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    • 2. 发明申请
    • METHODS FOR PREPARING RUTHENIUM CARBENE COMPLEX PRECURSORS AND RUTHENIUM CARBENE COMPLEXES
    • 制备碳酸亚铜复合前体和碳酸亚丁酯复合物的方法
    • WO2013055644A3
    • 2013-07-25
    • PCT/US2012059280
    • 2012-10-09
    • ELEVANCE RENEWABLE SCIENCESKUNZ LINDA ACOHEN STEVEN ALUETKENS MELVIN L
    • KUNZ LINDA ACOHEN STEVEN ALUETKENS MELVIN L
    • C07F15/00
    • C07F15/0053C07F15/0046
    • A method for preparing a ruthenium carbene complex precursor includes reacting a ruthenium refinery salt with a hydrogen halide to form a ruthenium intermediate, and reacting the ruthenium intermediate with an L-type ligand to form the ruthenium carbene complex precursor. A method for preparing a ruthenium vinylcarbene complex includes converting a ruthenium carbene complex precursor into a ruthenium hydrido halide complex, and reacting the ruthenium hydrido halide complex with a propargyl halide to form the ruthenium carbene complex. A method for preparing a ruthenium carbene complex includes converting a ruthenium carbene complex precursor into a ruthenium carbene complex having a structure (PR1 R2R3)2CI2Ru=CH-R4, wherein R1, R2, R3, and R4 are alike or different, and wherein covalent bonds may optionally exist between two or more of R1, R2, and R3 and/or two of R1, R2, and R3 taken together may optionally form a ring with phosphorous.
    • 制备钌卡宾络合物前体的方法包括使钌精炼盐与卤化氢反应形成钌中间体,并使钌中间体与L型配体反应形成钌卡宾络合物前体。 制备钌乙烯基卡巴因络合物的方法包括将钌卡宾络合物前体转化为卤化钌卤化物络合物,并将钌卤化物络合物与炔丙基卤反应形成钌卡宾络合物。 制备钌卡宾络合物的方法包括将钌卡宾络合物前体转化成具有结构(PR 1 R 2 R 3)2 Cl 2 R u = CH-R 4的钌卡宾络合物,其中R 1,R 2,R 3和R 4相同或不同,并且其中共价 键可以任选地存在于R 1,R 2和R 3中的两个或多个之间,和/或R 1,R 2和R 3中的两个可以任选地与磷形成环。
    • 3. 发明申请
    • METHODS FOR PREPARING RUTHENIUM CARBENE COMPLEX PRECURSORS AND RUTHENIUM CARBENE COMPLEXES
    • 制备钌碳配合物前体和钌碳配合物的方法
    • WO2013055644A2
    • 2013-04-18
    • PCT/US2012/059280
    • 2012-10-09
    • ELEVANCE RENEWABLE SCIENCES, INC.KUNZ, Linda, A.COHEN, Steven, A.LUETKENS, Melvin, L.
    • KUNZ, Linda, A.COHEN, Steven, A.LUETKENS, Melvin, L.
    • C07F15/00
    • C07F15/0053C07F15/0046
    • A method for preparing a ruthenium carbene complex precursor includes reacting a ruthenium refinery salt with a hydrogen halide to form a ruthenium intermediate, and reacting the ruthenium intermediate with an L-type ligand to form the ruthenium carbene complex precursor. A method for preparing a ruthenium vinylcarbene complex includes converting a ruthenium carbene complex precursor into a ruthenium hydrido halide complex, and reacting the ruthenium hydrido halide complex with a propargyl halide to form the ruthenium carbene complex. A method for preparing a ruthenium carbene complex includes converting a ruthenium carbene complex precursor into a ruthenium carbene complex having a structure (PR 1 R 2 R 3 ) 2 CI 2 Ru=CH-R 4 , wherein R 1 , R 2 , R 3 , and R 4 are alike or different, and wherein covalent bonds may optionally exist between two or more of R 1 , R 2 , and R 3 and/or two of R 1 , R 2 , and R 3 taken together may optionally form a ring with phosphorous.
    • 用于制备钌卡宾络合物前体的方法包括使钌精炼盐与卤化氢反应以形成钌中间体,并且使钌中间体与L型配体反应以形成钌卡宾络合物 前体。 用于制备钌乙烯基卡宾络合物的方法包括将钌卡宾络合物前体转化为氢卤化钌络合物,并使钌氢卤化物络合物与炔丙基卤化物反应以形成钌卡宾络合物。 用于制备钌卡宾络合物的方法包括将钌卡宾络合物前体转化为具有结构(PR 1 R 2 R 3 3)的钌卡宾络合物, 其中R 1,R 2,R 4,R 4,R 4,R 4,R 4, R 3和R 4相同或不同,并且其中共价键可以任选地存在于两个或多个R 1和R 2之间, ,R 2和R 3和/或R 1,R 2和R sup中的两个 > 3一起可以任选地与磷形成环。