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    • 3. 发明申请
    • FLAME RETARDANT CARPET PRODUCTS WITH COATING AND/OR ADHESIVE LAYERS FORMED FROM VINYL ACETATE/ETHLENE COPOLYMER DISPERSIONS
    • 具有由乙酸乙烯酯/乙烯共聚物分散体形成的涂层和/或粘合层的阻燃地毯产品
    • WO2012020319A3
    • 2012-04-26
    • PCT/IB2011002644
    • 2011-08-12
    • CELANESE EMULSIONS GMBHMUELLER HARMINWORMALD PAUL STUARTBAVAJ PAOLO
    • MUELLER HARMINWORMALD PAUL STUARTBAVAJ PAOLO
    • D06N7/00C09D131/04C09J131/04
    • D06N7/0063D06N7/0073D06N2203/042D06N2209/067Y10T428/23921
    • Disclosed are carpet products comprising at least one flexible substrate and at least one coating and/or adhesive layer associated with the at least one flexible substrate. The coating and/or adhesive layer is formed from an aqueous composition comprising: A) an emulsifier- stabilized vinyl acetate/ethylene (VAE) emulsion copolymer dispersion wherein the VAE copolymer therein comprises co-monomers which include at least vinyl acetate copolymerized with ethylene and optionally also with other additional functional and/or non- functional co-monomers; and B) at least one particulate filler material selected from particulate inorganic compounds and particulate plastic material. The vinyl acetate/ethylene copolymer in the copolymer dispersion has a selected ethylene content or glass transition temperature. It is also preferably substantially free of cross-linkable co-monomer moieties which generate formaldehyde upon curing and preferably has a particle size, dw, ranging from about 50 to about 500 nm. The carpet product is substantially free of polyvinyl chloride and bitumen and exhibits a Class Bl flame-retardancy in accordance with DIN 4102-14, corresponding to a critical heat flux of =about 4.5 kW/m2.
    • 公开了包含至少一个柔性基底和与至少一个柔性基底相关联的至少一个涂层和/或粘合剂层的地毯产品。 涂层和/或粘合剂层由水性组合物形成,所述水性组合物包含:A)乳化剂稳定的乙酸乙烯酯/乙烯(VAE)乳液共聚物分散体,其中其中的VAE共聚物包含共聚单体,其至少包括与乙烯共聚的乙酸乙烯和 任选地还可与其它附加功能和/或非功能性共聚单体一起使用; 和B)至少一种选自颗粒无机化合物和颗粒状塑料材料的颗粒填料。 共聚物分散体中的乙酸乙烯酯/乙烯共聚物具有选定的乙烯含量或玻璃化转变温度。 它还优选基本上不含可固化的共聚单体部分,其在固化时产生甲醛,优选具有约50至约500nm范围内的粒径dw。 地毯产品基本上不含聚氯乙烯和沥青,并且符合DIN 4102-14的Class B1阻燃性,对应于约4.5kW / m 2的临界热通量。
    • 6. 发明申请
    • WASHABLE CARPET PRODUCTS WITH COATING LAYERS FORMED FROM VINYL ESTER/ETHYLENE COPOLYMER DISPERSIONS
    • 由乙烯基酯/乙烯共聚物分散体形成的具有涂层的可洗地毯产品
    • WO2012020321A3
    • 2012-04-26
    • PCT/IB2011002652
    • 2011-08-12
    • CELANESE EMULSIONS GMBHMULLER HARMINWORMALD PAUL STUARTBAVAJ PAOLO
    • MULLER HARMINWORMALD PAUL STUARTBAVAJ PAOLO
    • D06N7/00C09D131/04C09J131/04
    • D06N3/042D06N3/0006D06N3/0009D06N3/0011D06N3/004D06N7/0073D06N2203/042D06N2209/106Y10T428/23979Y10T428/23986
    • Disclosed are carpet products comprising at least one flexible substrate and at least one coating layer associated with the at least one flexible substrate. The coating layer is formed from an aqueous composition comprising: A) an emulsifier-stabilized vinyl acetate/ethylene (VAE) emulsion copolymer dispersion wherein the VAE copolymer therein comprises co- monomers which include at least vinyl acetate copolymerized with ethylene and optionally also with other additional functional and/or non-functional co-monomers; and B) at least one particulate filler material selected from particulate inorganic compounds and particulate plastic material. The vinyl acetate/ethylene copolymer in the copolymer dispersion has a particle size, dw, ranging from about 50 to about 500 nm as determined by Laser Aerosol Spectroscopy. Such carpet products maintain their integrity and appearance after multiple machine washing operations. Some of these carpet products which have backing coated with certain of the coating compositions used herein also exhibit desirable non-slip properties.
    • 公开了包括至少一个柔性基底和与该至少一个柔性基底相关联的至少一个涂层的地毯产品。 所述涂层由含水组合物形成,所述含水组合物包含:A)乳化剂稳定的乙酸乙烯酯/乙烯(VAE)乳液共聚物分散体,其中所述VAE共聚物包含共聚单体,所述共聚单体至少包括与乙烯共聚的乙酸乙烯酯以及任选还与其他 另外的官能和/或非官能的共聚单体; 和B)至少一种选自颗粒状无机化合物和颗粒状塑料材料的颗粒状填充材料。 如通过激光气溶胶光谱法测定的,共聚物分散体中的乙酸乙烯酯/乙烯共聚物具有约50至约500nm的粒度dw。 这种地毯产品在多次机洗之后保持其完整性和外观。 这些具有用某些本文使用的涂料组合物涂布的背衬的地毯产品也表现出所需的防滑性能。
    • 7. 发明申请
    • WASHABLE CARPET PRODUCTS WITH COATING LAYERS FORMED FROM VINYL ESTER/ETHYLENE COPOLYMER DISPERSIONS
    • 乙烯酯/乙烯共聚物分散体形成的具有涂层的可洗地毯产品
    • WO2012020321A2
    • 2012-02-16
    • PCT/IB2011/002652
    • 2011-08-12
    • CELANESE EMULSIONS GMBHMULLER, HarminWORMALD, Paul, StuartBAVAJ, Paolo
    • MULLER, HarminWORMALD, Paul, StuartBAVAJ, Paolo
    • D06N3/042D06N3/0006D06N3/0009D06N3/0011D06N3/004D06N7/0073D06N2203/042D06N2209/106Y10T428/23979Y10T428/23986
    • Disclosed are carpet products comprising at least one flexible substrate and at least one coating layer associated with the at least one flexible substrate. The coating layer is formed from an aqueous composition comprising: A) an emulsifier-stabilized vinyl acetate/ethylene (VAE) emulsion copolymer dispersion wherein the VAE copolymer therein comprises co- monomers which include at least vinyl acetate copolymerized with ethylene and optionally also with other additional functional and/or non-functional co-monomers; and B) at least one particulate filler material selected from particulate inorganic compounds and particulate plastic material. The vinyl acetate/ethylene copolymer in the copolymer dispersion has a particle size, d w , ranging from about 50 to about 500 nm as determined by Laser Aerosol Spectroscopy. Such carpet products maintain their integrity and appearance after multiple machine washing operations. Some of these carpet products which have backing coated with certain of the coating compositions used herein also exhibit desirable non-slip properties.
    • 公开了包含至少一个柔性基底和与至少一个柔性基底相关联的至少一个涂层的地毯产品。 涂层由水性组合物形成,该组合物包含:A)乳化剂稳定的乙酸乙烯酯/乙烯(VAE)乳液共聚物分散体,其中其中的VAE共聚物包含共聚单体,其至少包括与乙烯共聚的乙酸乙烯酯, 附加功能和/或非功能性共聚单体; 和B)至少一种选自颗粒无机化合物和颗粒状塑料材料的颗粒填料。 通过激光气溶胶光谱测定,共聚物分散体中的乙酸乙烯酯/乙烯共聚物的粒度dw为约50至约500nm。 这样的地毯产品在多次洗衣操作后保持其完整性和外观。 这些具有背衬涂覆有本文所用的某些涂料组合物的这些地毯产品中的一些也表现出所需的防滑性能。
    • 8. 发明申请
    • FLAME RETARDANT CARPET PRODUCTS WITH COATING AND/OR ADHESIVE LAYERS FORMED FROM VINYL ACETATE/ETHYLENE COPOLYMER DISPERSIONS
    • 来自乙酸乙烯酯/乙烯共聚物分散体形成的具有涂层和/或粘合层的阻燃地毯产品
    • WO2012020319A2
    • 2012-02-16
    • PCT/IB2011/002644
    • 2011-08-12
    • CELANESE EMULSIONS GMBHMÜLLER, HarminWORMALD, Paul, StuartBAVAJ, Paolo
    • MÜLLER, HarminWORMALD, Paul, StuartBAVAJ, Paolo
    • D06N7/0063D06N7/0073D06N2203/042D06N2209/067Y10T428/23921
    • Disclosed are carpet products comprising at least one flexible substrate and at least one coating and/or adhesive layer associated with the at least one flexible substrate. The coating and/or adhesive layer is formed from an aqueous composition comprising: A) an emulsifier- stabilized vinyl acetate/ethylene (VAE) emulsion copolymer dispersion wherein the VAE copolymer therein comprises co-monomers which include at least vinyl acetate copolymerized with ethylene and optionally also with other additional functional and/or non- functional co-monomers; and B) at least one particulate filler material selected from particulate inorganic compounds and particulate plastic material. The vinyl acetate/ethylene copolymer in the copolymer dispersion has a selected ethylene content or glass transition temperature. It is also preferably substantially free of cross-linkable co-monomer moieties which generate formaldehyde upon curing and preferably has a particle size, d w , ranging from about 50 to about 500 nm. The carpet product is substantially free of polyvinyl chloride and bitumen and exhibits a Class Bl flame-retardancy in accordance with DIN 4102-14, corresponding to a critical heat flux of ≤about 4.5 kW/m2.
    • 公开了包含至少一个柔性基底和与至少一个柔性基底相关联的至少一个涂层和/或粘合剂层的地毯产品。 涂层和/或粘合剂层由水性组合物形成,所述水性组合物包含:A)乳化剂稳定的乙酸乙烯酯/乙烯(VAE)乳液共聚物分散体,其中其中的VAE共聚物包含共聚单体,其至少包括与乙烯共聚的乙酸乙烯和 任选地还可与其它附加功能和/或非功能性共聚单体一起使用; 和B)至少一种选自颗粒无机化合物和颗粒状塑料材料的颗粒填料。 共聚物分散体中的乙酸乙烯酯/乙烯共聚物具有选定的乙烯含量或玻璃化转变温度。 它还优选基本上不含可固化的共聚单体部分,其在固化时产生甲醛,优选具有约50至约500nm范围内的粒径dw。 地毯产品基本上不含聚氯乙烯和沥青,并且符合DIN 4102-14的Class B1阻燃性,对应于约4.5kW / m 2的临界热通量。