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    • 8. 发明申请
    • ULTRAVIOLET CURING PROCESS FOR POROUS LOW-K MATERIALS
    • 用于多孔低K材料的超紫外线固化方法
    • WO2003025994A1
    • 2003-03-27
    • PCT/US2002/029173
    • 2002-09-13
    • AXCELIS TECHNOLOGIES, INC.
    • ALBANO, RalphBARGERON, CoryBERRY, IvanBREMMER, JeffESCORCIA, OrlandoHAN, QingyuanMARGOLIS, AriWALDFRIED, Carlo
    • H01L21/316
    • H01L21/02126C09D183/02C09D183/04H01L21/0234H01L21/02348H01L21/3121H01L21/3122H01L21/31695
    • Low dielectric constant porous materials with improved elastic modulus. The process of making such porous materials involves providing a porous dielectric material and ultraviolet (UV) curing of the porous dielectric material to produce a UV cured porous dielectric material. UV curing of the porous dielectric material yields a material with improved modulus and comparable dielectric constant. The improvement in elastic modulus is typically greater than about 50%. The porous dielectric material is UV cured for no more than about 300 seconds at a temperature less than about 450°C. The UV cured porous dielectric material can optionally be post-UV treated. Rapid Anneal Processing (RAP) of the UV cured porous dielectric material reduces the dielectric constant of the material while maintaining an improved elastic modulus as compared to the UV cured porous dielectric material. The annealing temperature is typically less than about 450°C, and the annealing time is typically less than about 60 minutes. The post-UV treated, UV cured porous dielectric material has a dielectric constant between about 1.1 and about 3.5 and an improved elastic modulus.
    • 具有改善弹性模量的低介电常数多孔材料。 制造这种多孔材料的过程包括提供多孔电介质材料和多孔介电材料的紫外线(UV)固化以产生UV固化的多孔介电材料。 多孔介电材料的UV固化产生具有改进的模量和相当的介电常数的材料。 弹性模量的改善通常大于约50%。 多孔绝缘材料在小于约450℃的温度下UV固化不超过约300秒。UV固化的多孔电介质材料可以任选地进行后UV处理。 与UV固化的多孔介电材料相比,UV固化的多孔电介质材料的快速退火处理(RAP)降低了材料的介电常数,同时保持了改进的弹性模量。 退火温度通常小于约450℃,退火时间通常小于约60分钟。 后UV处理的UV固化多孔电介质材料的介电常数在约1.1和约3.5之间,并且具有改善的弹性模量。
    • 9. 发明申请
    • PLASMA CURING OF MSQ-BASED POROUS LOW-K FILM MATERIALS
    • 基于MSQ的多孔低K薄膜材料的等离子体固化
    • WO2003015150A1
    • 2003-02-20
    • PCT/US2002/022213
    • 2002-07-15
    • AXCELIS TECHNOLOGIES, INC.CHEMAT TECHNOLOGY, INC.
    • HAN, QingyuanWALDFRIED, CarloESCORCIA, OrlandoALBANO, RalphBERRY, Ivan, L., IIIJANG, JeffBALL, Ian
    • H01L21/312
    • C01B33/126H01L21/02137H01L21/02203H01L21/02282H01L21/0234H01L21/31058H01L21/3122H01L21/31695
    • Low dielectric constant film materials with improved elastic modulus. The method of making such film materials involves providing a porous methyl silsesquioxane based dielectric film material produced from a resin containing at least 2 Si-CH 3 groups and plasma curing the porous film material to convert the film into porous silica. Plasma curing of the porous film material yields a film with improved modulus and outgassing properties. The improvements in elastic modulus is typically greater than or about 100 %, and more typically greater than or about 200 %. The film is plasma cured for between about 15 and about 120 seconds at a temperature less than or about 350 °C. The plasma cured porous film material can optionally be annealed. The annealing of the plasma cured film may reduce the dielectric constant of the film while maintaining an improved elastic modulus as compared to the plasma cured porous film material. The annealing temperature is typically less than or about 450 °C. The annealed, plasma cured film has a dielectric constant in the range of from about 1.1 to about 2.4 and an improved elastic modulus.
    • 具有改善弹性模量的低介电常数薄膜材料。 制造这种膜材料的方法包括提供由含有至少2个Si-CH 3基团的树脂制备的多孔甲基倍半硅氧烷基电介质膜材料和等离子体固化多孔膜材料以将膜转化为多孔二氧化硅。 多孔膜材料的等离子体固化产生具有改进的模量和除气性质的膜。 弹性模量的改善通常大于或约100%,更典型地大于或约200%。 该膜在小于或约350℃的温度下等离子体固化约15至约120秒。等离子体固化的多孔膜材料可任选地退火。 与等离子体固化的多孔膜材料相比,等离子体固化膜的退火可以降低膜的介电常数,同时保持改善的弹性模量。 退火温度通常小于或约450℃。退火的等离子体固化膜具有约1.1至约2.4的介电常数和改进的弹性模量。