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    • 51. 发明申请
    • METHOD FOR SEPARATING TRIVALENT LANTHANIDE CATIONS BY SELECTIVE COMPLEXING
    • 通过选择性复合分离多种蓝藻酸盐的方法
    • WO99065824A1
    • 1999-12-23
    • PCT/FR1999/001386
    • 1999-06-11
    • C01F17/00C02F1/68C02F9/00C22B3/16C22B59/00
    • C22B59/00C01F17/0006C02F1/683C02F2101/006C02F2101/20C22B3/1625Y02P10/234
    • The invention concerns a method for separating trivalent lanthanide cations by selective complexing from an aqueous solution containing them. More precisely, the invention concerns a method for separating a trivalent lanthanide cation from an aqueous solution containing besides said lanthanide cation one or several other lanthanide cation(s) by contacting said solution with a specific ligand derived the all-cis-1,3,5-triamino-2,4,6-trihydroxycyclohexane (TATHC). Said solutions can be in particular aqueous solutions derived from plants reprocessing used fuel, such as solutions from fuel or aqueous effluent dissolution. They can also consist of aqueous solutions derived from rare earth, thorium and/or uranium ore treatment.
    • 本发明涉及通过从含有它们的水溶液中选择性络合来分离三价镧系元素阳离子的方法。 更准确地说,本发明涉及一种通过使所述溶液与衍生全顺式-1,3,...的特定配体接触,从含有所述镧系元素阳离子或其它镧系元素阳离子的水溶液中分离出三价镧系元素阳离子的方法, 5-三氨基-2,4,6-三羟基环己烷(TATHC)。 所述溶液可以特别是来自植物再处理用过的燃料的水溶液,例如来自燃料或含水流出物溶解的溶液。 它们也可以由衍生自稀土,钍和/或铀矿石处理的水溶液组成。
    • 53. 发明申请
    • METHOD FOR RECOVERING AND SEPARATING METALS FROM WASTE STREAMS
    • 从废物流中回收和分离金属的方法
    • WO99034926A1
    • 1999-07-15
    • PCT/US1998/000234
    • 1998-01-06
    • C02F1/54C02F1/66C02F1/68C02F9/00B03B1/00
    • C02F9/00C02F1/5245C02F1/54C02F1/62C02F1/66C02F1/683C02F11/12C02F2101/006C02F2101/20C02F2101/206C02F2101/22Y10S210/912Y10S210/913
    • The invention relates to a method for recovering and separating metals from waste streams. Conventional processes for removing metals from waste streams include ion exchange, electrolysis and settling, which are costly, complex, cumbersome, and/or do not allow for recycling of the metal. The invention overcomes these drawbacks through a method for recovering and separating precious and non-precious metals from waste water streams, which removes, separarates, and recovers such metals in a cost effective manner with more than 95 % removal from waste streams and with minimal amounts of unprocessed solids and sludge remaining in the environment. Metals such as chromium, manganese, cobalt, nickel, copper, zinc, silver, gold, platinum, vanadium, sodium, potassium, beryllium, magnesium, calcium, barium, lead, aluminum, tin and the like are removed and recovered from the waste streams with at least 95 % removal and other metals and compounds, such as antimony, sulfur, and selenium are removed and recovered from waste streams with at least 50 % removal. The method employs a unique complexing agent comprising a carbamate compound and an alkali metal hydroxide which facilitates the formation of the metals into ionic metal particles enabling them to be readily separated, removed and recovered.
    • 本发明涉及从废物流中回收和分离金属的方法。 用于从废物流中除去金属的常规方法包括离子交换,电解和沉降,其是昂贵的,复杂的,繁琐的和/或不允许金属的再循环。 本发明通过一种从废水流中回收和分离贵重金属和非贵重金属的方法克服了这些缺陷,其以成本有效的方式去除,分离和回收这些金属,其中从废物流中除去95%以上且最少量 未处理的固体和残留在环境中的污泥。 诸如铬,锰,钴,镍,铜,锌,银,金,铂,钒,钠,钾,铍,镁,钙,钡,铅,铝,锡等的金属被从废物中除去并回收 除去至少95%的物流和其它金属和化合物,如锑,硫和硒,并从废物流中回收至少50%的去除物质。 该方法采用独特的络合剂,其包含氨基甲酸酯化合物和碱金属氢氧化物,其促进金属形成离子金属颗粒,使得它们能够容易地分离,除去和回收。
    • 56. 发明申请
    • A METHOD FOR THE COMPLEX PURIFICATION OF WASTE SOLUTIONS
    • 一种废水处理方法
    • WO1995014368A2
    • 1995-06-01
    • PCT/BG1994000012
    • 1994-11-23
    • SOMLEV, Vladislav, PetrovTISHKOV SAVA HARALAMPIEV
    • C02F3/10C02F3/28C02F3/32
    • C02F3/28C02F3/10C02F3/327C02F2101/006Y02W10/15Y02W10/18
    • The method has an application in the industrial productions, which produce waste solutions, with various contaminants (organic matter, sulphate ions, ammonium ions, nitrite ions, nitrate ions, arsenic, cyanide, ions of heavy metals, radioactive elements, etc.). With this method a complex purification of waste solutions independently of their qualitative and quantitative composition is realized and it is minimum to SECOND CATEGORY for waters according to the BULGARIAN STATE STANDARD (State Newpaper, No. 96 from 1986 year). The essence of the method is: the waste solutions, containing contaminants independent of their concentrations, ascendingly and gravitationally pass through the system of biobasins with the form of "turned obelisk" through the supporting layer of broken carbonate rocks, iron and a source of organic carbon situated at the bottom of the basins, intensifying the activity of the applied mixed bacterial culture, adapted in a suitable way, obtained through the combination of activated sludge from the biobasins of a purifying municipal sewage plant and sludge from the digesters of such a plant concentrated additionally with a mixed culture of anaerobic microorganisms isolated from the sludge of polluted water accepting basin.
    • 该方法在工业生产中具有生产废溶液,各种污染物(有机物,硫酸根离子,铵离子,亚硝酸根离子,硝酸根离子,砷,氰化物,重金属离子,放射性元素等)的应用。 通过这种方法,可以实现独立于其定性和定量组成的废溶液的复杂净化,并且根据“保加利亚州标准”(State Newpaper,1986年第96期),对于第二类水域是最小的。 该方法的本质是:废物溶液含有与其浓度无关的污染物,通过破碎的碳酸盐岩,铁和有机物来源的支撑层,以“转向”方式上升和重力地通过生物池的系统 位于盆地底部的碳,通过将来自净化城市污水处理厂的生物池的活性污泥和来自这种植物的消化器的污泥相结合而获得的合适的方式增强了施用的混合细菌培养物的活性 另外用污水接受盆污泥分离的厌氧微生物混合培养。