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1. 发明申请

WO2003106369A1 ADDITIVE FOR HYDRAULICALLY SETTING SYSTEMS, THE HYDRAULICALLY SETTING MIXTURES AND THE USE THEREOF 审中-公开
标题翻译：液压设备系统的补充，液压设备的混合及其使用
公开(公告)号：WO2003106369A1
公开(公告)日：2003-12-24
申请号：PCT/EP2003/006132
申请日：2003-06-11
申请人： ELOTEX AG , WASER, Hanspeter , BÜHLER, Erwin , KOELLIKER, Robert
发明人： WASER, Hanspeter , BÜHLER, Erwin , KOELLIKER, Robert
IPC分类号： C04B28/02
CPC分类号： C04B24/383 , C04B40/0039 , C04B2103/0079 , C04B2103/46 , C04B2111/1006 , C04B24/32 , C04B28/02 , C04B24/2641
摘要： The invention relates to an additive for hydraulically setting systems based on modified polycarboxylates and water-soluble ethers of high polymeric polysaccharides, optionally containing further standard additives, characterized by a content of a) a water-soluble ether of cellulose or a cellulose-like compound with a viscosity of at least approximately 1,000 mPas, particularly at least approximately 2,000 mPas, measured as a 2% aqueous solution with a Brookfield viscosimeter at 20°C and 20 rpm and b) a polycarboxylate, whose main chain is linked by means of ester, ether, imide and/or amide groups with polyethylene oxide-containing side chains. The invention also relates to hydraulic mixtures having a content of the above additive and the use thereof. Using the additive according to the invention in hydraulically setting systems comparable and in part much better characteristics are obtained compared with casein-containing formulations, such as a rheological flow behaviour comparable to casein, but with improved water retention.
摘要翻译：本发明涉及一种基于改性聚羧酸盐和高分子多糖的水溶性醚的液压固化体系的添加剂，任选地含有另外的标准添加剂，其特征在于a）纤维素或纤维素样化合物的水溶性醚粘度为至少约1,000mPas，特别是至少约2,000mPas，用Brookfield粘度计在20℃和20rpm下以2％水溶液测量，b）多羧酸盐，其主链通过酯连接，醚，酰亚胺和/或酰胺基团与含聚氧化乙烯的侧链。本发明还涉及具有上述添加剂含量的水硬性混合物及其用途。与含酪蛋白的制剂相比，使用根据本发明的添加剂在水硬定型系统中可比较和部分更好的特性，如与酪蛋白相当的流变行为，但具有改善的保水性。

2. 发明申请

WO2011098412A1 PROCESS TO HYDROPHOBIZE CEMENT-FREE MORTARS 审中-公开
标题翻译：疏水化无水泥浆的方法
公开(公告)号：WO2011098412A1
公开(公告)日：2011-08-18
申请号：PCT/EP2011/051701
申请日：2011-02-07
申请人： AKZO NOBEL CHEMICALS INTERNATIONAL B.V. , ABERLE, Thomas , EMMENEGGER, Paul , KOELLIKER, Robert
发明人： ABERLE, Thomas , EMMENEGGER, Paul , KOELLIKER, Robert
IPC分类号： C04B28/02 , C04B28/08 , C04B28/10 , C04B28/14 , C04B28/16 , C04B28/18 , C04B28/26 , C04B28/30 , C04B40/00
CPC分类号： C04B28/021 , C04B28/08 , C04B28/10 , C04B28/14 , C04B28/16 , C04B28/18 , C04B28/26 , C04B28/30 , C04B40/0039 , C04B2103/0057 , C04B2111/1037 , C04B2111/27 , C04B24/283 , C04B24/302 , C04B24/32 , C04B24/34 , C04B24/42 , C04B2103/0053 , C04B2103/40 , C04B14/106 , C04B14/28 , C04B24/2623 , C04B24/383 , C04B40/0608 , C04B2103/22 , C04B40/0263
摘要： The present invention provides a process to hydrophobize a mortar which is essentially free of cement, comprising the steps of mixing the mortar with an additive and water and subsequently allowing the mortar to cure, wherein the additive contains a component which is a rosin, a rosin derivative, a mixture of a resin with a rosin, or a mixture of a resin with a rosin derivative, wherein when the softening point of the component is higher than 60°C, the curing step is performed at a temperature that is not lower than the softening point of the component minus 20°C and when the softening point of the component is 60°C or lower, the curing step is performed at 40°C or lower, and wherein the rosin and/or rosin derivative have an acid number of at least 50 mg KOH/g, and when the component is a mixture of a resin with a rosin, or a mixture of a resin with a rosin derivative, the resin at 23°C and pH 7 has a water solubility of about 5 g/l or less and a Brookfield viscosity of less than 20,000 mPas, measured at 23°C and 20 rpm. The invention also covers an additive as well as a pasty and a dry mortar composition.
摘要翻译：本发明提供一种使基本上不含水泥的砂浆疏水化的方法，包括以下步骤：将砂浆与添加剂和水混合，随后使砂浆固化，其中添加剂含有松香组分，松香衍生物，树脂与松香的混合物，或树脂与松香衍生物的混合物，其中当组分的软化点高于60℃时，固化步骤在不低于组分的软化点减去20℃，当组分的软化点为60℃或更低时，固化步骤在40℃或更低温度下进行，其中松香和/或松香衍生物具有酸值至少为50mg KOH / g，当该组分是松香的树脂混合物或树脂与松香衍生物的混合物时，该树脂在23℃和pH7下的水溶解度为约5 g / l以下，布氏粘度小于 20,000 mPas，在23°C和20 rpm下测量。本发明还包括添加剂以及糊状物和干砂浆组合物。

3. 发明申请

WO2011073224A3 PROCESS AND ADDITIVE TO IMPROVE ADHESION OF BUILDING COMPOSITIONS TO SUBSTRATES 审中-公开
公开(公告)号：WO2011073224A3
公开(公告)日：2011-06-23
申请号：PCT/EP2010/069690
申请日：2010-12-15
申请人： AKZO NOBEL CHEMICALS INTERNATIONAL B.V. , WILLIMANN, Hongli , KOELLIKER, Robert , PUSTOVGAR, Andrey Petrovich , WICKI, Hans , HEINI, Urs , ABERLE, Thomas
发明人： WILLIMANN, Hongli , KOELLIKER, Robert , PUSTOVGAR, Andrey Petrovich , WICKI, Hans , HEINI, Urs , ABERLE, Thomas
IPC分类号： C04B28/04 , C04B40/00 , C08J3/22 , C09D7/00 , C04B20/10
摘要： The present invention relates to the use of an additive as well as a process to improve the adhesion of a mortar to a building substrate, wherein the mortar is mixed with said additive and is applied to a building substrate selected from the group of polystyrene-containing substrates, polyolefin-containing substrates or polyvinyl chloride-containing substrates, the additive containing (i) a plasticizer that is liquid at 50°C or lower, has a boiling point of 100°C or higher, and that has a solubility parameter δ at 25°C between 22.5 MPa 1/2 and 11 MPa 1/2 ; (ii) optionally, a filler that has a BET surface area of at least 40 m 2 /g; (iii) optionally, a biopolymer; (iv) optionally, a protective colloid; and (v) optionally, a water-insoluble film-forming (co)polymer based on ethylenically unsaturated monomers. The invention also covers an additive and a kit of parts suitable for use in the above process.

4. 发明申请

WO2011073224A2 PROCESS AND ADDITIVE TO IMPROVE ADHESION OF BUILDING COMPOSITIONS TO SUBSTRATES 审中-公开
标题翻译：改进建筑组合物与基材粘合的工艺和添加剂
公开(公告)号：WO2011073224A2
公开(公告)日：2011-06-23
申请号：PCT/EP2010069690
申请日：2010-12-15
申请人： AKZO NOBEL CHEMICALS INT BV , WILLIMANN HONGLI , KOELLIKER ROBERT , PUSTOVGAR ANDREY PETROVICH , WICKI HANS , HEINI URS , ABERLE THOMAS
发明人： WILLIMANN HONGLI , KOELLIKER ROBERT , PUSTOVGAR ANDREY PETROVICH , WICKI HANS , HEINI URS , ABERLE THOMAS
IPC分类号： C04B28/04 , C04B40/00 , C08J3/22 , C09D7/00
CPC分类号： C04B16/02 , B05D7/02 , C04B20/1022 , C04B28/04 , C04B40/0039 , C04B40/0042 , C04B2111/00637 , C04B2111/00672 , C09D5/34 , E04F15/00 , Y02W30/94 , C04B14/06 , C04B22/062 , C04B24/383 , C04B40/0608 , C04B2103/30 , C04B14/062 , C04B24/085 , C04B14/00 , C04B20/008 , C04B24/008 , C04B24/005 , C04B24/38 , C04B2103/0088 , C04B18/146 , C04B24/045 , C04B2103/0066 , C04B24/128 , C04B24/16 , C04B14/305 , C04B24/20 , C04B14/10 , C04B24/026 , C04B22/064 , C04B14/066
摘要： The present invention relates to the use of an additive as well as a process to improve the adhesion of a mortar to a building substrate, wherein the mortar is mixed with said additive and is applied to a building substrate selected from the group of polystyrene-containing substrates, polyolefin-containing substrates or polyvinyl chloride-containing substrates, the additive containing (i) a plasticizer that is liquid at 50°C or lower, has a boiling point of 100°C or higher, and that has a solubility parameter d at 25°C between 22.5 MPa1/2 and 11 MPa1/2; (ii) optionally, a filler that has a BET surface area of at least 40 m2/g; (iii) optionally, a biopolymer; (iv) optionally, a protective colloid; and (v) optionally, a water-insoluble film-forming (co)polymer based on ethylenically unsaturated monomers. The invention also covers an additive and a kit of parts suitable for use in the above process.
摘要翻译：本发明涉及添加剂的使用以及改进砂浆与建筑基材的粘合性的方法，其中将砂浆与所述添加剂混合并施加到选自含聚苯乙烯的建筑基材基材，含聚烯烃的基材或含聚氯乙烯的基材，所述添加剂含有（i）在50℃以下为液体的增塑剂，沸点为100℃以上，溶解度参数d为 25°C在22.5 MPa1 / 2和11 MPa1 / 2之间; （ii）任选地，具有至少40m 2 / g的BET表面积的填料; （iii）任选地，生物聚合物; （iv）任选的保护胶体; 和（v）任选地，基于烯属不饱和单体的水不溶性成膜（共）聚合物。本发明还涵盖适用于上述方法的添加剂和成套工具。

5. 发明申请

WO2006002297A1 PROCESS TO GENERATE WATER BASED ADHESIVES AND THEIR USE 审中-公开
标题翻译：生产水性胶粘剂及其使用的方法
公开(公告)号：WO2006002297A1
公开(公告)日：2006-01-05
申请号：PCT/US2005/022202
申请日：2005-06-23
申请人： NATIONAL STARCH AND CHEMICAL INVESTMENT HOLDING CORPORATION , MAGNIN, Christophe , BURDETT, Susan, Moira , DUCKWORTH, David , UWE FLUCKEN, Rainer, Christian , KOELLIKER, Robert , SPRIGGS, Emma
发明人： MAGNIN, Christophe , BURDETT, Susan, Moira , DUCKWORTH, David , UWE FLUCKEN, Rainer, Christian , KOELLIKER, Robert , SPRIGGS, Emma
IPC分类号： C09J201/00
CPC分类号： C08J3/05 , B01F3/04099 , B01F5/0602 , B01F7/00416 , B01F2003/125 , B01F2215/0431 , B01F2215/0477 , B01F2215/0481 , B01F2215/0495
摘要： Process to generate a water based adhesive by mixing a re-dispersible powder adhesive and water, optionally together with other components, characterized by mixing a re-dispersible powder adhesive, water and optionally other components such that the final water based adhesive contains a re-dispersed powder adhesive in an amount of about 0.5% to 80% by weight and has a Brookfield viscosity (23°C/20 RPM) from about 10 to 250'000 mPas, wherein : the mixing is carried out as a micro-batch or a continuous process with a volume of the mixing chamber of about 0.001 to 200 litres and with a mixing time of about 0.01 to 500 seconds, and the ratio of the diameter of at least one mixer blade to the diameter of the mixing chamber is about 0.50 to 0.99.
摘要翻译：通过混合可再分散的粉末粘合剂和水，任选地与其它组分一起产生水基粘合剂的方法，其特征在于将可再分散的粉末粘合剂，水和任选的其它组分混合，使得最终的水基粘合剂含有重新分散的粉末粘合剂，分散粉末粘合剂的量为约0.5％至80％重量，并且具有约10至250,000mPas的布氏粘度（23℃/ 20RPM），其中：混合以微批次或混合室的体积为约0.001至200升并且混合时间为约0.01至500秒的连续方法，并且至少一个混合器叶片的直径与混合室的直径之比为约0.50 至0.99。

6. 发明申请

WO2012168347A1 PROCESS AND ADDITIVE TO IMPROVE ADHESION OF COMPOSITIONS TO SUBSTRATES 审中-公开
标题翻译：加工和添加剂以改善组合物对基材的粘合
公开(公告)号：WO2012168347A1
公开(公告)日：2012-12-13
申请号：PCT/EP2012/060780
申请日：2012-06-07
申请人： AKZO NOBEL CHEMICALS INTERNATIONAL B.V. , ABERLE, Thomas , KOELLIKER, Robert
发明人： ABERLE, Thomas , KOELLIKER, Robert
IPC分类号： C04B40/00 , C08K5/00 , C08J3/12 , C08L1/00
CPC分类号： C04B24/383 , C04B20/1048 , C04B24/38 , C04B28/02 , C04B28/14 , C08J3/12 , C08J3/21 , C08J2301/00 , C08J2301/28 , C08J2303/02 , C08J2303/04 , C08K5/0016 , C08L1/28 , C09J105/00 , C04B14/062 , C04B20/1022 , C08L5/00 , C08L3/00
摘要： The present invention provides a process to prepare a powdery additive suitable for improving adhesion of building material compositions to substrates having a surface energy of 50 mJ/m 2 or lower, measured according to DIN 5660-2:2011-12, the additive comprising a polysaccharide and a plasticizer, wherein the plasticizer is liquid at 50°C or lower, has a boiling point of 100°C or higher and is selected from a specific group,comprising the steps of a) admixing the plasticizer to an aqueous medium of the polysaccharide followed by the subsequent drying of the admixture, or b) preparing a first particle comprising the plasticizer by (i) adsorbing the plasticizer onto a carrier, or by emulsifying the plasticizer with a synthetic water-soluble polymer in water and subsequently drying the emulsion, and (ii) mixing this first particle with a second particle comprising the polysaccharide wherein the mean particle size of the coarser of the first and second particle is not more than 10 times the mean particle size of the finer particle, or agglomerating the first and second particles into one particle. The invention further provides the additive obtainable by this process, use of the additive and building material compositions containing the additive as well as a process to adhere such compositions to substrates having a surface energy of 50 mJ/m 2 or lower.
摘要翻译：本发明提供一种制备粉末添加剂的方法，该粉末添加剂适合于改善建筑材料组合物与根据DIN 5660-2：2011-12测量的表面能为50mJ / m 2或更低的基材的粘附性，该添加剂包含多糖和增塑剂，其中所述增塑剂在50℃以下为液体，沸点为100℃以上，选自特定组，包括以下步骤：a）将增塑剂与所述多糖的水性介质混合然后随后干燥混合物，或b）通过（i）将增塑剂吸附到载体上，或者用合成的水溶性聚合物在水中乳化增塑剂并随后干燥乳液来制备包含增塑剂的第一颗粒，和（ii）将该第一颗粒与包含多糖的第二颗粒混合，其中第一和第二颗粒的较粗的平均粒度不超过10倍较细颗粒的平均粒度，或将第一和第二颗粒聚集成一个颗粒。本发明还提供了可通过该方法获得的添加剂，含有添加剂的添加剂和建筑材料组合物的使用以及将这些组合物粘附到表面能为50mJ / m 2或更低的基材的方法。

7. 发明申请

WO2009156164A1 REDISPERSIBLE POLYMER POWDER 审中-公开
标题翻译：可重复聚合物粉末
公开(公告)号：WO2009156164A1
公开(公告)日：2009-12-30
申请号：PCT/EP2009/004607
申请日：2009-06-25
申请人： AKZO NOBEL N.V. , WILLIMANN, Hongli , WICKI , Hans , HEINI, Urs , ZAPF, Alexander , KOELLIKER, Robert
发明人： WILLIMANN, Hongli , WICKI , Hans , HEINI, Urs , ZAPF, Alexander , KOELLIKER, Robert
IPC分类号： C04B40/00 , C04B28/02 , C08J3/12 , C08L7/00 , C04B20/10 , C04B24/26
CPC分类号： C04B40/0042 , C04B20/1029 , C04B24/2611 , C04B2103/0057 , C04B2103/0058 , C08F253/00 , C08J3/122 , C08J2307/02 , C08J2329/04 , C08K3/013 , C08K7/02 , C08L15/00 , C08L51/04 , C08L2666/02 , C08L2666/04 , C09D151/04 , C09J151/04 , Y02W30/97 , C04B14/28 , C04B18/24 , C04B22/06 , C04B24/085 , C04B24/26 , C04B24/2623 , C04B24/2647 , C04B24/2652 , C04B24/38 , C04B24/383 , C04B24/42 , C04B2103/10 , C04B2103/20 , C04B2103/304 , C04B2103/408 , C04B2103/44 , C04B2103/46 , C04B2103/50 , C04B2103/54 , C04B2103/58 , C04B2103/608 , C04B2103/65 , C04B2103/67 , C04B2103/69 , C04B20/023 , C08L7/00
摘要： The present invention pertains to a water-redispersible polymer powder based on at least one modified natural latex. The modified natural latex can be obtained by mixing natural latex with at least one radical initiator and/or oxidising agent, by mixing and reacting natural latex with at least one olefinically unsaturated monomer and with at least one radical initiator, and/or by mixing natural latex with at least one filler. Preferably, the polymer powder contains up to about 95 wt.% of least one natural latex, about 0 to 50 wt.% of at least one protective colloid, about 2 to 70 wt.% of at least one filler and/or anti-caking agent, as well as optionally further additives. In addition, the invention pertains to a process for the preparation of the polymer powder, the use thereof as an additive in building material compositions, as well as building material compositions containing the polymer powder.
摘要翻译：本发明涉及基于至少一种改性天然胶乳的水可再分散聚合物粉末。改性天然胶乳可以通过将天然胶乳与至少一种自由基引发剂和/或氧化剂混合，通过将天然胶乳与至少一种烯属不饱和单体和至少一种自由基引发剂混合和反应，和/或通过混合天然胶乳具有至少一种填料的胶乳。优选地，聚合物粉末含有至多约95重量％的至少一种天然胶乳，约0至50重量％的至少一种保护胶体，约2-70重量％的至少一种填料和/ 结块剂，以及任选的其它添加剂。此外，本发明涉及制备聚合物粉末的方法，其作为建筑材料组合物中的添加剂的用途，以及含有聚合物粉末的建筑材料组合物。

8. 发明申请

WO2008031537A1 POWDER AND WATER-BASED ADHESIVE COMPOSITION 审中-公开
标题翻译：粉末和水基胶粘剂组合物
公开(公告)号：WO2008031537A1
公开(公告)日：2008-03-20
申请号：PCT/EP2007/007829
申请日：2007-09-07
申请人： NATIONAL STARCH AND CHEMICAL INVESTMENT HOLDING CORPORATION , KEHRER, Ulf , KOELLIKER, Robert , PATEL, Nalini , LIEBRAND, Roland, T., W., G. , MAGNIN, Christophe , BURDETT, Susan, Moira , HEINI, Urs
发明人： KEHRER, Ulf , KOELLIKER, Robert , PATEL, Nalini , LIEBRAND, Roland, T., W., G. , MAGNIN, Christophe , BURDETT, Susan, Moira , HEINI, Urs
IPC分类号： C09J201/00
CPC分类号： C09J201/00 , C08L2666/20
摘要： The invention relates to an adhesive composition which is in one embodiment a free flowing, water-redispersible powder adhesive, comprising about 30 to 99.9 wt.-% of at least one water-insoluble, film-forming polymer and/ or at least one water-soluble polymer in powder form, about 0.1 to 35 wt-% of at least one polyalkylene polyamine with a molecular weight of between about 300 and 10'000'000 and up to about 35 wt- % of at least one water-soluble salt. In another embodiment, the adhesive composition is a water-based adhesive composition, comprising, based on the solids content of the adhesive about 30 to 99.4 wt.-%, of at least one aqueous dispersion of a water- insoluble, film-forming polymer and at least one water-soluble polymer, wherein the weight ratio of the water-insoluble to the water-soluble polymer is from about 0.001 : 1 to 100 : 1, about 0.1 to 35 wt.-%, of at least one polyalkylene polyamine with a molecular weight of between about 300 and 10'000'000, and about 0.5 to 35 wt.-% of at least one water-soluble salt, whereas the solids content of the water-based adhesive composition is between about 5 and 70 wt.-%. The processes to manufacture the same and the uses are described as well. The inventive adhesive composition is cost effective and provides excellent adhesion, in particular to difficult to bond substrates.
摘要翻译：本发明涉及粘合剂组合物，其在一个实施方案中为自由流动的水可再分散的粉末粘合剂，其包含约30至99.9重量％的至少一种不溶于水的成膜聚合物和/或至少一种水粉末形式的可溶性聚合物，约0.1至35重量％的至少一种聚亚烷基多胺，其分子量为至少一种水溶性盐的分子量为约300至10,000至约35重量％。在另一个实施方案中，粘合剂组合物是水基粘合剂组合物，基于约30至99.4重量％的粘合剂的固体含量，包含至少一种不溶于水的成膜聚合物的水分散体和至少一种水溶性聚合物，其中水不溶性与水溶性聚合物的重量比为约0.001:1至100:1，约0.1-35重量％的至少一种聚亚烷基多胺分子量为约300至10,000,000，和约0.5至35重量％的至少一种水溶性盐，而水基粘合剂组合物的固体含量为约5至70 重量％。还描述了制造它们的过程和用途。本发明的粘合剂组合物是成本有效的并且提供优异的粘合性，特别是难以粘结基材。

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