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1. 发明申请

WO2012031061A2 FUNGICIDAL PYRAZOLES AND THEIR MIXTURES 审中-公开
标题翻译：杀真菌剂及其混合物
公开(公告)号：WO2012031061A2
公开(公告)日：2012-03-08
申请号：PCT/US2011/050124
申请日：2011-09-01
申请人： E. I. DU PONT DE NEMOURS AND COMPANY , LONG, Jeffrey, Keith , GREGORY, Vann , GUTTERIDGE, Steven , TAGGI, Andrew, Edmund , BEREZNAK, James, Francis
发明人： LONG, Jeffrey, Keith , GREGORY, Vann , GUTTERIDGE, Steven , TAGGI, Andrew, Edmund , BEREZNAK, James, Francis
IPC分类号： A01N43/48
CPC分类号： A01N43/56 , A01N37/34 , A01N37/44 , A01N43/12 , A01N43/26 , A01N43/30 , A01N43/40 , A01N43/42 , A01N43/48 , A01N43/50 , A01N43/54 , A01N43/653 , A01N43/78 , A01N43/80 , A01N43/84 , A01N43/90 , A01N47/08 , A01N47/12 , A01N47/28 , A01N59/20 , C07D231/20 , C07D231/38 , A01N37/38 , A01N37/46 , A01N43/36 , A01N45/02 , A01N47/04 , A01N47/14 , A01N47/24 , A01N47/34 , A01N47/38
摘要： Disclosed is a fungicidal composition comprising (a) at least one compound selected from the compounds of Formula (1), N -oxides, and salts thereof, wherein R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are as defined in the disclosure; and (b) at least one additional fungicidal compound. Also disclosed is a method for controlling plant diseases caused by fungal plant pathogens comprising applying to the plant or portion thereof, or to the plant seed, a fungicidally effective amount of a compound of Formula (1), an N -oxide, or salt thereof (e.g., as a component in the aforesaid composition). Also disclosed is a composition comprising: (a) at least one compound selected from the compounds of Formula (1) described above, N -oxides, and salts thereof; and at least one invertebrate pest control compound or agent.
摘要翻译：公开了一种杀真菌组合物，其包含（a）至少一种选自式（1）的化合物，N-氧化物及其盐的化合物，其中R 1，R 2，R 3，R 4，R 5和R 6如本公开中所定义; 和（b）至少一种另外的杀真菌化合物。还公开了一种用于控制由真菌植物病原体引起的植物病害的方法，包括向植物或其部分或植物种子施用杀真菌有效量的式（1），N-氧化物或其盐的化合物（例如，作为上述组合物中的组分）。还公开了一种组合物，其包含：（a）至少一种选自上述式（1）的化合物，N-氧化物及其盐的化合物; 和至少一种无脊椎害虫防治化合物或药剂。

2. 发明申请

WO2009137651A2 FUNGICIDAL SUBSTITUTED AZOLES 审中-公开
标题翻译：杀真菌剂替代品
公开(公告)号：WO2009137651A2
公开(公告)日：2009-11-12
申请号：PCT/US2009043096
申请日：2009-05-07
申请人： DU PONT , SELBY THOMAS PAUL , BEREZNAK JAMES FRANCIS , BISAHA JOHN JOSEPH , DING AMY X , GOPALSAMUTHIRAM VIJAYAGOPAL , HANAGAN MARY ANN , LONG JEFFREY KEITH , TAGGI ANDREW EDMUND
发明人： SELBY THOMAS PAUL , BEREZNAK JAMES FRANCIS , BISAHA JOHN JOSEPH , DING AMY X , GOPALSAMUTHIRAM VIJAYAGOPAL , HANAGAN MARY ANN , LONG JEFFREY KEITH , TAGGI ANDREW EDMUND
IPC分类号： C07D231/12 , C07D233/64 , C07D233/68 , C07D233/88 , C07D249/06
CPC分类号： C07D231/12 , A01N43/50 , A01N43/56 , A01N43/647 , C07D233/64 , C07D233/68 , C07D233/88 , C07D249/06 , C07D401/04 , C07D403/04 , C07D409/04 , C07D417/04
摘要： Disclosed are compounds of Formula 1, including all geometric and stereoisomers, N-oxides, and salts thereof, INSERT FORMULA 1 HERE wherein J is Q2 or R1; X is N, CR2 or CQ3; Y is N or CR3; Z is N or CR4; and Q1, Q2, Q3, R1 R2 and R3 are as defined in the disclosure. Also disclosed are compositions containing the compounds of Formula 1 and methods for controlling plant disease caused by a fungal pathogen comprising applying an effective amount of a compound or a composition of the invention.
摘要翻译：公开了式1的化合物，包括所有几何和立体异构体，N-氧化物及其盐，其中J为Q2或R1; X为N，CR2或CQ3; Y为N或CR 3; Z是N或CR4; 并且Q1，Q2，Q3，R1R2和R3如本公开中所定义。还公开了含有式1化合物的组合物和用于控制由真菌病原体引起的植物病害的方法，包括施用有效量的本发明化合物或组合物。

3. 发明申请

WO2009076440A3 FUNGICIDAL BICYCLIC PYRAZOLES 审中-公开
公开(公告)号：WO2009076440A3
公开(公告)日：2009-09-24
申请号：PCT/US2008086227
申请日：2008-12-10
申请人： DU PONT , BISAHA JOHN JOSEPH , CREWS ALVIN DONALD JR , HOWARD MICHAEL HENRY JR , SHARPE PAULA LOUISE , STEVENSON THOMAS MARTIN , TAGGI ANDREW EDMUND
发明人： BISAHA JOHN JOSEPH , CREWS ALVIN DONALD JR , HOWARD MICHAEL HENRY JR , SHARPE PAULA LOUISE , STEVENSON THOMAS MARTIN , TAGGI ANDREW EDMUND
IPC分类号： C07D471/04 , A01N43/90 , A01P3/00 , C07D487/04 , C07D498/04
CPC分类号： C07D487/04 , A01N43/90 , C07D471/04 , C07D498/04
摘要： Disclosed are compounds of Formulae 1 and 1a, N-oxides, and salts thereof, wherein R1, R1a, Y, and J are as defined in the disclosure. Also disclosed are compositions containing the compounds of Formula 1 and methods for controlling plant disease caused by a fungal pathogen comprising applying an effective amount of a compound or a composition of the invention. Further disclosed is a method for preparing compounds of Formula 1 from compounds of Formula 1a.

4. 发明申请

WO2009051956A2 PYRAZOLE-SUBSTITUTED ISOXAZOLINE INSECTICIDES 审中-公开
标题翻译：吡唑取代的异恶唑啉杀虫剂
公开(公告)号：WO2009051956A2
公开(公告)日：2009-04-23
申请号：PCT/US2008078374
申请日：2008-10-01
申请人： DU PONT , HOLYOKE CALEB WILLIAM JR , LAHM GEORGE PHILIP , TAGGI ANDREW EDMUND
发明人： HOLYOKE CALEB WILLIAM JR , LAHM GEORGE PHILIP , TAGGI ANDREW EDMUND
IPC分类号： C07D413/10 , A01N43/80
CPC分类号： C07D413/10 , A01N43/80
摘要： Disclosed are compounds of Formula (1), including all stereoisomers, N-oxides, and salts thereof, wherein R1 is F, Cl, Br, CF3, OCHF2, OCF3 or OCH2CF3; R2 is H, F, Cl, Br, CH3, cyano, CF3, CHF2, OHCF2, OCF3 or OCH2CF3; R3 is H, F, Cl, Br or CF3; R4 is cyano or C(S)NH2; R5 is F, Cl, Br, I, cyano, C(S)NH2 or C(O)NHR6; and R6 is H; or R6 is C1-C3 alkyl, cyclopropyl or cyclopropylmethyl, each optionally substituted with halogen and further optionally substituted with 1 or 2 CH3; or R6 is l-(trifluoromethyl)cyclopropyl. Also disclosed are compositions containing the compounds of Formula (1) and methods for controlling an invertebrate pest comprising contacting the invertebrate pest or its environment with a biologically effective amount of a compound or a composition of the invention.
摘要翻译：公开了式（1）化合物，包括所有立体异构体，N-氧化物和盐，其中R 1为F，Cl，Br，CF 3，OCHF 2，OCF 3或OCH 2 CF 3; R2是H，F，Cl，Br，CH3，氰基，CF3，CHF2，OHCF2，OCF3或OCH2CF3; R3是H，F，Cl，Br或CF3; R4是氰基或C（S）NH2; R5是F，Cl，Br，I，氰基，C（S）NH2或C（O）NHR6; 和R6是H; 或R6是C1-C3烷基，环丙基或环丙基甲基，各自任选被卤素取代并且进一步任选被1或2个CH3取代; 或者R6是1-（三氟甲基）环丙基。还公开了含有式（1）化合物的组合物和防治无脊椎害虫的方法，包括使无脊椎害虫或其环境与生物有效量的本发明化合物或组合物接触。

5. 发明申请

WO2006055922A3 ANTHRANILAMIDE INSECTICIDES 审中-公开
公开(公告)号：WO2006055922A3
公开(公告)日：2006-05-26
申请号：PCT/US2005/042196
申请日：2005-11-18
申请人： E.I. DUPONT DE NEMOURS AND COMPANY , LAHM, George, Philip , SELBY, Thomas, Paul , STEVENSON, Thomas, Martin , TAGGI, Andrew, Edmund , BEREZNAK, James, Francis
发明人： LAHM, George, Philip , SELBY, Thomas, Paul , STEVENSON, Thomas, Martin , TAGGI, Andrew, Edmund , BEREZNAK, James, Francis
IPC分类号： C07D401/04 , A01N43/56 , C07D401/00 , C07D233/72
摘要： Disclosed are compounds of Formula 1, including all geometric and stereoisomers, N -oxides, and salts thereof, wherein J is a phenyl optionally substituted with one to four substituents independently selected from R 5 ; or J is a heterocyclic ring selected from the group consisting of J-1 to J-8; R 4 is C 4 -C 12 alkylcycloalkyl, C 5 -C 12 alkenylcycloalkyl, C 5 -C 12 alkynylcycloalkyl, C 4 -C 12 cycloalkylalkyl, C 5 -C 12 cycloalkylalkenyl, C 5 -C 12 cycloalkylalkynyl, C 4 -C 12 cycloalkenylalkyl or C 4 -C 12 alkylcycloalkenyl; each optionally substituted with one to six substituents selected from CH 3 and halogen; or R 4 is C 3 -C 5 oxiranylalkyl, C 3 -C 5 thiiranylalkyl, C 4 -C 6 oxetanylalkyl, C 4 -C 6 thietanylalkyl, 3-oxetanyl or 3-thietanyl, each optionally substituted with one to five substituents independently selected from C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, halogen, CN, C 2 -C 4 alkoxycarbonyl and C 2 -C 4 haloalkoxycarbonyl; or R 4 is C 3 -C 5 aziridinylalkyl, C 4 -C 6 azetidinylalkyl or 3-azetidinyl, each with R 10 attached to the nitrogen atom, and optionally substituted on carbon atoms with one to five substituents independently selected from C l -C 3 alkyl, C 1 -C 3 haloalkyl, halogen, CN, C 2 -C 4 alkoxycarbonyl and C 2 -C 4 haloalkoxycarbonyl; and R la , R 1b , R 2 , R 3 and R 5 are as defined in the disclosure. Also disclosed are intermediate compounds, compositions containing the compounds of Formula 1 and methods for controlling an invertebrate pest comprising contacting the invertebrate pest or its environment with a biologically effective amount of a compound or a composition of the invention.

6. 发明申请

WO2009158258A1 HERBICIDAL DIHYDRO OXO SIX-MEMBERED AZINYL ISOXAZOLINES 审中-公开
标题翻译：除草剂二氢氧化钛六甲基异氰酸酯
公开(公告)号：WO2009158258A1
公开(公告)日：2009-12-30
申请号：PCT/US2009/047725
申请日：2009-06-18
申请人： E. I. DU PONT DE NEMOURS AND COMPANY , SMITH, Brenton, Todd , SELBY, Thomas, Paul , STEVENSON, Thomas, Martin , CLARK, David, Alan , TAGGI, Andrew, Edmund
发明人： SMITH, Brenton, Todd , SELBY, Thomas, Paul , STEVENSON, Thomas, Martin , CLARK, David, Alan , TAGGI, Andrew, Edmund
IPC分类号： C07D413/12 , A01N43/80
CPC分类号： C07D413/12 , C07D213/24
摘要： Disclosed are compounds of Formula (I), including all geometric and stereoisomers, N- oxides, and salts thereof, Formula (I) wherein J is Formula (II) and R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8a , R 8b , R 8c , R 8d , Q 1 , Q 2 , Q 3 , Q 4 , W 1 , W 2 , W 3 , W 4 , Y 1 , Y 2 , Y 3 , Y 4 , m and n are as defined in the disclosure. Also disclosed are compositions containing the compounds of Formula (I) and methods for controlling undesired vegetation comprising contacting the undesired vegetation or its environment with an effective amount of a compound or a composition of the invention.
摘要翻译：公开了式（I）的化合物，其包括所有几何和立体异构体的N-氧化物及其盐，其中J为式（II），R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8a ，R8b，R8c，R8d，Q1，Q2，Q3，Q4，W1，W2，W3，W4，Y1，Y2，Y3，Y4，m和n如本公开中所定义。还公开了含有式（I）化合物和控制不希望的植物的方法的组合物，包括使不需要的植物或其环境与有效量的本发明的化合物或组合物接触。

7. 发明申请

WO2008124092A8 SUBSTITUTED BENZENE FUNGICIDES 审中-公开
标题翻译：替代苯醌类杀真菌剂
公开(公告)号：WO2008124092A8
公开(公告)日：2009-12-03
申请号：PCT/US2008004443
申请日：2008-04-03
申请人： DU PONT , FINKELSTEIN BRUCE LAWRENCE , TAGGI ANDREW EDMUND , LONG JEFFREY KEITH , SHARPE PAULA LOUISE , TSENG CHI-PING , MCCANN STEPHEN FREDERICK , DING AMY X , SWANN JR STEVEN LEWIS
发明人： FINKELSTEIN BRUCE LAWRENCE , TAGGI ANDREW EDMUND , LONG JEFFREY KEITH , SHARPE PAULA LOUISE , TSENG CHI-PING , MCCANN STEPHEN FREDERICK , DING AMY X , SWANN JR STEVEN LEWIS
IPC分类号： A01N55/00
CPC分类号： A01N55/00 , A01N43/56 , A01N47/10 , A01N47/12 , A01N47/24 , A01N2300/00 , A61K31/415 , C07C271/08 , C07D231/02 , C07D231/10 , C07D231/12 , C07D239/26 , C07D249/06 , C07D417/04 , C07F7/10
摘要： Disclosed are compounds of Formula 1, including all geometric and stereoisomers, N-oxides, and salts thereof, wherein W is O or S; V is a direct bond or NR3; Q is or CR6aR6b, O, NR7, C=N-O-R7 or C(=O); Y is -C(R5)=N-O-(CR8aR8b)p-X-(CR9aR9b)q-SiR10aR10bR10c; or a phenyl ring subr stituted as defined in the disclosure; or Z; and R1, R2, R3, R4, R5, R6a, R6b, R7, R8a, R8b, R9a, R9b, R10a, R10b, R10c, Z, p and q are as defined in the disclosure. Also disclosed are compositions containing the compounds of Formula 1 and methods for controlling plant disease caused by a fungal pathogen comprising applying an effective amount of a compound or a composition of the invention.
摘要翻译：公开了式1的化合物，包括所有几何和立体异构体，N-氧化物及其盐，其中W是O或S; V是直接键或NR3; Q是或CR6aR6b，O，NR7，C = N-O-R7或C（= O）; Y是-C（R5）= N-O-（CR8aR8b）p-X-（CR9aR9b）q-SiR10aR10bR10c; 或如本公开中所定义的苯环; 或Z; 并且R1，R2，R3，R4，R5，R6a，R6b，R7，R8a，R8b，R9a，R9b，R10a，R10b，R10c，Z，p和q如本公开所定义。还公开了含有式1化合物的组合物和用于控制由真菌病原体引起的植物病害的方法，包括施用有效量的本发明化合物或组合物。

8. 发明申请

WO2009137538A2 FUNGICIDAL SUBSTITUTED AZOLES 审中-公开
标题翻译：杀真菌剂替代品
公开(公告)号：WO2009137538A2
公开(公告)日：2009-11-12
申请号：PCT/US2009/042922
申请日：2009-05-06
申请人： E. I. DU PONT DE NEMOURS AND COMPANY , SELBY, Thomas, Paul , BEREZNAK, James, Francis , BISAHA, John, Joseph , DING, Amy, X. , GOPALSAMUTHIRAM, Vijayagopal , HANAGAN, Mary, Ann , LONG, Jeffrey, Keith , TAGGI, Andrew, Edmund
发明人： SELBY, Thomas, Paul , BEREZNAK, James, Francis , BISAHA, John, Joseph , DING, Amy, X. , GOPALSAMUTHIRAM, Vijayagopal , HANAGAN, Mary, Ann , LONG, Jeffrey, Keith , TAGGI, Andrew, Edmund
IPC分类号： C07D231/12 , C07D233/64 , C07D233/68 , C07D233/88 , C07D249/06 , C07D401/04 , C07D403/04 , C07D409/04 , C07D417/04 , A01N43/50 , A01N43/707
CPC分类号： C07D231/12 , A01N43/50 , A01N43/56 , A01N43/647 , C07D233/64 , C07D233/68 , C07D233/88 , C07D249/06 , C07D401/04 , C07D403/04 , C07D409/04 , C07D417/04
摘要： Disclosed are compounds of Formula (1), including all geometric and stereoisomers, N -oxides, and salts thereof, wherein J is Q 2 or R 1 ; X is N, CR 2 or CQ 3 ; Y is N or CR 3 ; Z is N or CR 4 ; and Q 1 , Q 2 , Q 3 , R 1 R 2 and R 3 are as defined in the disclosure. Also disclosed are compositions containing the compounds of Formula (1) and methods for controlling plant disease caused by a fungal pathogen comprising applying an effective amount of a compound or a composition of the invention.
摘要翻译：公开了式（1）的化合物，包括所有几何和立体异构体的N-氧化物及其盐，其中J为Q2或R1; X为N，CR2或CQ3; Y为N或CR 3; Z是N或CR4; 并且Q1，Q2，Q3，R1R2和R3如本公开中所定义。还公开了含有式（1）化合物和控制由真菌病原体引起的植物病害的方法的组合物，其包括施用有效量的本发明化合物或组合物。

9. 发明申请

WO2008124092A3 SUBSTITUTED BENZENE FUNGICIDES 审中-公开
标题翻译：替代苯醌类杀真菌剂
公开(公告)号：WO2008124092A3
公开(公告)日：2008-12-18
申请号：PCT/US2008004443
申请日：2008-04-03
申请人： DU PONT , FINKELSTEIN BRUCE LAWRENCE , TAGGI ANDREW EDMUND , LONG JEFFREY KEITH , SHARPE PAULA LOUISE , TSENG CHI-PING , MCCANN STEPHEN FREDERICK , DING AMY X , SWANN JR STEVEN LEWIS
发明人： FINKELSTEIN BRUCE LAWRENCE , TAGGI ANDREW EDMUND , LONG JEFFREY KEITH , SHARPE PAULA LOUISE , TSENG CHI-PING , MCCANN STEPHEN FREDERICK , DING AMY X , SWANN STEVEN LEWIS JR
IPC分类号： A01N55/00
CPC分类号： A01N55/00 , A01N43/56 , A01N47/10 , A01N47/12 , A01N47/24 , A01N2300/00 , A61K31/415 , C07C271/08 , C07D231/02 , C07D231/10 , C07D231/12 , C07D239/26 , C07D249/06 , C07D417/04 , C07F7/10
摘要： Disclosed are compounds of Formula 1, including all geometric and stereoisomers, N-oxides, and salts thereof, wherein W is O or S; V is a direct bond or NR3; Q is or CR6aR6b, O, NR7, C=N-O-R7 or C(=O); Y is -C(R5)=N-O-(CR8aR8b)p-X-(CR9aR9b)q-SiR10aR10bR10c; or a phenyl ring subr stituted as defined in the disclosure; or Z; and R1, R2, R3, R4, R5, R6a, R6b, R7, R8a, R8b, R9a, R9b, R10a, R10b, R10c, Z, p and q are as defined in the disclosure. Also disclosed are compositions containing the compounds of Formula 1 and methods for controlling plant disease caused by a fungal pathogen comprising applying an effective amount of a compound or a composition of the invention.
摘要翻译：公开了式1的化合物，包括所有几何和立体异构体，N-氧化物及其盐，其中W是O或S; V是直接键或NR3; Q是或CR6aR6b，O，NR7，C = N-O-R7或C（= O）; Y是-C（R5）= N-O-（CR8aR8b）p-X-（CR9aR9b）q-SiR10aR10bR10c; 或如本公开中所定义的苯环; 或Z; 并且R1，R2，R3，R4，R5，R6a，R6b，R7，R8a，R8b，R9a，R9b，R10a，R10b，R10c，Z，p和q如本公开所定义。还公开了含有式1化合物的组合物和用于控制由真菌病原体引起的植物病害的方法，包括施用有效量的本发明化合物或组合物。

10. 发明申请

WO2006055922A8 ANTHRANILAMIDE INSECTICIDES 审中-公开
标题翻译： ANTHRANILAMIDE杀虫剂
公开(公告)号：WO2006055922A8
公开(公告)日：2007-03-15
申请号：PCT/US2005042196
申请日：2005-11-18
申请人： DU PONT , LAHM GEORGE PHILIP , SELBY THOMAS PAUL , STEVENSON THOMAS MARTIN , TAGGI ANDREW EDMUND , BEREZNAK JAMES FRANCIS
发明人： LAHM GEORGE PHILIP , SELBY THOMAS PAUL , STEVENSON THOMAS MARTIN , TAGGI ANDREW EDMUND , BEREZNAK JAMES FRANCIS
IPC分类号： C07D401/04 , A01N43/56 , C07D233/72 , C07D401/00
CPC分类号： C07D231/16 , A01N43/56 , C07D401/04 , C07D405/12 , C07D405/14 , A01N51/00 , A01N47/40 , A01N2300/00
摘要： Disclosed are compounds of Formula 1, including all geometric and stereoisomers, N-oxides, and salts thereof, wherein J is a phenyl optionally substituted with one to four substituents independently selected from R 5 ; or J is a heterocyclic ring selected from the group consisting of J-1 to J-8; R 4 is C 4 -C 12 alkylcycloalkyl, C 5 -C 12 alkenylcycloalkyl, C 5 -C 12 alkynylcycloalkyl, C 4 -C 12 cycloalkylalkyl, C 5 -C 12 cycloalkylalkenyl, C 5 -C 12 cycloalkylalkynyl, C 4 -C 12 cycloalkenylalkyl or C 4 -C 12 alkylcycloalkenyl; each optionally substituted with one to six substituents selected from CH 3 and halogen; or R 4 is C 3 -C 5 oxiranylalkyl, C 3 -C 5 thiiranylalkyl, C 4 -C 6 oxetanylalkyl, C 4 -C 6 thietanylalkyl, 3-oxetanyl or 3-thietanyl, each optionally substituted with one to five substituents independently selected from C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, halogen, CN, C 2 -C 4 alkoxycarbonyl and C 2 -C 4 haloalkoxycarbonyl; or R 4 is C 3 -C 5 aziridinylalkyl, C 4 -C 6 azetidinylalkyl or 3-azetidinyl, each with R 10 attached to the nitrogen atom, and optionally substituted on carbon atoms with one to five substituents independently selected from C l -C 3 alkyl, C 1 -C 3 haloalkyl, halogen, CN, C 2 -C 4 alkoxycarbonyl and C 2 -C 4 haloalkoxycarbonyl; and R la
摘要翻译：公开了式1的化合物，包括所有几何和立体异构体，N-氧化物及其盐，其中J是任选被一至四个独立地选自R 5的取代基取代的苯基; 或J为选自J-1至J-8的杂环; R 4是C 4 -C 12烷基环烷基，C 5 -C 12烷基，烯基环烷基，C 5 -C 12炔基环烷基，C 4 -C 12环烷基烷基，C 5 - C 12 -C 12环烷基烯基，C 5 -C 12环烷基炔基，C 4 -C 12个环烯基烷基或C 4 -C 12烷基环烯基; 各自任选被一个至六个选自CH 3和卤素的取代基取代; 或R 4是C 3 -C 5环氧烷基烷基，C 3 -C 5 >硫杂环烷基烷基，C 4 -C 6氧杂环丁烷基，C 4 -C 6亚硫代烷基烷基，3-氧杂环丁烷基或3 每个任选被一至五个独立地选自C 1 -C 3烷基，C 1 -C 3烷基的取代基取代的硫杂环丁烷基卤代烷基，卤素，CN，C 2 -C 4烷氧基羰基和C 2 -C 4烷基，卤代烷; 或R 4是C 3 -C 5氮丙啶基烷基，C 4 -C 6 >氮杂环丁烷基或3-氮杂环丁烷基，其各自具有与氮原子连接的R 10，并且任选地在碳原子上被一至五个独立地选自C 1 -C 10烷基的取代基取代， C 1 -C 3烷基，C 1 -C 3卤代烷基，卤素，CN，C 2 -C 4烷基，烷氧基羰基和C 2 -C 4卤代烷氧基羰基; 和R 1a

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