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2. 发明申请

WO2011066935A3 BLEACH CATALYST COMPOUNDS, METHOD FOR THE PRODUCTION THEREOF AND USE THEREOF 审中-公开
标题翻译： BLEACH催化剂化合物，工艺用于生产和使用
公开(公告)号：WO2011066935A3
公开(公告)日：2011-10-13
申请号：PCT/EP2010007235
申请日：2010-11-30
申请人： CLARIANT INT LTD , REINHARDT GERD , BEST MICHAEL
发明人： REINHARDT GERD , BEST MICHAEL
IPC分类号： C07F13/00 , C11D3/39 , C11D3/395 , D21C9/10 , D21C9/16
CPC分类号： C07F13/005 , C11D3/168 , C11D3/3932 , C11D17/0052 , C11D17/06 , C11D17/065 , D21C9/10 , D21C9/163
摘要： The invention relates to compounds in solid form, containing a) one or more manganese complex compounds of the general formula (1), where M is independently selected from manganese in the III or IV oxidation state, X is independently a co-ordinating or bridging species selected from H2O, O2 2-, O2 -, O2-, OH-, HO2 -, SH-, S2-, SO, CI-, N3-, SCN-, N3 -, RCOO-, NH2 - and NR3, where R is a radical selected from H, alkyl and aryl, L are independently organic ligands, each of which contains at least two nitrogen atoms co-ordinated on manganese, z is an integer from -4 to +4, Y is a monovalent or multivalent counter-ion selected from chloride, sulphate, hydrogen sulphate, nitrate and acetate, which leads to charge neutrality of the complex, and q is an integer from 1 to 4, and b) one or more salts of the general formula R'-C6H4-SO3Me, where R' is CH3 or C2H5 and denotes Me, Na, K, Ca or Mg, characterised in that the molar ratio of the manganese complex compound of the general formula (1) to salt of the general formula R'-C6H4-SO3Me is 1:0.5 to 1:5. The invention also describes a method for producing the compounds and to the use thereof as oxidation catalysts or bleach catalysts, in particular in detergents or cleaning agents.
摘要翻译：组合物以固体形式包括：a）通式中的一个或多个锰配位化合物（1）其中M独立地选自在III或IV氧化态锰中，X独立地是配位或桥连所选物种中描述，O2-，OH - ，HO 2 - - ，SH-，S2-，SO，Cl，N3-，SCN-，N 3 - H2O，O2 2-，O 2的，RCOO-，NH 2 - 和NR 3，其中R是 L是选自H，彼此独立地烷基和芳基中选择的基团，有机配体，各自包含至少两个锰协调氮原子，z是从-4至+4的整数，Y为单 - 或选自氯的多价抗衡离子，是硫酸根，硫酸氢盐，硝酸盐，乙酸盐，其导致所述络合物的电荷中性，并且q是从1至4的整数，和b）以下通式的一种或多种盐R'-C6H4-SO 3我其中R“是CH 3或C 2 H 5 且Me是Na，K，Ca或Mg意指特征gekennzeichn 等，即具有通式R'-C6H4-SO 3 Me无法1的通式（1）的锰配合物的盐的摩尔比：0.5至1：5，以及制备该组合物的方法及其作为氧化或漂白催化剂，特别是在洗涤剂或清洁剂。

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