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61. 发明申请

WO2015195680A1 METHODS FOR PRODUCING BORYLATED ARENES 审中-公开
标题翻译：生产ATED ATED的方法
公开(公告)号：WO2015195680A1
公开(公告)日：2015-12-23
申请号：PCT/US2015/036054
申请日：2015-06-16
申请人： DOW AGROSCIENCES LLC , BOARD OF TRUSTEES OF MICHIGAN STATE UNIVERSITY
发明人： SMITH, III, Milton, R. , MALECZKA, Robert, E. , SABASOVS, Dmitrijs , OPPENHEIMER, Jossian
IPC分类号： A01N55/08 , A61K31/69 , C07F5/02
CPC分类号： B01J31/22 , B01J31/181 , B01J31/1815 , B01J31/2273 , B01J31/2295 , B01J2231/4205 , B01J2531/0216 , B01J2531/845 , C07F5/025
摘要： Methods for preparing a borylated aromatic compound by contacting an aromatic substrate with a catalytic cobalt complex and a borylation reagent under conditions effective to form the borylated aromatic compound are provided. The catalytic cobalt complex can be any suitable cobalt(l) or cobalt(ll) complex that can catalyze the C-H activation-borylation of the aromatic substrate.
摘要翻译：提供了通过在有效形成硼化芳族化合物的条件下使芳族底物与催化钴络合物和硼化试剂接触来制备硼化芳族化合物的方法。催化钴络合物可以是可以催化芳族底物的C-H活化 - 硼酸化的任何合适的钴（I）或钴（II）络合物。

62. 发明申请

WO2015049047A1 IMMOBILIZED METATHESIS TUNGSTEN OXO ALKYLIDENE CATALYSTS AND USE THEREOF IN OLEFIN METATHESIS 审中-公开
标题翻译：稳定的METATHESIS TUNGSTEN OXO ALKYLIDENE催化剂及其在OLEFIN METATHESIS中的应用
公开(公告)号：WO2015049047A1
公开(公告)日：2015-04-09
申请号：PCT/EP2014/002654
申请日：2014-09-30
申请人： XIMO AG
发明人： FRÁTER, Georg, Emil , VARGA, Jeno , COPERET, Christophe , MOUGEL, Victor , CONLEY, Matthew, P.
IPC分类号： B01J31/16 , B01J31/18 , B01J31/22
CPC分类号： B01J31/2265 , B01J31/1608 , B01J31/1805 , B01J31/181 , B01J31/2208 , B01J31/2226 , B01J2231/543 , B01J2531/66 , C07C6/04 , C07C67/30 , C07C67/475 , C07C2531/22 , C07F11/00 , C08G61/08 , C08G2261/418 , C08G2261/419 , C07C11/02 , C07C69/593
摘要： Method of making an immobilized tungsten catalyst comprising or consisting of (≡SiO) x W(=O)(=CR 1 R 2 )(R 3 or R 4 ) 2-x (L) z , comprising at least the following step (i): (i) reacting silica (Si02) with a tungsten oxo alkylidene complex comprising or consisting of (R 3 )(R 4 )W(=O)(=CR 1 R 2 )(L) y , preferably wherein =CR 1 R 2 is selected from = CHC(CH 3 ) 3 or =CH(C(CH 3 ) 2 )C 6 H 5 and R 3 and R 4 are independently selected from pyrrol-1 -yl, 2,5-dimethylpyrrol-1-yl, or 2,5- diphenylpyrrol-1-yl, or -OR, wherein R is a six membered or 10 membered aryl ring, optionally substituted.
摘要翻译：由（≡SiO）xW（= O）（= CR1R2）（R3或R4）2-x（L）z组成或由（≡SiO）xW（= O）（= CR1R2））组成的固定化钨催化剂的方法，至少包括以下步骤（ⅰ）将二氧化硅（SiO 2）与包含（R 3）（R 4）W（= O）（= CR 1 R 2）（L）y的钨氧化亚烷基络合物反应，优选其中= CR 1 R 2选自= CHC（CH 3）3或= CH（C（CH 3）2）C 6 H 5，R 3和R 4独立地选自吡咯-1-基，2,5-二甲基吡咯-1-基或2,5-二苯基吡咯-1-基或-OR，其中R 是任选被取代的六元或十元芳环。

63. 发明申请

WO2015003815A1 IMMOBILIZED METATHESIS TUNGSTEN CATALYSTS AND USE THEREOF IN OLEFIN METATHESIS 审中-公开
标题翻译：固定化催化剂及其在油脂中的应用
公开(公告)号：WO2015003815A1
公开(公告)日：2015-01-15
申请号：PCT/EP2014/001910
申请日：2014-07-11
申请人： XIMO AG
发明人： COPERET, Christophe , MOUGEL, Victor , FRÁTER, Georg Emil , VARGA, Jeno , HEGEDUS, Csaba
IPC分类号： C07F11/00 , C07C6/04
CPC分类号： C07F11/00 , B01J31/181 , B01J2231/543 , B01J2531/66 , C07B2200/11 , C07C6/04 , C07C2531/18 , C07C2531/22 , C07C11/02
摘要： Compound of formula (I) wherein M is W; R 1 is H, aryl, heteroaryl, alkyl, or heteroalkyl, optionally substituted, respectively; R 2 and R 3 can be the same or different and are alkyl, alkenyl, heteroalkyl, heteroalkenyl, aryl, or heteroaryl, optionally substituted, respectively, or hydrogen; R 5 is a residue R 6 -X-, wherein R 6 is alkyl, aryl, heteroalkyl, heteroaryl, optionally substituted, respectively; (R 7 , R 8 , R 9 )Si; wherein R 7 , R 8 , R 9 are independently alkyl, alkoxy, phenyl or phenoxy, optionally substituted, respectively; (R 10 , R 11 , R 12 )C, wherein R 10 , R 11 , R 12 are independently phenyl, alkyl, optionally substituted, respectively; X = O, S, or NR 13 , wherein R 13 is H; or alkyl or aryl, optionally substituted, respectively; or R 5 is R 6 -CO-NR 13 , wherein R 6 and NR 13 have the meaning as defined above, or wherein R 6 and R 13 taken together form a carbon chain having from 2 to 6 carbon atoms; R 5 is a 4 to 8 membered N-containing carbon ring, wherein N is linked to M; and R 4 is a residue O-Si(O-) 3 , and represents silica to which M is linked forming a M-O-Si(O-) 3 moiety, preferably wherein silica is comprised in a solid support; under the proviso that a compound in which R 1 = 2,6-diisopropylphenyl, R 5 dimethylpyrrol-1-yl, R 2 = tBu, and R 3 = H is excluded.
摘要翻译：式（I）的化合物，其中M为W; R 1分别是H，芳基，杂芳基，烷基或杂烷基，任选被取代; R 2和R 3可以相同或不同，分别为烷基，烯基，杂烷基，杂烯基，芳基或杂芳基，分别任选被取代;或氢; R5是残基R6-X-，其中R6分别是烷基，芳基，杂烷基，杂芳基，任选取代; （R7，R8，R9）Si; 其中R 7，R 8，R 9分别独立地为烷基，烷氧基，苯基或苯氧基，任选被取代; （R 10，R 11，R 12）C，其中R 10，R 11，R 12分别独立地为苯基，烷基，任选取代; X = O，S或NR 13，其中R 13是H; 或烷基或芳基，分别任选取代; 或R 5是R 6 -CO-NR 13，其中R 6和NR 13具有如上所定义的含义，或其中R 6和R 13一起形成具有2至6个碳原子的碳链; R5是4至8元的含N的碳环，其中N与M连接; 并且R 4是残基O-Si（O-O）3，并且表示与M相连的形成M-O-Si（O-）3部分的二氧化硅，优选其中二氧化硅包含在固体载体中; 条件是排除其中R1 = 2,6-二异丙基苯基，R5二甲基吡咯-1-基，R2 = tBu和R3 = H的化合物。

64. 发明申请

WO2014139679A8 METATHESIS CATALYSTS AND REACTIONS USING THE CATALYSTS 审中-公开
标题翻译：使用催化剂的METATHESIS催化剂和反应
公开(公告)号：WO2014139679A8
公开(公告)日：2014-12-11
申请号：PCT/EP2014000671
申请日：2014-03-13
申请人： XIMO AG
发明人： ONDI LEVENTE , VARGA JENO , BUCSAI AGOTA , TOTH FLORIAN , LORINCZ KRISZTIAN , HEGEDUS CSABA , ROBE EMMANUEL , FRÁTER GEORG
IPC分类号： B01J31/22
CPC分类号： B01J31/2265 , B01J31/143 , B01J31/1608 , B01J31/1805 , B01J31/181 , B01J31/2208 , B01J31/2226 , B01J31/223 , B01J2231/543 , B01J2531/0266 , B01J2531/0288 , B01J2531/64 , B01J2531/66 , B01J2540/20 , B01J2540/22 , B01J2540/225 , C07C6/04 , C07C67/293 , C07C67/347 , C07C2531/12 , C07C2531/22 , C07C2601/10 , C07F11/00 , C08G61/08 , C08G2261/418 , C07C11/02
摘要： The invention relates to a method of forming an olefin from a first olefin and a second olefin in a metathesis reaction, comprising step (i): (i) reacting the first olefin with the second olefin in the presence of a compound that catalyzes said metathesis reaction such that the molar ratio of said compound to the first or the second olefin is from 1 : 500 or less, and the conversion of the first or the second olefin to said olefin is at least 50 %, characterized in that as compound that catalyzes said metathesis reaction a compound of formula (A) is used: wherein M is Mo or W; R1 is aryl, heteroaryl, alkyl, or heteroalkyl; optionally substituted; R2 and R3 can be the same or different and are hydrogen, alkyl, alkenyl, heteroalkyl, heteroalkenyl, aryl, or heteroaryl; optionally substituted; R5 is alkyl, alkoxy, heteroalkyl, aryl, heteroaryl, silylalkyl, silyloxy, optionally substituted; and R4 is a residue R6-X-, wherein X = O and R6 is aryl, optionally substituted; or X = S and R6 is aryl, optionally substituted; or X = O and R6 is (R7, R8, R9)Si; wherein R7, R8, R9 are alkyl or phenyl, optionally substituted; or X = O and R6 is (R10, R11, R12)C, wherein R10, R11, R12 are independently selected from phenyl, alkyl; optionally substituted; and to the catalysts used in the method.
摘要翻译：本发明涉及一种在复分解反应中由第一种烯烃和第二种烯烃形成烯烃的方法，包括步骤（i）：（i）在催化所述复分解的化合物存在下，使第一种烯烃与第二种烯烃反应使得所述化合物与第一或第二烯烃的摩尔比为1:500以下，第一或第二烯烃向所述烯烃的转化率为至少50％，其特征在于，作为催化剂的化合物所述复分解反应使用式（A）化合物：其中M是Mo或W; R 1是芳基，杂芳基，烷基或杂烷基; 任选取代; R2和R3可以相同或不同，为氢，烷基，烯基，杂烷基，杂烯基，芳基或杂芳基; 任选取代; R5是烷基，烷氧基，杂烷基，芳基，杂芳基，甲硅烷基烷基，甲硅烷基氧基，任意取代的; R4为残基R6-X-，其中X = O，R6为芳基，任选取代; 或X = S和R 6为芳基，任选取代; 或X = O，R6是（R7，R8，R9）Si; 其中R 7，R 8，R 9为烷基或苯基，任选取代; 或X = O，R 6是（R 10，R 11，R 12）C，其中R 10，R 11，R 12独立地选自苯基，烷基，任选取代; 以及该方法中使用的催化剂。

65. 发明申请

WO2013010902A1 VERFAHREN ZUR KATALYTISCHEN OXIDATION VON WASSER 审中-公开
标题翻译：工艺用水的催化氧化
公开(公告)号：WO2013010902A1
公开(公告)日：2013-01-24
申请号：PCT/EP2012/063661
申请日：2012-07-12
申请人： EVONIK INDUSTRIES AG , MARQUET, Nicolas , GOPINATHAN, Anilkumar , GÄRTNER, Felix , LOSSE, Sebastian , DENURRA, Stefania , COZZULA, Daniela , GLADIALI, Serafino , JUNGE, Henrik , BELLER, Matthias
发明人： MARQUET, Nicolas , GOPINATHAN, Anilkumar , GÄRTNER, Felix , LOSSE, Sebastian , DENURRA, Stefania , COZZULA, Daniela , GLADIALI, Serafino , JUNGE, Henrik , BELLER, Matthias
IPC分类号： C01B3/04 , C01B13/02 , B01J31/18
CPC分类号： C01B3/042 , B01J31/181 , B01J2231/70 , B01J2531/0208 , B01J2531/827 , C01B13/0207 , Y02E60/364
摘要： Die Erfindung betrifft ein Verfahren zur homogen oder heterogen katalysierten Oxidation von Wasser unter der Verwendung von Iridium(III)-Komplexen, welche starke cyclometallierte- Donorliganden (metallierte Phenyl-substituierte 5-gliedrige Heterocyclen) aufweisen, als Katalysatoren oder Katalysatorvorstufen.
摘要翻译：本发明涉及使用铱的下为水均匀或不均匀催化氧化的方法（III），其具有强cyclometallierte-供体配体（金属化的苯基取代的5元杂环），作为催化剂或催化剂前体配合物。

66. 发明申请

WO2013009836A1 SAMARIUM CONTAINING COMPLEXES AND CONDENSATION REACTION CATALYSTS, METHODS FOR PREPARING THE CATALYSTS, AND COMPOSITIONS CONTAINING THE CATALYSTS 审中-公开
标题翻译：含有复合物和凝结反应催化剂的SAMARIUM，制备催化剂的方法以及包含催化剂的组合物
公开(公告)号：WO2013009836A1
公开(公告)日：2013-01-17
申请号：PCT/US2012/046208
申请日：2012-07-11
申请人： DOW CORNING CORPORATION , BRANDSTADT, Kurt , COOK, Simon , DIAMOND, Gary , HALL, Keith , LOWER, Loren , SURGENOR, Avril , TAYLOR, Richard , TONGE, James , TZOU, Ming-shin
发明人： BRANDSTADT, Kurt , COOK, Simon , DIAMOND, Gary , HALL, Keith , LOWER, Loren , SURGENOR, Avril , TAYLOR, Richard , TONGE, James , TZOU, Ming-shin
IPC分类号： B01J31/22 , B01J31/18 , C08G77/08
CPC分类号： C08G77/08 , B01J31/1805 , B01J31/181 , B01J31/2204 , B01J31/2213 , B01J31/2217 , B01J31/2243 , B01J2531/0241 , B01J2531/38 , C07F5/00 , C08G77/16 , C08G77/18 , C08L83/04
摘要： A composition is capable of curing via condensation reaction. The composition uses a new condensation reaction catalyst. The new condensation reaction catalyst is used to replace conventional tin catalysts. The composition can react to form a gum, gel, rubber, or resin.
摘要翻译：组合物能够通过缩合反应固化。该组合物使用新的缩合反应催化剂。新的缩合反应催化剂用于代替常规的锡催化剂。组合物可以反应以形成胶，凝胶，橡胶或树脂。

67. 发明申请

WO2012037217A1 TRANSFER HYDROGENATION OF CYCLOPAMINE ANALOGS 审中-公开
标题翻译：环糊精类似物的转移氢化
公开(公告)号：WO2012037217A1
公开(公告)日：2012-03-22
申请号：PCT/US2011/051553
申请日：2011-09-14
申请人： INFINITY PHARMACEUTICALS, INC. , GENOV, Daniel, G. , AUSTAD, Brian, C. , WHITE, Brian, H.
发明人： GENOV, Daniel, G. , AUSTAD, Brian, C. , WHITE, Brian, H.
IPC分类号： A61K31/44 , B01J23/40
CPC分类号： C07D491/107 , B01J31/181 , B01J31/2428 , B01J2231/643 , B01J2531/821 , C07D491/048 , C07F17/02
摘要： Provided herein is a process for the transfer-hydrogenation of ketone analogs of members of the jervine type of Veratrum alkaloids, such as cyclopamine. Also provided herein are novel ruthenium transfer-hydrogenation catalysts.
摘要翻译：本文提供了一种用于转化氢化Ver藜类生物碱成员的酮类似物的方法，例如环巴胺。本文还提供了新的钌转移氢化催化剂。

68. 发明申请

WO2011108672A3 HOMOGENEOUS ASYMMETRIC HYDROGENATION CATALYST 审中-公开
标题翻译：均相不对称加氢催化剂
公开(公告)号：WO2011108672A3
公开(公告)日：2011-12-01
申请号：PCT/JP2011054980
申请日：2011-03-03
申请人： TAKASAGO PERFUMERY CO LTD , ITOH HISANORI , MAEDA HIRONORI , HORI YOJI
发明人： ITOH HISANORI , MAEDA HIRONORI , HORI YOJI
IPC分类号： B01J31/22 , C07B53/00 , C07B61/00 , C07C45/62 , C07C47/21
CPC分类号： C07B53/00 , B01J31/04 , B01J31/181 , B01J2231/645 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/847 , C07C45/62 , C07C47/21
摘要： Disclosed is a catalyst for producing an optically active aldehyde or optically active ketone, which are optically active carbonyl compounds, by the selective asymmetric hydrogenation of an a, ß-unsaturated carbonyl compound, particularly a catalyst which is insoluble in a reaction mixture and which can be used to obtain an optically active citronellal, which is useful as a fragrance, by the selective asymmetric hydrogenation of citral, geranial or neral. Further disclosed is a method for producing a corresponding optically active carbonyl compound. Particularly disclosed is a production method for obtaining the same optical isomer of citronellal by the asymmetric hydrogenation of citral, completely independent of the mixing ratio of neral and geranial. Using a catalyst which comprises a transition metal complex of at least one type of transition metal selected from the transition metals in groups 8-10 of the periodic table, an optically active nitrogen-containing cyclic compound, and an acid if required, an a, ß-unsaturated carbonyl compound undergoes selective asymmetric hydrogenation.
摘要翻译：本发明公开了一种通过α，β-不饱和羰基化合物，特别是不溶于反应混合物并能够选择性地催化不对称氢化α，β-不饱和羰基化合物的光学活性羰基化合物的光学活性醛或光学活性酮的催化剂，用于通过柠檬醛，香叶醛或橙醛的选择性不对称氢化获得可用作香料的光学活性香茅醛。还公开了制备相应的光学活性羰基化合物的方法。特别公开了通过柠檬醛的不对称氢化获得相同的香茅醛光学异构体的生产方法，其完全不依赖于醛缩醛和香叶醛的混合比例。使用包含选自周期表第8-10族中的过渡金属的至少一种过渡金属的过渡金属配合物的催化剂，如果需要，光学活性的含氮环状化合物和酸，a， β-不饱和羰基化合物经历选择性不对称氢化。

69. 发明申请

WO2011146155A2 ORGANO-METALLIC FRAMEWORKS DERIVED FROM CARBENOPHILIC METALS AND METHOD OF MAKING SAME 审中-公开
标题翻译：从碳化金属衍生的有机金属框架及其制造方法
公开(公告)号：WO2011146155A2
公开(公告)日：2011-11-24
申请号：PCT/US2011024671
申请日：2011-02-12
申请人： UNIV CALIFORNIA , BASF SE , YAGHI OMAR M , CZAJA ALEXANDER U , KONOSUKE OISAKI
发明人： YAGHI OMAR M , CZAJA ALEXANDER U , KONOSUKE OISAKI
IPC分类号： B01J31/16
CPC分类号： C07F15/006 , B01D53/02 , B01D2253/204 , B01D2253/306 , B01D2257/104 , B01D2257/108 , B01D2257/11 , B01D2257/406 , B01D2257/502 , B01D2257/504 , B01D2257/7025 , B01D2259/4525 , B01J20/226 , B01J31/04 , B01J31/1691 , B01J31/181 , B01J31/1815 , B01J31/183 , B01J31/2273 , B01J2531/0222 , B01J2531/26 , B01J2531/824 , C01B3/0015 , Y02C10/08 , Y02C20/20 , Y02E60/328 , Y02P20/152 , Y02P20/156
摘要： The disclosure provides organic frameworks comprising increased stability.
摘要翻译：本公开提供了包括增加的稳定性的有机骨架。

70. 发明申请

WO2011023788A1 PROCESS FOR THE PREPARATION OF HYDROGENATED NITRILE RUBBER 审中-公开
标题翻译：制备氢化橡胶的方法
公开(公告)号：WO2011023788A1
公开(公告)日：2011-03-03
申请号：PCT/EP2010/062529
申请日：2010-08-27
申请人： LANXESS DEUTSCHLAND GMBH , ONG, Christopher , MÜLLER, Julia, Maria
发明人： ONG, Christopher , MÜLLER, Julia, Maria
IPC分类号： B01J31/22 , C08C19/02 , C08C19/08 , C08L9/02 , C08L15/00
CPC分类号： C08C19/02 , B01J31/181 , B01J31/1815 , B01J31/2265 , B01J31/2291 , B01J2231/641 , B01J2531/821 , B01J2531/825 , C08C19/08 , C08C2019/09 , C08L15/005
摘要： The present invention relates to a process for the production of hydrogenated nitrile rubber polymers having lower molecular weights and narrower molecular weight distributions than those known in the art, wherein the process is carried out in the presence of hydrogen and optionally at least one co-olefin. The present invention further relates to the use of specific metal compounds in a process for the production of a hydrogenated nitrile rubber by simultaneous hydrogenation and metathesis of a nitrile rubber.
摘要翻译：本发明涉及生产具有比本领域已知的分子量低和分子量分布窄的氢化丁腈橡胶聚合物的方法，其中该方法在氢气和任选的至少一种共聚烯烃存在下进行。本发明还涉及通过丁腈橡胶的同时氢化和复分解在生产氢化丁腈橡胶的方法中使用特定的金属化合物。

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