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41. 发明申请

WO1995026332A1 OBTAINING TOLUENE 2,6-DIISOCYANATE FROM A MIXTURE CONTAINING TOLUENE 2,6-DIISOCYANATE AND TOLUENE 2,4-DIISOCYANATE 审中-公开
标题翻译：从含2,6-二异氰酸酯和二醇2,4-二异氰酸酯的混合物中混合得到2,6-二异氰酸酯
公开(公告)号：WO1995026332A1
公开(公告)日：1995-10-05
申请号：PCT/FR1995000366
申请日：1995-03-24
申请人： RHONE-POULENC CHIMIE , PARRON, Jean-Claude , REVELANT, Denis , VACHET, François
发明人： RHONE-POULENC CHIMIE
IPC分类号： C07C263/20
CPC分类号： C07C263/20 , C07C265/14
摘要： A method for obtaining substantially pure toluene 2,6-diisocyanate from a mixture of the 2,4 and 2,6 isomers of toluene diisocyanate, wherein at least one crystallising-melting cycle is performed on the mixture of said isomers to separate out the toluene 2,6-diisocyanate isomer. In an alternative embodiment, the mixture is contacted, prior to the crystallising-melting cycle, with a compound or catalyst capable of converting part of the toluene 2,4-diisocyanate isomer therein, and the reacted 2,4 isomer is separated. Said method is advantageous in that usable by-products are produced.
摘要翻译：从甲苯二异氰酸酯的2,4和2,6异构体的混合物中获得基本上纯的甲苯2,6-二异氰酸酯的方法，其中对所述异构体的混合物进行至少一个结晶熔融循环以分离甲苯 2,6-二异氰酸酯异构体。在另一个实施方案中，混合物在结晶 - 熔融循环之前与能够转化部分甲苯2,4-二异氰酸酯异构体的化合物或催化剂接触，并且分离出反应的2,4-异构体。所述方法的优点在于生产可用的副产物。

42. 发明申请

WO1995021136A1 METHOD FOR PURIFYING AN ORGANIC WASTE-CONTAINING MEDIUM 审中-公开
标题翻译：用于净化含有机废物的介质的方法
公开(公告)号：WO1995021136A1
公开(公告)日：1995-08-10
申请号：PCT/FR1995000113
申请日：1995-02-01
申请人： RHONE-POULENC CHIMIE , PESCHER, Yvette , RAES, Jean-Paul , DANDA, Sylvain , CASTELAS, Bernard , RABATEL, François , MORALES, José , BONFILL, Jean
发明人： RHONE-POULENC CHIMIE
IPC分类号： C02F09/00
CPC分类号： C02F1/5245 , C02F1/444 , C02F1/54 , C02F1/72 , C02F1/76 , C02F1/78 , C02F9/00 , C02F2103/20 , C02F2103/322 , C02F2103/325 , Y10S210/905 , Y10S210/906 , Y10S210/916
摘要： A method for purifying a medium containing organic waste such as organic dejecta, wherein said medium is (i) processed with an oxidising agent; (ii) processed with a coagulant; (iii) processed with an anionic or cationic polyelectrolyte; and (iv) filtered; whereafter (v) the filtrate from step (iv) is subjected to ultrafiltration. The method is suitable for processing animal manure and effluents from olive oil and wine production.
摘要翻译：一种净化含有有机废弃物的有机废物的培养基的方法，其中所述培养基是（i）用氧化剂处理; （ii）用凝结剂处理; （iii）用阴离子或阳离子聚电解质处理; 和（iv）过滤; 之后（v）对来自步骤（iv）的滤液进行超滤。该方法适用于从橄榄油和葡萄酒生产中处理动物粪便和废水。

43. 发明申请

WO1995018068A1 COMPOSITION PRECURSOR AND CERIUM AND ZIRCONIUM MIXED OXIDE BASED COMPOSITION, METHOD FOR ITS PREPARATION AND USE THEREOF 审中-公开
标题翻译：组合物前体和基于铈和锆的混合氧化物的组合物，其制备和使用方法
公开(公告)号：WO1995018068A1
公开(公告)日：1995-07-06
申请号：PCT/FR1994001489
申请日：1994-12-20
申请人： RHONE-POULENC CHIMIE , BONNEAU, Lionel , CHOPIN, Thierry , TOURET, Olivier , VILMIN, Gabriel
发明人： RHONE-POULENC CHIMIE
IPC分类号： C01G25/02
CPC分类号： C01G25/00 , B01J23/10 , C01F17/0043 , C01P2002/72 , C01P2004/61 , C01P2006/13 , C01P2006/14 , C01P2006/16
摘要： Method for the preparation of a cerium and zirconium mixed oxide based composition. The method is characterized by the following stages: a liquid mixture is prepared comprising cerium and zirconium compounds; said mixture is placed in contact with a carbonate or bicarbonate and a reactive medium is formed having, during the reaction, a neutral or basic pH, the resulting precipitate is then recovered. A cerium and zirconium mixed oxide based composition is obtained by calcining this precursor. The composition is characterized by having a total porous volume of at least 0.6 cm /g and in that at least 40 %, and more particularly 50 %, of the total porous volume is provided by pores having a diameter of a maximum of 1 mu m.
摘要翻译：制备铈和锆混合氧化物基组合物的方法。该方法的特征在于以下阶段：制备包含铈和锆化合物的液体混合物; 将所述混合物与碳酸盐或碳酸氢盐接触，形成反应性介质，其在反应期间具有中性或碱性pH，然后回收所得沉淀物。通过煅烧该前体获得铈和锆混合氧化物基组合物。该组合物的特征在于具有至少0.6cm 3 / g的总多孔体积，并且所述总多孔体积的至少40％，更特别地50％由具有最大直径 1亩

44. 发明申请

WO1995017960A1 METHOD FOR THE PREPARATION OF A CATALYST FOR THE HYDROGENATION OF NITRILES INTO AMINES AND USE OF SAID HYDROGENATING CATALYST 审中-公开
标题翻译：制备用于将氨加成到氨基酸中的催化剂的方法和使用加氢催化剂
公开(公告)号：WO1995017960A1
公开(公告)日：1995-07-06
申请号：PCT/FR1994001477
申请日：1994-12-16
申请人： RHONE-POULENC CHIMIE , BESSON, Michèle , CORDIER, Georges , FOUILLOUX, Pierre , MASSON, Jacqueline
发明人： RHONE-POULENC CHIMIE
IPC分类号： B01J25/02
CPC分类号： C07C209/48 , B01J25/00 , B01J25/02 , C07C211/12
摘要： The present invention concerns the field of catalytic hydrogenation of nitriles into amines and, especially dinitriles such as adiponitrile (ADN) into diamines such as diamine hexamethylene (DHM). In particular, a method is provided for the preparation of a catalyst for hydrogenating nitriles into amines, of the Raney nickel type doped by at least one metallic addition element selected from columns IVB, VB and VIB of the periodic table. The aim of the invention is to provide an economical and easy to carry out method for obtaining stable catalysts which are both active and selective in relation to nitriles. The method is characterized by placing in suspension Raney nickel in a solution, preferably acid, of the metallic addition element.
摘要翻译：本发明涉及腈向胺，特别是二腈如己二腈（ADN）催化氢化成二胺如二胺六亚甲基（DHM）的领域。特别地，提供了一种制备用于将腈氢化成胺的催化剂的方法，该催化剂是由选自元素周期表的IVB，VB和VIB族的至少一种金属添加元素掺杂的阮内镍型。本发明的目的是提供一种经济且易于实施的方法，用于获得与腈相关的活性和选择性的稳定的催化剂。该方法的特征在于将阮内镍置于金属添加元素的溶液（优选酸）中。

45. 发明申请

WO1994029253A1 METHOD FOR PREPARING DIFUNCTIONAL COMPOUNDS HAVING HIGH ENANTIOMERIC PURITY 审中-公开
标题翻译：制备具有高透光性的多功能化合物的方法
公开(公告)号：WO1994029253A1
公开(公告)日：1994-12-22
申请号：PCT/FR1994000673
申请日：1994-06-08
申请人： RHONE-POULENC CHIMIE , RADISSON, Xavier
发明人： RHONE-POULENC CHIMIE
IPC分类号： C07C29/147
CPC分类号： C07C31/20 , C07B53/00 , C07C29/147 , C07C31/205 , C07C33/22
摘要： A method for preparing difunctional compounds, e.g. diols, having high enantiomeric purity (compound If) from alpha -hydroxycarboxylic acid esters (compound Id) in an anhydrous medium by a) reducing compound (Id) into compound (If) in an organic solvent medium; b) adding to the reaction medium at least one coreagent which is substituted by at least one and preferably at least two XH or YH radicals, can move compound (If) in the intermediate from a), and has a higher boiling point at normal atmospheric pressure than compound (If); and c) directly distilling the reaction medium to recover said compound (If). The coreagent is pyrocatechol, hydride, NaBH4. The method may be used to prepare an intermediate for chiral synthesis.
摘要翻译：制备双官能化合物的方法，例如在无水介质中由α-羟基羧酸酯（化合物Id）具有高对映体纯度的二醇（化合物If）a）在有机溶剂介质中还原化合物（Id）成化合物（If）; b）向反应介质中加入至少一个被至少一个，优选至少两个XH或YH基取代的化合物，可以从a）移动中间体中的化合物（If），并在正常大气压下具有较高的沸点压力比化合物（If）; 和c）直接蒸馏反应介质以回收所述化合物（If）。核心剂是邻苯二酚，氢化物，NaBH 4。该方法可用于制备用于手性合成的中间体。

46. 发明申请

WO1993005875A1 CONCENTRATED COLLOIDAL SOLUTIONS OF MONOCRYSTALLINE NON AGGREGATED PARTICLES OF METAL OXIDES, METHOD FOR THEIR PREPARATION AND APPLICATION TO THE PRODUCTION OF FILMS 审中-公开
标题翻译：金属氧化物单结晶非聚集颗粒的浓缩胶体溶液，其制备和应用于膜生产的方法
公开(公告)号：WO1993005875A1
公开(公告)日：1993-04-01
申请号：PCT/FR1992000876
申请日：1992-09-18
申请人： RHONE-POULENC CHIMIE , CHATRY, Murielle , HENRY, Marc , In, Martin , SANCHEZ, Clément
发明人： RHONE-POULENC CHIMIE
IPC分类号： B01J13/00
CPC分类号： C01B13/32 , B01J13/00 , C03C1/008 , C09D1/00 , C09J1/00
摘要： Colloidal solutions concentrated in a non aqueous solvent of monocrystalline and aggregated particles having a hydrodynamic diameter from 2 to 10 nm, of oxides of metals M of the groups 1b to 7b,8 and lanthanides, complexed by a ligand susceptible of complexing said metals in the form of alcoxides particularly. Said solutions are obtained by complexing, by the ligand, the alcoxide of metal M in non aqueous solvent medium, hydrolysis and polycondensation by means of a strong acid and heating. Utilization of said solutions to the production of oxide films.

47. 发明申请

WO1992004395A1 THERMOSETTING COMPOSITIONS BASED ON CYANATE ESTER COMPOUNDS AND POLYIMIDE COMPOUNDS HAVING DIORGANOPOLYSILOXANE GROUPING(S) 审中-公开
标题翻译：基于氰化酯化合物的热固化组合物和具有二甘醇聚氧乙烯醚基团的聚酰亚胺化合物（S）
公开(公告)号：WO1992004395A1
公开(公告)日：1992-03-19
申请号：PCT/FR1991000703
申请日：1991-09-03
申请人： RHONE-POULENC CHIMIE , CAMBERLIN, Yves
发明人： RHONE-POULENC CHIMIE
IPC分类号： C08G73/12
CPC分类号： C08G73/125 , C08G73/0638 , C08G73/0672 , C08L79/085
摘要： Thermosetting compositions including (A) at least one cyanate ester compound essentially consisting of a polyfunctional aromatic cyanic ester having at least two cyanate groups (-O-C=N) bonded to an aromatic core, in a prepolymer derived from said organic ester or in acoprepolymer derived from said cyanic ester and a polyamine; and (B) at least one elastomer essentially consisting of an N,N'-bis-maleimide having a diorganopolysiloxane grouping, in a prepolymer derived from said bismaleimide or in a coprepolymer derived from said bis-maleimide and a diamine. Said thermosetting compositions may further contain an appropriate catalyst and one or more additional polymerizable compounds including in particular a conventional bis-maleimide, an optionally halogenated epoxy resin, an acrylate reagent or an alkenylphenol, and may also be combined with known reinforcing fillers.

48. 发明申请

WO1991015537A1 SEMI-CRYSTALLINE, SEMI-AROMATIC COPOLYAMIDES 审中-公开
标题翻译：半结晶，半芳族共聚酰胺
公开(公告)号：WO1991015537A1
公开(公告)日：1991-10-17
申请号：PCT/FR1991000235
申请日：1991-03-22
申请人： RHONE-POULENC CHIMIE , LAHARY, Pierre-Yves , COQUARD, Jean
发明人： RHONE-POULENC CHIMIE
IPC分类号： C08G69/26
CPC分类号： C08K7/02 , C08G69/265 , C08K7/16 , Y10T428/31725 , C08L77/00
摘要： The invention relates to semi-crystalline, semi-aromatic copolyamides which have a temperature of deflection under a load of 1 MPa at least of 240 °C when filled with one or more filling or reinforcing fibrous fillers and moulded. They have a structure comprising recurrent units of formulae (I), (II), (III) and (IV), the units of formula (III) being optional. These copolyamides can be converted using conventional injection, extrusion or spinning machines to produce shaped objects such as solid moulded articles, yarns or films.

49. 发明申请

WO1991000303A1 CHIRAL POLYMERS AND THEIR USE FOR THE SYNTHESIS OF OPTICALLY ACTIVE COMPOUNDS WITH A HIGH DEGREE OF PURITY 审中-公开
标题翻译： CHIRAL POLYMERS及其用于合成具有高纯度的光学活性化合物的用途
公开(公告)号：WO1991000303A1
公开(公告)日：1991-01-10
申请号：PCT/FR1990000491
申请日：1990-06-29
申请人： RHONE-POULENC CHIMIE , JACQUIER, Robert , CALMES, Monique , DAUNIS, Jacques
发明人： RHONE-POULENC CHIMIE
IPC分类号： C08F246/00
CPC分类号： C08F246/00
摘要： The invention relates to chiral polymers and their use in asymmetric synthesis operations for deracemization and optical inversion, said polymers being characterized by the fact that they include a chiral pattern, a functionalization pattern, and an optional cross-linking pattern. Application: chiral organic synthesis.

50. 发明申请

WO1998002486A1 ADDITIVATION OF CELLULOSE NANOFIBRILS WITH CARBOXYL CELLULOSE WITH LOW DEGREE OF SUBSTITUTION 审中-公开
标题翻译：纤维素纳米纤维素与低取代度的羧基纤维素的添加
公开(公告)号：WO1998002486A1
公开(公告)日：1998-01-22
申请号：PCT/FR1997001290
申请日：1997-07-11
申请人： RHONE-POULENC CHIMIE , CANTIANI, Robert , GUERIN, Gilles , SENECHAL, Alain , VINCENT,Isabelle , BENCHIMOL, Joël
发明人： RHONE-POULENC CHIMIE
IPC分类号： C08L01/02
CPC分类号： B82Y5/00 , A61K8/027 , A61K8/731 , A61K2800/413 , A61Q19/00 , C08L1/02 , C08L2205/02 , C09K8/10 , C09K8/206 , C08L1/286
摘要： The invention concerns compositions containing essentially amorphous cellulose nanofibrils, carboxyl cellulose with a degree of substitution not more than 0.95 as additive, and optionally at least one co-additive, the content in additive and optional co-additive being less than 30 wt.% relative to the weight of nanofibrils and additive and optional co-additive. The invention also concerns a method for preparing such compositions, consisting in adding to a substantially amorphous nanofibril suspension, the additive and optionally the co-additive(s), then in drying the suspension thus additivated. The resulting compositions are easily redispersable and preserve all their rheological properties.
摘要翻译：本发明涉及包含基本上无定形纤维素纳米原纤维，具有不超过0.95的取代度的羧基纤维素作为添加剂和任选的至少一种共添加剂的组合物，添加剂和任选的共添加剂中的含量小于30重量％至纳米原纤维和添加剂和任选的共添加剂的重量。本发明还涉及一种制备这种组合物的方法，该方法包括添加基本无定形的纳米原纤维悬浮液，添加剂和任选的辅助添加剂，然后干燥由此添加的悬浮液。所得组合物容易再分散并保持其所有的流变性质。

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