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    • 8. 发明申请
    • PHOTOVOLTAIC DEVICE WITH TRANSPARENT TUNNEL JUNCTION
    • 带透明隧道结的光伏设备
    • WO2018071509A1
    • 2018-04-19
    • PCT/US2017/056092
    • 2017-10-11
    • FIRST SOLAR, INC.
    • GLOECKLER, MarkusMEI, FangZHANG, Wei
    • H01L31/0224H01L31/0725H01L31/073
    • A photovoltaic device includes a substrate, a semiconductor stack and a transparent tunnel junction. The semiconductor stack includes an n-type layer selected from a first transparent conductive oxide layer, or a window layer, or both; and a p-type absorber layer disposed on the n-type layer, wherein the absorber layer consists essentially of CdSexTe(1-x), wherein x is from 1 to about 40 at. %. The transparent tunnel junction comprises a transparent interface layer of Cd y Zn (1-y) Te doped to be p+type, and a transparent contact layer doped to be n+type, and the interface layer is disposed between the p-type absorber layer and the transparent contact layer. In bifacial embodiments, the tunnel junction forms a transparent back contact and electrode; and in multi-junction embodiments, the tunnel junction forms a diode-like connector between top and bottom cells. The transparent contact layer may comprise tin oxide or zinc oxide doped with aluminum, fluorine or indium. The photovoltaic device may also include an electron reflector layer and/or an optical reflector layer.
    • 光伏器件包括衬底,半导体堆叠和透明隧道结。 该半导体堆叠包括选自第一透明导电氧化物层或窗口层或两者的n型层; 以及设置在所述n型层上的p型吸收层,其中所述吸收层基本上由CdSexTe(1-x)组成,其中x为1至约40at。 %。 透明隧道结包括掺杂为p +型的Cd y Zn(1-y)Te的透明界面层和掺杂为n + 型,并且界面层设置在p型吸收层和透明接触层之间。 在双面实施例中,隧道结形成透明背接触和电极; 并且在多结实施例中,隧道结在顶部和底部单元之间形成二极管状连接器。 透明接触层可以包含掺杂有铝,氟或铟的氧化锡或氧化锌。 光伏器件还可以包括电子反射层和/或光反射层。