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1. 发明申请

WO1996028763A1 LIQUID PHOTOCURABLE COMPOSITIONS 审中-公开
标题翻译：液体光电组合物
公开(公告)号：WO1996028763A1
公开(公告)日：1996-09-19
申请号：PCT/GB1996000518
申请日：1996-03-06
申请人： ZENECA LIMITED , POPAT, Ajay, Haridas , LAWSON, John, Robert
发明人： ZENECA LIMITED
IPC分类号： G03F07/027
CPC分类号： G03F7/0037 , B33Y70/00 , G03F7/027
摘要： This invention relates to a liquid composition comprising: a) 2 to 20 parts of a monomeric poly(meth)acrylate having a functionality of at least 3 and a MW of at least 650; b) 20 to 60 parts of a urethane(meth)acrylate having a functionality of 2 to 4 and a MW of 400 to 10,000; c) 20 to 80 parts of a monomeric or oligomeric di(meth)acrylate based on bisphenol A or bisphenol F; and d) 0.1 to 10 parts of a photoinitiator; wherein all parts are by weight and the total number of parts of a) + b) + c) + d) add up to 100. The compositions are suitable for the sterolithographic production of three-dimensional articles such as models of mechanical and body parts and are particularly notable for their low curl and shrinkage coupled with fast rate of cure.
摘要翻译：液体组合物本发明涉及一种液体组合物，其包含：a）2至20份官能度至少为3且MW至少为650的单体聚（甲基）丙烯酸酯; b）20〜60份官能度为2〜4，MW为400〜10,000的氨基甲酸酯（甲基）丙烯酸酯; c）20至80份基于双酚A或双酚F的单体或低聚二（甲基）丙烯酸酯; 和d）0.1至10份光引发剂; 其中所有份数均为重量百分比，并且a）+ b）+ c）+ d）的总数量加在100上。该组合物适用于三维制品的固体生产，例如机械和身体部位的模型并且特别值得注意的是它们的低卷曲和收缩以及快速的固化速率。

2. 发明申请

WO2003106572A1 PRINTING PROCESS USING SPECIFIED AZO COMPOUNDS 审中-公开
标题翻译：使用指定的AZO化合物的印刷工艺
公开(公告)号：WO2003106572A1
公开(公告)日：2003-12-24
申请号：PCT/GB2003/001575
申请日：2003-04-11
申请人： AVECIA LIMITED , BRADBURY, Roy , DICKINSON, Alan , DOUBLE, Philip, John , GREGORY, Peter , HADJISOTERIOU, Maria, Soteri , PAUL, Thomas , POPAT, Ajay, Haridas , THOMPSON, Neil, James , WIGHT, Paul
发明人： BRADBURY, Roy , DICKINSON, Alan , DOUBLE, Philip, John , GREGORY, Peter , HADJISOTERIOU, Maria, Soteri , PAUL, Thomas , POPAT, Ajay, Haridas , THOMPSON, Neil, James , WIGHT, Paul
IPC分类号： C09D11/00
CPC分类号： D06P5/30 , C09B33/22 , C09B35/40 , C09B35/52 , C09B35/58 , C09B35/60 , C09B35/64 , C09B45/24 , C09D11/328 , C09D11/40 , D06P1/18
摘要： A process for printing an image on a substrate comprising applying thereto a composition comprising a liquid medium and a compound of Formula (1): T-Q-N=N-L-T wherein each T independently is an azo group; Q is an optionally substituted, optionally metallised 1,8-dihydroxy-naphthyl group; and L is a divalent organic linker group. Also claimed are compositions and dyes.
摘要翻译：一种用于在基材上印刷图像的方法，包括向其施加包含液体介质和式（1）的化合物的组合物：T-Q-N = N-L-T，其中每个T独立地为偶氮基; Q是任选取代的，任选金属化的1,8-二羟基 - 萘基; L是二价有机连接基团。还要求的是组合物和染料。

3. 发明申请

WO1997009168A1 PROCESS FOR PRODUCING POLYMERIC LAYERS HAVING SELECTIVELY COLOURED REGIONS 审中-公开
标题翻译：生产具有多种颜色区域的聚合物层的方法
公开(公告)号：WO1997009168A1
公开(公告)日：1997-03-13
申请号：PCT/GB1996002111
申请日：1996-08-28
申请人： ZENECA LIMITED , POPAT, Ajay, Haridas , EDWARDS, Martin, Russell
发明人： ZENECA LIMITED
IPC分类号： B29C67/00
CPC分类号： G03F7/027 , B29C64/135 , B29K2995/002 , B33Y10/00 , B33Y70/00 , G03F7/0037
摘要： Process for forming a selectively coloured polymeric layer, or a three-dimensional article made of polymeric layers, wherein a photocurable, photocolorable composition is irradiated with a low dose of light to cure and a different, preferably higher, dose of light to colour. The process is particularly useful for preparing selectively coloured ornamental and industrial articles and models of plant and animal parts, especially medical models.
摘要翻译：用于形成选择性着色的聚合物层的方法或由聚合物层制成的三维制品，其中可光固化的可光着色组合物用低剂量的光照射以固化，并且不同的，优选较高的剂量的光进行着色。该方法对于制备选择性着色的观赏和工业制品以及植物和动物部件，特别是医学模型的模型特别有用。

4. 发明申请

WO1996028762A1 LIQUID PHOTOCURABLE COMPOSITIONS 审中-公开
标题翻译：液体光电组合物
公开(公告)号：WO1996028762A1
公开(公告)日：1996-09-19
申请号：PCT/GB1996000517
申请日：1996-03-06
申请人： ZENECA LIMITED , POPAT, Ajay, Haridas , LAWSON, John, Robert , MCLEAN, Colin, Henry
发明人： ZENECA LIMITED
IPC分类号： G03F07/027
CPC分类号： G03F7/0037 , G03F7/027
摘要： A liquid composition comprising: a) 5 to 25 parts of a monomeric aliphatic or cycloaliphatic di(meth)acrylate having a MW of not more than 800; b) 2 to 20 parts of a monomeric poly(meth)acrylate having a functionality of at least 3 and a MW of at least 610; c) 12 to 40 parts of a urethane(meth)acrylate having a functionality of 2 to 4 and a MW of 400 to 10,000; d) 35 to 70 parts of a monomeric or oligomeric di(meth)acrylate based on bisphenol A or bisphenol F; and e) 0.1 to 10 parts of a photoinitiator; wherein all parts are by weight, the total number of parts of a) + b) does not exceed 30 and the total number of parts of a) + b) + c) + d) + e) add up to 100. The compositions are suitable for the stereolighographic production of three-dimensional solid articles such as mechanical parts and models of body parts.
摘要翻译：一种液体组合物，其包含：a）5〜25份MW不大于800的单体脂族或脂环族二（甲基）丙烯酸酯; b）2至20份官能度至少为3且MW至少为610的单体聚（甲基）丙烯酸酯; c）12〜40份官能度为2〜4，MW为400〜10,000的氨基甲酸酯（甲基）丙烯酸酯; d）35〜70份基于双酚A或双酚F的单体或低聚二（甲基）丙烯酸酯; 和e）0.1至10份光引发剂; 其中所有部分都是重量比，a）+ b）的部分总数不超过30，a）+ b）+ c）+ d）+ e）的总数量加到100上。组合物适用于三维固体制品如机械零件和车身部件型号的立体定向生产。

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