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1. 发明申请

WO2012072417A1 POLYMERISATION CONTROL PROCESS 审中-公开
标题翻译：聚合控制过程
公开(公告)号：WO2012072417A1
公开(公告)日：2012-06-07
申请号：PCT/EP2011/070280
申请日：2011-11-16
申请人： INEOS COMMERCIAL SERVICES UK LIMITED , CHAMAYOU, Jean-Louis , MARISSAL, Daniel
发明人： CHAMAYOU, Jean-Louis , MARISSAL, Daniel
IPC分类号： C08F10/00 , C08F2/34
CPC分类号： C08F2/34 , C08F10/00 , C08F2400/02 , Y02P20/582 , C08F2/00
摘要： The present invention relates to a process for maintaining a continuous gas-phase (co-) polymerisation of olefins in a large fluidised bed reactor in a homogeneous mode whilst operating at high space time yield and condensation rate in the presence of a polymerisation catalyst.
摘要翻译：本发明涉及在大型流化床反应器中以均相模式维持烯烃的连续气相（共）聚合的方法，同时在聚合催化剂存在下以高空间时间产率和缩合速率运行。

2. 发明申请

WO2009030644A1 SLURRY PHASE POLYMERISATION PROCESS 审中-公开
标题翻译：浆料相聚合方法
公开(公告)号：WO2009030644A1
公开(公告)日：2009-03-12
申请号：PCT/EP2008/061369
申请日：2008-08-29
申请人： INEOS MANUFACTURING BELGIUM NV , KOCH, Benoit , MARISSAL, Daniel , PARISEL, Marc , WALWORTH, Brent, R , FREDERICH, Andre
发明人： KOCH, Benoit , MARISSAL, Daniel , PARISEL, Marc , WALWORTH, Brent, R , FREDERICH, Andre
IPC分类号： C08F10/02 , C08F2/12 , C08F2/14
CPC分类号： C08F6/20 , C08F6/003 , C08F10/02 , C08F110/02 , C08F210/16 , C08L23/04 , C08F2/001 , C08F2/14
摘要： A polymerisation process is disclosed in which polyethylene is produced in slurry in a polymerisation reactor in the presence of a Ziegler Natta catalyst and an activator, and slurry containing the polymer is withdrawn from the reactor and transferred to a flash tank operating at a pressure and temperature such that at least 50mol% of the liquid component of the slurry is withdrawn from the flash tank as a vapour and at least 98mol%, more preferably at least 98.5mol%, and most preferably at least 99.5mol%, of the vapour withdrawn from the flash tank is capable of being condensed at a temperature of between 15 and 40C without compression, wherein a by-product suppressor, which reduces the amount of by-product formed per unit of polyethylene produced by at least 10% compared with an identical polymerisation process where the by-product suppressor is not present, is used in the reactor.
摘要翻译：公开了一种聚合方法，其中聚乙烯在齐格勒纳塔催化剂和活化剂存在下在聚合反应器中以淤浆形式制备，含有聚合物的浆料从反应器中排出并转移到在压力和温度下操作的闪蒸罐使得至少50mol％的浆液的液体组分作为蒸气从闪蒸罐中取出，并且至少98mol％，更优选至少98.5mol％，最优选至少99.5mol％的蒸气从闪蒸罐能够在不压缩的情况下在15至40℃的温度下冷凝，其中副产物抑制剂与相同的聚合相比减少了每单位聚乙烯形成的副产物的量至少10％在反应器中使用副产物抑制剂不存在的方法。

3. 发明申请

WO2011141250A1 SLURRY LOOP POLYMERIZATION REACTOR AND PROCESS 审中-公开
标题翻译：浆料环聚合反应器和工艺
公开(公告)号：WO2011141250A1
公开(公告)日：2011-11-17
申请号：PCT/EP2011/055685
申请日：2011-04-12
申请人： INEOS COMMERCIAL SERVICES UK LIMITED , MARISSAL, Daniel , LEE, Stephen, Kevin
发明人： MARISSAL, Daniel , LEE, Stephen, Kevin
IPC分类号： B01J4/02 , B01J19/00 , B01J19/18 , B01J4/00
CPC分类号： B01J4/002 , B01J4/02 , B01J19/002 , B01J19/1837 , B01J2219/00186 , B01J2219/00247 , B01J2219/00254 , C08F10/00 , C08F210/06 , C08F210/16 , C08F2/06 , C08F2/01 , C08F210/08
摘要： The present invention relates to a polymerisation process in a slurry loop polymerisation reactor which comprises: a) a reaction zone in the form of a slurry loop, b) at least one feed inlet for monomers, comonomers and diluent, c) at least one catalyst inlet for polymerisation catalyst, and d) at least one discharge conduit for removal of polymer, characterised in that the at least one catalyst inlet is in the form of an inlet pipe and no part of the inlet pipe protrudes beyond the wall of the reaction zone and into the reaction zone by more than 1/10th of the diameter of the reaction zone at the point where the inlet pipe joins the reaction zone.
摘要翻译：本发明涉及一种浆液回路聚合反应器中的聚合方法，其包括：a）浆料环形式的反应区，b）单体，共聚单体和稀释剂的至少一个进料入口，c）至少一种催化剂用于聚合催化剂的入口，以及d）用于除去聚合物的至少一个排出导管，其特征在于，所述至少一个催化剂入口是入口管的形式，并且没有一部分入口管突出超过反应区的壁并且在入口管连接反应区的点处，反应区的直径大于反应区直径的1/10，进入反应区。

4. 发明申请

WO2009030645A1 SLURRY PHASE POLYMERISATION PROCESS 审中-公开
标题翻译：浆料相聚合方法
公开(公告)号：WO2009030645A1
公开(公告)日：2009-03-12
申请号：PCT/EP2008/061370
申请日：2008-08-29
申请人： INEOS MANUFACTURING BELGIUM NV , KOCH, Benoit , MARISSAL, Daniel , PARISEL, Marc , WALWORTH, Brent, R.
发明人： KOCH, Benoit , MARISSAL, Daniel , PARISEL, Marc , WALWORTH, Brent, R.
IPC分类号： C08F10/02 , C08F297/08 , C08F2/12 , C08F2/14
CPC分类号： C08F10/02 , C08F210/16 , C08F2/001 , C08F2/14 , C08F210/14 , C08F2500/12 , C08F2500/02 , C08F2500/01
摘要： Process for producing a multimodal polyethylene in at least two reactors connected in series, in which 20-80wt% of a first polymer is made in suspension in a first reactor and 80-20wt% of a second polymer is made in suspension in a second reactor in the presence of the first polymer, and a stream or slurry containing the resulting polymer is withdrawn from the second reactor and transferred to a flash tank operating at a pressure and temperature such that at least 50mol% of the liquid component of the slurry, or the non- polymer component of the stream entering the flash tank, is withdrawn from the flash tank as a vapour, wherein the concentration in the stream or slurry entering the flash tank of components having a molecular weight below 50 g/mol, Qjghts (mol%), satisfies the equation C lights c ) + 4.4(P c - 0.8) - 7(C H2 /C Et ) where T c and P c are respectively the temperature (in °C) and pressure (MPa g) at the location where the vapour withdrawn from the flash tank is condensed, and C H2 and C Et are the molar concentrations in the flash tank of hydrogen and ethylene respectively.
摘要翻译：在至少两个串联连接的反应器中制备多峰聚乙烯的方法，其中将20-80重量％的第一聚合物悬浮在第一反应器中，并将80-20重量％的第二聚合物悬浮在第二反应器在第一聚合物的存在下，将含有所得聚合物的料流或浆料从第二反应器中取出并转移到在压力和温度下操作的闪蒸罐中，使得至少50mol％的浆液的液体组分或进入闪蒸罐的物流的非聚合物组分作为蒸汽从闪蒸罐中取出，其中进入闪蒸罐的料流或浆料中的分子量低于50g / mol的组分的浓度Qjghts（mol ％）满足等式Clights c）+ 4.4（Pc-0.8）-7（CH 2 / CEt）其中Tc和Pc分别是从蒸汽中取出的蒸气的温度（℃）和压力（MPa g）闪蒸罐冷凝，CH 2和CEt分别是闪蒸罐中氢气和乙烯的摩尔浓度。

5. 发明申请

WO2009030642A1 SLURRY PHASE POLYMERISATION PROCESS 审中-公开
标题翻译：浆料相聚合方法
公开(公告)号：WO2009030642A1
公开(公告)日：2009-03-12
申请号：PCT/EP2008/061366
申请日：2008-08-29
申请人： INEOS MANUFACTURING BELGIUM NV , KOCH, Benoit , MARISSAL, Daniel , PARISEL, Marc , WALWORTH, Brent, R.
发明人： KOCH, Benoit , MARISSAL, Daniel , PARISEL, Marc , WALWORTH, Brent, R.
IPC分类号： C08F10/02 , C08F2/00 , C08L23/06
CPC分类号： B01J19/2435 , B01J2219/0004 , B01J2219/00166 , B01J2219/00186 , C08F10/02 , C08F110/02 , C08F2/14 , C08F2/001 , C08F2500/01 , C08F2500/12 , C08F2500/02
摘要： Process for producing a multimodal polyethylene in at least two reactors connected in series, in which 20-80wt% of a high molecular weight (HMW) polymer is made in suspension in a first reactor and 20-80wt% of a low molecular weight (LMW) polymer is made in suspension in a second reactor, wherein the ratio of the average activity in the LMW reactor to the average activity in the HMW reactor is from 0.25 and 1.5, where average activity in each reactor is defined as the rate of polyethylene produced in the reactor (kgPE/hr) / [ethylene concentration in the reactor (mol%) x residence time in the reactor (hours) x feed rate of catalyst into the reactor (g/hr)], residence time being defined as the mass of the polymer in the reactor (kg)/the output rate of polymer from the reactor (kg/hr), and wherein the volume of the second reactor is at least 10%, preferably at least 30% and more preferably at least 50% greater than the volume of the first reactor, and the ratio of length to diameter of the first reactor, L/D(l), is greater than that of the second reactor, L/D(2), and preferably at least 20% greater.
摘要翻译：在至少两个串联的反应器中制备多峰聚乙烯的方法，其中将20-80重量％的高分子量（HMW）聚合物悬浮在第一反应器和20-80重量％的低分子量（LMW））聚合物在第二反应器中悬浮制备，其中LMW反应器中的平均活性与HMW反应器中的平均活性的比例为0.25和1.5，其中每个反应器中的平均活性定义为产生的聚乙烯的速率在反应器中（kgPE / hr）/ [反应器中的乙烯浓度（mol％）×在反应器中的停留时间（小时）×催化剂进入反应器的进料速率（g / hr）]，停留时间定义为质量的反应器中的聚合物（kg）/来自反应器的聚合物的输出速率（kg / hr），并且其中第二反应器的体积为至少10％，优选至少30％，更优选至少50％大于第一反应器的体积，以及长度与直径之比t 他的第一反应器L / D（1）大于第二反应器的L / D（2），优选至少大于20％。

6. 发明申请

WO2006056761A1 SLURRY PHASE POLYMERISATION PROCESS 审中-公开
标题翻译：浆料相聚合方法
公开(公告)号：WO2006056761A1
公开(公告)日：2006-06-01
申请号：PCT/GB2005/004484
申请日：2005-11-22
申请人： INNOVENE MANUFACTURING BELGIUM NV , LEE, Stephen, Kevin , MARISSAL, Daniel , WALWORTH, Brent, R.
发明人： LEE, Stephen, Kevin , MARISSAL, Daniel , WALWORTH, Brent, R.
IPC分类号： B01J19/18 , B01J19/24
CPC分类号： C08F2/01 , B01J8/20 , B01J19/2435 , B01J2219/0004 , B01J2219/00166 , B01J2219/00243 , B01J2219/00247 , C08F210/16 , Y10S526/918 , C08F2/14 , C08F210/14
摘要： A process comprising polymerising in a loop reactor an olefin monomer optionally together with an olefin commoner in the presence of a polymerisation catalyst in a diluent to produce a slurry comprising solid particulate olefin polymer and the diluent wherein the Froude number is maintained at or below 20 is disclosed.
摘要翻译：一种方法，其包括在环流反应器中聚合烯烃单体，任选地与烯烃共聚物在聚合催化剂存在下在稀释剂中一起产生包含固体颗粒烯烃聚合物和稀释剂的浆料，其中弗劳德数维持在或低于20是披露。

7. 发明申请

WO2011051367A1 SLURRY PHASE POLYMERISATION PROCESS 审中-公开
标题翻译：浆料相聚合方法
公开(公告)号：WO2011051367A1
公开(公告)日：2011-05-05
申请号：PCT/EP2010/066314
申请日：2010-10-28
申请人： INEOS MANUFACTURING BELGIUM NV , MARISSAL, Daniel
发明人： MARISSAL, Daniel
IPC分类号： C08F10/00 , C08F2/14 , B01J19/18
CPC分类号： B01J19/2435 , B01J2208/00663 , B01J2219/00171 , B01J2219/00243 , C08F10/00 , C08F110/02 , C08F2/14 , C08F2500/24 , C08F2500/17
摘要： Process for polymerising, in a loop reactor, at least one olefin monomer in a liquid diluent to produce a slurry comprising solid particulate olefin polymer and said diluent, wherein the ratio between the actual volumetric solids concentration of the slurry and the maximum possible geometric volume solids concentration of the slurry as measured by the bulk density of an unpacked settled bed of particles, SVCR, is V*0.065 or greater, and the ratio of the cumulative settling distance of an average size particle at any point in the reactor in any direction perpendicular to the direction of the flow, to the internal diameter of the loop reactor, is maintained below [0.084*(V - 6.62) + (0.69 - SVCR)* 1.666], where V is the circulation velocity of the slurry in m/s and "cumulative settling distance" is defined as the cumulative distance, expressed as a fraction of the diameter,travelled by a particle in any direction perpendicular to the direction of the flow since the previous upstream pump.
摘要翻译：在环管反应器中聚合至少一种在液体稀释剂中的烯烃单体以产生包含固体颗粒烯烃聚合物和所述稀释剂的浆料的方法，其中浆料的实际体积固体浓度与最大可能的几何体积固体之间的比率通过未包装的沉降床颗粒（SVCR）的体积密度测量的浆料浓度为V * 0.065或更大，并且在任何方向垂直于反应器中的任何点处的平均粒度的累积沉降距离的比流向环流反应器的内径的方向保持在[0.084 *（V-6.62）+（0.69-SVCR）* 1.666]以下，其中V是浆料的循环速度，m / s 和“累积沉降距离”被定义为累积距离，表示为直径的分数，颗粒在与上一个上游泵的流动方向垂直的任何方向上行进。

8. 发明申请

WO2009127645A1 POLYMER STREAM TRANSFER 审中-公开
标题翻译：聚合物流转移
公开(公告)号：WO2009127645A1
公开(公告)日：2009-10-22
申请号：PCT/EP2009/054441
申请日：2009-04-15
申请人： INEOS MANUFACTURING BELGIUM NV , MARISSAL, Daniel , PARISEL, Marc , WALWORTH, Brent
发明人： MARISSAL, Daniel , PARISEL, Marc , WALWORTH, Brent
IPC分类号： B01J19/24 , C08F6/00
CPC分类号： B01J19/2415 , B01J19/2425 , B01J2208/00672 , B01J2219/00015 , B01J2219/00038 , B01J2219/00085 , B01J2219/00094 , B01J2219/00108 , B01J2219/0011 , B01J2219/00114 , B01J2219/00135 , B01J2219/00164 , B01J2219/00184 , B01J2219/00247 , B01J2219/00254 , B01J2219/182 , B01J2219/185 , B01J2219/1943 , B01J2219/1946 , C08F6/001 , F28F27/00 , C08L23/00
摘要： A process for heating a polymer-containing stream being transferred from a polymerization reactor to a separation zone or device is described, comprising passing the stream through a heater comprising at least one transfer line for the stream and means for heating the transfer line, wherein the average particle size of the solid polymer is less than 3mm, the mass flowrate of the polymer-containing stream exiting the heater is no more than 15% greater than the mass flowrate exiting the reactor, and the average velocity of the polymer-containing stream at 80% along the length of the heated part of the transfer line measured from the transfer line inlet is at least 6 m/s, preferably at least 8m/s and more preferably at least 10m/s and the pressure drop across the transfer line is between 0.01 bar/m and 0.2 bar/m.
摘要翻译：描述了将从聚合反应器转移到分离区或装置中的含聚合物流的加热方法，其包括使流通过加热器，该加热器包括用于流的至少一个输送管线和用于加热输送管线的装置，其中固体聚合物的平均粒径小于3mm，离开加热器的含聚合物流的质量流量不比离开反应器的质量流量大15％，并且含聚合物流的平均速度在从传输线入口测得的传输线加热部分的长度为80％至少为6m / s，优选为至少8m / s，更优选为至少10m / s，并且传输线上的压降为在0.01巴/米到0.2巴/米之间。

9. 发明申请

WO2009030647A1 SLURRY PHASE POLYMERISATION PROCESS 审中-公开
标题翻译：浆料相聚合方法
公开(公告)号：WO2009030647A1
公开(公告)日：2009-03-12
申请号：PCT/EP2008/061372
申请日：2008-08-29
申请人： INEOS MANUFACTURING BELGIUM NV , KOCH, Benoit , MARISSAL, Daniel , PARISEL, Marc , WALWORTH, Brent R
发明人： KOCH, Benoit , MARISSAL, Daniel , PARISEL, Marc , WALWORTH, Brent R
IPC分类号： C08F10/02 , C08F2/00 , C08L23/06
CPC分类号： C08F10/02 , C08F110/02 , C08L23/06 , C08L2205/02 , C08L2205/025 , C08L2308/00 , C08F2/14 , C08F2/001 , C08L2666/06 , C08F2500/02 , C08F2500/12 , C08F2500/01
摘要： Process for producing a multimodal polyethylene in at least two loop reactors connected in series, in which 20-80wt% of a high molecular weight (HMW) polymer is made in suspension in a first reactor and 20-80wt% of a low molecular weight (LMW) polymer is made in suspension in a second reactor, one polymer being made in the presence of the other in either order, wherein the ratio of the average activity in the LMW reactor to the average activity in the HMW reactor is from 0.25 and 1.5, where average activity in each reactor is defined as the rate of polyethylene produced in the reactor (kgPE/hr) / [ethylene concentration in the reactor (mol%) x residence time in the reactor (hours) x feed rate of catalyst into the reactor (g/hr)], residence time being defined as the mass of the polymer in the reactor (kg)/the output rate of polymer from the reactor (kg/hr), and the volumes of the two reactors differ by less than 10%.
摘要翻译：在至少两个串联连接的环管反应器中制备多峰聚乙烯的方法，其中20-80重量％的高分子量（HMW）聚合物在第一个反应器中悬浮，20-80wt％的低分子量（ LMW）聚合物在第二反应器中以悬浮液形式制备，一种聚合物在另一种反应器的存在下制备，其中LMW反应器中的平均活性与HMW反应器中的平均活性的比例为0.25和1.5 ，其中每个反应器中的平均活性定义为在反应器中生产的聚乙烯（kgPE / hr）/ [反应器中的乙烯浓度（mol％）×在反应器中的停留时间（小时））×催化剂进入反应器（g / hr）]，停留时间定义为反应器中聚合物的质量（kg）/来自反应器的聚合物的输出速率（kg / hr），两个反应器的体积相差小于 10％。

10. 发明申请

WO2009030646A1 SLURRY PHASE POLYMERISATION PROCESS 审中-公开
标题翻译：浆料相聚合方法
公开(公告)号：WO2009030646A1
公开(公告)日：2009-03-12
申请号：PCT/EP2008/061371
申请日：2008-08-29
申请人： INEOS MANUFACTURING BELGIUM NV , KOCH, Benoit , MARISSAL, Daniel , PARISEL, Marc , WALWORTH, Brent, R.
发明人： KOCH, Benoit , MARISSAL, Daniel , PARISEL, Marc , WALWORTH, Brent, R.
IPC分类号： C08F10/02 , C08F2/00 , C08L23/06
CPC分类号： B01J19/2435 , B01J2219/0004 , B01J2219/00166 , B01J2219/00186 , C08F10/02 , C08F110/02 , C08F2/14 , C08F2/001 , C08F2500/01 , C08F2500/12 , C08F2500/02
摘要： Process for producing a multimodal polyethylene in at least two reactors connected in series, in which 20-80wt% of a high molecular weight (HMW) polymer is made in suspension in a first reactor and 20-80wt% of a low molecular weight (LMW) polymer is made in suspension in a second reactor in the presence of the HMW polymer, wherein the solids concentration in the second LMW reactor, defined as the mass of polymer divided by the total mass of slurry, is at least 35wt%, most preferably between 45wt% and 60wt%, and/or the the ratio of solids concentration in the first reactor to that in the second reactor is maintained at less than 1.0, preferably between 0.6 and 0.8, and further wherein the volume of the second reactor is at least 10%, preferably at least 30% and more preferably at least 50% greater than the volume of the first reactor.
摘要翻译：在至少两个串联的反应器中制备多峰聚乙烯的方法，其中将20-80重量％的高分子量（HMW）聚合物悬浮在第一反应器和20-80重量％的低分子量（LMW））聚合物在HMW聚合物存在下在第二反应器中悬浮制备，其中定义为聚合物质量除以浆料总质量的第二LMW反应器中的固体浓度为至少35重量％，最优选在45重量％至60重量％之间，和/或第一反应器中的固体浓度与第二反应器中的固体浓度之比保持在小于1.0，优选0.6至0.8之间，此外，其中第二反应器的体积为比第一反应器的体积大至少10％，优选至少30％，更优选至少50％。

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