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1. 发明申请

WO2013032977A1 HEAT-RESISTANT LIQUID CRYSTALLINE POLYMER COMPOSITION HAVING A LOW MELTING TEMPERATURE 审中-公开
标题翻译：具有低熔点温度的耐热液晶聚合物组合物
公开(公告)号：WO2013032977A1
公开(公告)日：2013-03-07
申请号：PCT/US2012/052442
申请日：2012-08-27
申请人： TICONA LLC , GRAY, Steven, D. , NAIR, Kamlesh, P. , GRENCI, Joseph, J.
发明人： GRAY, Steven, D. , NAIR, Kamlesh, P. , GRENCI, Joseph, J.
IPC分类号： C08K5/20 , C09K19/22 , C09K19/30 , C09K19/32 , C09K19/34 , C09K19/48
CPC分类号： C09K19/22 , C09K19/3086 , C09K19/322 , C09K19/3444 , C09K19/48 , C09K2019/0481
摘要： A thermotropic liquid crystalline polymer composition capable of exhibiting both a low melting temperature and good heat resistance without the use of conventional naphthenic acids is provided. The melting temperature may, for example, range from about 250°C to about 400°C. Even at such low melting temperatures, the present inventors have surprisingly discovered that the ratio of the deflection temperature under load ("DTUL"), a measure of short term heat resistance, to the melting temperature may remain relatively high. The specific DTUL values may range from about 200°C to about 300°C. The ability to form a polymer composition with the properties noted above may be achieved, at least in part, by the use of an aromatic amide oligomer.
摘要翻译：本发明提供能够在不使用常规环烷酸的情况下显示低熔点和良好耐热性的热致液晶聚合物组合物。熔融温度例如可以在约250℃至约400℃的范围内。即使在这样低的熔融温度下，本发明人惊奇地发现，负载下的挠曲温度（“DTUL”）与短期耐热性的测量值与熔融温度的比值可能保持相对较高。特定的DTUL值可以在约200℃至约300℃的范围内。形成具有上述性质的聚合物组合物的能力可以至少部分地通过使用芳族酰胺低聚物来实现。

2. 发明申请

WO2013032967A1 CAST MOLDED PARTS FORMED FORM A LIQUID CRYSTALLINE POLYMER 审中-公开
标题翻译： CAST模制部件形成液晶聚合物
公开(公告)号：WO2013032967A1
公开(公告)日：2013-03-07
申请号：PCT/US2012/052429
申请日：2012-08-27
申请人： TICONA LLC , NAIR, Kamlesh, P. , GRAY, Steven, D. , GRENCI, Joseph, J.
发明人： NAIR, Kamlesh, P. , GRAY, Steven, D. , GRENCI, Joseph, J.
IPC分类号： C09K19/22 , C09K19/30 , C09K19/32 , C09K19/34 , C09K19/48 , C08K5/20
CPC分类号： C09K19/54 , B29C39/006 , C08K5/20 , C08K5/34922 , C08L77/12 , C09K19/22 , C09K19/3086 , C09K19/322 , C09K19/3444 , C09K19/48 , C09K2019/0481
摘要： A molded part having a predetermined shape is provided. The molded part may be formed by casting a liquid crystalline polymer composition into a mold cavity at a relatively low shear rate. Due to the use of a relatively low shear rate, the polymer composition does not generally undergo extensive shear orientation, which can allow the resulting part to be further processed using standard finishing techniques. Low shear casting can also inhibit shear-induced molecular alignment, which can translate into a part having generally isotropic mechanical properties. The ability to use relatively low shear rates during casting is achieved in the present invention through the use of an aromatic amide oligomer. More particularly, the present inventors have discovered that the aromatic amide oligomer can serve as a flow aid by altering intermolecular polymer chain interactions, thereby lowering the overall viscosity of the polymer matrix to "ultralow" levels without having a significant impact on the mechanical properties. Among other things, such an ultralow viscosity can allow the composition to more readily flow into the cavity of a mold without requiring an extensive amount of shear.
摘要翻译：提供具有预定形状的模制件。模制部件可以通过将液晶聚合物组合物以相对低的剪切速率浇铸到模腔中而形成。由于使用相对低的剪切速率，聚合物组合物通常不经受广泛的剪切取向，这可以允许使用标准精整技术进一步处理所得到的部分。低剪切铸造也可以抑制剪切诱导的分子对准，其可以转化为具有大体各向同性机械性能的部分。在本发明中通过使用芳族酰胺低聚物实现了在铸造过程中使用相对低的剪切速率的能力。更具体地，本发明人已经发现，通过改变分子间聚合物链相互作用，芳族酰胺低聚物可以用作流动助剂，从而将聚合物基质的总体粘度降低到“超低”水平，而对机械性能没有显着的影响。除此之外，这种超低粘度可以允许组合物更容易地流入模具的空腔中，而不需要大量的剪切。

3. 发明申请

WO2009058930A1 METHODS FOR IMPROVING HEAT TRANSFER IN POLYMERIZATION PROCESSES 审中-公开
标题翻译：改进聚合工艺中热传递的方法
公开(公告)号：WO2009058930A1
公开(公告)日：2009-05-07
申请号：PCT/US2008/081683
申请日：2008-10-30
申请人： FINA TECHNOLOGY, INC. , KNOEPPEL, David, W. , NITZ, Steve , GRAY, Steven, D.
发明人： KNOEPPEL, David, W. , NITZ, Steve , GRAY, Steven, D.
IPC分类号： C08F2/00
CPC分类号： C08F10/02 , C08F110/02 , C08F2/14 , C08F2/00 , C08F2500/23 , C08F2500/02 , C08F2500/12 , C08F2500/05 , C08F2500/24
摘要： Methods for improving heat transfer in polymerization processes are described herein. The methods generally include contacting olefin monomer with a catalyst system within a reaction zone to form particles having a first average particle size and altering the reaction zone to improve heat transfer and form polymer particles having a second average particle size. For example, the second average particle size may be larger than the first average particle size and the second particle size results in improved heat transfer over the first particle size.
摘要翻译：本文描述了改善聚合方法中热传递的方法。所述方法通常包括使烯烃单体与反应区内的催化剂体系接触以形成具有第一平均粒径并改变反应区以改善热传递并形成具有第二平均粒度的聚合物颗粒的颗粒。例如，第二平均粒径可以大于第一平均粒径，第二粒径导致在第一粒径上的热传递改善。

4. 发明申请

WO2013032976A1 HIGH FLOW LIQUID CRYSTALLINE POLYMER COMPOSITION 审中-公开
标题翻译：高流动性液晶聚合物组合物
公开(公告)号：WO2013032976A1
公开(公告)日：2013-03-07
申请号：PCT/US2012/052439
申请日：2012-08-27
申请人： TICONA LLC , NAIR, Kamlesh P. , GRENCI, Joseph J. , GRAY, Steven D.
发明人： NAIR, Kamlesh P. , GRENCI, Joseph J. , GRAY, Steven D.
IPC分类号： C09K19/22 , C09K19/30 , C09K19/32 , C09K19/34 , C09K19/38 , C09K19/48
CPC分类号： C09K19/22 , C08L77/12 , C09K19/3086 , C09K19/322 , C09K19/3444 , C09K19/3809 , C09K19/48 , C09K2019/0481
摘要： A liquid crystalline polymer composition that contains a liquid crystalline polymer and an aromatic amide oligomer is provided. The oligomer can serve as a flow aid by altering intermolecular polymer chain interactions, thereby lowering the overall viscosity of the polymer matrix under shear. The oligomer is also not easily volatized or decomposed during compounding, molding, and/or use, which minimizes off-gassing and the formation of blisters that would otherwise impact the final mechanical properties of a part made from the polymer composition. While providing the benefits noted, the aromatic amide oligomer does not generally react with the polymer backbone of the liquid crystalline polymer to any appreciable extent so that the mechanical properties of the polymer are not adversely impacted.
摘要翻译：提供了包含液晶聚合物和芳族酰胺低聚物的液晶聚合物组合物。该低聚物可以通过改变分子间聚合物链相互作用而起流动助剂的作用，从而降低剪切下聚合物基质的总体粘度。低聚物在配混，成型和/或使用过程中也不容易挥发或分解，这最大限度地减少了废气和泡罩的形成，否则这些泡罩会影响由聚合物组合物制成的部件的最终机械性能。虽然提供了所提到的益处，但芳族酰胺低聚物通常不会与液晶聚合物的聚合物骨架发生任何明显程度的反应，从而不会不利地影响聚合物的机械性能。

5. 发明申请

WO2009091730A1 PROCESS FOR THE PRODUCTION OF POLYETHYLENE RESIN 审中-公开
标题翻译：聚乙烯树脂生产工艺
公开(公告)号：WO2009091730A1
公开(公告)日：2009-07-23
申请号：PCT/US2009/030843
申请日：2009-01-13
申请人： FINA TECHNOLOGY, INC. , GUENTHER, Gerhard, K. , GRAY, Steven, D. , COFFY, Tim, J.
发明人： GUENTHER, Gerhard, K. , GRAY, Steven, D. , COFFY, Tim, J.
IPC分类号： C08F2/01
CPC分类号： C08F210/16 , C08F110/02 , C08F2/001 , C08F2/00 , C08F2500/02 , C08F210/14 , C08F2500/01
摘要： Process for the polymerization of ethylene to produce a polymer of enhanced long chain branching. Ethylene and hydrogen are introduced into a first reaction zone to produce an ethylene polymer having a first molecular weight distribution. The polymer from the first reaction zone is applied to a second reaction zone along with ethylene and a C 3 -C 8 alpha- olefin monomer. The second reaction zone is operated to produce a copolymer having a second molecular weight distribution different from the first molecular weight distribution. A polymer fluff of bimodal molecular weight distribution is recovered from the second reaction zone and heated to melt the fluff and then extruded. Concomitantly with the heating and or extrusion, the polymer fluff is treated in order to enhance the long chain branching and reduce the melt index MI 5 of the polymer product.
摘要翻译：乙烯聚合制备增强长链支化聚合物的方法。将乙烯和氢气引入第一反应区以产生具有第一分子量分布的乙烯聚合物。来自第一反应区的聚合物与乙烯和C 3 -C 8α-烯烃单体一起施加到第二反应区。操作第二反应区以产生具有不同于第一分子量分布的第二分子量分布的共聚物。从第二反应区回收双峰分子量分布的聚合物绒毛，并加热熔化绒毛然后挤出。伴随着加热和/或挤出，处理聚合物绒毛以增强长链支化并降低聚合物产物的熔体指数MI5。

6. 发明申请

WO2005000402A2 ANTI-ADHESION COMPOSITES AND METHODS OS USE THEREOF 审中-公开
标题翻译：抗粘连复合材料及其使用方法
公开(公告)号：WO2005000402A2
公开(公告)日：2005-01-06
申请号：PCT/US2004014965
申请日：2004-05-13
申请人： UNIV UTAH RES FOUND , PRESTWICH GLENN D , KIRKER KELLY R , GRAY STEVEN D , SHU XIAO ZHENG , LI HAO , LIU YANCHUN
发明人： PRESTWICH GLENN D , KIRKER KELLY R , GRAY STEVEN D , SHU XIAO ZHENG , LI HAO , LIU YANCHUN
IPC分类号： A61K31/00 , A61P20060101 , A61P1/00 , A61P
CPC分类号： A61K45/06 , A61K31/717 , A61K31/728 , A61L27/34 , A61L27/54 , A61L2300/236 , A61L2300/414 , A61L2300/416 , A61L2300/424 , A61L2300/432 , A61L2300/45 , A61K2300/00
摘要： Described herein are composites that inhibit or reduce adhesion between two or more tissues. Also described herein are methods of using the composites.
摘要翻译：这里描述的是抑制或减少两个或更多个组织之间的粘附的复合材料。本文还描述了使用复合材料的方法。

7. 发明申请

WO2013032978A1 METHOD FOR MINIMIZING PROCESS DISRUPTIONS DURING FORMATION OF A LIQUID CRYSTALLINE POLYMER 审中-公开
标题翻译：在形成液晶聚合物过程中最小化工艺破坏的方法
公开(公告)号：WO2013032978A1
公开(公告)日：2013-03-07
申请号：PCT/US2012/052443
申请日：2012-08-27
申请人： TICONA LLC , NAIR, Kamlesh, P. , GRAY, Steven, D.
发明人： NAIR, Kamlesh, P. , GRAY, Steven, D.
IPC分类号： C08K5/20 , C09K19/22 , C09K19/30 , C09K19/32 , C09K19/34 , C09K19/48
CPC分类号： C09K19/22 , C08K5/20 , C09K19/3086 , C09K19/322 , C09K19/3444 , C09K19/48 , C09K2019/0481 , C08L67/03
摘要： A method for lowering melt viscosity of a liquid crystalline polymer as it is formed in a reactor vessel. More particularly, a reaction mixture is initially supplied to the reactor vessel that contains two or more precursor monomers (e.g., acetylated or non-acetylated). The reaction mixture is heated to an elevated temperature under agitation to initiate formation of the polymer. After a certain period of time, an aromatic amide oligomer is added to the reaction mixture. Among other things, the present inventors have discovered that such an oligomer can serve as a flow aid by altering intermolecular polymer chain interactions, thereby lowering the overall viscosity of the polymer matrix under shear. This minimizes the likelihood of "freeze off" of the polymer within the reactor vessel and limits the impact of process disruptions on the production of the liquid crystalline polymer. Another benefit of the oligomer is that it is not easily volatized or decomposed. This allows the oligomer to be added to the reaction mixture while it is still at relatively high temperatures. While providing the benefits noted, the aromatic amide oligomer does not generally react with the polymer backbone of the liquid crystalline polymer to any appreciable extent so that the mechanical properties of the polymer are not adversely impacted.
摘要翻译：液晶聚合物在反应器容器中形成时的熔融粘度降低的方法。更具体地，反应混合物最初被供应到含有两种或更多种前体单体（例如乙酰化或非乙酰化）的反应器容器中。在搅拌下将反应混合物加热至高温以引发聚合物的形成。经过一段时间后，向反应混合物中加入芳香族酰胺低聚物。其中，本发明人发现，通过改变分子间聚合物链的相互作用，这样的低聚物可以作为流动助剂，从而降低聚合物基体在剪切下的总粘度。这使得反应器容器内的聚合物“冻结”的可能性最小化，并限制了工艺中断对液晶聚合物生产的影响。低聚物的另一个好处是它不容易挥发或分解。这使得当反应混合物仍处于相对高的温度下时，可将其加入反应混合物中。在提供所提及的优点的同时，芳族酰胺低聚物通常不会与液晶聚合物的聚合物主链反应任何明显的程度，使得聚合物的机械性能不会受到不利影响。

8. 发明申请

WO2013032973A1 AROMATIC AMIDE COMPOUND 审中-公开
标题翻译：芳香酰胺化合物
公开(公告)号：WO2013032973A1
公开(公告)日：2013-03-07
申请号：PCT/US2012/052436
申请日：2012-08-27
申请人： TICONA LLC , NAIR, Kamlesh, P. , GRAY, Steven, D.
发明人： NAIR, Kamlesh, P. , GRAY, Steven, D.
IPC分类号： C07C233/80 , C08G69/00
CPC分类号： C07C233/80 , C07C231/02 , C08K5/20 , C08L77/12 , C09K19/22 , C09K19/38 , C09K19/54 , C09K2019/0481
摘要： An aromatic amide compound having the following general formula (I) is provided: wherein, X 1 and X 2 are independently C(O)HN or NHC(O); G 1 , G 2 and G 3 are independently hydrogen, C(O)HN-phenyl, or NHC(O)-phenyl, wherein at least one of G 1 , G 2 and G 3 is C(O)HN-phenyl or NHC(O)-phenyl; Q 1 , Q 2 , and Q 3 are independently hydrogen, C(O)HN-phenyl, or NHC(O)-phenyl, wherein at least one of Q 1 , Q 2 , and Q 3 is C(O)HN-phenyl or NHC(O)-phenyl; R 5 is halo, haloalkyl, alkyl, alkenyl, aryl, heteroaryl, cycloalkyl, or heterocyclyl; and m is from 0 to 4.
摘要翻译：提供具有以下通式（I）的芳族酰胺化合物：其中，X 1和X 2独立地为C（O）HN或NHC（O）; G1，G2和G3独立地是氢，C（O）HN-苯基或NHC（O） - 苯基，其中G1，G2和G3中的至少一个是C（O）HN-苯基或NHC（O） ; Q1，Q2和Q3独立地为氢，C（O）HN-苯基或NHC（O） - 苯基，其中Q1，Q2和Q3中的至少一个为C（O）HN-苯基或NHC（O） - 苯基; R5是卤素，卤代烷基，烷基，烯基，芳基，杂芳基，环烷基或杂环基; m为0〜4。

9. 发明申请

WO2009097398A1 POLYETHYLENE MATERIALS PREPARED USING MIXED ZIEGLER-NATTA CATALYST SYSTEMS 审中-公开
标题翻译：使用混合的ZIEGLER-NATTA催化剂体系制备的聚乙烯材料
公开(公告)号：WO2009097398A1
公开(公告)日：2009-08-06
申请号：PCT/US2009/032386
申请日：2009-01-29
申请人： FINA TECHNOLOGY, INC. , BARRE, Vincent , VIZZINI, Kayo , GRAY, Steven, D.
发明人： BARRE, Vincent , VIZZINI, Kayo , GRAY, Steven, D.
IPC分类号： B01J31/00
CPC分类号： C08F110/02 , C08F10/00 , C08F2410/04 , Y02P20/52 , Y10T428/139 , C08F2/00 , C08F4/6546 , C08F4/025 , C08F4/022 , C08F4/6557 , C08F2500/18 , C08F2500/12
摘要： A polyethylene may be prepared using a mixture of a silica supported catalyst and a magnesium chloride supported catalyst. By changing the ratio of the two catalysts, the polyethylene produced may have a varying bulk density and shear response. The method allows for the tuning or targeting of properties to fit a specific application, such as a blow molding or vapor barrier film.
摘要翻译：可以使用二氧化硅负载的催化剂和负载氯化镁的催化剂的混合物制备聚乙烯。通过改变两种催化剂的比例，所生产的聚乙烯可能具有变化的体积密度和剪切响应。该方法允许调整或定位特性以适应特定应用，例如吹塑或蒸气阻隔膜。

10. 发明申请

WO2006065714A2 DIKETONATE COMPLEX-DERIVED CATALYSTS USEFUL FOR PREPARING POLYOLEFINS 审中-公开
标题翻译：用于制备聚烯烃的二酮复合衍生催化剂
公开(公告)号：WO2006065714A2
公开(公告)日：2006-06-22
申请号：PCT/US2005/044827
申请日：2005-12-12
申请人： FINA TECHNOLOGY, INC. , COFFY, Tim, J. , GRAY, Steven, D.
发明人： COFFY, Tim, J. , GRAY, Steven, D.
IPC分类号： C08F4/44 , B01J31/00 , C07F7/28
CPC分类号： C08F10/00 , C07C45/77 , C07C49/92 , C07F3/003 , C08F110/02 , C08F4/651 , C08F4/6557 , C08F4/6548 , C08F2500/18 , C08F2500/12 , C08F2500/24 , C08F2500/07
摘要： An olefin polymerization catalyst may be prepared using a process including contacting a metal compound of the formula M(OR 1 ) 2 with a diketone to form a catalyst precursor having the general formula (I) or (II) wherein M is a Group IIA metal; O is oxygen; n = 1 or 2; R 1 , R 2 , R 3 , and R 4 are the same or different; and are a hydrogen or a substituted or unsubstituted alkyl or aryl moiety having from about 1 to about 20 carbons atoms.
摘要翻译：烯烃聚合催化剂可以使用包括使式M（OR 1）2 N 2的金属化合物与二酮接触以形成具有通式（I）或（II）其中M是IIA族金属; O是氧; n = 1或2; R 1，R 2，R 3和R 4相同或不同; R 1，R 2，R 3和R 4相同或不同; 并且是具有约1至约20个碳原子的氢或取代或未取代的烷基或芳基部分。

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