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1. 发明申请

WO2006100120A1 GEL TIME DRIFT-FREE RESIN COMPOSITIONS 审中-公开
标题翻译：凝胶时间免洗树脂组合物
公开(公告)号：WO2006100120A1
公开(公告)日：2006-09-28
申请号：PCT/EP2006/002984
申请日：2006-03-23
申请人： DSM IP ASSETS B.V. , JANSEN, Johan, Franz, Gradus, Antonius , KLEUSKENS, Engelina, Catharina , KRAEGER, Ivo, Ronald
发明人： JANSEN, Johan, Franz, Gradus, Antonius , KLEUSKENS, Engelina, Catharina , KRAEGER, Ivo, Ronald
IPC分类号： C08K5/07 , C08L67/06 , C08L63/10 , C08F290/06 , C08F290/14 , C08F283/01 , C08F4/40
CPC分类号： C08F290/144 , C08F283/01 , C08F290/06 , C08F290/061 , C08F290/064 , C08F290/14 , C08F290/141 , C08K5/07 , C08K5/14 , C08L67/06
摘要： The present invention relates to unsaturated polyester resin or vinyl ester resin compositions that are essentially free of cobalt; that are curable with a peroxide component; and that, comprise a polymer containing reactive unsaturations, optionally a reactive diluent, and a dioxo-component; which dioxocomponent consists of one or more dioxo-compounds having a calculated reduction energy (CRE), being the energy difference in kcal/mole between the lowest energy conformations of the radical anion and the corresponding neutral molecule as calculated by means of the Turbomole Version 5 program, in the range of from -5 to -30 kcal/mole. These resin compositions show a reduced gel-time drift tendency. The present invention further also relates to objects and structural parts prepared from such unsaturated polyester or vinyl ester resin compositions by curing with a peroxide. The present invention finally also relates to methods of peroxide curing of unsaturated polyester resin or vinyl ester resin compositions.
摘要翻译：本发明涉及基本上不含钴的不饱和聚酯树脂或乙烯基酯树脂组合物; 可用过氧化物组分固化; 并且包括含有反应性不饱和的聚合物，任选的反应性稀释剂和二氧代组分; 该二氧组分由具有计算的还原能（CRE）的一种或多种二氧代化合物组成，其是通过涡轮调制剂版本5计算的自由基阴离子和相应的中性分子的最低能量构象之间的kcal /摩尔的能量差程序，范围从-5到-30千卡/摩尔。这些树脂组合物显示出降低的凝胶时间漂移趋势。本发明还涉及通过用过氧化物固化由这种不饱和聚酯或乙烯基酯树脂组合物制备的物体和结构部件。本发明最终还涉及不饱和聚酯树脂或乙烯基酯树脂组合物的过氧化物固化方法。

2. 发明申请

WO2006100124A1 GEL TIME DRIFT-FREE RESIN COMPOSITIONS 审中-公开
标题翻译：凝胶时间无树脂组合物
公开(公告)号：WO2006100124A1
公开(公告)日：2006-09-28
申请号：PCT/EP2006/002988
申请日：2006-03-23
申请人： DSM IP ASSETS B.V. , JANSEN, Johan, Franz, Gradus, Antonius , KLEUSKENS, Engelina, Catharina , KRAEGER, Ivo, Ronald
发明人： JANSEN, Johan, Franz, Gradus, Antonius , KLEUSKENS, Engelina, Catharina , KRAEGER, Ivo, Ronald
IPC分类号： C08K5/07 , C08L67/06 , C08L63/10 , C08F283/01 , C08F290/14 , C08F290/06 , C08F4/40
CPC分类号： C08K5/07 , C08L67/06
摘要： The present invention relates to unsaturated polyester resin or vinyl ester resin compositions having an acid value higher than 0 mg KOH/g of resin (namely in the range of from 0,01 to 400 mg KOH/g of resin), that are essentially free of cobalt; that are curable with a peroxide component; and that comprise a polymer containing reactive unsaturations, optionally a reactive diluent, and a dioxo-component; which dioxo-component consists of one or more dioxo-compounds having a calculated reduction energy (CRE), being the energy difference in kcal/mole between the lowest energy conformations of the radical anion and the corresponding neutral molecule as calculated by means of the Turbomole Version 5 program, in the range of from -5 to - 30 kcal/mole. These resin compositions show a reduced gel-time drift tendency. Moreover, it has been found that gel-time of these resin compositions can be easily and favorably adjusted by adjusting their acid value. The present invention further also relates to objects and structural parts prepared from such unsaturated polyester or vinyl ester resin compositions by curing with a peroxide. The present invention finally also relates to methods of peroxide curing of unsaturated polyester resin or vinyl ester resin compositions.
摘要翻译：本发明涉及酸值高于0mg KOH / g树脂的不饱和聚酯树脂或乙烯基酯树脂组合物（即在0.01-100mg KOH / g树脂的范围内），其基本上是游离的的钴; 可用过氧化物组分固化; 并且其包含含有反应性不饱和的聚合物，任选的反应性稀释剂和二氧代组分; 该二氧代 - 组分由一种或多种具有计算的还原能（二氧化碳）的二氧代化合物组成，其是由自由基阴离子和相应的中性分子的最低能量构象之间的kcal /摩尔的能量差，通过涡轮摩尔版本5程序，范围从-5到-30千卡/摩尔。这些树脂组合物显示出降低的凝胶时间漂移趋势。此外，已经发现，通过调节其酸值，可以容易且有利地调节这些树脂组合物的凝胶时间。本发明还涉及通过用过氧化物固化由这种不饱和聚酯或乙烯基酯树脂组合物制备的物体和结构部件。本发明最终还涉及不饱和聚酯树脂或乙烯基酯树脂组合物的过氧化物固化方法。

3. 发明申请

WO2006100122A1 GEL TIME DRIFT-FREE RESIN COMPOSITIONS 审中-公开
标题翻译：凝胶时间无树脂组合物
公开(公告)号：WO2006100122A1
公开(公告)日：2006-09-28
申请号：PCT/EP2006/002986
申请日：2006-03-23
申请人： DSM IP ASSETS B.V. , JANSEN, Johan, Franz, Gradus, Antonius , KLEUSKENS, Engelina, Catharina , KRAEGER, Ivo, Ronald
发明人： JANSEN, Johan, Franz, Gradus, Antonius , KLEUSKENS, Engelina, Catharina , KRAEGER, Ivo, Ronald
IPC分类号： C08K5/07 , C08L67/06 , C08L63/10 , C08K5/098 , C08K5/057 , C08K5/00 , C08K3/10 , C08K3/16 , C08K3/22 , C08K3/26 , C08F283/01 , C08F290/14 , C08F290/06
CPC分类号： C08F290/14 , C08F283/01 , C08F290/06 , C08F290/061 , C08F290/064 , C08F290/141 , C08F290/144 , C08K5/07 , C08L67/06
摘要： The present invention relates to unsaturated polyester resin or vinyl ester resin compositions; that are curable with a peroxide component; and that, comprise a transition metal compound, a polymer containing reactive unsaturations, optionally a reactive diluent, and a dioxo-component; which compositions are essentially free of cobalt; and in which the dioxo-component consists of one or more dioxo-compounds having a calculated reduction energy (CRE), being the energy difference in kcal/mole between the lowest energy conformations of the radical anion and the corresponding neutral molecule as calculated by means of the Turbomole Version 5 program, in the range of from -5 to -30 kcal/mole. These resin compositions show a reduced gel-time drift tendency. Moreover, it has been found that gel-time of these resin compositions can be easily and favorably adjusted by adjusting their transition metal content. The present invention further also relates to objects and structural parts prepared from such unsaturated polyester or vinyl ester resin compositions by curing with a peroxide. The present invention finally also relates to methods of peroxide curing of unsaturated polyester resin or vinyl ester resin compositions.
摘要翻译：本发明涉及不饱和聚酯树脂或乙烯基酯树脂组合物; 可用过氧化物组分固化; 并且其包含过渡金属化合物，含有反应性不饱和的聚合物，任选的反应性稀释剂和二氧代组分; 该组合物基本上不含钴; 并且其中二氧代组分由具有计算的还原能（CRE）的一种或多种二氧代化合物组成，其是通过手段计算的自由基阴离子和相应的中性分子的最低能量构象之间的kcal /摩尔的能量差的Turbomol版本5程序，范围为-5至-30千卡/摩尔。这些树脂组合物显示出降低的凝胶时间漂移趋势。此外，已经发现，通过调节它们的过渡金属含量，可以容易且有利地调节这些树脂组合物的凝胶时间。本发明还涉及通过用过氧化物固化由这种不饱和聚酯或乙烯基酯树脂组合物制备的物体和结构部件。本发明最终还涉及不饱和聚酯树脂或乙烯基酯树脂组合物的过氧化物固化方法。

4. 发明申请

WO2006100121A1 GEL TIME DRIFT-FREE RESIN COMPOSITIONS 审中-公开
标题翻译：凝胶时间免洗树脂组合物
公开(公告)号：WO2006100121A1
公开(公告)日：2006-09-28
申请号：PCT/EP2006/002985
申请日：2006-03-23
申请人： DSM IP ASSETS B.V. , JANSEN, Johan, Franz, Gradus, Antonius , KLEUSKENS, Engelina, Catharina , KRAEGER, Ivo, Ronald
发明人： JANSEN, Johan, Franz, Gradus, Antonius , KLEUSKENS, Engelina, Catharina , KRAEGER, Ivo, Ronald
IPC分类号： C08K5/07 , C08L67/06 , C08L67/07 , C08L63/10 , C08F290/06 , C08F290/14 , C08F283/01
CPC分类号： C08K5/07 , C08L67/06
摘要： The present invention relates to unsaturated polyester resin or vinyl ester resin compositions; that are curable with a peroxide component; and that, comprise an Inhibitor, a polymer containing reactive unsaturations, optionally a reactive diluent, and a dioxo-component; which compositions are essentially free of cobalt; and in which the dioxo-component consists of one or more dioxo-compounds having a calculated reduction energy (CRE), being the energy difference in kcal/mole between the lowest energy conformations of the radical anion and the corresponding neutral molecule as calculated by means of the Turbomole Version 5 program, in the ränge of from -5 to -30 kcal/mole. These resin compositions show a reduced gel-time drift tendency. Moreover, it has been found that gel-time of these resin compositions can be easily and favorably adjusted by adjusting their transition metal content. The present invention further also relates to objects and structural parts prepared from such unsaturated polyester or vinyl ester resin compositions by curing with a peroxide. The present invention finally also relates to methods of peroxide curing of unsaturated polyester resin or vinyl ester resin compositions.
摘要翻译：本发明涉及不饱和聚酯树脂或乙烯基酯树脂组合物; 可用过氧化物组分固化; 并且其包含抑制剂，含有反应性不饱和的聚合物，任选的反应性稀释剂和二氧代组分; 该组合物基本上不含钴; 并且其中二氧代组分由具有计算的还原能（CRE）的一种或多种二氧代化合物组成，其是通过手段计算的自由基阴离子和相应的中性分子的最低能量构象之间的kcal /摩尔的能量差的Turbomol版本5程序，在-5至-30千卡/摩尔的范围内。这些树脂组合物显示出降低的凝胶时间漂移趋势。此外，已经发现，通过调节它们的过渡金属含量，可以容易且有利地调节这些树脂组合物的凝胶时间。本发明还涉及通过用过氧化物固化由这种不饱和聚酯或乙烯基酯树脂组合物制备的物体和结构部件。本发明最终还涉及不饱和聚酯树脂或乙烯基酯树脂组合物的过氧化物固化方法。

5. 发明申请

WO2011135029A1 METATHESIS CROSSLINKABLE COATING COMPOSITIONS 审中-公开
标题翻译： METATHESIS可交联涂料组合物
公开(公告)号：WO2011135029A1
公开(公告)日：2011-11-03
申请号：PCT/EP2011/056745
申请日：2011-04-28
申请人： DSM IP ASSETS B.V. , JANSEN, Johan, Franz, Gradus, Antonius , PANELLA, Lavinia , KLEUSKENS, Engelina, Catharina , BENTHEM, VAN, Rudolfus, Antonius, Theodorus, Maria
发明人： JANSEN, Johan, Franz, Gradus, Antonius , PANELLA, Lavinia , KLEUSKENS, Engelina, Catharina , BENTHEM, VAN, Rudolfus, Antonius, Theodorus, Maria
IPC分类号： B01J23/46 , C08G61/06 , C08K5/56
CPC分类号： B01J37/0219 , B01J31/2273 , B01J31/2278 , B01J2231/543 , B01J2531/64 , B01J2531/66 , B01J2531/72 , B01J2531/821 , B01J2531/825 , C08G61/08 , C08G2261/418 , C08G2261/419 , C08G2261/46 , C08K5/56 , C08L65/00
摘要： The invention relates to a metathesis crosslinkable binder composition comprising: i) at least one polymer comprising non-aromatic C=C double bonds, the polymer comprising an average of at least 4 unsaturated fatty acid residues per polymer chain, wherein at least one of the fatty acid residues has from C18 to C26 carbon atoms; and ii) at least a transition metal based metathesis catalyst according to formula (I) wherein L 1 is a neutral amine containing electron donor ligand; L 2 is an optional neutral electron donor ligand; X 1 , X 2 are independently from each other an anionic ligand; a, b in (X 1 ) a and (X 2 ) b of formula (I) are independently from each other an integer from 0 to 4; R is selected from the group consisting of linear or branched alkyl, cycloalkyl, aralkyl, aryl or their substituted equivalents; Ra is selected from the group consisting of hydrogen, linear or branched alkyl, cycloalkyl, aralkyl, aryl, or their substituted equivalents; M is a transition metal selected from the group consisting of Ruthenium (Ru), Manganese (Mn), Osmium (Os), Tungsten (W) and Molybdenum (Mo); wherein two or more of any of L 1 , L 2 , X 1 , X 2 , R and/or Ra are optionally covalently linked together to form one or more cyclic groups, and wherein two or more of any of L 1 , L 2 , X 1 , X 2 , R and/or Ra are optionally attached to a support.
摘要翻译：本发明涉及易位可交联粘合剂组合物，其包含：i）至少一种包含非芳族C = C双键的聚合物，所述聚合物包含每个聚合物链平均至少4个不饱和脂肪酸残基，其中至少一个脂肪酸残基具有C18至C26碳原子; 和ii）至少一种根据式（I）的基于过渡金属的复分解催化剂，其中L1是含中性胺的电子给体配体; L2是任选的中性电子给体配体; X1，X2彼此独立地为阴离子配体; 式（I）的（X1）a和（X2）b中的a，b彼此独立地为0至4的整数; R选自直链或支链烷基，环烷基，芳烷基，芳基或其取代的等价物; R a选自氢，直链或支链烷基，环烷基，芳烷基，芳基或其取代的等价物; M是选自钌（Ru），锰（Mn），锇（Os），钨（W）和钼（Mo））的过渡金属; 其中L1，L2，X1，X2，R和/或Ra中的任意一个中的两个或更多个任选地共价连接在一起形成一个或多个环状基团，并且其中L1，L2，X1，X2，R 和/或Ra任选地连接到载体上。

6. 发明申请

WO2011098587A1 MANGANESE COMPLEX AS DRIER FOR COATING COMPOSITIONS 审中-公开
标题翻译：锰复合材料作为涂料组合物的干燥剂
公开(公告)号：WO2011098587A1
公开(公告)日：2011-08-18
申请号：PCT/EP2011/052073
申请日：2011-02-11
申请人： DSM IP ASSETS B.V. , JANSEN, Johan Franz Gradus Antonius , BERGMAN, Franciscus Adrianus Cornelis , KLEUSKENS, Engelina Catharina
发明人： JANSEN, Johan Franz Gradus Antonius , BERGMAN, Franciscus Adrianus Cornelis , KLEUSKENS, Engelina Catharina
IPC分类号： C09D167/06 , C08G18/36 , C09D175/04
CPC分类号： C09D167/03 , C08G18/0804 , C09D7/63 , C09D167/06 , C09D175/14
摘要： An air drying auto-oxidisable resin composition comprising components: a) a drier comprising a manganese carboxylate complex, and b) a polymer comprising unsaturated fatty acid residues, wherein the manganese carboxylate complex a) has the following structure I: wherein R 1 =H, C1-C20 alkyl optionally substituted with heteroatoms, or C6-C20 aryl optionally substituted with heteroatoms; X and Y are independently selected from O and OC(R 3 )O, in which a=4 when X=O, and a=3 when X= OC(R 3 )O, and in which b=4 when Y=O, and b=3 when Y= OC(R 3 )O; R 2 = C1-C20 alkyl optionally substituted with heteroatoms, C6-C20 aryl optionally substituted with heteroatoms, or a polymeric residue; and R 3 = C1-C20 alkyl optionally substituted with heteroatoms, C6-C20 aryl optionally substituted with heteroatoms, or a polymeric residue.
摘要翻译：一种空气干燥自动氧化树脂组合物，其包含以下组分：a）包含羧酸锰络合物的干燥剂，和b）包含不饱和脂肪酸残基的聚合物，其中所述羧酸锰络合物a）具有以下结构I：其中R 1 = H，任选被杂原子取代的C 1 -C 20烷基或任选被杂原子取代的C 6 -C 20芳基; X和Y独立地选自O和OC（R3）O，当X = O时a = 4，当X = OC（R3）O时a = 3，当Y = O时b = 4，当Y = 当Y = OC（R3）O时，b = 3; R2 =任选被杂原子取代的C 1 -C 20烷基，任选被杂原子取代的C 6 -C 20芳基或聚合物残基; 和R3 =任选被杂原子取代的C 1 -C 20烷基，任选被杂原子取代的C 6 -C 20芳基或聚合物残基。

7. 发明申请

WO2011098584A1 MANGANESE SALT COMPLEX AS DRIER FOR COATING COMPOSITIONS 审中-公开
标题翻译：锰酸盐复合物作为涂料组合物的干燥剂
公开(公告)号：WO2011098584A1
公开(公告)日：2011-08-18
申请号：PCT/EP2011/052070
申请日：2011-02-11
申请人： DSM IP ASSETS B.V. , JANSEN, Johan Franz Gradus Antonius , BERGMAN, Franciscus Adrianus Cornelis , KLEUSKENS, Engelina Catharina , HAGE, Ronald
发明人： JANSEN, Johan Franz Gradus Antonius , BERGMAN, Franciscus Adrianus Cornelis , KLEUSKENS, Engelina Catharina , HAGE, Ronald
IPC分类号： C09D167/06 , C08G18/36 , C09D175/04
CPC分类号： C09D167/03 , C08G18/0804 , C09D7/63 , C09D167/06 , C09D175/14
摘要： An air drying auto-oxidisable resin composition comprising components: a) a drier comprising a manganese salt complex, and b) a polymer comprising unsaturated fatty acid residues, wherein the manganese salt complex has the following structure I: wherein the anion is selected from Cl - , NO 3 - or R 2 COO - , in which case n=2; or the anion is SO 4 2- , in which case n=1; wherein X,Y,Z are independently selected from O, OH, OH 2 , OC(R 3 )O, and R 4 BO 2 and wherein a and b are independently an integer of value 2, 3 or 4; R 1 =H, C1-C20 alkyl optionally substituted with heteroatoms, C6-C20 aryl optionally substituted with heteroatoms; R 2 = C1-C20 alkyl optionally substituted with heteroatoms, C6-C20 aryl optionally substituted with heteroatoms, or a polymeric residue; and R 3 = C1-C20 alkyl optionally substituted with heteroatoms, C6-C20 aryl optionally substituted with heteroatoms, or a polymeric residue. R 4 = C1-C20 alkyl optionally substituted with heteroatoms, or C6-C20 aryl optionally substituted with heteroatoms.
摘要翻译：一种空气干燥自氧化树脂组合物，其包含以下成分：a）包含锰盐络合物的干燥剂，和b）包含不饱和脂肪酸残基的聚合物，其中所述锰盐络合物具有以下结构I：其中所述阴离子选自Cl - ，NO 3 - 或R 2 COO-，在这种情况下n = 2; 或阴离子为SO4 2-，在这种情况下n = 1; 其中X，Y，Z独立地选自O，OH，OH2，OC（R3）O和R4BO2，并且其中a和b独立地是数值2,3或4的整数; R1 = H，任选被杂原子取代的C 1 -C 20烷基，任选被杂原子取代的C 6 -C 20芳基; R2 =任选被杂原子取代的C 1 -C 20烷基，任选被杂原子取代的C 6 -C 20芳基或聚合物残基; 和R3 =任选被杂原子取代的C 1 -C 20烷基，任选被杂原子取代的C 6 -C 20芳基或聚合物残基。 R4 =任选被杂原子取代的C 1 -C 20烷基，或任选被杂原子取代的C 6 -C 20芳基。

8. 发明申请

WO2011098583A1 MANGANESE COMPLEX DRIER FOR COATING COMPOSITIONS 审中-公开
标题翻译：用于涂料组合物的MANGANESE复合干燥剂
公开(公告)号：WO2011098583A1
公开(公告)日：2011-08-18
申请号：PCT/EP2011/052069
申请日：2011-02-11
申请人： DSM IP ASSETS B.V. , JANSEN, Johan Franz Gradus Antonius , KLEUSKENS, Engelina Catharina , SUMMEREN VAN, Ruben , ALSTERS, Paulus Lambertus
发明人： JANSEN, Johan Franz Gradus Antonius , KLEUSKENS, Engelina Catharina , SUMMEREN VAN, Ruben , ALSTERS, Paulus Lambertus
IPC分类号： C09D167/06 , C08G18/36 , C09D175/04
CPC分类号： C09D167/03 , C08G18/0804 , C09D7/63 , C09D167/06 , C09D175/14
摘要： Use of a transition metal complex a) as a drier for air drying auto-oxidative resin composition comprising a polymer b) comprising unsaturated fatty acid residues, wherein the transition metal complex a) has a cation of the following structure (I) wherein R=C1-C20 alkyl optionally substituted with heteroatoms, C6-C20 aryl optionally substituted with heteroatoms, or a polymeric residue; R 1 =H, C1-C20 alkyl optionally substituted with heteroatoms, C6-C20 aryl optionally substituted with heteroatoms; X=O, OC(R 2 )O in which a=4 when X=O, and a=3 when X= OC(R 2 )O, R 2 = C1-C20 alkyl optionally substituted with heteroatoms, C6-C20 aryl optionally substituted with heteroatoms, or a polymeric residue.
摘要翻译：使用过渡金属络合物a）作为用于空气干燥自动氧化树脂组合物的干燥器，其包含聚合物b）包含不饱和脂肪酸残基，其中过渡金属络合物a）具有以下结构（I）的阳离子，其中R = 任选被杂原子取代的C 1 -C 20烷基，任选被杂原子取代的C 6 -C 20芳基或聚合物残基; R1 = H，任选被杂原子取代的C 1 -C 20烷基，任选被杂原子取代的C 6 -C 20芳基; X = O，OC（R2）O，其中当X = O时a = 4，当X = OC（R2）O时，a = 3，R2 =任选被杂原子取代的C 1 -C 20烷基，杂原子或聚合物残基。

9. 发明申请

WO2007042175A1 PEROXIDE DECOMPOSITION CATALYST 审中-公开
标题翻译：过氧化物分解催化剂
公开(公告)号：WO2007042175A1
公开(公告)日：2007-04-19
申请号：PCT/EP2006/009572
申请日：2006-10-02
申请人： DSM IP ASSETS B.V. , JANSEN, Johan, Franz, Gradus, Antonius , KLEUSKENS, Engelina, Catharina , KRAEGER, Ivo, Ronald
发明人： JANSEN, Johan, Franz, Gradus, Antonius , KLEUSKENS, Engelina, Catharina , KRAEGER, Ivo, Ronald
IPC分类号： B01J27/20 , C07D317/04
CPC分类号： B01J27/20
摘要： This invention relates to a method for the catalytic decomposition of peroxides, wherein the peroxide is decomposed by means of one or more dioxo- compounds selected from the group of diketones, dialdehydes or ketoaldehydes having a calculated reduction energy (CRE) in the range of from -10 to -30 kcal/mole, the CRE being the energy difference in kcal/mole between the lowest energy conformations of the radical anion and the corresponding neutral molecule as calculated by means of the Turbomole Version 5 program. The present invention also relates to the formation of radicals by means of catalytic decomposition of peroxides using any of such dioxo-compounds. The radicals so formed can suitably be applied in any application selected from the group of radical polymerizations, grafting reactions, bleaching, drying of alkyds, epoxidation reactions, sterilization processes, and desinfection processes.
摘要翻译：本发明涉及一种催化分解过氧化物的方法，其中过氧化物通过一种或多种选自二酮，二醛或酮醛的二氧化合物分解，所述二酮，二醛或酮醛具有计算的还原能（CRE），范围为 -10至-30千卡/摩尔，CRE是通过Turbomol版本5程序计算的自由基阴离子和相应的中性分子的最低能量构象之间的kcal /摩尔的能量差。本发明还涉及通过使用任何这种二氧代化合物的过氧化物的催化分解来形成自由基。如此形成的基团可以适用于选自自由基聚合，接枝反应，漂白，醇酸树脂干燥，环氧化反应，灭菌工艺和脱盐工艺的任何应用。

10. 发明申请

WO2006100123A1 GEL TIME DRIFT-FREE RESIN COMPOSITIONS 审中-公开
标题翻译：凝胶时间免洗树脂组合物
公开(公告)号：WO2006100123A1
公开(公告)日：2006-09-28
申请号：PCT/EP2006/002987
申请日：2006-03-23
申请人： DSM IP ASSETS B.V. , JANSEN, Johan, Franz, Gradus, Antonius , KLEUSKENS, Engelina, Catharina , KRAEGER, Ivo, Ronald
发明人： JANSEN, Johan, Franz, Gradus, Antonius , KLEUSKENS, Engelina, Catharina , KRAEGER, Ivo, Ronald
IPC分类号： C08K5/07 , C08L67/06 , C08L67/07 , C08L63/10 , C08K3/22 , C08K3/24 , C08K3/26 , C08K5/05 , C08K5/098 , C08K5/17 , C08F290/06 , C08F290/14 , C08F4/40
CPC分类号： C08K5/07 , C08F283/01 , C08F290/06 , C08F290/061 , C08F290/064 , C08F290/14 , C08F290/141 , C08F290/144 , C08K5/14 , C08L67/06
摘要： The present invention relates to unsaturated polyester resin or vinyl ester resin compositions; that are curable with a peroxide component; and that, comprise a salt and/or a base, a polymer containing reactive unsaturations, optionally a reactive diluent, and a dioxo-component; which compositions are essentially free of cobalt; and contain either as the salt an organic or inorganic salt of which the cation has a redox potential of the metal of at most -1 V, or is an ammonium ion; and/or as the base either an inorganic base of which the cation has a redox potential of the metal of at most -1 V, or a nitrogen containing organic compound; and in which the dioxo-component consists of one or more dioxo-compounds having a calculated reduction energy (CRE), being the energy difference in kcal/mole between the lowest energy conformations of the radical anion and the corresponding neutral molecule as calculated by means of the Turbomole Version 5 program, in the range of from -5 to -30 kcal/mole. These resin compositions show a reduced gel-time drift tendency. Moreover, it has been found that gel-time of these resin compositions can be easily and favorably adjusted by varying the amount of base. The present invention further also relates to objects and structural parts prepared from such unsaturated polyester or vinyl ester resin compositions by curing with a peroxide. The present invention finally also relates to methods of peroxide curing of unsaturated polyester resin or vinyl ester resin compositions.
摘要翻译：本发明涉及不饱和聚酯树脂或乙烯基酯树脂组合物; 可用过氧化物组分固化; 并且其包含盐和/或碱，含有反应性不饱和的聚合物，任选的反应性稀释剂和二氧代组分; 该组合物基本上不含钴; 并且含有作为盐的有机或无机盐，其阳离子的金属氧化还原电位至多为-1V，或者是铵离子; 和/或作为碱，其阳离子的金属氧化还原电位至多为-1V的无机碱或含氮有机化合物; 并且其中二氧代组分由具有计算的还原能（CRE）的一种或多种二氧代化合物组成，其为通过手段计算的自由基阴离子和相应的中性分子的最低能量构象之间的kcal /摩尔的能量差的Turbomol版本5程序，范围为-5至-30千卡/摩尔。这些树脂组合物显示出降低的凝胶时间漂移趋势。此外，已经发现通过改变碱的量可以容易且有利地调节这些树脂组合物的凝胶时间。本发明还涉及通过用过氧化物固化由这种不饱和聚酯或乙烯基酯树脂组合物制备的物体和结构部件。本发明最终还涉及不饱和聚酯树脂或乙烯基酯树脂组合物的过氧化物固化方法。

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