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    • 1. 发明申请
    • OXAZOLINE AND THIAZOLINE ARTHROPODICIDES
    • 奥沙星和噻唑啉酮类
    • WO1996033180A1
    • 1996-10-24
    • PCT/US1996004478
    • 1996-04-01
    • E.I. DU PONT DE NEMOURS AND COMPANYAMOO, Victor, Ekow
    • E.I. DU PONT DE NEMOURS AND COMPANY
    • C07D263/40
    • A01N43/74C07D263/40C07F7/0812
    • Compounds of Formula (I), and their N-oxides and agriculturally-suitable salts, are disclosed which are useful as arthropodicides, wherein X is selected from the group C1-C4 alkylene, -(CH2)n-A-, -(CH2)p-A-CH2-, each group optionally substituted with one to four R ; Y and Z are independently selected from the group O and S; A is selected from the group O, S and NR ; R is selected from the group 1-2 halogen, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, S(O)tR , cyano and nitro; R is selected from the group H, 1-2 halogen, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, S(O)tR , cyano and nitro; m is 1 or 2; n is 1, 2 or 3; p is 1 or 2; and E, Q, R , R , R , R , q and t are as defined in the text. Also disclosed are compositions containing the compounds of Formula (I) and a method for controlling arthropods which involves contacting the arthropods or their environment with an effective amount of a compound of Formula (I).
    • 公开了式(I)化合物及其N-氧化物和农业上合适的盐,其可用作杀节磷剂,其中X选自C1-C4亚烷基, - (CH2)nA-, - (CH2)pA -CH 2 - ,每个基团任选被一至四个R 4取代; Y和Z独立地选自O和S组; A选自O,S和NR 10; R 1选自1-2个卤素,C 1 -C 6烷基,C 1 -C 6卤代烷基,C 1 -C 6烷氧基,C 1 -C 6卤代烷氧基,S(O)t R 11,氰基和硝基; R 2选自H,1-2卤素,C 1 -C 6烷基,C 1 -C 6卤代烷基,C 1 -C 6烷氧基,C 1 -C 6卤代烷氧基,S(O)t R 11,氰基和硝基; m为1或2; n为1,2或3; p为1或2; 和E,Q,R 4,R 5,R 10,R 11,q和t如本文所定义。 还公开了含有式(I)化合物和控制节肢动物的方法的组合物,其涉及将节肢动物或其环境与有效量的式(I)化合物接触。
    • 3. 发明申请
    • ARTHROPODICIDAL OXAZOLINES AND THIAZOLINES
    • 抗坏血酸氧化氮和噻唑啉
    • WO1993024470A1
    • 1993-12-09
    • PCT/US1993004788
    • 1993-05-25
    • E.I. DU PONT DE NEMOURS AND COMPANYAMOO, Victor, EkowLAHM, George, PhilipSTEVENSON, Thomas, Martin
    • E.I. DU PONT DE NEMOURS AND COMPANY
    • C07D263/10
    • C07D413/04A01N43/74C07D263/10
    • Arthropodicidally active compounds, compositions and a method for using them, the compounds having formula (I) wherein: A is selected from the group having a direct bond and C1-C3 straight or branched chain alkylene; E is selected from the group C1-C4 alkyl and C1-C4 haloalkyl; Z is selected from the group O and S; q is 0, 1, 2 or 3; Q is a 5- to 16- membered aromatic ring system selected from the group: (i) monocylic aromatic ring containing 1 to 4 heteroatoms independently selected from the group 0-4 nitrogen, 0-1 oxygen, and 0-1 sulfur; (ii) fused carbobicyclic ring containing 8 to 12 carbons; (iii) fused carbotricyclic ring containing 12 to 16 carbons; (iv) fused bicylic ring containing 1 to 4 heteroatoms independently selected from the group 0-4 nitrogen, 0-2 oxygen, and 0-2 sulfur; (v) fused tricylic ring containing 1 to 6 heteroatoms independently selected from the group 0-4 nitrogen, 0-2 oxygen, and 0-2 sulfur; and (vi) phenyl substituted with M-J ; Q being substituted with 1 to 6 substituents selected independently from the group R , R , (R )p and (R )m; R and R are independently selected from the group H, halogen, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 haloalkoxy, C1-C6 alkylthio, CN and NO2.
    • 具有式(I)的化合物,其中:A选自具有直接键的基团和C 1 -C 3直链或支链亚烷基的化合物,组合物及其使用方法, E选自C 1 -C 4烷基和C 1 -C 4卤代烷基; Z选自O和S组; q为0,1,2或3; Q是选自以下的5至16元芳环体系:(i)含有1-4个独立地选自0-4个氮,0-1个氧和0-1个硫的杂原子的单环芳环; (ii)含有8至12个碳的稠合的碳双环; (iii)含有12至16个碳的稠合碳鎓环; (iv)含有1至4个独立地选自0-4个氮,0-2个氧和0-2个硫的杂原子的稠合双环; (v)含有1至6个独立地选自0-4个氮,0-2个氧和0-2个硫的杂原子的稠合三环; 和(vi)被M-J 1取代的苯基; Q被独立地选自基团R 3,R 4,(R 5)p和(R 6)m取代的1至6个取代基取代; R 1和R 2独立地选自H,卤素,C 1 -C 6烷基,C 1 -C 6卤代烷基,C 1 -C 6卤代烷氧基,C 1 -C 6烷硫基,CN和NO 2。