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    • 2. 发明申请
    • GLYCOLIDE PRODUCTION PROCESS, AND GLYCOLIC ACID OLIGOMER FOR GLYCOLIDE PRODUCTION
    • 甘油三酯生产工艺和甘油酸低聚物
    • WO2002083661A1
    • 2002-10-24
    • PCT/JP2002/003570
    • 2002-04-10
    • KUREHA CHEMICAL INDUSTRY COMPANY, LIMITEDYAMANE, KazuyukiKAWAKAMI, Yukichika
    • YAMANE, KazuyukiKAWAKAMI, Yukichika
    • C07D319/12
    • C07D319/12
    • The invention relates to a glycolide production process wherein a depolymerization reaction system comprising a glycolic acid oligomer or a glycolic acid oligomer and a polar organic solvent is heated to depolymerize the glycolic acid oligomer into glycolide, the resulting glycolide or the glycolide and polar organic solvent are distilled out of the depolymerization reaction system, and the glycolide is recovered from distillates obtained by distillation. The glycolic acid oligomer or the glycolic acid oligomer and polar organic solvent are continuously or intermittently charged into the depolymerization reaction system, thereby carrying out depolymerization reactions continuously or repeatedly. During the depolymerization reactions, a compound having an alcoholic hydroxyl group is permitted to exist at a specific quantitative ratio in the depolymerization reaction system. The invention is also concerned with a glycolic acid oligomer for the production of glycolide, which is obtained by condensation of glycolic acid in the presence of the compound having an alcoholic hydroxyl group.
    • 本发明涉及一种乙交酯生产方法,其中加热包含乙醇酸低聚物或乙醇酸低聚物和极性有机溶剂的解聚反应体系,使乙醇酸低聚物解聚成乙交酯,得到的乙交酯或乙交酯和极性有机溶剂为 从解聚反应体系中蒸出,从蒸馏得到的馏出物中回收乙交酯。 将乙醇酸低聚物或乙醇酸低聚物和极性有机溶剂连续或间歇地加入到解聚反应体系中,从而连续或反复进行解聚反应。 在解聚反应中,在解聚反应体系中允许具有醇羟基的化合物以特定的定量比存在。 本发明还涉及通过乙醇酸在具有醇羟基的化合物的存在下缩合而获得的用于生产乙交酯的乙醇酸低聚物。