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    • 3. 发明申请
    • METHOD FOR TREATING OF ETCHING ACID WASTE CONTAINING PHOSPHORIC ACID, ACETIC ACID AND NITRIC ACID
    • 用于处理含酸性磷酸,乙酸和硝酸的消毒酸性废物的方法
    • WO2005120675A1
    • 2005-12-22
    • PCT/KR2005/001665
    • 2005-06-03
    • DAEIL DEVELOPMENT CO., LTD.KIM, Ho-SukAHN, Jae-WooKIM, Ju-YupKIM, Jun-YoungSHIN, Chang-Hoon
    • KIM, Ho-SukAHN, Jae-WooKIM, Ju-YupKIM, Jun-YoungSHIN, Chang-Hoon
    • B01D11/04
    • B01D11/0426C23F1/46
    • The present invention relates to a method for treating an etching waste with tri-octyl-phosphate (TOP) and tri-butyl-phosphate (TBP) as organic extraction solvents and more particularly, a method for treating an etching waste from the production process of liquid crystals to recover acids from the etching waste by means of solvent extraction comprising: a phase separation process of contacting the tricomponent waste solution (aqueous) comprising phosphoric acid and acetic acid, nitric acid or a mixture thereof with a diluted organic phase comprising tri-octyl-phosphate (TOP) and a diluent at a predetermined volume ratio, followed by uniformly stirring and standstilling to separate an extract phase containing the selectively extracted acetic acid and nitric acid and raffinate comprising phosphoric acid remaining in the waste solution; a separation process of stripping the acetic acid and nitric acid from the separated extract phase with water to recover the acids; and a phosphoric acid recovery process of extracting phosphoric acid remaining in the raffinate with an organic phase comprising tri-butyl-phosphate(TBP), followed by stripping with water to recover purified phosphoric acid.
    • 本发明涉及一种用磷酸三辛酯(TOP)和磷酸三丁酯(TBP)作为有机萃取溶剂处理蚀刻废料的方法,更具体地说,涉及一种从生产过程中处理蚀刻废物的方法 液晶,以通过溶剂萃取从蚀刻废料中回收酸,其包括:使包含磷酸和乙酸的三组分废液(水溶液),硝酸或其混合物与包含三 - 辛基磷酸酯(TOP)和稀释剂,然后均匀搅拌和静置以分离含有选择性提取的乙酸和硝酸的提取相和残留在废溶液中的包含磷酸的残液; 用水从分离的萃取相中汽提乙酸和硝酸以回收酸的分离过程; 以及用含磷酸三丁酯(TBP)的有机相萃取剩余残液中的磷酸的磷酸回收方法,然后用水汽提回收纯化的磷酸。