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1. 发明申请

WO2005000447A8 METHOD FOR PREPURIFYING AIR IN AN ACCELERATED TSA CYCLE 审中-公开
标题翻译：在加速TSA循环中预制空气的方法
公开(公告)号：WO2005000447A8
公开(公告)日：2005-03-10
申请号：PCT/FR2004050283
申请日：2004-06-18
申请人： AIR LIQUIDE , HEMERYCK CELINA , MONEREAU CHRISTIAN
发明人： HEMERYCK CELINA , MONEREAU CHRISTIAN
IPC分类号： B01D53/04
CPC分类号： B01D53/0431 , B01D53/0462 , B01D53/261 , B01D2253/104 , B01D2253/108 , B01D2257/404 , B01D2257/504 , B01D2257/702 , B01D2257/80 , B01D2259/40007 , B01D2259/40052 , B01D2259/4006 , B01D2259/4009 , B01D2259/402 , B01D2259/4146 , B01D2259/416 , Y02C10/08
摘要： The invention relates to a method for prepurifying air by means of adsorption, using two adsorption recipients operating alternately, in parallel, and in a TSA cycle, each recipient containing an adsorbent arranged on a radial adsorption bed, and each adsorption cycle consisting of (a) an adsorption stage during which the impurities are eliminated on the adsorbent at an adsorption temperature (rads), the air crossing the adsorption bed in a centripetal manner; (b) a regeneration stage during which the adsorbent is regenerated by flushing with a regeneration gas at a regeneration temperature (Treg), such as Treg > Tads, in order to desorb the impurities; et (c) an adsorbent cooling stage during which the temperature of the regenerated adsorbent is reduced. The maximum duration (rads) of the adsorption is 120 minutes, preferably between 60 and 120 minutes. The regeneration gas is introduced in such a way that it flushes the bed containing the adsorbent in the centrifugal direction. The maximum regeneration rate is 35 % of the adsorption rate. The regeneration temperature is reached by means of a heat exchanger arrange outside the adsorber.
摘要翻译：本发明涉及一种通过吸附预净化空气的方法，该方法使用交替操作的两个吸附接收器，并行地和在TSA循环中，每个接收器包含布置在径向吸附床上的吸附剂，并且每个吸附循环由（a ）吸附阶段，在吸附阶段期间吸附剂上的杂质在吸附温度（rads）下被消除，空气以向心方式穿过吸附床; （b）再生阶段，在该阶段中，通过在再生温度（Treg）下用再生气体冲洗再生吸附剂，例如Treg> Tads，以解吸杂质; 和（c）吸附剂冷却阶段，在此期间再生吸附剂的温度降低。吸附的最大持续时间（rads）是120分钟，优选60-120分钟。再生气体以这样的方式引入，即它在离心方向上冲洗含有吸附剂的床。最大再生率是吸附率的35％。借助布置在吸附器外部的热交换器达到再生温度。

2. 发明申请

WO2010001038A3 DUST-LADEN WET GAS TREATMENT 审中-公开
公开(公告)号：WO2010001038A3
公开(公告)日：2010-02-25
申请号：PCT/FR2009051130
申请日：2009-06-15
申请人： AIR LIQUIDE , MONEREAU CHRISTIAN , DARDE ARTHUR , BERTHELEMOT ANNE
发明人： MONEREAU CHRISTIAN , DARDE ARTHUR , BERTHELEMOT ANNE
IPC分类号： B01D53/047 , B01D53/26 , B01D53/62 , B01D53/75 , C01B32/50
CPC分类号： B01D53/047 , B01D53/0462 , B01D53/261 , B01D53/265 , B01D53/75 , B01D2253/102 , B01D2253/104 , B01D2253/106 , B01D2253/108 , B01D2256/22 , F23J15/08 , F23J2219/60
摘要： Method of producing a CO2-enriched gas from a feed gas comprising 10 to 75 mol% carbon dioxide (CO2), water vapour, at least one constituent chosen from hydrogen, CO, methane, nitrogen, oxygen and argon, and solid particles, employing a PSA unit, characterized in that the feed gas is at least partially dried upstream of the PSA unit and enters said PSA unit with a solid-particle concentration of between 0.01 and 100 mg/m3.
摘要翻译：包括10至75mol％二氧化碳（CO 2），水蒸气，至少一种选自氢，CO，甲烷，氮，氧和氩的组分和固体颗粒的进料气体生产富含CO 2的气体的方法，采用 PSA单元，其特征在于，所述进料气体至少部分地在所述PSA单元的上游被干燥，并以0.01至100mg / m 3的固体颗粒浓度进入所述PSA单元。

3. 发明申请

WO2008132377A3 LIMITING OF IMPURITY PEAKS 审中-公开
标题翻译：限制峰值
公开(公告)号：WO2008132377A3
公开(公告)日：2009-02-05
申请号：PCT/FR2008050478
申请日：2008-03-20
申请人： AIR LIQUIDE , MONEREAU CHRISTIAN , PULLUMBI PLUTON , RODRIGUES GUILLAUME
发明人： MONEREAU CHRISTIAN , PULLUMBI PLUTON , RODRIGUES GUILLAUME
IPC分类号： C01B3/56 , B01D53/047
CPC分类号： C01B3/56 , B01D53/04 , B01D53/047 , B01D2253/108 , B01D2253/342 , B01D2256/16 , B01D2257/502 , B01D2259/41 , C01B2203/047
摘要： A process of purifying or separating a feed gas stream containing hydrogen H2 and a molar content of carbon monoxide (CO) greater than or equal to 1000 ppm, in which: a) said feed gas stream is introduced continuously into a first purification unit (10) of the PSA type containing a first adsorbent on which the CO is preferably adsorbed; b) the gas originating from step a), at least partially purified of CO and having an average molar CO content T less than or equal to Tacc and selectively a first maximum CO content TMo greater than Tacc, is recovered; c) the gas originating from step b) is introduced into a downstream adsorber (20) containing at least a second adsorbent (21) on which the CO is preferably adsorbed; d) the H2-enriched gas originating from step c) having an average CO content T and a maximum CO content TMi that are both less than or equal to Tacc, is recovered, characterized in that Tacc is less than or equal to 100 ppm.
摘要翻译：一种净化或分离含氢H 2和一氧化碳（CO）的摩尔含量大于或等于1000ppm的进料气流的方法，其中：a）将所述进料气流连续引入第一纯化单元（10 ）含有优选吸附有CO的第一吸附剂的PSA型; b）回收至少部分纯化的CO并且具有小于或等于Tacc的平均摩尔CO含量T和选择性地大于Tacc的第一最大CO含量TMo的气体; c）将来自步骤b）的气体引入含有至少第二吸附剂（21）的下游吸附器（20），CO吸附在其上优选被吸附; d）回收源自小于或等于Tacc的平均CO含量T和最大CO含量TMi的步骤c）的富H 2气体，其特征在于Tacc小于或等于100ppm。

4. 发明申请

WO2016003484A3 A RAPID TEMPERATURE SWING ADSORPTION (RTSA) METHOD USING STRUCTURED ADSORBENT FOR CO2 CAPTURE FROM LOW PRESSURE AND LOW CO2 CONCENTRATION SOURCES 审中-公开
标题翻译：使用结构吸附剂从低压和低二氧化碳浓度来源获得二氧化碳捕获的快速温度吸收（RTSA）方法
公开(公告)号：WO2016003484A3
公开(公告)日：2016-03-03
申请号：PCT/US2014066721
申请日：2014-11-20
申请人： AIR LIQUIDE , CHEN YUDONG , MONEREAU CHRISTIAN , SANDERS JR EDGAR S , TESSIER PASCAL
发明人： CHEN YUDONG , MONEREAU CHRISTIAN , SANDERS JR EDGAR S , TESSIER PASCAL
IPC分类号： B01D53/04
CPC分类号： B01D53/0462 , B01D53/0438 , B01D53/06 , B01D2253/108 , B01D2253/342 , B01D2253/3425 , B01D2256/10 , B01D2257/504 , B01D2257/80 , B01D2258/0233 , B01D2258/0283 , B01D2259/40001 , B01D2259/40011 , B01D2259/403 , B01D2259/404 , Y02C10/08
摘要： A Temperature Swing Adsorption method for separating a first component, comprising a more adsorbable component, from a feed stream comprising more than 50 mol% of a second component, comprising a less adsorbable component, is provided. The method includes providing an adsorbent structure suitable for adsorbing the first component, the structure being of the parallel passage contactor type, and cyclically implementing the following steps. Passing the feed stream through the adsorbent structure thus adsorbing the first component and producing a stream depleted in the first component and enriched in the second component. Heating the adsorbent structure to desorb the adsorbed first component by means of circulating a heating stream enriched in the first component at a temperature suitable for regeneration. And cooling the structure by means of passing through it more than 50% of the stream enriched in the second component produced in the step a).
摘要翻译：提供了一种用于从包含较多可吸附组分的包含多于50mol％的第二组分的进料流中分离包含更易吸附组分的第一组分的温度摆动吸附方法。该方法包括提供适于吸附第一组分的吸附结构，该结构是平行通道接触器类型，并循环地实施以下步骤。使进料流通过吸附剂结构从而吸附第一组分并产生在第一组分中贫化并富含第二组分的流。加热吸附剂结构以通过在适于再生的温度下循环富含第一组分的加热流来解吸所吸附的第一组分。并且通过使超过50％的富含步骤a）中生成的第二组分的物流通过其冷却结构。

5. 发明申请

WO2009010692A3 METHOD FOR ELIMINATING MERCURY FROM A GAS CONTAINING CO2 AND OXYGEN 审中-公开
标题翻译：从含有CO 2和氧气的气体中除去汞的方法
公开(公告)号：WO2009010692A3
公开(公告)日：2009-03-26
申请号：PCT/FR2008051275
申请日：2008-07-08
申请人： AIR LIQUIDE , COURT PHILIPPE , DARDE ARTHUR , HASANOV VLADIMIR , MONEREAU CHRISTIAN , MOREAU SERGE , TRANIER JEAN-PIERRE
发明人： COURT PHILIPPE , DARDE ARTHUR , HASANOV VLADIMIR , MONEREAU CHRISTIAN , MOREAU SERGE , TRANIER JEAN-PIERRE
IPC分类号： B01D53/04 , B01J20/02 , C01B32/50 , F23J15/02
CPC分类号： F23J15/02 , B01D53/04 , B01D53/64 , B01D2253/102 , B01D2253/104 , B01D2255/104 , B01D2257/602 , F23J2215/60 , F23J2219/30 , F23J2219/60
摘要： The invention relates to a method for the purification of a feed gas stream at a pressure of = 3 bar, containing at least 1 vol.-% oxygen (O2) and at least 75 vol.-% CO2 and mercury. The invention is characterised in that it includes an adsorption purification step comprising the use of at least one fixed adsorbent bed containing a sulphur and/or silver adsorbent, such as to eliminate the mercury at least partially.
摘要翻译：本发明涉及一种用于净化含有至少1体积％氧气（O 2）和至少75体积％CO 2和汞的= 3巴压力的进料气流的方法。本发明的特征在于它包括吸附纯化步骤，该步骤包括使用至少一个含有硫和/或银吸附剂的固定吸附床，以便至少部分地除去汞。

6. 发明申请

WO2009010690A3 METHOD FOR THE PURIFICATION OF A GAS CONTAINING CO2 审中-公开
标题翻译：净化含二氧化碳的气体的方法
公开(公告)号：WO2009010690A3
公开(公告)日：2009-03-19
申请号：PCT/FR2008051273
申请日：2008-07-08
申请人： AIR LIQUIDE , ALBAN BRUNO , CLAEYS CHRISTOPHE , COURT PHILIPPE , DARDE ARTHUR , DE SMEDT GUILLAUME , HA BAO , HASANOV VLADIMIR , JALLAIS SIMON , MONEREAU CHRISTIAN , MOREAU SERGE , RENOU ELISE , SANCHEZ-MOLINERO IVAN , TRANIER JEAN-PIERRE
发明人： ALBAN BRUNO , CLAEYS CHRISTOPHE , COURT PHILIPPE , DARDE ARTHUR , DE SMEDT GUILLAUME , HA BAO , HASANOV VLADIMIR , JALLAIS SIMON , MONEREAU CHRISTIAN , MOREAU SERGE , RENOU ELISE , SANCHEZ-MOLINERO IVAN , TRANIER JEAN-PIERRE
IPC分类号： B01D53/02 , C01B32/50 , F25J3/00
CPC分类号： F25J3/067 , B01D53/002 , B01D53/0462 , B01D53/047 , B01D53/12 , B01D2253/102 , B01D2256/22 , B01D2257/102 , B01D2257/104 , B01D2257/11 , B01D2257/2045 , B01D2257/2047 , B01D2257/2064 , B01D2257/302 , B01D2257/304 , B01D2257/404 , B01D2257/408 , B01D2257/504 , B01D2257/60 , B01D2257/708 , B01D2257/80 , C01B32/50 , F25J2205/40 , F25J2205/60 , F25J2210/70 , F25J2220/82 , F25J2230/30 , F25J2230/80 , Y02C10/08 , Y02C10/12 , Y02P20/129 , Y02P20/152 , Y02P20/154 , Y02P20/544
摘要： The invention relates to a method for the purification of a feed gas stream containing CO2 and at least one impurity, comprising the following successive steps: a) a pre-treatment step; b) a compression step; c) a step comprising the elimination of at least one impurity contained in the compressed gas stream, selected from nitrogen, oxygen, argon and noble gases, using exchangers combined with separators in a cold cycle, i.e. temperature 2-enriched purified gas stream is recovered in liquid, gaseous or supercritical form. The invention is characterised in that a purification step is performed between steps (a) and (c) in order to eliminate at least paritally at least one impuritiy selected from nitrogen oxides and water.
摘要翻译：本发明涉及一种纯化含有CO 2和至少一种杂质的进料气流的方法，包括以下连续步骤：a）预处理步骤; b）压缩步骤; c）包括在冷循环中使用与分离器结合的交换器来消除选自氮气，氧气，氩气和稀有气体的压缩气流中所含的至少一种杂质，即回收温度为2的富集纯化气流以液体，气体或超临界形式。本发明的特征在于在步骤（a）和（c）之间进行纯化步骤以至少部分地消除选自氮氧化物和水的至少一种杂质。

7. 发明申请

WO2015102765A3 A METHOD OF MANUFACTURING A STRUCTURED ADSORBENT BED FOR CAPTURE OF CO2 FROM LOW PRESSURE AND LOW CONCENTRATION SOURCES 审中-公开
标题翻译：制造用于从低压和低浓度源捕获CO2的结构化吸附床的方法
公开(公告)号：WO2015102765A3
公开(公告)日：2015-09-03
申请号：PCT/US2014066724
申请日：2014-11-20
申请人： AIR LIQUIDE , CHEN YUDONG , MONEREAU CHRISTIAN , SANDERS EDGAR S JR , TESSIER PASCAL
发明人： CHEN YUDONG , MONEREAU CHRISTIAN , SANDERS EDGAR S JR , TESSIER PASCAL
IPC分类号： B01J20/08 , B01D53/047 , B01J20/10 , B01J20/20 , B01J20/22 , B01J20/28 , B01J20/30 , B01J20/34 , B32B38/00
CPC分类号： B01J20/3085 , B01D53/02 , B01D53/0438 , B01D53/047 , B01D2253/10 , B01D2253/102 , B01D2253/104 , B01D2253/106 , B01D2253/108 , B01D2253/204 , B01D2253/34 , B01D2257/504 , B01D2259/40096 , B01J20/08 , B01J20/10 , B01J20/103 , B01J20/165 , B01J20/18 , B01J20/20 , B01J20/226 , B01J20/28004 , B01J20/28007 , B01J20/2803 , B01J20/28035 , B01J20/2804 , B01J20/3042 , B01J20/3441 , Y02C10/08 , Y10T156/10
摘要： A method of forming a structured adsorbent sheet is provided. The method includes, combining a nano-adsorbent powder and a binder material to form an adsorbent material, and sandwiching a porous electrical heating substrate between two layers of adsorbent material. The nano-adsorbent powder may be a nano-particle adsorbent. The nano-adsorbent powder may be selected from the group consisting of crystal zeolite, activated carbon, activated alumina, silica gel, and metal organic framework (MOF).
摘要翻译：提供了一种形成结构化吸附片的方法。该方法包括将纳米吸附剂粉末和粘合剂材料组合以形成吸附剂材料，并将多孔电加热衬底夹在两层吸附剂材料之间。纳米吸附剂粉末可以是纳米颗粒吸附剂。纳米吸附剂粉末可以选自晶体沸石，活性炭，活性氧化铝，硅胶和金属有机骨架（MOF）。

8. 发明申请

WO2008139085A3 METHOD FOR COOLING A CRYOGENIC EXCHANGE LINE 审中-公开
标题翻译：冷冻冷冻交换线的方法
公开(公告)号：WO2008139085A3
公开(公告)日：2013-02-28
申请号：PCT/FR2008050575
申请日：2008-04-02
申请人： AIR LIQUIDE , COURT PHILIPPE , HERNANDEZ ANTOINE , MONEREAU CHRISTIAN
发明人： COURT PHILIPPE , HERNANDEZ ANTOINE , MONEREAU CHRISTIAN
IPC分类号： F25J3/02 , F25B9/02 , F25J1/02 , F25J3/06
CPC分类号： F25J3/0695 , F25J1/0022 , F25J1/0055 , F25J1/0247 , F25J3/0295 , F25J3/062 , F25J3/0635 , F25J3/064 , F25J3/0655 , F25J2210/42 , F25J2240/40 , F25J2245/02 , F25J2270/04 , F25J2270/18 , F25J2270/904 , F25J2280/10
摘要： The invention relates to a method for the cryogenic separation, the cooling or the liquefaction of a fluid using an exchange line, that comprises extracting from said exchange line at least one dual phase fluid (11), separating said dual phase fluid into at least one vapour fraction (4) and one liquid fraction (5) in a phase separator (40), expanding at least one portion of the liquid fraction (5) using a first expansion means (60, 90), reinjecting, reheating and at least partially vaporising said expanded liquid fraction in the exchange line, the first expansion means being a valve, wherein during the cooling of said exchange line, at least a fraction of the fluid extracted from the exchange line (2, 4 or 5) and/or from the phase separator (40) is expanded in second expansion means (61, 71, 81, 91) parallel to the first expansion means (6), while during a normal operation, the second expansion means is essentially closed.
摘要翻译：本发明涉及一种用于低温分离，使用交换线冷却或液化流体的方法，其包括从所述交换管线提取至少一个双相流体（11），将所述双相流体分离成至少一个在相分离器（40）中的蒸气馏分（4）和一个液体馏分（5），使用第一膨胀装置（60,90）使至少一部分液体馏分（5）膨胀，再注入，再加热和至少部分地在所述交换管线中蒸发所述膨胀的液体馏分，所述第一膨胀装置是阀，其中在所述交换管线的冷却期间，从所述交换管线（2,4或5）提取的至少一部分流体和/ 相分离器40在与第一膨胀机构6平行的第二膨胀机构61,71,81,91中膨胀，而在正常运转时，第二膨胀机构基本上是闭合的。

9. 发明申请

WO2008099106A3 METHOD AND APPARATUS FOR PRODUCING CARBON MONOXIDE BY CRYOGENIC DISTILLATION 审中-公开
标题翻译：通过低温蒸馏生产一氧化碳的方法和装置
公开(公告)号：WO2008099106A3
公开(公告)日：2009-05-22
申请号：PCT/FR2008050046
申请日：2008-01-10
申请人： AIR LIQUIDE , BRIGLIA ALAIN , COURT PHILIPPE , HAIK-BERAUD NATACHA , HERNANDEZ ANTOINE , MONEREAU CHRISTIAN
发明人： BRIGLIA ALAIN , COURT PHILIPPE , HAIK-BERAUD NATACHA , HERNANDEZ ANTOINE , MONEREAU CHRISTIAN
IPC分类号： F25J3/02 , C01B3/50 , C01B32/40
CPC分类号： F25J3/0223 , C01B3/506 , C01B32/40 , C01B2203/046 , C01B2203/047 , F25J3/0252 , F25J3/0261 , F25J2205/02 , F25J2205/04 , F25J2205/30 , F25J2210/06 , F25J2210/42 , F25J2240/40 , F25J2245/02 , F25J2270/02 , F25J2270/904 , F25J2280/02
摘要： The invention relates to an apparatus for producing carbon monoxide by cryogenic distillation, that comprises an exchange line (7) in which a mixture containing at least carbon monoxide and hydrogen is cooled and partially condensed, a phase separator (11), a stripping column (23), a duct (15) for feeding the liquid from the phase separator to the stripping column, a duct (25) for drawing a carbon monoxide-rich liquid at the vat of the stripping column, a duct (51) for drawing the residual gas at the head of the stripping column, and a duct (53) for injecting liquid nitrogen into the stripping column.
摘要翻译：本发明涉及一种用于通过低温蒸馏生产一氧化碳的装置，其包括其中至少包含一氧化碳和氢气的混合物被冷却并部分冷凝的交换管线（7），相分离器（11），汽提塔 23），用于将液体从相分离器供给到汽提塔的管道（15），用于在汽提塔的槽处抽出富含一氧化碳的液体的管道（25），用于拉伸汽提塔头部的残留气体，以及用于将液氮注入汽提塔的管道（53）。

10. 发明申请

WO2008078028A3 RADIAL ABSORBERS INSTALLED IN PARALLEL 审中-公开
标题翻译：径向吸收器并联安装
公开(公告)号：WO2008078028A3
公开(公告)日：2008-11-06
申请号：PCT/FR2007052453
申请日：2007-12-06
申请人： AIR LIQUIDE , BELLEC INGRID , MONEREAU CHRISTIAN
发明人： BELLEC INGRID , MONEREAU CHRISTIAN
IPC分类号： B01D53/04 , B01D53/047
CPC分类号： B01D53/0431 , B01D53/0462 , B01D53/047 , B01D2257/504 , Y02C10/08
摘要： The invention relates to a method for the purification or separation of a gas mixture with at least two constituents, such as air or CO 2 containing impurities, comprising at least two groups of absorbers with each group containing at least two parallel absorbers which are each subjected to a pressure cycle consisting of a gas production phase and a regeneration phase, each phase comprising one or more steps. The invention is characterised in that at least two absorbers from each group are in the same phase and operate in unison for at least 75% of each of the phases of the cycle. The invention also relates to the facility used to carry out said method.
摘要翻译：本发明涉及一种用于纯化或分离具有至少两种成分（例如空气或含有杂质的CO 2）的气体混合物的方法，其包含至少两组吸收剂，每一组吸收剂至少含有两个平行吸收器，每个吸收器经历由气体生产阶段和再生阶段组成的压力循环，每个阶段包括一个或多个步骤。本发明的特征在于，来自每个组的至少两个吸收器处于同一相并且对于该循环的每个阶段的至少75％一致地操作。本发明还涉及用于执行所述方法的设施。

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