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    • 1. 发明申请
    • PYRAZOLE-SUBSTITUTED ISOXAZOLINE INSECTICIDES
    • 吡唑取代的异恶唑啉杀虫剂
    • WO2009051956A2
    • 2009-04-23
    • PCT/US2008078374
    • 2008-10-01
    • DU PONTHOLYOKE CALEB WILLIAM JRLAHM GEORGE PHILIPTAGGI ANDREW EDMUND
    • HOLYOKE CALEB WILLIAM JRLAHM GEORGE PHILIPTAGGI ANDREW EDMUND
    • C07D413/10A01N43/80
    • C07D413/10A01N43/80
    • Disclosed are compounds of Formula (1), including all stereoisomers, N-oxides, and salts thereof, wherein R1 is F, Cl, Br, CF3, OCHF2, OCF3 or OCH2CF3; R2 is H, F, Cl, Br, CH3, cyano, CF3, CHF2, OHCF2, OCF3 or OCH2CF3; R3 is H, F, Cl, Br or CF3; R4 is cyano or C(S)NH2; R5 is F, Cl, Br, I, cyano, C(S)NH2 or C(O)NHR6; and R6 is H; or R6 is C1-C3 alkyl, cyclopropyl or cyclopropylmethyl, each optionally substituted with halogen and further optionally substituted with 1 or 2 CH3; or R6 is l-(trifluoromethyl)cyclopropyl. Also disclosed are compositions containing the compounds of Formula (1) and methods for controlling an invertebrate pest comprising contacting the invertebrate pest or its environment with a biologically effective amount of a compound or a composition of the invention.
    • 公开了式(1)化合物,包括所有立体异构体,N-氧化物和盐,其中R 1为F,Cl,Br,CF 3,OCHF 2,OCF 3或OCH 2 CF 3; R2是H,F,Cl,Br,CH3,氰基,CF3,CHF2,OHCF2,OCF3或OCH2CF3; R3是H,F,Cl,Br或CF3; R4是氰基或C(S)NH2; R5是F,Cl,Br,I,氰基,C(S)NH2或C(O)NHR6; 和R6是H; 或R6是C1-C3烷基,环丙基或环丙基甲基,各自任选被卤素取代并且进一步任选被1或2个CH3取代; 或者R6是1-(三氟甲基)环丙基。 还公开了含有式(1)化合物的组合物和防治无脊椎害虫的方法,包括使无脊椎害虫或其环境与生物有效量的本发明化合物或组合物接触。
    • 2. 发明申请
    • ANTHRANILAMIDE INSECTICIDES
    • ANTHRANILAMIDE杀虫剂
    • WO2006055922A8
    • 2007-03-15
    • PCT/US2005042196
    • 2005-11-18
    • DU PONTLAHM GEORGE PHILIPSELBY THOMAS PAULSTEVENSON THOMAS MARTINTAGGI ANDREW EDMUNDBEREZNAK JAMES FRANCIS
    • LAHM GEORGE PHILIPSELBY THOMAS PAULSTEVENSON THOMAS MARTINTAGGI ANDREW EDMUNDBEREZNAK JAMES FRANCIS
    • C07D401/04A01N43/56C07D233/72C07D401/00
    • C07D231/16A01N43/56C07D401/04C07D405/12C07D405/14A01N51/00A01N47/40A01N2300/00
    • Disclosed are compounds of Formula 1, including all geometric and stereoisomers, N-oxides, and salts thereof, wherein J is a phenyl optionally substituted with one to four substituents independently selected from R 5 ; or J is a heterocyclic ring selected from the group consisting of J-1 to J-8; R 4 is C 4 -C 12 alkylcycloalkyl, C 5 -C 12 alkenylcycloalkyl, C 5 -C 12 alkynylcycloalkyl, C 4 -C 12 cycloalkylalkyl, C 5 -C 12 cycloalkylalkenyl, C 5 -C 12 cycloalkylalkynyl, C 4 -C 12 cycloalkenylalkyl or C 4 -C 12 alkylcycloalkenyl; each optionally substituted with one to six substituents selected from CH 3 and halogen; or R 4 is C 3 -C 5 oxiranylalkyl, C 3 -C 5 thiiranylalkyl, C 4 -C 6 oxetanylalkyl, C 4 -C 6 thietanylalkyl, 3-oxetanyl or 3-thietanyl, each optionally substituted with one to five substituents independently selected from C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, halogen, CN, C 2 -C 4 alkoxycarbonyl and C 2 -C 4 haloalkoxycarbonyl; or R 4 is C 3 -C 5 aziridinylalkyl, C 4 -C 6 azetidinylalkyl or 3-azetidinyl, each with R 10 attached to the nitrogen atom, and optionally substituted on carbon atoms with one to five substituents independently selected from C l -C 3 alkyl, C 1 -C 3 haloalkyl, halogen, CN, C 2 -C 4 alkoxycarbonyl and C 2 -C 4 haloalkoxycarbonyl; and R la
    • 公开了式1的化合物,包括所有几何和立体异构体,N-氧化物及其盐,其中J是任选被一至四个独立地选自R 5的取代基取代的苯基; 或J为选自J-1至J-8的杂环; R 4是C 4 -C 12烷基环烷基,C 5 -C 12烷基, 烯基环烷基,C 5 -C 12炔基环烷基,C 4 -C 12环烷基烷基,C 5 - C 12 -C 12环烷基烯基,C 5 -C 12环烷基炔基,C 4 -C 12个环烯基烷基或C 4 -C 12烷基环烯基; 各自任选被一个至六个选自CH 3和卤素的取代基取代; 或R 4是C 3 -C 5环氧烷基烷基,C 3 -C 5 >硫杂环烷基烷基,C 4 -C 6氧杂环丁烷基,C 4 -C 6亚硫代烷基烷基,3-氧杂环丁烷基或3 每个任选被一至五个独立地选自C 1 -C 3烷基,C 1 -C 3烷基的取代基取代的硫杂环丁烷基 卤代烷基,卤素,CN,C 2 -C 4烷氧基羰基和C 2 -C 4烷基, 卤代烷; 或R 4是C 3 -C 5氮丙啶基烷基,C 4 -C 6 >氮杂环丁烷基或3-氮杂环丁烷基,其各自具有与氮原子连接的R 10,并且任选地在碳原子上被一至五个独立地选自C 1 -C 10烷基的取代基取代, C 1 -C 3烷基,C 1 -C 3卤代烷基,卤素,CN,C 2 -C 4烷基, 烷氧基羰基和C 2 -C 4卤代烷氧基羰基; 和R 1a
    • 3. 发明申请
    • ANTHRANILAMIDE INSECTICIDES
    • 蒽威杀虫剂
    • WO2006055922A2
    • 2006-05-26
    • PCT/US2005042196
    • 2005-11-18
    • DU PONTLAHM GEORGE PHILIPSELBY THOMAS PAULSTEVENSON THOMAS MARTINTAGGI ANDREW EDMUNDBEREZNAK JAMES FRANCIS
    • LAHM GEORGE PHILIPSELBY THOMAS PAULSTEVENSON THOMAS MARTINTAGGI ANDREW EDMUNDBEREZNAK JAMES FRANCIS
    • C07D231/16A01N43/56C07D401/04C07D405/12C07D405/14A01N51/00A01N47/40A01N2300/00
    • Disclosed are compounds of Formula 1, including all geometric and stereoisomers, N-oxides, and salts thereof, wherein J is a phenyl optionally substituted with one to four substituents independently selected from R 5 ; or J is a heterocyclic ring selected from the group consisting of J-1 to J-8; R 4 is C 4 -C 12 alkylcycloalkyl, C 5 -C 12 alkenylcycloalkyl, C 5 -C 12 alkynylcycloalkyl, C 4 -C 12 cycloalkylalkyl, C 5 -C 12 cycloalkylalkenyl, C 5 -C 12 cycloalkylalkynyl, C 4 -C 12 cycloalkenylalkyl or C 4 -C 12 alkylcycloalkenyl; each optionally substituted with one to six substituents selected from CH 3 and halogen; or R 4 is C 3 -C 5 oxiranylalkyl, C 3 -C 5 thiiranylalkyl, C 4 -C 6 oxetanylalkyl, C 4 -C 6 thietanylalkyl, 3-oxetanyl or 3-thietanyl, each optionally substituted with one to five substituents independently selected from C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, halogen, CN, C 2 -C 4 alkoxycarbonyl and C 2 -C 4 haloalkoxycarbonyl; or R 4 is C 3 -C 5 aziridinylalkyl, C 4 -C 6 azetidinylalkyl or 3-azetidinyl, each with R 10 attached to the nitrogen atom, and optionally substituted on carbon atoms with one to five substituents independently selected from C l -C 3 alkyl, C 1 -C 3 haloalkyl, halogen, CN, C 2 -C 4 alkoxycarbonyl and C 2 -C 4 haloalkoxycarbonyl; and R la
    • 公开了式1的化合物,包括所有几何和立体异构体,N-氧化物及其盐,其中J是任选被独立选自R 5的一至四个取代基取代的苯基; 或J是选自J-1至J-8的杂环; R 4是C 4 -C 12烷基环烷基,C 5 -C 12烷基,C 5 -C 12芳基, 烯基环烷基,C 5 -C 12炔基环烷基,C 4 -C 12环烷基烷基,C 5 -C 10环烷基烷基, C 12环烷基链烯基,C 5 -C 12环烷基炔基,C 4 -C 12环烷基炔基, 12环烯基烷基或C 4 -C 12烷基环烯基; 各自任选被1至6个选自CH 3和卤素的取代基取代; 或R 4是C 3 -C 5环氧乙烷基烷基,C 3 -C 5 S >噻吩基烷基,C 4 -C 6氧杂环丁基烷基,C 4 -C 6硫杂环丁基烷基,3-氧杂环丁烷基或3-氧杂环丁烷基 - 各自任选被1至5个独立选自以下的取代基取代:-C 1 -C 3烷基,C 1 -C 3烷基, 卤代烷基,CN,C 2 -C 4烷氧基羰基和C 2 -C 4烷基, 卤代烷; 或R 4是C 3 -C 5的氮丙啶基烷基,C 4 -C 6的 1