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    • 5. 发明申请
    • MONOAZOCOMPOUNDS WITH AN INDANYL MOIETY
    • MONOAZOCOMPOUNDS与INDANYL MOIETY
    • WO1998027165A1
    • 1998-06-25
    • PCT/GB1997003362
    • 1997-12-04
    • ZENECA LIMITEDTALLANT, NeilGREGORY, PeterWIGHT, Paul
    • ZENECA LIMITED
    • C09B29/00
    • C09D11/328C09B29/0018C09B29/30C09B33/052
    • Compounds of Formula (1) have utility as dyes for ink-jet printing where Formula (1) comprises: Tq-W which includes all acceptable forms of such compounds selected from one or more of the following (including mixtures thereof and combinations thereof in the same species): stereoisomers, zwitterions, polymorphs, solvates, isotopic forms; and all suitable salts thereof; in which: q represents from 1 to 4 inclusive; W comprises an optionally substituted hydrocarbyl group (preferably an optionally substituted aromatic group, or an optionally substituted aliphatic group); and each T independently comprises a group of the Formula (2): B-N=N-J-Y- in which: B comprises an optionally substituted indanyl group; Y comprises a carbonyl group or a sulphonyl group; and J comprises a group of Formula (3) in which: R comprises H or optionally substituted hydrocarbyl (preferably H or optionally substituted alkyl); and n represents from 0 to 3 inclusive; the compounds of Formula (1) being substantially free from fibre reactive groups.
    • 式(1)的化合物可用作喷墨印刷用染料,其中式(1)包括:Tq-W,其包括选自以下一种或多种的所有可接受的形式的化合物(包括其混合物及其组合 相同物种):立体异构体,两性离子,多晶型物,溶剂化物,同位素形式; 及其所有合适的盐; 其中:q表示1〜4; W包括任选取代的烃基(优选任选取代的芳族基团,或任选取代的脂族基团); 并且每个T独立地包含式(2)的基团:B-N = N-J-Y-,其中:B包含任选取代的茚满基; Y包含羰基或磺酰基; 并且J包括式(3)的基团,其中:R 1包含H或任选取代的烃基(优选H或任选取代的烷基); n表示0〜3, 式(1)的化合物基本上不含纤维反应性基团。
    • 6. 发明申请
    • AZO COMPOUND
    • AZO化合物
    • WO1997032932A1
    • 1997-09-12
    • PCT/GB1997000483
    • 1997-02-21
    • ZENECA LIMITEDGREGORY, PeterKENYON, Ronald, WynfordWIGHT, Paul
    • ZENECA LIMITED
    • C09B31/08
    • C09D11/328C09B31/08C09B67/0055
    • A compound of formula (1) or a salt thereof, wherein, J is -OR or -NR R ; R is H or optionally substituted alkyl or acyl; and R H or optionally substituted alkyl; or R and R taken together with the N atom to which they are attached form a 5- or 6-membered carbocyclic group optionally containing a ring oxygen atom; A is optionally substituted phenylene or optionally substituted naphthylene; Y is naphthylene of formula (1a) or phenylene of formula (1b), wherein R and R each independently is H, -COOH or -SO3H; Z and Z each independently is H, optionally substituted alkyl, optionally substituted alkoxy or -NZ Z ; Z is H, halo, -COOH, SO3H, optionally substituted alkyl, optionally substituted alkoxy, or optionally substituted alkylthio; Z is H or optionally substituted alkyl; and Z is H, optionally substituted alkyl or acyl; R is H or optionally substituted alkyl, alkylcarbonyl, alkylsulphonyl, alkoxycarbonyl, alkoxysulphonyl, arylcarbonyl or arylsulphonyl; T and T each independently is H or SO3H; R is H or optionally substituted alkyl or aryl, or a group -B-NQ Q ; B is optionally substituted C2-6-alkylene; and Q and Q each independently is H, optionally substituted C1-4-alkyl or Q and Q together with the N atom to which they are attached form an optionally substituted 5- or 6-membered carbocyclic group optionally containing a ring oxygen atom. The compounds are useful as black colorants for ink jet printing inks.
    • 式(1)的化合物或其盐,其中,J为-OR 4或-NR 4 R 5; R 4是H或任选取代的烷基或酰基; 和R 5 H或任选取代的烷基; 或R 4和R 5与它们所连接的N原子一起形成任选含有环氧原子的5-或6-元碳环基; A是任选取代的亚苯基或任选取代的亚萘基; Y是式(1a)的亚萘基或式(1b)的亚苯基,其中R 2和R 3各自独立地是H,-COOH或-SO 3 H; Z 1和Z 5各自独立地为H,任选取代的烷基,任选取代的烷氧基或-NZ 3 Z 4; Z 2是H,卤素,-COOH,SO 3 H,任选取代的烷基,任选取代的烷氧基或任选取代的烷硫基; Z 3是H或任选取代的烷基; 且Z 4为H,任选取代的烷基或酰基; R 1是H或任选取代的烷基,烷基羰基,烷基磺酰基,烷氧基羰基,烷氧基磺酰基,芳基羰基或芳基磺酰基; T和T 1各自独立地是H或SO 3 H; R为H或任选取代的烷基或芳基,或基团-B-NQ 1 Q 2; B是任选取代的C 2-6 - 亚烷基; 且Q 1和Q 2各自独立地为H,任选取代的C 1-4 - 烷基或Q 1和Q 2与它们所连接的N原子一起形成任选取代的5-或6 任选地含有环氧原子的碳环基团。 这些化合物可用作喷墨印刷油墨的黑色着色剂。
    • 7. 发明申请
    • AZO COMPOUNDS
    • AZO化合物
    • WO1997032931A1
    • 1997-09-12
    • PCT/GB1997000482
    • 1997-02-21
    • ZENECA LIMITEDGREGORY, PeterKENYON, Ronald, WynfordWIGHT, Paul
    • ZENECA LIMITED
    • C09B31/08
    • C09D11/328C09B31/08C09B67/0055
    • A compound of Formula (1) or a salt thereof, wherein: J is a group of the Formula (1a) wherein: R and R each independently is H, alkyl or alkoxy; and R is H, -COOH, -SO3H or optionally substituted alkyl, aryl, alkylcarbonyl, alkylsulphonyl, alkoxycarbonyl, alkoxysulphonyl, arylcarbonyl or arylsulphonyl; A is optionally substituted phenylene or optionally substituted naphthylene; Y is naphthylene of Formula (1b) or phenylene of Formula (1c) wherein: R and R each independently is H, -COOH or -SO3H; Z and Z each independently is H, optionally substituted alkyl, optionally substituted alkoxy or -NZ Z ; Z is H, halo, -COOH, -SO3H, -OH, optionally substituted alkyl, optionally substituted alkoxy, or optionally substituted alkylthio; Z is H or optionally substituted alkyl; Z is H, optionally substituted alkyl or acyl; R is H, optionally substituted alkyl, alkylcarbonyl, alkylsulphonyl, alkoxycarbonyl, alkoxysulphonyl, arylcarbonyl or arylsulphonyl; T and T each independently is H or -SO3H; R is H, optionally substituted alkyl, optionally substituted aryl, or a group -B-NQ Q ; B is optionally substituted C2-6-alkylene; and Q and Q each independently is H, optionally substituted C1-4-alkyl or Q and Q together with the N atom to which they are attached form an optionally substituted 5- or 6-membered ring. The compounds are useful as black colorants for ink jet printing inks.
    • 式(1)的化合物或其盐,其中:J为式(1a)的基团,其中:R 4和R 5各自独立地为H,烷基或烷氧基; R 6为H,-COOH,-SO 3 H或任选取代的烷基,芳基,烷基羰基,烷基磺酰基,烷氧基羰基,烷氧基磺酰基,芳基羰基或芳基磺酰基; A是任选取代的亚苯基或任选取代的亚萘基; Y是式(1b)的亚萘基或式(1c)的亚苯基,其中:R 2和R 3各自独立地是H,-COOH或-SO 3 H; Z 1和Z 5各自独立地为H,任选取代的烷基,任选取代的烷氧基或-NZ 3 Z 4; Z 2是H,卤素,-COOH,-SO 3 H,-OH,任选取代的烷基,任选取代的烷氧基或任选取代的烷硫基; Z 3是H或任选取代的烷基; Z 4是H,任选取代的烷基或酰基; R 1是H,任选取代的烷基,烷基羰基,烷基磺酰基,烷氧基羰基,烷氧基磺酰基,芳基羰基或芳基磺酰基; T和T 1各自独立地是H或-SO 3 H; R为H,任选取代的烷基,任选取代的芳基或基团-B-NQ 1 Q 2; B是任选取代的C 2-6 - 亚烷基; 且Q 1和Q 2各自独立地为H,任选取代的C 1-4 - 烷基或Q 1和Q 2与它们所连接的N原子一起形成任选取代的5-或6 记忆戒指 这些化合物可用作喷墨印刷油墨的黑色着色剂。
    • 8. 发明申请
    • DYES
    • 染料
    • WO1994010248A1
    • 1994-05-11
    • PCT/GB1993002158
    • 1993-10-20
    • ZENECA LIMITEDCAVANAGH, DeniseJAMES, Mark, RobertMEYRICK, Barry, HustonWIGHT, Paul
    • ZENECA LIMITED
    • C09B23/00
    • C09B67/0034C09B23/0091Y10S8/921Y10S8/922Y10S8/924Y10S8/926
    • A pyrrolidone dye of Formula (1), wherein: D is a group of Formula (2), or a group of Formula (3), or a group of Formula (4), R is alkyl, cycloalkyl, aryl, alkenyl or aralkyl each of which may be optionally substituted; R is optionally substituted C7-20-alkyl; or R and R together with the nitrogen atom to which they are attached form a pyrrolidino or piperidino ring; R is alkyl, alkenyl or aralkyl each of which may be optionally substituted or -COR in which R is -H or alkyl, phenyl, cycloalkyl or aralkyl each of which may be optionally substituted or -H; and R is an electron withdrawing group; R is optionally substituted C1-6-alkyl; or R and R together with the nitrogen atom to which they are attached form a piperidino or pyrrolidino ring; R , R , R and R each independently is alkyl, cycloalkyl, aryl, alkenyl or aralkyl each of which may be optionally substituted or -H; W is oxygen or sulphur; Z is a direct link or N-R in which R is -H or optionally substituted alkyl; Ring A is unsubstituted apart from the -NR R group or is substituted by from 1 to 4 further groups; Ring B is unsubstituted or substituted by from 1 to 3 groups; provided that when D is a group of Formula (2) and R and R are both allyl that R is not -CN or that when D is a group of Formula (3) that R and R are different and R is not -C2H5, -C3H7 or -C4H9 when R is -C2H4phenyl, -C3H6phenyl and ethyl substituted by -OH, -CN, -OCH3, -NHCOCH3, -Ophenyl and -NHSO2CH3 or that at least one of R and R is branched chain alkyl except for 3-(4-(N-ethyl-N-ethoxyethoxyethylamino)phenyl)-4-cyano-5-dicyanomethylidene-2-oxo-2,5-dihydropyrrole and 3-(4-(N,N-di-n-octylamino)phenyl)-4-cyano-5-dicyanomethylidene-2-oxo-2,5-dihydropyrrole. The dyes and dye mixtures produce blue to green shades on synthetic textile materials such as polyester which have good build up and good light- and wet-fastness.
    • 式(1)的吡咯烷酮染料,其中:D是式(2)的基团,或式(3)的基团或式(4)的基团,R 1是烷基,环烷基,芳基, 烯基或芳烷基,其各自可以任选被取代; R 2是任选取代的C 3-20 - 烷基; 或R 1和R 2与它们所连接的氮原子一起形成吡咯烷子基或哌啶子基环; R 3是烷基,烯基或芳烷基,其各自可以是任选取代的或-COR,其中R是-H或烷基,苯基,环烷基或芳烷基,其各自可以是任选取代的或-H; R 4为吸电子基团; R 6是任选取代的C 1-6 - 烷基; 或R 1和R 6与它们所连接的氮原子一起形成哌啶子基或吡咯烷子基环; R 7,R 8,R 9和R 10各自独立地是烷基,环烷基,芳基,烯基或芳烷基,其各自可以是任选取代的或-H; W是氧或硫; Z是直链或N-R 11,其中R 11是-H或任选取代的烷基; 除了-NR 1 R 2基团之外,环A是未取代的或被其它1至4个其它基团取代; 环B是未取代的或被1至3个基团取代; 条件是当D是式(2)的基团且R 1和R 2都是R 4不是-CN的烯丙基时,或当D是式(3)的基团时,R 1 >和R 6不同,当R 6为-C 2 H 4苯基,-C 3 H 6苯基和被-OH,-CN,-OCH 3,-NHCOCH 3取代的乙基时,R 1不为-C 2 H 5,-C 3 H 7或-C 4 H 9, - 苯基和-NHSO 2 CH 3,或者R 1和R 6中的至少一个是支链烷基,除了3-(4-(N-乙基-N-乙氧基乙氧基乙基氨基)苯基)-4-氰基-5-二氰基亚甲基 -2-氧代-2,5-二氢吡咯和3-(4-(N,N-二正辛基氨基)苯基)-4-氰基-5-二氰基亚甲基-2-氧代-2,5-二氢吡咯。 染料和染料混合物在合成纺织材料如聚酯上产生蓝色至绿色的色调,其具有良好的聚集性和良好的耐光牢度和耐湿牢度。