 , C08F210/16 , Y02P20/52 , C08F2/02 , C08F2/34 , C08F2500/07 , C08F2500/17 , C08F210/14 , C08F2500/05 , C08F2500/12 , C08F4/61904 , C08F4/7042
摘要： Process for the preparation of an ethylene copolymer composition having a polydispersity index M w /M n of from 3 to 100, comprising a) feeding ethylene to at least one polymerization reactor; b) performing in the at least one polymerization reactor an oligomerization of ethylene in the presence of an oligomerization catalyst component (C) to produce comonomer; c) performing simultaneously in the at least one polymerization reactor polymerization reactions in the presence of catalyst components (A) and (B) producing, respectively, a first and a second polyethylene fraction, wherein the weight average molecular weight M w of the first polyethylene fraction produced by catalyst component (A) is less than the M w of the second polyethylene fraction produced by catalyst component (B) and the comonomer incorporation ability of catalyst component (B) is higher than the comonomer incorporation ability of catalyst component (A); and d) withdrawing the ethylene copolymer composition from the polymerization reactor.
摘要翻译：制备多分散指数Mw / Mn为3至100的乙烯共聚物组合物的方法，包括：a）将乙烯进料至至少一个聚合反应器; b）在所述至少一个聚合反应器中在低聚催化剂组分（C）的存在下进行乙烯的低聚以产生共聚单体; c）在催化剂组分（A）和（B）的存在下在所述至少一个聚合反应器聚合反应中同时进行第一和第二聚乙烯级分的制备，其中第一聚乙烯级分的重均分子量Mw 由催化剂成分（A）制造的催化剂成分（B）的共聚单体引入能力低于催化剂成分（B）生成的第二聚乙烯馏分的Mw，催化剂成分（B）的共聚单体引入能力高于催化剂成分（A）的共聚单体引入能力。和d）从聚合反应器中取出乙烯共聚物组合物。

8. 发明申请

WO2007012406A1 METHOD OF CONTROLLING THE RELATIVE ACTIVITY OF THE DIFFERENT ACTIVE CENTERS OF HYBRID CATALYSTS 审中-公开
标题翻译：控制混合催化剂不同活性中心相对活性的方法
公开(公告)号：WO2007012406A1
公开(公告)日：2007-02-01
申请号：PCT/EP2006/006857
申请日：2006-07-13
申请人： BASELL POLYOLEFINE GMBH , MIHAN, Shahram , KARER, Rainer , SCHMITZ, Harald , LILGE, Dieter
发明人： MIHAN, Shahram , KARER, Rainer , SCHMITZ, Harald , LILGE, Dieter
IPC分类号： C08F210/16 , C08F2/40 , C08F2/42 , C08F4/70 , C08F4/6192
CPC分类号： C08F210/16 , C08F4/61916 , C08F4/61925 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F2400/02 , Y10S526/943 , C08F4/65925 , C08F4/61904 , C08F2/40 , C08F2/42 , C08F4/61912 , C08F2/00 , C08F210/14 , C08F2500/17 , C08F2500/04 , C08F2500/18 , C08F2500/12 , C08F4/7042
摘要： Method of preparing olefin polymers, which comprises the polymerization of at least one α-olefin in the presence of a hybrid catalyst to produce a polymer comprising at least a higher molecular weight polymer component and a lower molecular weight polymer component in the presence of water in an amount of from 2 to 100 mol ppm and/or carbon dioxide in an amount of from 2 to 100 mol ppm, in each case based on the total reaction mixture, in order to alter the ratio of the higher molecular weight polymer component to the lower molecular weight polymer component. This enables the ratio of the higher molecular weight component to the lower molecular weight component to be controlled selectively.
摘要翻译：制备烯烃聚合物的方法，其包括在杂化催化剂存在下聚合至少一种α-烯烃以在水存在下制备包含至少较高分子量聚合物组分和较低分子量聚合物组分的聚合物 2〜100摩尔ppm的量的二氧化碳和/或2〜100摩尔ppm的二氧化碳，相对于总反应混合物，为了将高分子量聚合物成分与低分子量聚合物组分。这使得能够选择性地控制较高分子量组分与较低分子量组分的比例。

9. 发明申请

WO2011072850A1 POLYMERIZATION PROCESS IN THE PRESENCE OF AN ANTISTATIC AGENT 审中-公开
标题翻译：抗静电剂存在下的聚合方法
公开(公告)号：WO2011072850A1
公开(公告)日：2011-06-23
申请号：PCT/EP2010/007668
申请日：2010-12-16
申请人： BASELL POLYOLEFINE GMBH , KOELLING, Lars , MIHAN, Shahram , MEIER, Gerhardus
发明人： KOELLING, Lars , MIHAN, Shahram , MEIER, Gerhardus
IPC分类号： C08F10/00 , C08F2/00
CPC分类号： C08F10/00 , C08F110/02 , C08F2/005 , C08F2500/12 , C08F2500/04
摘要： Process for the polymerization of olefins at temperatures of from -20 to 200°C and pressures of from 0.1 to 20 MPa in the presence of a polymerization catalyst and an antistatic agent, wherein the antistatic agent is an antistatically acting composition comprising a polysulfone copolymer, a polymeric compound comprising basic nitrogen atoms, an oil-soluble sulfonic acid and optionally a solvent and the polysulfone copolymer, the polymeric compound comprising basic nitrogen atoms and the oil-soluble sulfonic acid constitute together at least 1 wt.-% of the antistatically acting composition, and wherein the antistatically acting composition, when contacted as solution or suspension in heptane, wherein the solution or suspension has a concentration of about 80 g of the antistatically acting composition per liter of heptane, with a 2 M solution of triethylaluminum in heptane at 0°C, generates less than 5 cm 3 , measured at 23°C and atmospheric pressure, of ethane per gram of the antistatically acting composition and use of an antistatically acting composition as antistatic agent for the polymerization of olefins at temperatures of from -20 to 200°C and pressures of from 0.1 to 20 MPa in the presence of a polymerization catalyst.
摘要翻译：在聚合催化剂和抗静电剂存在下，在-20〜200℃的温度和0.1〜20MPa的压力下使烯烃聚合的方法，其中所述抗静电剂是包含聚砜共聚物的抗静电作用组合物，包含碱性氮原子的聚合化合物，油溶性磺酸和任选的溶剂和聚砜共聚物，包含碱性氮原子的聚合化合物和油溶性磺酸一起构成抗静电作用的至少1重量％组合物，并且其中所述抗静电作用组合物当作为溶液或悬浮液在庚烷中接触时，其中所述溶液或悬浮液的浓度为每升庚烷约80g抗静电作用组合物，与二乙基铝在庚烷中的2M溶液 0℃，在23℃和大气压下产生小于5cm 3的乙烷/克抗静电剂在-20℃至200℃的温度和0.1至20MPa的压力下，在聚合催化剂存在下，采用抗静电作用组合物作为抗静电剂的抗静电剂。

10. 发明申请

WO2005124324A1 NMR METHOD OF DETERMINING AND REGULATING THE COMPOSITION OF POLYMER MIXTURES IN POLYMERIZATION 审中-公开
标题翻译： NMR测定和调节聚合物混合物组合物的方法
公开(公告)号：WO2005124324A1
公开(公告)日：2005-12-29
申请号：PCT/EP2005/052683
申请日：2005-06-09
申请人： BASELL POLYOLEFINE GMBH , MIHAN, Shahram , LILGE, Dieter , ROHDE, Wolfgang
发明人： MIHAN, Shahram , LILGE, Dieter , ROHDE, Wolfgang
IPC分类号： G01N24/08
CPC分类号： G01N24/08 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2400/02 , G01N24/085 , G01R33/44 , Y02P20/125 , C08F2/00
摘要： Method of determining the composition of polymer mixtures comprising defined polymer components of differing mean molar masses M n , which comprises the steps (a) recording of at least one 1 H-NMR relaxation curve of the polymer mixture and (b) calculating the proportions of the polymer components by matching the measured relaxation curve with the relaxation curves of the individual polymer components. In this way, the composition of polymer mixtures can be determined quickly and simply. Furthermore, process integration for regulating the polymerization is possible.
摘要翻译：确定包含不同平均摩尔质量Mn的限定的聚合物组分的聚合物混合物的组成的方法，其包括步骤（a）记录聚合物混合物的至少一个1 H-NMR松弛曲线，（b）计算比例通过将测量的松弛曲线与各个聚合物组分的松弛曲线相匹配来获得聚合物组分。以这种方式，可以快速且简单地确定聚合物混合物的组成。此外，用于调节聚合的方法集成是可能的。

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