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    • 90. 发明申请
    • MESOSTRUCTURED FILM, MESPOROUS MATERIAL FILM, AND PRODUCTION METHODS FOR THE SAME
    • 组合膜,多孔材料薄膜及其生产方法
    • WO2005014480A1
    • 2005-02-17
    • PCT/JP2004/011582
    • 2004-08-05
    • CANON KABUSHIKI KAISHAMIYATA, HirokatsuKAWASHIMA, YasuhiroKURODA, Kazuyuki
    • MIYATA, HirokatsuKAWASHIMA, YasuhiroKURODA, Kazuyuki
    • C01B37/02
    • G21K1/06C01B37/02Y10T428/24322Y10T428/24496Y10T428/249967Y10T428/249969Y10T428/31504
    • A mesostructured film is provided having a structure in which surfactant molecular assemblies are regularly arranged three-dimensionally. A polymer compound thin film is formed on the substrate surface through spin coating or the like, and a rotating roller wrapped with a cloth is pressed against the polymer film for rubbing in one direction. The polymer material includes polyimide, polyamide, and polystyrene. The substrate includes a silica glass substrate and a silicon substrate. The mesostructured film can be formed by retaining the substrate in an aqueous solution containing a surfactant, silicon alkoxide, and acid. After being retained in the solution, the substrate is heated at about 60 to 120 ° C for several hours to several days for reaction. The surfactant includes C 18 H 37 (OCH 2 CH 2 ) 20 0H and C 16 H 33 (OCH 2 CH 2 ) 20 0H . The alkoxide included tetraethoxysilane, tetramethoxysilane, and tetrapropoxysilane. Hydrochloric acid, nitric acid, or sulfuric acid'is used as a catalyst.
    • 提供了具有其中表面活性剂分子组件被三维规则地排列的结构的介孔结构膜。 通过旋涂等在基材表面上形成高分子化合物薄膜,将用布覆盖的旋转辊按压在聚合物膜上以在一个方向上摩擦。 聚合物材料包括聚酰亚胺,聚酰胺和聚苯乙烯。 基板包括石英玻璃基板和硅基板。 可以通过将基材保持在含有表面活性剂,硅醇盐和酸的水溶液中来形成介孔结构膜。 在保留在溶液中之后,将基底在约60至120℃下加热数小时至数天以进行反应。 表面活性剂包括C18H37(OCH2CH2)200H和C16H33(OCH2CH2)200H。 醇盐包括四乙氧基硅烷,四甲氧基硅烷和四丙氧基硅烷。 将盐酸,硝酸或硫酸用作催化剂。