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    • 2. 发明申请
    • POLYMERISABLE PHOTOINITIATORS FOR LED CURABLE COMPOSITIONS
    • 用于LED固化组合物的可聚合光敏元件
    • WO2012052288A1
    • 2012-04-26
    • PCT/EP2011/067274
    • 2011-10-04
    • AGFA-GEVAERTLOCCUFIER, Johan
    • LOCCUFIER, Johan
    • C07D335/16C08F220/26G03F7/027
    • C07D335/16C09D11/101C09D11/30G03F7/027G03F7/029G03F7/2051
    • A polymerisable photoinitiator according to Formula (I): wherein: R1 and R2 are independently selected from the group consisting of hydrogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkynyl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted alkaryl group, a substituted or unsubstituted aryl or heteroaryl group, a halogen, an ether group, a thioether group, an aldehyde group, a ketone group, an ester group, an amide group, an amine and a nitro group; R 1 and R 2 may represent the necessary atoms to form a five to eight memberering; L represents an n+m-valent linking group comprising 1 to 30 carbon atoms; A represents a radically polymerizable group selected from the group consisting of an acrylate group, a methacrylate group, a styrene group, an acryl amide group a methacryl amide group, a maleate group, a fumarate group, an itaconate group, a vinyl ether group, an allyl ether group, a vinyl ester group and an allyl ester group;and n and m independently represent an integer from 1 to 5. Methods for preparing the polymerisable photoinitiator and radiation curable compositions including the polymerisable photoinitiator are also disclosed.
    • 根据式(I)的可聚合光引发剂:其中:R 1和R 2独立地选自氢,取代或未取代的烷基,取代或未取代的烯基,取代或未取代的炔基,取代或未取代的 芳烷基,取代或未取代的烷芳基,取代或未取代的芳基或杂芳基,卤素,醚基,硫醚基,醛基,酮基,酯基,酰胺基,胺和 硝基; R1和R2可以代表形成五至八个膜的必需原子; L表示含有1至30个碳原子的n + m价连接基团; A表示选自丙烯酸酯基,甲基丙烯酸酯基,苯乙烯基,丙烯酰胺基,甲基丙烯酰胺基,马来酸酯基,富马酸酯基,衣康酸酯基,乙烯基醚基, 烯丙基醚基,乙烯基酯基和烯丙基酯基; n和m独立地表示1〜5的整数。还公开了包含可聚合光引发剂的可聚合光引发剂和可辐射固化组合物的制备方法。
    • 5. 发明申请
    • PIGMENT DISPERSIONS WITH POLYMERIC DISPERSANTS HAVING PENDING CHROMOPHORE GROUPS.
    • 色素分散体与具有待染色体组的聚合物分散体。
    • WO2007006639A2
    • 2007-01-18
    • PCT/EP2006/063495
    • 2006-06-23
    • AGFA-GEVAERTLOCCUFIER, JohanJAUNKY, WojciechDEROOVER, GeertGROENENDAAL, Lambertus
    • LOCCUFIER, JohanJAUNKY, WojciechDEROOVER, GeertGROENENDAAL, Lambertus
    • C09B67/20C09B69/10C09D11/00C09B67/22
    • C09B69/106C09B67/0033C09B67/0036C09B67/0051C09B67/0063C09B67/009C09B69/10C09B69/109C09D11/101C09D11/326
    • A pigment dispersion comprising a colour pigment and a polymeric dispersant having at least one pending chromophore group covalently bound to the polymeric backbone of the polymeric dispersant through a linking group wherein the at least one pending chromophore group is a derivative from a colour pigment selected from the group consisting of monoazo pigments, disazo pigments, β-naphtol pigments, naphtol AS pigments, azo pigment lakes, benzimidazolone pigments, disazo condensation pigments, metal complex pigments, isoindolinone pigments, isoindolinine pigments, phthalocyanine pigments, quinacridone pigments, diketopyrrolo-pyrrole pigments, thioindigo pigments, anthraquinone pigments, anthrapyrimidine pigments, indanthrone pigments, flavanthrone pigments, pyranthrone pigments, anthanthrone pigments, isoviolanthrone pigments, aluminium pigment lakes, dioxazine pigments, triarylcarbonium pigments and quinophthalone pigments; the at least one pending chromophore group is a chromophore group occurring as a side group on the polymeric backbone and not a group in the polymeric backbone itself or occurring solely as an end group of the polymeric backbone; the linking group consists of all the atoms between the polymeric backbone and the first atom of the aromatic group by which the pending chromophore group is linked to the polymeric backbone; the polymeric dispersant has a polymeric backbone with a polymerization degree between 5 and 1000; and at most 30 % of the monomer units of the polymeric backbone have a pending chromophore group. The pigment dispersion can be advantageously used in inkjet inks. Also disclosed is a method for preparing the pigment dispersion comprising the step of preparing the polymeric dispersant by copolymerizing a monomer already containing the pending chromophore group.
    • 一种颜料分散体,其包含着色颜料和聚合物分散剂,其具有通过连接基团与聚合物分散剂的聚合物主链共价结合的至少一个待处理的发色团,其中所述至少一个未决发色团组为选自 由单偶氮颜料,双偶氮颜料,β-萘酚颜料,萘酚AS颜料,偶氮颜料湖,苯并咪唑酮颜料,双偶氮缩合颜料,金属络合物颜料,异吲哚啉酮颜料,异二氢吲哚颜料,酞菁颜料,喹吖啶酮颜料,二酮吡咯并 - 吡咯颜料, 硫靛颜料,蒽醌颜料,蒽嘧啶颜料,阴丹酮颜料,黄烷酮酮颜料,吡喃酮颜料,蒽醌颜料,异卤蒽酮颜料,铝颜料湖,二恶嗪颜料,三芳基碳鎓颜料和喹酞酮颜料; 所述至少一个待处理的发色团组是作为聚合物主链上的侧基而不是聚合物主链本身中的基团而发生或仅作为聚合物主链的端基发生的发色团。 连接基团由聚合物主链和芳族基团的第一个原子之间的所有原子组成,待处理的发色团通过该原子与聚合物主链连接; 聚合物分散剂具有聚合度在5和1000之间的聚合物主链; 并且至多30%的聚合物主链的单体单元具有未决发色团组。 颜料分散体可有利地用于喷墨油墨中。 还公开了一种制备颜料分散体的方法,其包括通过共聚已经含有未决发色团的单体来制备聚合物分散剂的步骤。
    • 7. 发明申请
    • PIGMENT DISPERSIONS WITH POLYMERIC DISPERSANTS HAVING PENDING CHROMOPHORE GROUPS.
    • 聚合物分散剂带有色素组的色素分散体。
    • WO2007006636A2
    • 2007-01-18
    • PCT/EP2006/063486
    • 2006-06-23
    • AGFA-GEVAERTJAUNKY, WojciechDEROOVER, GeertLOCCUFIER, JohanGROENENDAAL, Lambertus
    • JAUNKY, WojciechDEROOVER, GeertLOCCUFIER, JohanGROENENDAAL, Lambertus
    • C09B67/20C09B69/10C09D11/00C09B67/22
    • C09B67/009C09B67/0046C09B67/0051C09B69/106C09D11/326C09D17/003
    • A pigment dispersion comprising a colour pigment represented by formula (I) wherein, R1 is selected from the group consisting of hydrogen, a halogen atom, a methyl group, an ethyl group, a methoxy group, an ethoxy group, -CF 3 , -COOH, -COOCH 3 and; R2, R4 and R5 are independently selected from the group consisting of hydrogen, a halogen atom, a methyl group, an ethyl group, a methoxy group, an ethoxy group,-CF 3 , -COOH and -COOCH 3 ; R3 is selected from the group consisting of hydrogen, a halogen atom, a methyl group, an ethyl group, a methoxy group, an ethoxy group,-CF 3 , -COOH, -COOCH 3 , -SO 2 NH-C 6 H 5 , -CONH-C 6 H 5 , -CONH-C 6 H 5 -CONH 2 and -CONH 2 ; R6 and R7 are independently selected from the group consisting of hydrogen, a halogen atom, a methyl group, an ethyl group, a methoxy group, an ethoxy group,- CF 3 , -COOH and -COOCH 3 , or R6 and R7 represent the necessary atoms to form an imidazolone ring; and a polymeric dispersant having via a linking group covalently linked to its polymeric backbone at least one pending chromophore group which has a molecular weight smaller than 95% of the molecular weight of said colour pigment. The pigment dispersion can be advantageously used in inkjet inks.
    • 包含由式(I)表示的着色颜料的颜料分散体,其中,R 1选自氢,卤素原子,甲基,乙基,甲氧基, 乙氧基,-CF 3,-COOH,-COOCH 3和; R 2,R 4和R 5独立地选自氢,卤素原子,甲基,乙基,甲氧基,乙氧基,-CF 3,-COOH和 - COOCH <子> 3 ; R 3选自氢,卤素原子,甲基,乙基,甲氧基,乙氧基,-CF 3,-COOH,-COOCH 3 -SO 2 NH-C 6 H 5,-CONH-C 6 H 5, -5H,-CONH-C 6 H 5 -CONH 2和-CONH 2 - ; R6和R7独立地选自由氢,卤素原子,甲基,乙基,甲氧基,乙氧基,-CF3,-COOH和-COOCH3组成的组, 或者R6和R7代表形成咪唑啉酮环所需的原子; 以及一种聚合物分散剂,其通过与其聚合物主链共价连接的连接基团具有至少一个分子量小于所述彩色颜料分子量95%的未决发色团。 颜料分散体可以有利地用于喷墨油墨中。
    • 8. 发明申请
    • METHOD FOR MAKING NEGATIVE-WORKING HEAT-SENSITIVE LITHOGRAPHIC PRINTING PLATE PRECURSOR.
    • 制造负离子热敏光刻印刷机前驱体的方法。
    • WO2006005688A1
    • 2006-01-19
    • PCT/EP2005/053141
    • 2005-07-01
    • AGFA-GEVAERTVERMEERSCH, JoanLOCCUFIER, JohanCALLANT, PaulJUNG, JürgenVAN DAMME, Marc
    • VERMEERSCH, JoanLOCCUFIER, JohanCALLANT, PaulJUNG, JürgenVAN DAMME, Marc
    • B41C1/10
    • B41C1/1008B41C1/1025B41C2210/04B41C2210/08B41C2210/22B41C2210/24B41C2210/26
    • A method for making a negative-working heat-sensitive lithographic printing plate precursor is provided which comprises the steps of (i) providing a support having a hydrophilic surface or which is provided with a hydrophilic layer, and (ii) applying on said support a coating which comprises a product DQ, wherein DQ is obtained by - the step of coating a solution or dispersion comprising a nucleophilic compound Q and a dye D selected from the list consisting of di- or tri-arylmethane dyes, cyanine dyes, styryl dyes and merostyryl dyes; or by - the step of coating a solution or dispersion comprising said compound Q and coating another solution or dispersion comprising said dye D; wherein D and Q interact to form interaction product DQ, having a white light optical density which is lower than the white light optical density of dye D, and wherein said interaction product DQ is capable of at least partially releasing a dye directly after exposure to infrared light or heat, thereby forming a visible image in said coating.
    • 提供了一种制备负性热敏平版印刷版原版的方法,其包括以下步骤:(i)提供具有亲水性表面的或具有亲水层的载体,和(ii)在所述载体上施加 包括产物DQ的涂层,其中DQ是通过以下步骤获得的:涂覆包含亲核化合物Q和染料D的溶液或分散体的步骤,所述染料D选自二 - 或三 - 芳基甲烷染料,花青染料,苯乙烯基染料和 美洛斯坦林染料; 或者通过以下步骤:涂布包含所述化合物Q的溶液或分散体并涂覆包含所述染料D的其它溶液或分散体; 其中D和Q相互作用以形成具有低于染料D的白光光密度的白光光密度的相互作用产物DQ,并且其中所述相互作用产物DQ能够在暴露于红外线之后直接至少部分地释放染料 光或热,从而在所述涂层中形成可见图像。