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1. 发明申请

WO2008099106A3 METHOD AND APPARATUS FOR PRODUCING CARBON MONOXIDE BY CRYOGENIC DISTILLATION 审中-公开
标题翻译：通过低温蒸馏生产一氧化碳的方法和装置
公开(公告)号：WO2008099106A3
公开(公告)日：2009-05-22
申请号：PCT/FR2008050046
申请日：2008-01-10
申请人： AIR LIQUIDE , BRIGLIA ALAIN , COURT PHILIPPE , HAIK-BERAUD NATACHA , HERNANDEZ ANTOINE , MONEREAU CHRISTIAN
发明人： BRIGLIA ALAIN , COURT PHILIPPE , HAIK-BERAUD NATACHA , HERNANDEZ ANTOINE , MONEREAU CHRISTIAN
IPC分类号： F25J3/02 , C01B3/50 , C01B32/40
CPC分类号： F25J3/0223 , C01B3/506 , C01B32/40 , C01B2203/046 , C01B2203/047 , F25J3/0252 , F25J3/0261 , F25J2205/02 , F25J2205/04 , F25J2205/30 , F25J2210/06 , F25J2210/42 , F25J2240/40 , F25J2245/02 , F25J2270/02 , F25J2270/904 , F25J2280/02
摘要： The invention relates to an apparatus for producing carbon monoxide by cryogenic distillation, that comprises an exchange line (7) in which a mixture containing at least carbon monoxide and hydrogen is cooled and partially condensed, a phase separator (11), a stripping column (23), a duct (15) for feeding the liquid from the phase separator to the stripping column, a duct (25) for drawing a carbon monoxide-rich liquid at the vat of the stripping column, a duct (51) for drawing the residual gas at the head of the stripping column, and a duct (53) for injecting liquid nitrogen into the stripping column.
摘要翻译：本发明涉及一种用于通过低温蒸馏生产一氧化碳的装置，其包括其中至少包含一氧化碳和氢气的混合物被冷却并部分冷凝的交换管线（7），相分离器（11），汽提塔 23），用于将液体从相分离器供给到汽提塔的管道（15），用于在汽提塔的槽处抽出富含一氧化碳的液体的管道（25），用于拉伸汽提塔头部的残留气体，以及用于将液氮注入汽提塔的管道（53）。

2. 发明申请

WO2008139085A3 METHOD FOR COOLING A CRYOGENIC EXCHANGE LINE 审中-公开
标题翻译：冷冻冷冻交换线的方法
公开(公告)号：WO2008139085A3
公开(公告)日：2013-02-28
申请号：PCT/FR2008050575
申请日：2008-04-02
申请人： AIR LIQUIDE , COURT PHILIPPE , HERNANDEZ ANTOINE , MONEREAU CHRISTIAN
发明人： COURT PHILIPPE , HERNANDEZ ANTOINE , MONEREAU CHRISTIAN
IPC分类号： F25J3/02 , F25B9/02 , F25J1/02 , F25J3/06
CPC分类号： F25J3/0695 , F25J1/0022 , F25J1/0055 , F25J1/0247 , F25J3/0295 , F25J3/062 , F25J3/0635 , F25J3/064 , F25J3/0655 , F25J2210/42 , F25J2240/40 , F25J2245/02 , F25J2270/04 , F25J2270/18 , F25J2270/904 , F25J2280/10
摘要： The invention relates to a method for the cryogenic separation, the cooling or the liquefaction of a fluid using an exchange line, that comprises extracting from said exchange line at least one dual phase fluid (11), separating said dual phase fluid into at least one vapour fraction (4) and one liquid fraction (5) in a phase separator (40), expanding at least one portion of the liquid fraction (5) using a first expansion means (60, 90), reinjecting, reheating and at least partially vaporising said expanded liquid fraction in the exchange line, the first expansion means being a valve, wherein during the cooling of said exchange line, at least a fraction of the fluid extracted from the exchange line (2, 4 or 5) and/or from the phase separator (40) is expanded in second expansion means (61, 71, 81, 91) parallel to the first expansion means (6), while during a normal operation, the second expansion means is essentially closed.
摘要翻译：本发明涉及一种用于低温分离，使用交换线冷却或液化流体的方法，其包括从所述交换管线提取至少一个双相流体（11），将所述双相流体分离成至少一个在相分离器（40）中的蒸气馏分（4）和一个液体馏分（5），使用第一膨胀装置（60,90）使至少一部分液体馏分（5）膨胀，再注入，再加热和至少部分地在所述交换管线中蒸发所述膨胀的液体馏分，所述第一膨胀装置是阀，其中在所述交换管线的冷却期间，从所述交换管线（2,4或5）提取的至少一部分流体和/ 相分离器40在与第一膨胀机构6平行的第二膨胀机构61,71,81,91中膨胀，而在正常运转时，第二膨胀机构基本上是闭合的。

3. 发明申请

WO2010136698A3 SCRUBBING A GAS CONTAINING NITROGEN OXIDES 审中-公开
标题翻译：包含氮氧化物的气体
公开(公告)号：WO2010136698A3
公开(公告)日：2011-01-20
申请号：PCT/FR2010050952
申请日：2010-05-18
申请人： AIR LIQUIDE , BRIGLIA ALAIN , GRANADOS LUDOVIC , MONEREAU CHRISTIAN , RENOU ELISE
发明人： BRIGLIA ALAIN , GRANADOS LUDOVIC , MONEREAU CHRISTIAN , RENOU ELISE
IPC分类号： B01D53/56 , B01D53/86
CPC分类号： B01D53/56 , B01D53/002 , B01D53/75 , B01D53/8625 , B01D2253/102 , B01D2253/104 , B01D2253/106 , B01D2255/30 , B01D2257/404 , B01D2257/80 , F25J3/0266 , F25J2205/40 , F25J2205/82 , F25J2220/84 , Y02C10/12
摘要： The invention relates to a method for removing nitrogen monoxide (NO) and nitrogen oxides (NOx with x>1) from a gas stream, implementing a device including a catalytic bed for converting a portion at least a part of the NO into NOx with x>1, and a unit for reducing the NOx with x>1, and in which the gas stream is placed into contact with the catalytic bed before entering the unit for reducing the NOx with x>1.
摘要翻译：本发明涉及一种从气流中除去一氧化氮（NO）和氮氧化物（NOx> x> 1）的方法，实现了一种装置，该装置包括催化床，用于将至少一部分NO转化为NOx， > 1，并且用于将x x还原为NOx的单元，其中在进入用于还原NO x的单元之前，气流与催化剂床接触，x> 1。

4. 发明申请

WO2009010692A3 METHOD FOR ELIMINATING MERCURY FROM A GAS CONTAINING CO2 AND OXYGEN 审中-公开
标题翻译：从含有CO 2和氧气的气体中除去汞的方法
公开(公告)号：WO2009010692A3
公开(公告)日：2009-03-26
申请号：PCT/FR2008051275
申请日：2008-07-08
申请人： AIR LIQUIDE , COURT PHILIPPE , DARDE ARTHUR , HASANOV VLADIMIR , MONEREAU CHRISTIAN , MOREAU SERGE , TRANIER JEAN-PIERRE
发明人： COURT PHILIPPE , DARDE ARTHUR , HASANOV VLADIMIR , MONEREAU CHRISTIAN , MOREAU SERGE , TRANIER JEAN-PIERRE
IPC分类号： B01D53/04 , B01J20/02 , C01B32/50 , F23J15/02
CPC分类号： F23J15/02 , B01D53/04 , B01D53/64 , B01D2253/102 , B01D2253/104 , B01D2255/104 , B01D2257/602 , F23J2215/60 , F23J2219/30 , F23J2219/60
摘要： The invention relates to a method for the purification of a feed gas stream at a pressure of = 3 bar, containing at least 1 vol.-% oxygen (O2) and at least 75 vol.-% CO2 and mercury. The invention is characterised in that it includes an adsorption purification step comprising the use of at least one fixed adsorbent bed containing a sulphur and/or silver adsorbent, such as to eliminate the mercury at least partially.
摘要翻译：本发明涉及一种用于净化含有至少1体积％氧气（O 2）和至少75体积％CO 2和汞的= 3巴压力的进料气流的方法。本发明的特征在于它包括吸附纯化步骤，该步骤包括使用至少一个含有硫和/或银吸附剂的固定吸附床，以便至少部分地除去汞。

5. 发明申请

WO2009010690A3 METHOD FOR THE PURIFICATION OF A GAS CONTAINING CO2 审中-公开
标题翻译：净化含二氧化碳的气体的方法
公开(公告)号：WO2009010690A3
公开(公告)日：2009-03-19
申请号：PCT/FR2008051273
申请日：2008-07-08
申请人： AIR LIQUIDE , ALBAN BRUNO , CLAEYS CHRISTOPHE , COURT PHILIPPE , DARDE ARTHUR , DE SMEDT GUILLAUME , HA BAO , HASANOV VLADIMIR , JALLAIS SIMON , MONEREAU CHRISTIAN , MOREAU SERGE , RENOU ELISE , SANCHEZ-MOLINERO IVAN , TRANIER JEAN-PIERRE
发明人： ALBAN BRUNO , CLAEYS CHRISTOPHE , COURT PHILIPPE , DARDE ARTHUR , DE SMEDT GUILLAUME , HA BAO , HASANOV VLADIMIR , JALLAIS SIMON , MONEREAU CHRISTIAN , MOREAU SERGE , RENOU ELISE , SANCHEZ-MOLINERO IVAN , TRANIER JEAN-PIERRE
IPC分类号： B01D53/02 , C01B32/50 , F25J3/00
CPC分类号： F25J3/067 , B01D53/002 , B01D53/0462 , B01D53/047 , B01D53/12 , B01D2253/102 , B01D2256/22 , B01D2257/102 , B01D2257/104 , B01D2257/11 , B01D2257/2045 , B01D2257/2047 , B01D2257/2064 , B01D2257/302 , B01D2257/304 , B01D2257/404 , B01D2257/408 , B01D2257/504 , B01D2257/60 , B01D2257/708 , B01D2257/80 , C01B32/50 , F25J2205/40 , F25J2205/60 , F25J2210/70 , F25J2220/82 , F25J2230/30 , F25J2230/80 , Y02C10/08 , Y02C10/12 , Y02P20/129 , Y02P20/152 , Y02P20/154 , Y02P20/544
摘要： The invention relates to a method for the purification of a feed gas stream containing CO2 and at least one impurity, comprising the following successive steps: a) a pre-treatment step; b) a compression step; c) a step comprising the elimination of at least one impurity contained in the compressed gas stream, selected from nitrogen, oxygen, argon and noble gases, using exchangers combined with separators in a cold cycle, i.e. temperature 2-enriched purified gas stream is recovered in liquid, gaseous or supercritical form. The invention is characterised in that a purification step is performed between steps (a) and (c) in order to eliminate at least paritally at least one impuritiy selected from nitrogen oxides and water.
摘要翻译：本发明涉及一种纯化含有CO 2和至少一种杂质的进料气流的方法，包括以下连续步骤：a）预处理步骤; b）压缩步骤; c）包括在冷循环中使用与分离器结合的交换器来消除选自氮气，氧气，氩气和稀有气体的压缩气流中所含的至少一种杂质，即回收温度为2的富集纯化气流以液体，气体或超临界形式。本发明的特征在于在步骤（a）和（c）之间进行纯化步骤以至少部分地消除选自氮氧化物和水的至少一种杂质。

6. 发明申请

WO2009010691A3 METHOD FOR THE PURIFICATION OF A GAS CONTAINING CO2, USING AN ADSORPTION PURIFICATION UNIT 审中-公开
标题翻译：利用吸附净化装置净化含CO 2气体的方法
公开(公告)号：WO2009010691A3
公开(公告)日：2009-03-19
申请号：PCT/FR2008051274
申请日：2008-07-08
申请人： AIR LIQUIDE , ALBAN BRUNO , CLAEYS CHRISTOPHE , COURT PHILIPPE , DARDE ARTHUR , DE SMEDT GUILLAUME , HA BAO , HASANOV VLADIMIR , JALLAIS SIMON , MONEREAU CHRISTIAN , MOREAU SERGE , RENOU ELISE , SANCHEZ-MOLINERO IVAN , TRANIER JEAN-PIERRE
发明人： ALBAN BRUNO , CLAEYS CHRISTOPHE , COURT PHILIPPE , DARDE ARTHUR , DE SMEDT GUILLAUME , HA BAO , HASANOV VLADIMIR , JALLAIS SIMON , MONEREAU CHRISTIAN , MOREAU SERGE , RENOU ELISE , SANCHEZ-MOLINERO IVAN , TRANIER JEAN-PIERRE
IPC分类号： B01D53/02 , C01B32/50 , F25J3/00
CPC分类号： F25J3/067 , B01D53/0462 , B01D2253/106 , B01D2256/22 , B01D2257/102 , B01D2257/302 , B01D2257/404 , B01D2257/80 , F25J2205/40 , F25J2205/60 , F25J2210/70 , F25J2220/82 , F25J2230/30 , F25J2230/32 , F25J2230/80 , Y02C10/12
摘要： The invention relates to a method for the purification of a feed gas stream containing CO2 and at least one impurity selected from water, SOx and NOx, comprising the following successive steps: a) a pre-treatment step; b) a compression step; and c) a step in which the CO2-enriched purified gas stream is recovered in liquid, gaseous or supercritical form. The invention is characterised in that a purification step is performed between steps (a) and (c), using at least a first bed of NOx- and/or SOx-neutral adsorbents having adsorption properties enabling at least the partial elimination of the water.
摘要翻译：本发明涉及一种纯化含有CO 2和至少一种选自水，SO x和NO x的杂质的进料气流的方法，包括以下连续步骤：a）预处理步骤; b）压缩步骤; 和c）富含CO 2的纯化气流以液体，气体或超临界形式回收的步骤。本发明的特征在于，在步骤（a）和（c）之间使用具有至少部分消除水的吸附性质的至少第一NOx吸附剂床和/或SOx中性吸附剂床进行纯化步骤。

7. 发明申请

WO2010001038A3 DUST-LADEN WET GAS TREATMENT 审中-公开
公开(公告)号：WO2010001038A3
公开(公告)日：2010-02-25
申请号：PCT/FR2009051130
申请日：2009-06-15
申请人： AIR LIQUIDE , MONEREAU CHRISTIAN , DARDE ARTHUR , BERTHELEMOT ANNE
发明人： MONEREAU CHRISTIAN , DARDE ARTHUR , BERTHELEMOT ANNE
IPC分类号： B01D53/047 , B01D53/26 , B01D53/62 , B01D53/75 , C01B32/50
CPC分类号： B01D53/047 , B01D53/0462 , B01D53/261 , B01D53/265 , B01D53/75 , B01D2253/102 , B01D2253/104 , B01D2253/106 , B01D2253/108 , B01D2256/22 , F23J15/08 , F23J2219/60
摘要： Method of producing a CO2-enriched gas from a feed gas comprising 10 to 75 mol% carbon dioxide (CO2), water vapour, at least one constituent chosen from hydrogen, CO, methane, nitrogen, oxygen and argon, and solid particles, employing a PSA unit, characterized in that the feed gas is at least partially dried upstream of the PSA unit and enters said PSA unit with a solid-particle concentration of between 0.01 and 100 mg/m3.
摘要翻译：包括10至75mol％二氧化碳（CO 2），水蒸气，至少一种选自氢，CO，甲烷，氮，氧和氩的组分和固体颗粒的进料气体生产富含CO 2的气体的方法，采用 PSA单元，其特征在于，所述进料气体至少部分地在所述PSA单元的上游被干燥，并以0.01至100mg / m 3的固体颗粒浓度进入所述PSA单元。

8. 发明申请

WO2008132377A3 LIMITING OF IMPURITY PEAKS 审中-公开
标题翻译：限制峰值
公开(公告)号：WO2008132377A3
公开(公告)日：2009-02-05
申请号：PCT/FR2008050478
申请日：2008-03-20
申请人： AIR LIQUIDE , MONEREAU CHRISTIAN , PULLUMBI PLUTON , RODRIGUES GUILLAUME
发明人： MONEREAU CHRISTIAN , PULLUMBI PLUTON , RODRIGUES GUILLAUME
IPC分类号： C01B3/56 , B01D53/047
CPC分类号： C01B3/56 , B01D53/04 , B01D53/047 , B01D2253/108 , B01D2253/342 , B01D2256/16 , B01D2257/502 , B01D2259/41 , C01B2203/047
摘要： A process of purifying or separating a feed gas stream containing hydrogen H2 and a molar content of carbon monoxide (CO) greater than or equal to 1000 ppm, in which: a) said feed gas stream is introduced continuously into a first purification unit (10) of the PSA type containing a first adsorbent on which the CO is preferably adsorbed; b) the gas originating from step a), at least partially purified of CO and having an average molar CO content T less than or equal to Tacc and selectively a first maximum CO content TMo greater than Tacc, is recovered; c) the gas originating from step b) is introduced into a downstream adsorber (20) containing at least a second adsorbent (21) on which the CO is preferably adsorbed; d) the H2-enriched gas originating from step c) having an average CO content T and a maximum CO content TMi that are both less than or equal to Tacc, is recovered, characterized in that Tacc is less than or equal to 100 ppm.
摘要翻译：一种净化或分离含氢H 2和一氧化碳（CO）的摩尔含量大于或等于1000ppm的进料气流的方法，其中：a）将所述进料气流连续引入第一纯化单元（10 ）含有优选吸附有CO的第一吸附剂的PSA型; b）回收至少部分纯化的CO并且具有小于或等于Tacc的平均摩尔CO含量T和选择性地大于Tacc的第一最大CO含量TMo的气体; c）将来自步骤b）的气体引入含有至少第二吸附剂（21）的下游吸附器（20），CO吸附在其上优选被吸附; d）回收源自小于或等于Tacc的平均CO含量T和最大CO含量TMi的步骤c）的富H 2气体，其特征在于Tacc小于或等于100ppm。

9. 发明申请

WO2005000447A8 METHOD FOR PREPURIFYING AIR IN AN ACCELERATED TSA CYCLE 审中-公开
标题翻译：在加速TSA循环中预制空气的方法
公开(公告)号：WO2005000447A8
公开(公告)日：2005-03-10
申请号：PCT/FR2004050283
申请日：2004-06-18
申请人： AIR LIQUIDE , HEMERYCK CELINA , MONEREAU CHRISTIAN
发明人： HEMERYCK CELINA , MONEREAU CHRISTIAN
IPC分类号： B01D53/04
CPC分类号： B01D53/0431 , B01D53/0462 , B01D53/261 , B01D2253/104 , B01D2253/108 , B01D2257/404 , B01D2257/504 , B01D2257/702 , B01D2257/80 , B01D2259/40007 , B01D2259/40052 , B01D2259/4006 , B01D2259/4009 , B01D2259/402 , B01D2259/4146 , B01D2259/416 , Y02C10/08
摘要： The invention relates to a method for prepurifying air by means of adsorption, using two adsorption recipients operating alternately, in parallel, and in a TSA cycle, each recipient containing an adsorbent arranged on a radial adsorption bed, and each adsorption cycle consisting of (a) an adsorption stage during which the impurities are eliminated on the adsorbent at an adsorption temperature (rads), the air crossing the adsorption bed in a centripetal manner; (b) a regeneration stage during which the adsorbent is regenerated by flushing with a regeneration gas at a regeneration temperature (Treg), such as Treg > Tads, in order to desorb the impurities; et (c) an adsorbent cooling stage during which the temperature of the regenerated adsorbent is reduced. The maximum duration (rads) of the adsorption is 120 minutes, preferably between 60 and 120 minutes. The regeneration gas is introduced in such a way that it flushes the bed containing the adsorbent in the centrifugal direction. The maximum regeneration rate is 35 % of the adsorption rate. The regeneration temperature is reached by means of a heat exchanger arrange outside the adsorber.
摘要翻译：本发明涉及一种通过吸附预净化空气的方法，该方法使用交替操作的两个吸附接收器，并行地和在TSA循环中，每个接收器包含布置在径向吸附床上的吸附剂，并且每个吸附循环由（a ）吸附阶段，在吸附阶段期间吸附剂上的杂质在吸附温度（rads）下被消除，空气以向心方式穿过吸附床; （b）再生阶段，在该阶段中，通过在再生温度（Treg）下用再生气体冲洗再生吸附剂，例如Treg> Tads，以解吸杂质; 和（c）吸附剂冷却阶段，在此期间再生吸附剂的温度降低。吸附的最大持续时间（rads）是120分钟，优选60-120分钟。再生气体以这样的方式引入，即它在离心方向上冲洗含有吸附剂的床。最大再生率是吸附率的35％。借助布置在吸附器外部的热交换器达到再生温度。

10. 发明申请

WO2016003484A3 A RAPID TEMPERATURE SWING ADSORPTION (RTSA) METHOD USING STRUCTURED ADSORBENT FOR CO2 CAPTURE FROM LOW PRESSURE AND LOW CO2 CONCENTRATION SOURCES 审中-公开
标题翻译：使用结构吸附剂从低压和低二氧化碳浓度来源获得二氧化碳捕获的快速温度吸收（RTSA）方法
公开(公告)号：WO2016003484A3
公开(公告)日：2016-03-03
申请号：PCT/US2014066721
申请日：2014-11-20
申请人： AIR LIQUIDE , CHEN YUDONG , MONEREAU CHRISTIAN , SANDERS JR EDGAR S , TESSIER PASCAL
发明人： CHEN YUDONG , MONEREAU CHRISTIAN , SANDERS JR EDGAR S , TESSIER PASCAL
IPC分类号： B01D53/04
CPC分类号： B01D53/0462 , B01D53/0438 , B01D53/06 , B01D2253/108 , B01D2253/342 , B01D2253/3425 , B01D2256/10 , B01D2257/504 , B01D2257/80 , B01D2258/0233 , B01D2258/0283 , B01D2259/40001 , B01D2259/40011 , B01D2259/403 , B01D2259/404 , Y02C10/08
摘要： A Temperature Swing Adsorption method for separating a first component, comprising a more adsorbable component, from a feed stream comprising more than 50 mol% of a second component, comprising a less adsorbable component, is provided. The method includes providing an adsorbent structure suitable for adsorbing the first component, the structure being of the parallel passage contactor type, and cyclically implementing the following steps. Passing the feed stream through the adsorbent structure thus adsorbing the first component and producing a stream depleted in the first component and enriched in the second component. Heating the adsorbent structure to desorb the adsorbed first component by means of circulating a heating stream enriched in the first component at a temperature suitable for regeneration. And cooling the structure by means of passing through it more than 50% of the stream enriched in the second component produced in the step a).
摘要翻译：提供了一种用于从包含较多可吸附组分的包含多于50mol％的第二组分的进料流中分离包含更易吸附组分的第一组分的温度摆动吸附方法。该方法包括提供适于吸附第一组分的吸附结构，该结构是平行通道接触器类型，并循环地实施以下步骤。使进料流通过吸附剂结构从而吸附第一组分并产生在第一组分中贫化并富含第二组分的流。加热吸附剂结构以通过在适于再生的温度下循环富含第一组分的加热流来解吸所吸附的第一组分。并且通过使超过50％的富含步骤a）中生成的第二组分的物流通过其冷却结构。

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