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1. 发明申请

WO2005026082A3 METHOD FOR REUSING HEAVY END BY-PRODUCTS IN THE MANUFACTURE OF POLYCHLORINATED ALKANES 审中-公开
公开(公告)号：WO2005026082A3
公开(公告)日：2005-03-24
申请号：PCT/US2004/028298
申请日：2004-08-31
申请人： VULCAN CHEMICALS A BUSINESS GROUP OF VULCAN MATERIALS COMPANY
发明人： KLAUSMEYER, Rodney, L.
IPC分类号： C07C17/02
摘要： A method for recovering much of the carbon and chlorine value in the heavy ends and other undesired by-products formed during the production of a C 3 or higher polychlorinated alkane through the reaction of carbon tetrachloride with an olefine or chlorinated olefine, the improvement comprising the step of first separating the heavy ends and any other higher or lower boiling chlorohydrocarbon impurities from most of the desired product, and subjecting the separated heavy ends and impurities therewith to a high temperature exhaustive chlorination to produce carbon tetrachloride, tetrachloroethene, and minor amounts of hexachlorobutadiene and hexachlorobenzene by-products.

2. 发明申请

WO2005021473A1 METHOD FOR PRODUCING 1,1,1,3-TETRACHLOROPROPANE AND OTHER HALOALKANES WITH IRON CATALYST 审中-公开
标题翻译：使用铁催化剂生产1,1,1,3-四氯丙烯和其他卤代醇的方法
公开(公告)号：WO2005021473A1
公开(公告)日：2005-03-10
申请号：PCT/US2004/027520
申请日：2004-08-25
申请人： VULCAN CHEMICALS A BUSINESS GROUP OF VULCAN MATERIALS COMPANY
发明人： WILSON, Richard, L. , DAWKINS, John, L.
IPC分类号： C07C17/00
CPC分类号： C07C17/275 , C07C17/383 , C07C19/01
摘要： A continuous process is provided for the manufacture of haloalkanes by the reaction of carbon tetrachloride with olefins in the presence of iron metal, trialkylphosphate, and ferric chloride. A fraction of the catalyst and co-catalyst are separated after the reaction and recycled. In a preferred application, the olefin is ethene, and the haloalkane product is 1,1,1,3-tetrachloropropane. Two distillation steps take place in order to enhance the production of 1,1,1,3-tetrachloropropane.
摘要翻译：提供了在铁金属，三烷基磷酸盐和氯化铁存在下通过四氯化碳与烯烃的反应制备卤代烷烃的连续方法。催化剂和助催化剂的一部分在反应后分离并再循环。在优选的应用中，烯烃是乙烯，卤代烷烃产物是1,1,1,3-四氯丙烷。进行两个蒸馏步骤以增强1,1,1,3-四氯丙烷的生产。

3. 发明申请

WO2002100809A2 DEHYDROCHLORINATION STABILIZATION OF POLYCHLORINATED ALKANES 审中-公开
标题翻译：多氯化烷烃的脱氯化稳定性
公开(公告)号：WO2002100809A2
公开(公告)日：2002-12-19
申请号：PCT/US2002/018171
申请日：2002-06-08
申请人： VULCAN CHEMICALS
发明人： KLAUSMEYER, Rodney, L.
IPC分类号： C07C17/00
CPC分类号： C07C17/42 , C07C19/01 , C07C19/05
摘要： A process is provided for the stabilization of polychlorinated alkanes against dehydrochlorination. The process comprises adding a phenol compound to a polychlorinated alkane such that the dehydrochlorination of the polychlorinated alkane is suppressed when heated in the presence of iron(III). In a preferred embodiment, the process comprises the prevention or reduction of dehydrochlorination of 1,1,1,3,3-pentachloropropane when heated in the presence of iron(III) contamination by the addition of monomethyl ether hydroquinone. In another embodiment, the long term storage stability of polychlorinated alkanes against dehydrochlorination is improved due to the addition of a phenol compound.
摘要翻译：提供了一种用于稳定多氯代烷烃以防止脱氯化氢的方法。该方法包括向多氯代烷烃中加入酚化合物，使得在铁（III）存在下加热时，抑制多氯代烷烃的脱氯化氢。在优选的实施方案中，该方法包括当在加入单甲醚氢醌的铁（III）污染物存在下加热时，防止或减少1,1,1,3,3-五氯丙烷的脱氯化氢。在另一个实施方案中，由于加入酚化合物，多氯代烷烃对脱氯化氢的长期保存稳定性得到改善。

4. 发明申请

WO2003068838A1 ISOPROPYL CHLORIDE WITH HYDROFLUOROCARBON OR HYDROFLUORETHER AS FOAM BLOWING AGENTS 审中-公开
标题翻译：氟氯烃与氢氟碳化物作为泡沫发泡剂
公开(公告)号：WO2003068838A1
公开(公告)日：2003-08-21
申请号：PCT/US2003/004211
申请日：2003-02-11
申请人： VULCAN CHEMICALS
发明人： NYBERG, Janice, M. , MAINZ, Eric, L.
IPC分类号： C08G18/00
CPC分类号： C08J9/149 , C08J2203/12 , C08J2203/142 , C08J2203/146
摘要： A composition useful as a blowing agent having no flash point or reduced combustibility comprising 2-chloropropane and a gas selected from the group consisting of a fluorohydrocarbon, perfluorocarbons, fluoroethers, hydrofluoropolyethers and mixtures thereof is disclosed. A polyisocyanurate foam or a polyurethane modified polyisocyanurate foam having a mainly closed cell structure and also a method for preparing this foam, the latter comprising closed cells wherein a foam blowing agent consisting of a mixture of 2-chloropropane and one or more HFC compounds including pentafluoropropane, pentafluorobutane, heptafluoropropane, hexafluoropropane or pentafluoroethane are disclosed. Pentanes can be added if desired. Azeotropic mixtures in which 2-chloropropane is an ingredient are disclosed.
摘要翻译：公开了可用作不含闪点或降低的可燃性的发泡剂的组合物，其包含2-氯丙烷和选自氟代烃，全氟化碳，氟醚，氢氟聚醚及其混合物的气体。具有主要闭孔结构的聚异氰脲酸酯泡沫或聚氨酯改性的聚异氰脲酸酯泡沫，以及制备该泡沫的方法，后者包括闭孔，其中由2-氯丙烷和一种或多种包含五氟丙烷的HFC化合物的混合物组成的泡沫发泡剂，五氟丁烷，七氟丙烷，六氟丙烷或五氟乙烷。如果需要，可以加入戊烷。公开了其中2-氯丙烷是成分的共沸混合物。

5. 发明申请

WO2005023984A3 METHOD FOR PRODUCING 1,1,1,3-TETRACHLOROPROPANE AND OTHER HALOALKANES USING A COPPER CATALYST 审中-公开
公开(公告)号：WO2005023984A3
公开(公告)日：2005-03-17
申请号：PCT/US2004/027754
申请日：2004-08-26
申请人： VULCAN CHEMICALS A BUSINESS GROUP OF VULCAN MATERIALS COMPANY
发明人： WILSON, Richard, L.
IPC分类号： C07C17/275
摘要： A process is provided for the manufacture of a haloalkane by the reaction of carbon tetrachloride with an olefin in the presence of dissolved catalytic copper compounds and a cosolvent. A fraction of the catalyst and co-catalyst is recycled to the reactor. In a preferred application, the olefin is ethene and the desired haloalkane is 1,1,1,3-tetrachloropropane, or the olefin is vinyl chloride and the haloalkane is 1,1,1,3,3-pentachloropropane, or the olefin is 1,1-dichloroethene and the haloalkane is 1,1,1,3,3,3,-hexachloropropane, or the olefin is 2-chloropropene and the haloalkane product is 1,1,1,3,3-pentachlorobutane. Other preferred implementations provide an efficient continuous process.

6. 发明申请

WO2005023984A2 METHOD FOR PRODUCING 1,1,1,3-TETRACHLOROPROPANE AND OTHER HALOALKANES USING A COPPER CATALYST 审中-公开
标题翻译：使用铜催化剂生产1,1,1,3-四氯丙烯和其他卤代醇的方法
公开(公告)号：WO2005023984A2
公开(公告)日：2005-03-17
申请号：PCT/US2004027754
申请日：2004-08-26
申请人： VULCAN CHEMICALS A BUSINESS GR
发明人： WILSON RICHARD L
IPC分类号： C07C17/275 , C07C17/278 , C12N
CPC分类号： C07C17/275 , C07C17/278 , Y02P20/584 , C07C19/01
摘要： A process is provided for the manufacture of a haloalkane by the reaction of carbon tetrachloride with an olefin in the presence of dissolved catalytic copper compounds and a cosolvent. A fraction of the catalyst and co-catalyst is recycled to the reactor. In a preferred application, the olefin is ethene and the desired haloalkane is 1,1,1,3-tetrachloropropane, or the olefin is vinyl chloride and the haloalkane is 1,1,1,3,3-pentachloropropane, or the olefin is 1,1-dichloroethene and the haloalkane is 1,1,1,3,3,3,-hexachloropropane, or the olefin is 2-chloropropene and the haloalkane product is 1,1,1,3,3-pentachlorobutane. Other preferred implementations provide an efficient continuous process.
摘要翻译：提供了在溶解的催化铜化合物和助溶剂的存在下通过四氯化碳与烯烃的反应制备卤代烷烃的方法。催化剂和助催化剂的一部分再循环到反应器中。在优选的应用中，烯烃是乙烯，所需的卤代烷烃是1,1,1,3-四氯丙烷，或者烯烃是氯乙烯，卤代烷烃是1,1,1,3,3-五氯丙烷，或者烯烃是 1,1-二氯乙烯和卤代烷烃是1,1,1,3,3,3,6-六氯丙烷，或烯烃是2-氯丙烯，卤代烷烃产物是1,1,1,3,3-五氯丁烷。其他优选的实施方案提供了有效的连续过程。

7. 发明申请

WO02100809A3 INBITION OF THE DEHYDROCHLORINATION REACTION OF POLYCHLORINATED ALKANES 审中-公开
标题翻译：多氯代烷烃脱氢反应的反应
公开(公告)号：WO02100809A3
公开(公告)日：2003-10-16
申请号：PCT/US0218171
申请日：2002-06-11
申请人： VULCAN CHEMICALS
发明人： KLAUSMEYER RODNEY L
IPC分类号： C07C17/42 , C07C19/01
CPC分类号： C07C17/42 , C07C19/01 , C07C19/05
摘要： A process is provided for the stabilization of polychlorinated alkanes against dehydrochlorination. The process comprises adding a phenol compound to a polychlorinated alkane such that the dehydrochlorination of the polychlorinated alkane is suppressed when heated in the presence of iron(III). In a preferred embodiment, the process comprises the prevention or reduction of dehydrochlorination of 1,1,1,3,3-pentachloropropane when heated in the presence of iron(III) contamination by the addition of monomethyl ether hydroquinone. In another embodiment, the long term storage stability of polychlorinated alkanes against dehydrochlorination is improved due to the addition of a phenol compound.
摘要翻译：提供了一种用于稳定多氯代烷烃以防止脱氯化氢的方法。该方法包括向多氯代烷烃中加入酚化合物，使得在铁（III）存在下加热时，抑制多氯代烷烃的脱氯化氢。在优选的实施方案中，该方法包括当在加入单甲醚氢醌的铁（III）污染物存在下加热时，防止或减少1,1,1,3,3-五氯丙烷的脱氯化氢。在另一个实施方案中，由于加入酚化合物，多氯代烷烃对脱氯化氢的长期保存稳定性得到改善。

8. 发明申请

WO2002102750A2 WATER-ENHANCED PRODUCTION OF 1,1,1,3,3-PENTACHLOROPROPANE 审中-公开
标题翻译： 1,1,1,3,3-邻苯二酚的水提高生产
公开(公告)号：WO2002102750A2
公开(公告)日：2002-12-27
申请号：PCT/US2002/018253
申请日：2002-06-12
申请人： VULCAN CHEMICALS
发明人： BRANAM, Lloyd, B.
IPC分类号： C07C19/01
CPC分类号： C07C17/278 , C07C17/275 , C07C19/01
摘要： A process is provided by which addition of water is used to enhance the production of any hydrochlorocarbon feedstock through the use of Kharasch chemistry, i.e. the combination of a polychlorinated alkane with an olefin to produce a chlorinated or hydrochlorinated alkane with the use of a transition metal compound in homogeneous solution as catalyst. Preferably, water is added to increase the production of 1,1,1,3,3- pentachloropropane by the reaction of carbon tetrachloride and vinyl chloride in the presence of a catalyst mixture of organo phosphate solvent, iron metal and ferric chloride.
摘要翻译：提供了一种方法，通过使用添加水来通过使用Kharasch化学来增加任何氢氯烃原料的生产，即多氯代烷烃与烯烃的组合，以产生使用过渡金属的氯化或氢氯化烷烃化合物在均相溶液中作为催化剂。优选地，在有机磷酸盐溶剂，铁金属和氯化铁的催化剂混合物的存在下，加入水以通过四氯化碳和氯乙烯的反应来增加1,1,1,3,3-五氯丙烷的产生。

9. 发明申请

WO2005026082A2 METHOD FOR REUSING HEAVY END BY-PRODUCTS IN THE MANUFACTURE OF POLYCHLORINATED ALKANES 审中-公开
标题翻译：在多氯化铝制造中重新制造重型副产品的方法
公开(公告)号：WO2005026082A2
公开(公告)日：2005-03-24
申请号：PCT/US2004028298
申请日：2004-08-31
申请人： VULCAN CHEMICALS A BUSINESS GR
发明人： KLAUSMEYER RODNEY L
IPC分类号： C07C17/275 , C07C17/278 , C07C17/383 , C07C17/395 , C07C
CPC分类号： C07C17/383 , C07C17/275 , C07C17/278 , C07C17/395 , C07C19/01
摘要： A method for recovering much of the carbon and chlorine value in the heavy ends and other undesired by-products formed during the production of a C3 or higher polychlorinated alkane through the reaction of carbon tetrachloride with an olefine or chlorinated olefine, the improvement comprising the step of first separating the heavy ends and any other higher or lower boiling chlorohydrocarbon impurities from most of the desired product, and subjecting the separated heavy ends and impurities therewith to a high temperature exhaustive chlorination to produce carbon tetrachloride, tetrachloroethene, and minor amounts of hexachlorobutadiene and hexachlorobenzene by-products.
摘要翻译：通过四氯化碳与烯烃或氯化烯烃的反应，在C3或更高的多氯代烷烃的生产过程中回收重馏分中大部分碳和氯值以及其它不希望的副产物的方法，其改进包括步骤首先从大部分所需产物中分离出重的末端和任何其它更高或更低沸点的氯代烃杂质，并将分离出的重质末端和杂质进行高温彻底氯化，得到四氯化碳，四氯乙烯和少量六氯丁二烯，六氯苯副产品。

10. 发明申请

WO2003089391A1 1,1,1,3,3-PENTACHLOROPROPANE PROCESS PURGE STREAM CONCENTRATION USING A SECONDARY REFLUXED EVAPORATOR AND SECONDARY PRODUCT RECOVERY 审中-公开
标题翻译： 1,1,1,3,3-PENTACHLOROPROPANE工艺流程浓度使用二次回流蒸发器和二次产品回收
公开(公告)号：WO2003089391A1
公开(公告)日：2003-10-30
申请号：PCT/US2003/004212
申请日：2003-02-11
申请人： VULCAN CHEMICALS
发明人： WILSON, Richard, L. , DAWKINS, John, L. , KLAUSMEYER, Rodney, L. , WELLER, James, J.
IPC分类号： C07C17/02
CPC分类号： C07C17/383 , C07C17/275 , C07C17/278 , C07C17/38 , Y02P20/582 , C07C19/01
摘要： A process for economically producing 1,1,1,3,3-pentachloropropane under conditions which preserve the activity of the catalyst. In a preferred embodiment, a two-stage distillation process is employed. In the two-stage process, the size of the equipment, temperature and vacuum are varied.
摘要翻译：在保持催化剂活性的条件下经济地生产1,1,1,3,3-五氯丙烷的方法。在优选的实施方案中，采用两阶段蒸馏方法。在两阶段工艺中，设备的尺寸，温度和真空度都有差异。

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