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1. 发明申请

WO2005026397A3 PROCESS AND PLANT FOR THE HEAT TREATMENT OF SOLIDS CONTAINING TITANIUM 审中-公开
标题翻译：用于热处理含钛固体的方法和装置
公开(公告)号：WO2005026397A3
公开(公告)日：2005-07-21
申请号：PCT/EP2004010276
申请日：2004-09-15
申请人： OUTOKUMPU OY , STOCKHAUSEN WERNER , BEYZAVI ALI-NAGHI , NUBER DIRK
发明人： STOCKHAUSEN WERNER , BEYZAVI ALI-NAGHI , NUBER DIRK
IPC分类号： B01J8/00 , B01J8/18 , B01J8/38 , C01G23/00 , C22B1/10 , C22B34/12
CPC分类号： C22B34/12 , B01J8/0055 , B01J8/1836 , B01J8/388 , B01J2208/00725 , B01J2219/00006 , C22B1/10
摘要： This invention relates to a process and a plant for the heat treatment of solids containing titanium. For this purpose, the fine-grained solids are heated to a temperature of 700 to 1000 °C in a reactor (4) with circulating fluidized bed and are partly discharged from the reactor (4) together with waste gases into a downstream separator (9). In the same, the solids are separated from the waste gases and are recirculated to the reactor (4) at least partly and/or phase by phase. Downstream of the reactor (4) and/or the separator (9) an injection cooler (13) is provided, in which the solids are cooled to below 250 °C by injecting a coolant. Downstream of the injection cooler (13) a fluidized-bed cooler (16) can be provided for the further cooling of the solids.
摘要翻译：本发明涉及用于含钛固体的热处理的方法和设备。为此，将细颗粒固体在具有循环流化床的反应器（4）中加热至700至1000℃的温度，并与废气一起从反应器（4）部分排出至下游分离器（9 ）。同样，将固体与废气分离并且至少部分地和/或逐相地再循环至反应器（4）。在反应器（4）和/或分离器（9）的下游提供注入冷却器（13），其中通过注入冷却剂将固体冷却到低于250℃。注入冷却器（13）的下游可以设置流化床冷却器（16）以进一步冷却固体。

2. 发明申请

WO2004056465A1 METHOD AND APPARATUS FOR HEAT TREATMENT IN A FLUIDIZED BED 审中-公开
标题翻译：流化床热处理方法及装置
公开(公告)号：WO2004056465A1
公开(公告)日：2004-07-08
申请号：PCT/EP2003/013982
申请日：2003-12-10
申请人： OUTOKUMPU, Oyj , NUBER, Dirk , STOCKHAUSEN, Werner , STRÖDER, Michael
发明人： NUBER, Dirk , STOCKHAUSEN, Werner , STRÖDER, Michael
IPC分类号： B01J8/18
CPC分类号： B01J8/1836 , B01J8/0055 , B01J8/1863 , B01J2208/00141 , B01J2208/0053 , B01J2208/00548 , B01J2208/00654 , B01J2219/00006 , C04B11/0283 , F27B15/02 , F27B15/10 , F27B15/16
摘要： The present invention relates to a method for the heat treatment of fine-grained solids, in particular gypsum, in which the solids are heated to a temperature of 50 to 1000 °C in a fluidized bed reactor (1), and to a corresponding plant. To improve the energy utilization, it is proposed to introduce a first gas or gas mixture from below through a preferably central gas supply tube (3) into a mixing chamber (21) of the reactor (1), the gas supply tube (3) being at least partly surrounded by a stationary annular fluidized bed (2) which is fluidized by supplying fluidizing gas, and to adjust the gas velocities of the first gas or gas mixture as well as of the fluidizing gas for the annular fluidized bed (2) such that the particle Froude numbers in the gas supply tube (3) are between 1 and 100, in the annular fluidized bed (2) between 0.02 and 2 and in the mixing chamber (21) between 0.3 and 30.
摘要翻译：本发明涉及一种用于热处理细粒固体，特别是石膏的方法，其中将固体在流化床反应器（1）中加热至50至1000℃的温度，以及相应的设备。为了提高能量利用率，建议从下方通过优选的中心气体供给管（3）将第一气体或气体混合物引入反应器（1）的混合室（21），气体供给管（3）至少部分地被固定的环形流化床（2）包围，所述静止环形流化床（2）通过供应流化气体而流化，并且调节第一气体或气体混合物以及用于环形流化床（2）的流化气体的气体速度，使得在环形流化床（2）中0.02和2之间以及在混合室（21）中的0.3至30之间，气体供应管（3）中的微粒Froude数在1和100之间。

3. 发明申请

WO2005014866A3 PROCESS AND PLANT FOR REDUCING SOLIDS CONTAINING IRON OXIDE 审中-公开
标题翻译：用于还原含氧化铁的固体的方法和设备
公开(公告)号：WO2005014866A3
公开(公告)日：2005-03-31
申请号：PCT/EP2004007904
申请日：2004-07-16
申请人： OUTOKUMPU OY , SNEYD STUART , HIRSCH MARTIN , NUBER DIRK
发明人： SNEYD STUART , HIRSCH MARTIN , NUBER DIRK
IPC分类号： C21B13/00 , C22B1/248 , C22B5/14 , C22B5/18
CPC分类号： C22B5/18 , C21B13/0033 , C21B13/008 , C21B13/0086 , C22B1/248 , C22B5/14 , Y02P10/136
摘要： This invention relates to a process for reducing solids containing iron oxide, such as iron ore, in which fine-grained solids are heated and at least partly calcined in a pre heating stage (2, 9). In a first fluidized-bed reactor (14) downstream of the preheating stage (2, 9), the solids are prereduced and reduced further in a second fluidized-bed reactor (16). Downstream of the second reactor (16) a briquetting stage (20) is pro vided, in which the solids are briquetted at a temperature above 500°C To increase the energy efficiency of the process and improve the flowability of the solids in the briquetting stage (20), magnesite is added to the preheating stage (2, 9) together with the solids containing iron oxide, which magnesite is at least partly calcined in the preheating stage (2, 9) to obtain magnesium oxide. Furthermore, the invention relates to a corresponding plant.
摘要翻译：本发明涉及一种用于减少含有氧化铁（例如铁矿石）的固体的方法，其中细粒固体在预加热阶段（2,9）中被加热并且至少部分地被煅烧。在预热阶段（2,9）下游的第一流化床反应器（14）中，将固体预还原并在第二流化床反应器（16）中进一步还原。在第二反应器（16）的下游提供压块阶段（20），其中固体在高于500℃的温度下压块。为了提高该过程的能量效率并且改进在压块阶段中固体的流动性（20）中，将菱镁矿与含有氧化铁的固体一起加入到预热阶段（2,9）中，该菱镁矿在预热阶段（2,9）中至少部分地煅烧以获得氧化镁。此外，本发明涉及相应的设备。

4. 发明申请

WO2004057039A1 METHOD AND PLANT FOR THE HEAT TREATMENT OF SOLIDS CONTAINING IRON OXIDE USING A FLUIDIZED BED REACTOR 审中-公开
标题翻译：使用流化床反应器处理含氧化铁的固体的方法和装置
公开(公告)号：WO2004057039A1
公开(公告)日：2004-07-08
申请号：PCT/EP2003/013500
申请日：2003-12-01
申请人： OUTOKUMPU OYJ , ORTH, Andreas , HIRSCH, Martin , WEBER, Peter , SNEYD, Stuart , NUBER, Dirk , STRÖDER, Michael
发明人： ORTH, Andreas , HIRSCH, Martin , WEBER, Peter , SNEYD, Stuart , NUBER, Dirk , STRÖDER, Michael
IPC分类号： C22B1/10
CPC分类号： B01J8/18 , B01J8/1863 , B01J8/30 , B01J8/44 , B01J2208/00061 , C22B1/10 , C22B5/14 , F27B15/02 , F27B15/08 , F27B15/10
摘要： The present invention relates to a method and a plant for the heat treatment of solids containing iron oxide, in which fine-grained solids are heated to a temperature of 700 to 1150°C in a fluidized bed reactor (8) . To improve the utilization of energy, it is proposed to introduce a first gas or gas mixture from below through at least one gas supply tube (9) into a mixing chamber region (15) of the reactor (8), the gas supply tube (9) being at least partly surrounded by a stationary annular fluidized bed (12) which is fluidized by supplying fluidizing gas. The gas velocities of the first gas or gas mixture and of the fluidizing gas for the annular fluidized bed (12) are adjusted such that the Particle-Froude-Numbers in the gas supply tube (9) are between 1 and 100, in the annular fluidized bed (12) between 0.02 and 2, and in the mixing chamber (15) between 0.3 and 30.
摘要翻译：本发明涉及用于热处理包含氧化铁的固体的方法和设备，其中在流化床反应器（8）中将细粒固体加热至700至1150℃的温度。为了提高能量的利用率，建议从下方通过至少一个气体供给管（9）将第一气体或气体混合物引入反应器（8）的混合室区域（15），气体供给管 9）至少部分地被固定的环形流化床（12）包围，所述静止环形流化床通过供应流化气体而被流化。第一气体或气体混合物以及用于环形流化床（12）的流化气体的气体速度被调整为使得气体供应管（9）中的“微粒 - 弗劳德数”在1和100之间，在环形流化床（12）在0.02和2之间，在混合室（15）中在0.3和30之间。

5. 发明申请

WO2005026397A2 PROCESS AND PLANT FOR THE HEAT TREATMENT OF SOLIDS CONTAINING TITANIUM 审中-公开
标题翻译：含钛的固体的热处理工艺和设备
公开(公告)号：WO2005026397A2
公开(公告)日：2005-03-24
申请号：PCT/EP2004/010276
申请日：2004-09-15
申请人： OUTOKUMPU OYJ , STOCKHAUSEN, Werner , BEYZAVI, Ali-Naghi , NUBER, Dirk
发明人： STOCKHAUSEN, Werner , BEYZAVI, Ali-Naghi , NUBER, Dirk
IPC分类号： C22B1/10
CPC分类号： C22B34/12 , B01J8/0055 , B01J8/1836 , B01J8/388 , B01J2208/00725 , B01J2219/00006 , C22B1/10
摘要： This invention relates to a process and a plant for the heat treatment of solids containing titanium. For this purpose, the fine-grained solids are heated to a temperature of 700 to 1000 °C in a reactor (4) with circulating fluidized bed and are partly discharged from the reactor (4) together with waste gases into a downstream separator (9). In the same, the solids are separated from the waste gases and are recirculated to the reactor (4) at least partly and/or phase by phase. Downstream of the reactor (4) and/or the separator (9) an injection cooler (13) is provided, in which the solids are cooled to below 250 °C by injecting a coolant. Downstream of the injection cooler (13) a fluidized-bed cooler (16) can be provided for the further cooling of the solids.
摘要翻译：本发明涉及一种用于热处理含钛固体的方法和设备。为此，将细粒固体在具有循环流化床的反应器（4）中加热至700至1000℃的温度，并与废气一起部分地从反应器（4）排放到下游分离器（9））。在同样的情况下，固体与废气分离，并且至少部分地和/或逐相再循环到反应器（4）。反应器（4）和/或分离器（9）的下游设置有注射冷却器（13），其中通过注入冷却剂将固体冷却至低于250℃。注射冷却器（13）的下游可以设置流化床冷却器（16），用于进一步冷却固体。

6. 发明申请

WO2005014866A2 PROCESS AND PLANT FOR REDUCING SOLIDS CONTAINING IRON OXIDE 审中-公开
标题翻译：用于减少含氧化铁的固体的方法和设备
公开(公告)号：WO2005014866A2
公开(公告)日：2005-02-17
申请号：PCT/EP2004/007904
申请日：2004-07-16
申请人： OUTOKUMPU OYJ , SNEYD, Stuart , HIRSCH, Martin , NUBER, Dirk
发明人： SNEYD, Stuart , HIRSCH, Martin , NUBER, Dirk
IPC分类号： C21B13/00
CPC分类号： C22B5/18 , C21B13/0033 , C21B13/008 , C21B13/0086 , C22B1/248 , C22B5/14 , Y02P10/136
摘要： This invention relates to a process for reducing solids containing iron oxide, such as iron ore, in which fine-grained solids are heated and at least partly calcined in a pre heating stage (2, 9). In a first fluidized-bed reactor (14) downstream of the preheating stage (2, 9), the solids are prereduced and reduced further in a second fluidized-bed reactor (16). Downstream of the second reactor (16) a briquetting stage (20) is pro vided, in which the solids are briquetted at a temperature above 500°C To increase the energy efficiency of the process and improve the flowability of the solids in the briquetting stage (20), magnesite is added to the preheating stage (2, 9) together with the solids containing iron oxide, which magnesite is at least partly calcined in the preheating stage (2, 9) to obtain magnesium oxide. Furthermore, the invention relates to a corresponding plant.
摘要翻译：本发明涉及一种用于还原含铁氧化物的固体的方法，例如铁矿石，其中细粒固体被加热并且在预热阶段（2,9）中至少部分地煅烧。在预热阶段（2,9）下游的第一流化床反应器（14）中，固体在第二流化床反应器（16）中被进一步还原并还原。在第二反应器（16）的下游，提供压块阶段（20），其中固体在500℃以上的压块压块。为了提高该方法的能量效率并提高压块阶段的固体的流动性（20）中，将菱镁矿与含有氧化铁的固体一起加入到预热段（2,9）中，该氧化铁在预热阶段（2,9）中至少部分地煅烧以获得氧化镁。此外，本发明涉及相应的设备。

7. 发明申请

WO2004057040A1 FLUIDIZED BED METHOD AND PLANT FOR THE HEAT TREATMENT OF SOLIDS CONTAINING TITANIUM 审中-公开
标题翻译：流化床方法和用于处理含钛的固体的热处理
公开(公告)号：WO2004057040A1
公开(公告)日：2004-07-08
申请号：PCT/EP2003/013983
申请日：2003-12-10
申请人： OUTOKUMPU OYJ , NUBER, Dirk , STRÖDER, Michael , STOCKHAUSEN, Werner , BEYZAVI, Ali-Naghi , FORMANEK, Lothar , HIRSCH, Martin
发明人： NUBER, Dirk , STRÖDER, Michael , STOCKHAUSEN, Werner , BEYZAVI, Ali-Naghi , FORMANEK, Lothar , HIRSCH, Martin
IPC分类号： C22B1/10
CPC分类号： B01J8/1818 , B01J8/1836 , B01J8/26 , B01J2208/00548 , B01J2208/00725 , C21B13/0033 , C22B1/10 , C22B5/14 , C22B34/1204 , C22B34/1209 , F27B15/02 , F27B15/10 , Y02P10/136
摘要： The present invention relates to a method and a plant for the heat treatment of solids containing titanium and possibly further metal oxides, in which fine-grained solids are heated to a temperature of 700 to 950 °C in a fluidized bed reactor (1). To improve the energy utilization, it is proposed to introduce a first gas or gas mixture from below through a gas supply tube (3) into a mixing chamber (7) of the reactor (1), the gas supply tube (3) being at least partly surrounded by a stationary annular fluidized bed (10) which is fluidized by supplying fluidizing gas. The gas velocities of the first gas or gas mixture as well as of the fluidizing gas for the annular fluidized bed (10) are adjusted such that the particle Froude numbers in the gas supply tube (3) are between 1 and 100, in the annular fluidized bed (10) between 0.02 and 2 and in the mixing chamber (7) between 0.3 and 30.
摘要翻译：本发明涉及用于热处理含钛和可能的其它金属氧化物的固体的方法和设备，其中细粒固体在流化床反应器（1）中被加热至700-950℃。为了提高能量利用率，建议从下方通过气体供给管（3）将第一气体或气体混合物引入反应器（1）的混合室（7），气体供给管（3）处于最少部分地被固定的环形流化床（10）包围，所述静止环形流化床通过供应流化气体而被流化。调节第一气体或气体混合物以及用于环形流化床（10）的流化气体的气体速度，使得气体供应管（3）中的微粒弗劳德数在1和100之间，在环形流化床（10）在0.02和2之间，并且在混合室（7）中在0.3和30之间。

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