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    • 1. 发明申请
    • PROCESS AND APPARATUS FOR THE POLYMERISATION OF OLEFINS
    • 烯烃聚合的方法和装置
    • WO2012084628A1
    • 2012-06-28
    • PCT/EP2011/072701
    • 2011-12-14
    • INEOS COMMERCIAL SERVICES UK LIMITEDBELL, Andrew DavidCHAMAYOU, Jean-LouisRAMSAY, Kevin Peter
    • BELL, Andrew DavidCHAMAYOU, Jean-LouisRAMSAY, Kevin Peter
    • C08F10/00C08F2/34
    • C08F10/00C08F2/34C08F110/02C08F2/007
    • The present invention relates to a process for the gas-phase polymerisation of olefins in a fluidised bed reactor, which process comprises: a) passing a fluidising gas comprising one or more olefin monomers through a fluidised bed of polymer particles in the presence of a polymerisation catalyst. b) withdrawing a first gaseous stream comprising solid particles from the top of the reactor, c) passing the first gaseous stream to a gas/solids separator, separating solid particles therefrom, and forming a second gaseous stream comprising residual solid particles, d) passing at least a portion of the second gaseous stream to one or more heat exchangers to remove the heat of reaction, and e) recycling at least a portion of the cooled stream from step (d) as the fluidising gas in step (a), characterised in that the rate of fouling of the one or more heat exchangers is such that i) the increase in pressure drop across the heat exchangers is equivalent to less than 5% per year, and/or ii) the decrease in heat transfer of the heat exchangers is equivalent to less than 5% per year.
    • 本发明涉及在流化床反应器中烯烃气相聚合的方法,该方法包括:a)在聚合反应存在下使包含一种或多种烯烃单体的流化气体通过聚合物颗粒的流化床 催化剂。 b)从反应器顶部排出包含固体颗粒的第一气流,c)将第一气流送至气/固分离器,从其中分离固体颗粒,形成包含残留固体颗粒的第二气流,d)通过 至少一部分所述第二气流到一个或多个热交换器以去除反应热,以及e)将步骤(d)中的至少一部分冷却流作为步骤(a)中的流化气体再循环,其特征在于 因为一个或多个热交换器的结垢率使得i)热交换器上的压降的增加等于每年小于5%,和/或ii)热量的传热减少 交换机每年相当于不到5%。
    • 3. 发明申请
    • DEGASSING PROCESS
    • 脱脂工艺
    • WO2003011920A1
    • 2003-02-13
    • PCT/GB2002/003240
    • 2002-07-15
    • BP CHEMICALS LIMITEDBELL, Andrew, DavidFARGIE, David, AndrewNOBLE, David, EdwardPOWER, Michael, BernardROSS, Iain, David
    • BELL, Andrew, DavidFARGIE, David, AndrewNOBLE, David, EdwardPOWER, Michael, BernardROSS, Iain, David
    • C08F10/00
    • C08F6/001C08F10/00C08F210/16Y10S526/901C08L23/00C08F2/34C08F210/14
    • An improved process for the polymerisation of olefin monomer selected from (a) ethylene, (b) propylene, (c) mixtures of ethylene and propylene and (d) mixtures of (a), (b) or (c) with one or more alpha-olefins in a fluidised bed gas phase reactor, said process comprising passing a gaseous mixture of said olefin monomer(s) through the fluidised bed under effective polymerisation conditions to provide a polymer product containing unreacted monomer(s) and a gaseous effluent stream comprising unreacted monomer(s), removing the polymer product to a degassing vessel, recycling a first portion of the gaseous effluent stream to the fluidised bed and passing a second portion of the gaseous effluent stream to counter currently contact the polymer product in said degassing vessel to produce a polymer product having a reduced amount of unreacted monomer(s), characterised in that the improvements to the process comprise: (i) removing heavy hydrocarbons from the second portion of the effluent stream and returning said hydrocarbons to the first portion of the effluent stream for recycle to the fluidised bed, (ii) removing substantially all of the monomers(s) from the second portion of the effluent stream and returning said monomers(s) to the first portion of the effluent stream for recycle to the fluidised bed, and (iii) recycling the second effluent stream after passage through the degassing vessel to the gaseous effluent stream.
    • 选自(a)乙烯,(b)丙烯,(c)乙烯和丙烯的混合物和(d)(a),(b)或(c)与一种或多种的混合物的烯烃单体的聚合的改进方法 α-烯烃在流化床气相反应器中,所述方法包括在有效聚合条件下使所述烯烃单体的气态混合物通过流化床,以提供含有未反应单体的聚合物产物和包含 将未反应的单体除去聚合物产物至脱气容器,将第一部分气体流出物流再循环到流化床中,并将第二部分气态流出物流反向与目前接触的脱气容器中的聚合物产物接触 产生具有减少量的未反应单体的聚合物产物,其特征在于该方法的改进包括:(i)从流出物流的第二部分除去重质烃 并将所述烃返回到流出物流的第一部分以再循环到流化床,(ii)从流出物流的第二部分中基本上除去所有单体,并将所述单体返回到第一部分 的流出物流再循环到流化床,和(iii)在通过脱气容器之后再循环第二流出物流至气态流出物流。