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1. 发明申请

WO2007005458A3 ETHYLENE/ALKYL ACRYLATE COPOLYMERS AND COMPOUNDS AND VULCANIZATES THEREOF 审中-公开
标题翻译：乙烯/丙烯酸烷基酯共聚物及其化合物及其硫化物
公开(公告)号：WO2007005458A3
公开(公告)日：2007-03-29
申请号：PCT/US2006025154
申请日：2006-06-26
申请人： DU PONT , WU YUN-TAI , STEWART MARK AARON , YE YI
发明人： WU YUN-TAI , STEWART MARK AARON , YE YI
IPC分类号： C08F210/02 , C08F220/14 , C08L33/12
CPC分类号： C08L33/08 , C08F220/14 , C08L23/0869 , C08L33/12 , C08L2205/02 , C08L2666/06 , C08L2666/04 , C08F210/02 , C08F2500/12 , C08F2500/17 , C08F2500/04
摘要： Disclosed are copolymers derived from copolymerization of from about 50 to about 70 weight % of methyl acrylate; optionally from about 0.5 to about 5 weight % of 1,4 butene-dioic acid moieties, or anhydrides or monoalkyl esters thereof; the remainder being ethylene, wherein the copolymer has a number average molecular weight from about 40,000 to about 65,000 and a melt index from about 1 to about 14 g/10 minutes. Also disclosed are compounded compositions comprising these copolymers, and cured compositions (i.e., vulcanizates) as well as rubber articles formed from these compounded compositions, such as tubing, hoses, including fluid handling hoses and turbocharger hoses, dampers, boots, seals, and gaskets for automotive and nonautomotive applications. Blends of other polymers with these copolymers are also disclosed.
摘要翻译：公开了由约50至约70重量％的丙烯酸甲酯共聚得到的共聚物; 任选地约0.5至约5重量％的1,4丁烯二酸部分，或其酸酐或单烷基酯; 其余为乙烯，其中共聚物具有约40,000至约65,000的数均分子量和约1至约14g / 10分钟的熔体指数。还公开了包含这些共聚物和固化组合物（即硫化橡胶）的复合组合物以及由这些复合组合物形成的橡胶制品，例如管材，软管，包括流体处理软管和涡轮增压器软管，阻尼器，靴子，密封件和垫片用于汽车和非汽车应用。其他聚合物与这些共聚物的共混物也被公开。

2. 发明申请

WO2007005458A2 ETHYLENE/ALKYL ACRYLATE COPOLYMERS AND COMPOUNDS AND VULCANIZATES THEREOF 审中-公开
标题翻译：乙烯/丙烯酸丙烯酯共聚物及其化合物及其组合物
公开(公告)号：WO2007005458A2
公开(公告)日：2007-01-11
申请号：PCT/US2006/025154
申请日：2006-06-26
申请人： E. I. DU PONT DE NEMOURS AND COMPANY , WU, Yun-Tai , STEWART, Mark, Aaron , YE, Yi
发明人： WU, Yun-Tai , STEWART, Mark, Aaron , YE, Yi
IPC分类号： C08F210/02 , C08F220/14 , C08L33/12
CPC分类号： C08L33/08 , C08F220/14 , C08L23/0869 , C08L33/12 , C08L2205/02 , C08L2666/06 , C08L2666/04 , C08F210/02 , C08F2500/12 , C08F2500/17 , C08F2500/04
摘要： Disclosed are copolymers derived from copolymerization of from about 50 to about 70 weight % of methyl acrylate; optionally from about 0.5 to about 5 weight % of 1,4 butene-dioic acid moieties, or anhydrides or monoalkyl esters thereof; the remainder being ethylene, wherein the copolymer has a number average molecular weight from about 40,000 to about 65,000 and a melt index from about 1 to about 14 g/10 minutes. Also disclosed are compounded compositions comprising these copolymers, and cured compositions (i.e., vulcanizates) as well as rubber articles formed from these compounded compositions, such as tubing, hoses, including fluid handling hoses and turbocharger hoses, dampers, boots, seals, and gaskets for automotive and nonautomotive applications. Blends of other polymers with these copolymers are also disclosed.
摘要翻译：公开了衍生自约50至约70重量％的丙烯酸甲酯的共聚的共聚物; 任选地约0.5至约5重量％的1,4-丁二烯酸部分，或其酸酐或单烷基酯; 其余为乙烯，其中共聚物的数均分子量为约40,000至约65,000，熔体指数为约1至约14g / 10分钟。还公开了包含这些共聚物和固化的组合物（即，硫化橡胶）以及由这些复合组合物形成的橡胶制品的复合组合物，例如管道，软管，包括流体处理软管和涡轮增压器软管，阻尼器，靴子，密封件和垫圈用于汽车和非汽车应用。还公开了其它聚合物与这些共聚物的共混物。

3. 发明申请

WO2005010059A1 RANDOM ETHYLENE/ALKYL ACRYLATE COPOLYMERS, COMPOUNDS AND ELASTOMERIC COMPOSITIONS THEREOF WITH IMPROVED LOW TEMPERATURE PROPERTIES 审中-公开
标题翻译：随机乙烯/丙烯酸烯丙酯共聚物，其化合物和弹性体组合物具有改善的低温特性
公开(公告)号：WO2005010059A1
公开(公告)日：2005-02-03
申请号：PCT/US2004/023669
申请日：2004-07-22
申请人： E.I. DUPONT DE NEMOURS AND COMPANY , WU, Yun-Tai , STEWART, Mark, Aaron , MITCHELL, David, John , MCBRIDE, Edward
发明人： WU, Yun-Tai , STEWART, Mark, Aaron , MITCHELL, David, John , MCBRIDE, Edward
IPC分类号： C08F10/02
CPC分类号： C08L33/08 , C08F220/12
摘要： Disclosed are random copolymers derived from ethylene and at least two different alkyl acrylate comonomers, with or without an acid cure site-containing comonomer. In particular, disclosed are copolymers derived from copolymerization of (a) from 10 to 50 weight % of ethylene; (b) from 5 to 55 weight % of a first alkyl acrylate; (b) from 15 to 80 weight % of a second alkyl acrylate; and (d) from 0 to 7 weight % of a monoalkyl ester of 1,4-butene-dioic acid. Such copolymers exhibit lower glass transition temperatures (Tg) relative to previous ethylene copolymers comprising a single alkyl acrylate comonomer and maintain the good heat and fluid resistance when employed to produce cured elastomeric compositions as well as the improved low temperature properties. This invention also provides compounded compositions comprising these copolymers, and cured compositions (i.e., vulcanizates) as well as rubber articles formed from these compounded compositions, such as hoses, dampers, seals, gaskets, constant velocity joint (CVJ) boots and shaft boots.
摘要翻译：公开了衍生自乙烯和至少两种不同的丙烯酸烷基酯共聚单体的无规共聚物，具有或不具有含酸固化位点的共聚单体。特别地，公开了衍生自（a）10至50重量％的乙烯的共聚合的共聚物; （b）5至55重量％的第一丙烯酸烷基酯; （b）15至80重量％的第二丙烯酸烷基酯; 和（d）0至7重量％的1,4-丁二烯酸的单烷基酯。这种共聚物相对于包含单一烷基丙烯酸酯共聚单体的先前乙烯共聚物显示较低的玻璃化转变温度（Tg），并且当用于产生固化的弹性体组合物以及改进的低温性能时，保持良好的耐热和耐流体性。本发明还提供了包含这些共聚物和固化的组合物（即硫化橡胶）的复合组合物以及由这些复合组合物形成的橡胶制品，例如软管，阻尼器，密封件，垫圈，等速万向节（CVJ）靴和轴靴。

4. 发明申请

WO2007005899A3 ETHYLENE/ALKYL ACRYLATE COPOLYMERS, COMPOUNDS AND VULCANIZATES THEREOF 审中-公开
标题翻译：乙烯/丙烯酸烷基酯共聚物，化合物及其硫化物
公开(公告)号：WO2007005899A3
公开(公告)日：2007-02-22
申请号：PCT/US2006026085
申请日：2006-06-30
申请人： DU PONT , WU YUN-TAI , STEWART MARK AARON , YE YI
发明人： WU YUN-TAI , STEWART MARK AARON , YE YI
IPC分类号： C08F210/00
CPC分类号： C08F210/02 , C08F220/12 , C08F220/14 , C08F2500/12 , C08F2500/04 , C08F2500/17
摘要： Disclosed are copolymers derived from ethylene and at least two different alkyl acrylate comonomers, with or without an acid cure site-containing comonomer. The copolymers can be derived from (a) from 10 to 50 weight % of ethylene; (b) 20 to 30 weight % of a first alkyl acrylate having from 1 to 4 carbons in the alkyl group; from 35 to 45 weight % of a second different alkyl acrylate having from 1 to 4 carbons in the alkyl group; and (d) from 0 to 5 weight % of a 1,4-butene-dioic acid moiety, or anhydride or monoalkyl ester thereof; the remainder being ethylene: wherein the copolymer has a number average molecular weight (M n ) above 40,000. Also disclosed are compounded compositions comprising these copolymers and cured compositions (i.e., vulcanizates) as well as rubber articles formed from these compounded compositions, such as constant velocity joint boots and shaft boots, hoses, dampers, seals and gaskets. These copolymers provide improved dynamic fatigue resistance of cured compounds while maintaining an expanded operating temperature range and oil resistance. Blends of other polymers with these copolymers are also disclosed.
摘要翻译：公开了衍生自乙烯和至少两种不同的丙烯酸烷基酯共聚单体的共聚物，其具有或不具有含酸固化点的共聚单体。该共聚物可以衍生自（a）10至50重量％的乙烯; （b）20至30重量％的烷基中具有1至4个碳原子的第一种丙烯酸烷基酯; 35至45重量％的烷基中具有1至4个碳的第二种不同的丙烯酸烷基酯; 和（d）0-5重量％的1,4-丁烯二酸部分或其酸酐或单烷基酯; 其余为乙烯：其中共聚物的数均分子量（M n）大于40,000。还公开了包含这些共聚物和固化组合物（即硫化橡胶）的复合组合物以及由这些复合组合物形成的橡胶制品，例如等速接头靴和轴靴，软管，阻尼器，密封件和垫圈。这些共聚物提供改进的固化化合物的动态抗疲劳性，同时保持扩大的操作温度范围和耐油性。其他聚合物与这些共聚物的共混物也被公开。

5. 发明申请

WO2007005899A2 ETHYLENE/ALKYL ACRYLATE COPOLYMERS, COMPOUNDS AND VULCANIZATES THEREOF 审中-公开
标题翻译：乙烯/丙烯酸丙烯酸酯共聚物，化合物及其组合物
公开(公告)号：WO2007005899A2
公开(公告)日：2007-01-11
申请号：PCT/US2006/026085
申请日：2006-06-30
申请人： E.I. DU PONT DE NEMOURS AND COMPANY , WU, Yun-Tai , STEWART, Mark, Aaron , YE, Yi
发明人： WU, Yun-Tai , STEWART, Mark, Aaron , YE, Yi
IPC分类号： C08F210/00
CPC分类号： C08F210/02 , C08F220/12 , C08F220/14 , C08F2500/12 , C08F2500/04 , C08F2500/17
摘要： Disclosed are copolymers derived from ethylene and at least two different alkyl acrylate comonomers, with or without an acid cure site-containing comonomer. The copolymers can be derived from (a) from 10 to 50 weight % of ethylene; (b) 20 to 30 weight % of a first alkyl acrylate having from 1 to 4 carbons in the alkyl group; from 35 to 45 weight % of a second different alkyl acrylate having from 1 to 4 carbons in the alkyl group; and (d) from 0 to 5 weight % of a 1,4-butene-dioic acid moiety, or anhydride or monoalkyl ester thereof; the remainder being ethylene: wherein the copolymer has a number average molecular weight (M n ) above 40,000. Also disclosed are compounded compositions comprising these copolymers and cured compositions (i.e., vulcanizates) as well as rubber articles formed from these compounded compositions, such as constant velocity joint boots and shaft boots, hoses, dampers, seals and gaskets. These copolymers provide improved dynamic fatigue resistance of cured compounds while maintaining an expanded operating temperature range and oil resistance. Blends of other polymers with these copolymers are also disclosed.
摘要翻译：公开了衍生自乙烯和至少两种不同的丙烯酸烷基酯共聚单体的共聚物，具有或不具有酸固化位点的共聚单体。共聚物可以衍生自（a）10至50重量％的乙烯; （b）20〜30重量％的烷基中具有1〜4个碳原子的丙烯酸烷基酯; 35至45重量％的烷基中具有1至4个碳的第二种不同的丙烯酸烷基酯; 和（d）0至5重量％的1,4-丁烯二酸部分，或其酸酐或单烷基酯; 其余为乙烯：其中该共聚物具有高于40,000的数均分子量（M N n N）。还公开了包含这些共聚物和固化组合物（即硫化橡胶）的复合组合物以及由这些复合组合物形成的橡胶制品，例如恒速接头靴和轴靴，软管，阻尼器，密封件和垫圈。这些共聚物在保持膨胀的工作温度范围和耐油性的同时提供了改进的固化化合物的动态抗疲劳性。还公开了其它聚合物与这些共聚物的共混物。

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