基本信息:
- 专利标题: METATHESIS CROSSLINKABLE COATING COMPOSITIONS
- 专利标题(中):METATHESIS可交联涂料组合物
- 申请号:PCT/EP2011/056745 申请日:2011-04-28
- 公开(公告)号:WO2011135029A1 公开(公告)日:2011-11-03
- 发明人: JANSEN, Johan, Franz, Gradus, Antonius , PANELLA, Lavinia , KLEUSKENS, Engelina, Catharina , BENTHEM, VAN, Rudolfus, Antonius, Theodorus, Maria
- 申请人: DSM IP ASSETS B.V. , JANSEN, Johan, Franz, Gradus, Antonius , PANELLA, Lavinia , KLEUSKENS, Engelina, Catharina , BENTHEM, VAN, Rudolfus, Antonius, Theodorus, Maria
- 申请人地址: Het Overloon 1 NL-6411 TE Heerlen NL
- 专利权人: DSM IP ASSETS B.V.,JANSEN, Johan, Franz, Gradus, Antonius,PANELLA, Lavinia,KLEUSKENS, Engelina, Catharina,BENTHEM, VAN, Rudolfus, Antonius, Theodorus, Maria
- 当前专利权人: DSM IP ASSETS B.V.,JANSEN, Johan, Franz, Gradus, Antonius,PANELLA, Lavinia,KLEUSKENS, Engelina, Catharina,BENTHEM, VAN, Rudolfus, Antonius, Theodorus, Maria
- 当前专利权人地址: Het Overloon 1 NL-6411 TE Heerlen NL
- 代理机构: SCHMITT, Maja
- 优先权: EP10161309.9 20100428
- 主分类号: B01J23/46
- IPC分类号: B01J23/46 ; C08G61/06 ; C08K5/56
摘要:
The invention relates to a metathesis crosslinkable binder composition comprising: i) at least one polymer comprising non-aromatic C=C double bonds, the polymer comprising an average of at least 4 unsaturated fatty acid residues per polymer chain, wherein at least one of the fatty acid residues has from C18 to C26 carbon atoms; and ii) at least a transition metal based metathesis catalyst according to formula (I) wherein L 1 is a neutral amine containing electron donor ligand; L 2 is an optional neutral electron donor ligand; X 1 , X 2 are independently from each other an anionic ligand; a, b in (X 1 ) a and (X 2 ) b of formula (I) are independently from each other an integer from 0 to 4; R is selected from the group consisting of linear or branched alkyl, cycloalkyl, aralkyl, aryl or their substituted equivalents; Ra is selected from the group consisting of hydrogen, linear or branched alkyl, cycloalkyl, aralkyl, aryl, or their substituted equivalents; M is a transition metal selected from the group consisting of Ruthenium (Ru), Manganese (Mn), Osmium (Os), Tungsten (W) and Molybdenum (Mo); wherein two or more of any of L 1 , L 2 , X 1 , X 2 , R and/or Ra are optionally covalently linked together to form one or more cyclic groups, and wherein two or more of any of L 1 , L 2 , X 1 , X 2 , R and/or Ra are optionally attached to a support.
摘要(中):
本发明涉及易位可交联粘合剂组合物,其包含:i)至少一种包含非芳族C = C双键的聚合物,所述聚合物包含每个聚合物链平均至少4个不饱和脂肪酸残基,其中至少一个 脂肪酸残基具有C18至C26碳原子; 和ii)至少一种根据式(I)的基于过渡金属的复分解催化剂,其中L1是含中性胺的电子给体配体; L2是任选的中性电子给体配体; X1,X2彼此独立地为阴离子配体; 式(I)的(X1)a和(X2)b中的a,b彼此独立地为0至4的整数; R选自直链或支链烷基,环烷基,芳烷基,芳基或其取代的等价物; R a选自氢,直链或支链烷基,环烷基,芳烷基,芳基或其取代的等价物; M是选自钌(Ru),锰(Mn),锇(Os),钨(W)和钼(Mo))的过渡金属; 其中L1,L2,X1,X2,R和/或Ra中的任意一个中的两个或更多个任选地共价连接在一起形成一个或多个环状基团,并且其中L1,L2,X1,X2,R 和/或Ra任选地连接到载体上。
IPC结构图谱:
B | 作业;运输 |
--B01 | 一般的物理或化学的方法或装置 |
----B01J | 化学或物理方法,例如,催化作用、胶体化学;其有关设备 |
------B01J23/00 | 不包含在B01J21/00组中的,包含金属或金属氧化物或氢氧化物的催化剂 |
--------B01J23/16 | .砷、锑、铋、钒、铌、钽、钋、铬、钼、钨、锰、锝或铼的 |
----------B01J23/40 | ..铂系金属的 |
------------B01J23/46 | ...钌、铑、锇或铱 |