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    • 3. 发明申请
    • IMPROVED PROCESS FOR THE SOLVENT-BASED EXTRACTION OF POLYHYDROXYALKANOATES FROM BIOMASS
    • 用于从生物量中溶剂萃取聚羟基烷基酯的改进方法
    • WO2006004895A1
    • 2006-01-12
    • PCT/US2005/023221
    • 2005-06-29
    • THE PROCTER & GAMBLE COMPANYNARASIMHAN, KarunakaranCEARLEY, Angella, C.GIBSON, Michael, StevenWELLING, Stanley, James
    • NARASIMHAN, KarunakaranCEARLEY, Angella, C.GIBSON, Michael, StevenWELLING, Stanley, James
    • C08G63/89
    • B01D11/0288C08G63/06C08G63/89
    • Improved processes for extracting polyhydroxyalkanoate from a biomass containing the polyhydroxyalkanoate including the steps of: combining the biomass containing the polyhydroxyalkanoate with a solvent selected from lower chain ketones, and mixtures thereof to form a biomass liquor wherein the biomass liquor comprises less than about 25% water; mixing the biomass liquor for from about 10 to about 300 minutes at a temperature in the range of from about 70° C to about 120 °C; separating the polyhydroxyalkanoate from the biomass liquor to form a PHA-enriched liquor, wherein the separating occurs at a temperature of at least about 40°C; mixing the PHA-enriched liquor with water to form precipitated polyhydroxyalkanoate and an impure solvent liquor, wherein the water is mixed with the PHA-enriched liquor in the ratio of from at least least 3 parts water to one part polyhydroxyalkanoate; and recovering the precipitated polyhydroxyalkanoate from the impure solvent liquor. Optional treatment with oxidizing agents or mild surfactant or mild bleach is used to enhance color and odor.
    • 用于从含有聚羟基链烷酸酯的生物质提取聚羟基链烷酸酯的改进方法包括以下步骤:将含有聚羟基链烷酸酯的生物质与选自下链酮的溶剂及其混合物组合以形成生物质液体,其中生物质液体包含小于约25%的水 ; 在约70℃至约120℃的温度范围内将生物质液体混合约10至约300分钟; 从生物质液体中分离聚羟基链烷酸酯以形成富含PHA的液体,其中分离在至少约40℃的温度下进行; 将富含PHA的液体与水混合以形成沉淀的聚羟基链烷酸酯和不纯的溶剂液体,其中水与富含PHA的液体以至少3份水与1份聚羟基链烷酸酯的比例混合; 并从不纯的溶剂液中回收沉淀的聚羟基链烷酸酯。 使用氧化剂或温和表面活性剂或温和漂白剂进行任选处理以增强颜色和气味。