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1. 发明申请

WO1994029253A1 METHOD FOR PREPARING DIFUNCTIONAL COMPOUNDS HAVING HIGH ENANTIOMERIC PURITY 审中-公开
标题翻译：制备具有高透光性的多功能化合物的方法
公开(公告)号：WO1994029253A1
公开(公告)日：1994-12-22
申请号：PCT/FR1994000673
申请日：1994-06-08
申请人： RHONE-POULENC CHIMIE , RADISSON, Xavier
发明人： RHONE-POULENC CHIMIE
IPC分类号： C07C29/147
CPC分类号： C07C31/20 , C07B53/00 , C07C29/147 , C07C31/205 , C07C33/22
摘要： A method for preparing difunctional compounds, e.g. diols, having high enantiomeric purity (compound If) from alpha -hydroxycarboxylic acid esters (compound Id) in an anhydrous medium by a) reducing compound (Id) into compound (If) in an organic solvent medium; b) adding to the reaction medium at least one coreagent which is substituted by at least one and preferably at least two XH or YH radicals, can move compound (If) in the intermediate from a), and has a higher boiling point at normal atmospheric pressure than compound (If); and c) directly distilling the reaction medium to recover said compound (If). The coreagent is pyrocatechol, hydride, NaBH4. The method may be used to prepare an intermediate for chiral synthesis.
摘要翻译：制备双官能化合物的方法，例如在无水介质中由α-羟基羧酸酯（化合物Id）具有高对映体纯度的二醇（化合物If）a）在有机溶剂介质中还原化合物（Id）成化合物（If）; b）向反应介质中加入至少一个被至少一个，优选至少两个XH或YH基取代的化合物，可以从a）移动中间体中的化合物（If），并在正常大气压下具有较高的沸点压力比化合物（If）; 和c）直接蒸馏反应介质以回收所述化合物（If）。核心剂是邻苯二酚，氢化物，NaBH 4。该方法可用于制备用于手性合成的中间体。

2. 发明申请

WO1998012377A1 DE-INKING LIQUID COMPOSITION AND ITS USE FOR DE-INKING PAPER 审中-公开
标题翻译：去油液体组合物及其用于脱脂纸
公开(公告)号：WO1998012377A1
公开(公告)日：1998-03-26
申请号：PCT/FR1997001642
申请日：1997-09-17
申请人： RHONE-POULENC CHIMIE , LAFON, Marie-Odile , PENNAVAIRE, Maryse
发明人： RHONE-POULENC CHIMIE
IPC分类号： D21C05/02
CPC分类号： D21C5/027 , Y02W30/648
摘要： The invention concerns a liquid composition containing at least one first surfactant (A) and at least one second surfactant selected between (B) and (C). The non-ionic surfactant (A) is a fatty alcohol selected among the polyethoxylated or polypropoxylated fatty alcohols of the formula R1-O-[(CH2CH2O)x (CH2-CH O)y]-H. The non-ionic surfactant (B) is a fatty alcohol selected among the polyethoxylated fatty alcohols of the general formula R2-O-(CH2CH2O)z-H. The non-ionic surfactant (C) is a fatty alcohol selected among the polyethoxylated fatty alcohols corresponding to the formula R3-O-(CH2CH2O)w-H. The composition can be used for de-inking paper.
摘要翻译：本发明涉及含有至少一种第一表面活性剂（A）和至少一种选自（B）和（C）之间的第二表面活性剂的液体组合物。非离子表面活性剂（A）是选自式R 1 -O - [（CH 2 CH 2 O）x - （CH 2 -CH 2 CH 3）O] -H的聚乙氧基化或聚丙氧基化脂肪醇中的脂肪醇。非离子表面活性剂（B）是选自通式R2-O-（CH2CH2O）z-H的聚乙氧基化脂肪醇中的脂肪醇。非离子表面活性剂（C）是选自对应于式R3-O-（CH2CH2O）w-H的聚乙氧基化脂肪醇中的脂肪醇。该组合物可用于脱墨纸。

3. 发明申请

WO1998007798A1 STABLE POLYORGANOSILOXANE BASED COMPOSITIONS WITH CROSS-LINKABLE FUNCTIONAL GROUPS AND THEIR USE FOR PRODUCING ANTIADHESIVE COATING 审中-公开
标题翻译：具有交联功能团的稳定的基于聚硅氧烷基的组合物及其用于生产抗蚀涂层的用途
公开(公告)号：WO1998007798A1
公开(公告)日：1998-02-26
申请号：PCT/FR1997001492
申请日：1997-08-14
申请人： RHONE-POULENC CHIMIE , PRIOU, Christian , SOLDAT, André , KERR, Stuart, R., III , BEATY, Reeshemah
发明人： RHONE-POULENC CHIMIE
IPC分类号： C09D183/06
CPC分类号： C08K5/0008 , C09D183/06 , C08L83/06 , C08L2666/28
摘要： The invention concerns a composition cross-linkable under radiation. This composition has a base of at least one polyorganosiloxane with cross-linkable functional groups, and is characterised in that said composition contains a stabilising amine agent, and an initiator system for hardening under radiation, in particular UV radiation, said composition being stable for use and storage. The amine agent is a secondary or tertiary amine of formula (VIII), a sterically congested cyclic amine of formula (IX), or an amine consisting of patterns of formulae (VIII) and (IX) mutually linked.
摘要翻译：本发明涉及在辐射下可交联的组合物。该组合物具有至少一种具有可交联官能团的聚有机硅氧烷的碱，其特征在于所述组合物含有稳定胺剂和用于在辐射下特别是UV辐射下硬化的引发剂体系，所述组合物使用稳定和存储。胺剂是式（VIII）的仲胺或叔胺，式（IX）的空间拥塞的环胺或由相互连接的式（VIII）和（IX）的图案组成的胺。

4. 发明申请

WO1998002518A1 GRANULATES OF A PERFUMED PRODUCT WITH CONTROLLED RELEASING, METHOD OF PRODUCTION AND USE IN DETERGENT COMPOSITIONS FOR DISH WASHER 审中-公开
标题翻译：具有受控释放的富含产品的颗粒，生产方法和用于洗涤剂洗涤剂组合物的方法
公开(公告)号：WO1998002518A1
公开(公告)日：1998-01-22
申请号：PCT/FR1997001248
申请日：1997-07-09
申请人： RHONE-POULENC CHIMIE , GALLIOT, Jean-Claude , JOUBERT, Daniel , LAVAULT, Sylvie , MUGUET, Jacques
发明人： RHONE-POULENC CHIMIE
IPC分类号： C11D17/00
CPC分类号： C11D3/505 , C11D17/0039
摘要： The invention concerns novel granulates of a perfumed product with controlled releasing, their method of production and their use in detergents, more particularly in compositions for dish washing. The novel granulates of a perfumed product with controlled releasing are characterised in that they comprise a central core formed essentially of the perfumed product in powder form enclosed in a peripheral layer formed essentially by a coating agent in solid state at room temperature and capable of being modified when used in a dish washer, so as to release its perfume under of the rise in temperature, during the washing cycle.
摘要翻译：本发明涉及具有控制释放的加香产品的新型颗粒，其生产方法及其在洗涤剂中的用途，更具体地涉及用于洗碗的组合物。具有控制释放的加香产品的新型颗粒的特征在于它们包括主要由粉末形式形成的中心芯，其包封在基本上由固体状态的包衣剂在室温下形成并能够被改性的外围层中当在洗碗机中使用时，以便在洗涤循环期间在温度升高的情况下释放其香料。

5. 发明申请

WO1998002487A1 ADDITIVATION OF ESSENTIALLY AMORPHOUS CELLULOSE NANOFIBRILS WITH CARBOXYL CELLULOSE WITH A HIGH DEGREE OF SUBSTITUTION 审中-公开
标题翻译：具有高度取代度的羧基纤维素的基本无定形纤维素纳米纤维的添加
公开(公告)号：WO1998002487A1
公开(公告)日：1998-01-22
申请号：PCT/FR1997001291
申请日：1997-07-11
申请人： RHONE-POULENC CHIMIE , CANTIANI, Robert , GUERIN, Gilles , SENECHAL, Alain , VINCENT, Isabelle , BENCHIMOL, Joël
发明人： RHONE-POULENC CHIMIE
IPC分类号： C08L01/02
CPC分类号： B82Y5/00 , A23L29/262 , A23L29/27 , A61K8/02 , A61K8/027 , A61K8/731 , A61K2800/413 , A61Q19/00 , C04B18/24 , C04B40/0039 , C04B2103/44 , C08L1/00 , C08L1/02 , C08L2205/02 , C09K8/10 , C09K8/206 , C11D3/222 , Y02W30/97 , C08L2666/02 , C04B24/383 , C04B24/38 , C04B24/02 , C04B20/008 , C04B20/006
摘要： The invention concerns compositions containing essentially amorphous cellulose nanofibrils, at least one additive selected among carboxyl cellulose with a degree of substitution higher than 0.95, one natural polysaccharide, one polyol. and optionally at least one co-additive, the content in additive and optional co-additive being not more than wt.30 % relative to the weight of nanofibrils and additive and optional co-additive. The invention also concerns a method for preparing such compositions, consisting in adding to an essentially amorphous nanofibril suspension, the additive, the optional co-additive, then in drying the suspension thus additivated. The resulting compositions are easily redispersable and preserve their original rheological properties.
摘要翻译：本发明涉及包含基本上无定形纤维素纳米原纤维的组合物，至少一种选自取代度高于0.95的羧基纤维素，一种天然多糖，一种多元醇的添加剂。和任选的至少一种共添加剂，相对于纳米原纤维和添加剂和任选的共添加剂的重量，添加剂和任选的共添加剂中的含量不超过重量％。本发明还涉及一种制备这种组合物的方法，该方法包括添加基本无定形的纳米原纤维悬浮液，添加剂，任选的共添加剂，然后干燥由此添加的悬浮液。所得组合物容易再分散并保持其原始的流变性质。

6. 发明申请

WO1997048665A1 ACYLATION METHOD FOR AN AROMATIC COMPOUND 审中-公开
标题翻译：芳香化合物的酰化方法
公开(公告)号：WO1997048665A1
公开(公告)日：1997-12-24
申请号：PCT/FR1997001066
申请日：1997-06-13
申请人： RHONE-POULENC CHIMIE , SPAGNOL, Michel , GILBERT, Laurent , GUILLOT, Henri , TIREL, Philippe-Jean
发明人： RHONE-POULENC CHIMIE
IPC分类号： C07B41/06
CPC分类号： C07C45/46 , C07B41/06 , Y02P20/582
摘要： The invention discloses an acylation method for an aromatic compound. The acylation method that consists in reacting the said aromatic compound with an acylation agent, in the presence of a zeolite catalyst, is characterised in that it consists: in mixing, by whatever means, the aromatic compound and the acylation agent; in passing the said mixture on a catalytic bed comprising at least one zeolite; in subjecting the reaction mixture from the catalytic bed to a recirculation the catalytic bed, for a number of times sufficient to obtain the desired conversion ratio of the substrate.
摘要翻译：本发明公开了一种芳族化合物的酰化方法。在沸石催化剂存在下使所述芳族化合物与酰化剂反应的酰化方法的特征在于：通过任何方法混合芳族化合物和酰化剂; 使所述混合物在包含至少一种沸石的催化床上通过; 在使来自催化床的反应混合物使催化床再循环足够多的时间以获得所需的转化率。

7. 发明申请

WO1997047677A1 METHOD FOR PREPARING SILICONE OILS BY HYDROSILYLATION WITH POLYORGANOHYDROGENOSILOXANES AND UNITS CONTAINING AT LEAST ONE HYDROCARBON RING INCLUDING AN OXYGEN ATOM, IN THE PRESENCE OF A HETEROGENEOUS CATALYTIC COMPOSITION 审中-公开
标题翻译：通过在多异氰酸酯基硅氧烷中的氢化制备硅油的方法以及包含氧原子的至少一个烃环的单体，在异构催化组合物存在下
公开(公告)号：WO1997047677A1
公开(公告)日：1997-12-18
申请号：PCT/FR1997001055
申请日：1997-06-12
申请人： RHONE-POULENC CHIMIE , BREUNIG, Stefan , MIGNANI, Gérard
发明人： RHONE-POULENC CHIMIE
IPC分类号： C08G77/38
CPC分类号： C07F7/21 , C08G77/38
摘要： A method for preparing low-colour, low-turbidity silicone oils by the hydrosilylation of polyorganohydrogenosiloxanes with different or identical synthons containing at least one hydrocarbon ring including an oxygen atom, said reaction being carried out in the presence of a heterogeneous catalytic composition including a metal selected from the group which consists of cobalt, rhodium, ruthenium, platinum and nickel, and deposited on an inert substrate.
摘要翻译：一种通过使用含有至少一个包含氧原子的烃环的不同或相同合成体的聚有机氢硅氧烷的氢化硅烷化制备低色低浊硅油的方法，所述反应是在非均相催化组合物的存在下进行的，包括金属选自由钴，铑，钌，铂和镍组成的组，并沉积在惰性衬底上。

8. 发明申请

WO1997047629A1 IMPROVED METHOD FOR OBTAINING ORGANOSILANES IMPLEMENTING A REDISTRIBUTION REACTION 审中-公开
标题翻译：获得有机物实现再分配反应的改进方法
公开(公告)号：WO1997047629A1
公开(公告)日：1997-12-18
申请号：PCT/FR1997001034
申请日：1997-06-11
申请人： RHONE-POULENC CHIMIE , CATHALA, Max , COLIN, Pascale , DARDARE, Michel , IGERSHEIM, Françoise
发明人： RHONE-POULENC CHIMIE
IPC分类号： C07F07/12
CPC分类号： C07F7/20 , C07F7/125
摘要： Improved method for obtaining organosilanes comprising: a redistribution reaction between a chlorinated organohydrogenosilane of formula (1) (R)a(H)bSiCl4-a-b and an organo-substituted and optionally chlorinated silane of formula (2) (R')cSiCl4-c, formulae in which: a = 1 or 2; b = 1 or 2; a + b = 3; c = 1,2, 3 or 4; the symbols R and R', the same or different, represent alkyl and aryl radicals; the distribution reaction taking place in the presence of a sufficient amount of a catalyst consisting of a Lewis acid of formula (3) M(X)d in which: M represents a metal selected among Ti, Fe, Cu, Ag, Zn, Cd, Hg, Al, Ga, In, B, Sn, Pb, Sb, and Bi; X represents a halogen atom; d represents the valency of metal M; and separation by distillation of the chlorinated organohydrogenosilane produced by redistribution; the said method being characterised in that, after redistribution, at least one redistribution catalyst inhibiting compound satisfying the following definitions is used: it is selected among the fluid polyorganosiloxanes (POS) having a viscosity at 25 DEG C not exceeding 5000 mPa.s; it is used in such proportions that the ratio r = number of gram-atoms of metal M given by the catalyst/number of gram-atoms of oxygen given by the inhibitor does not exceed 0.9.
摘要翻译：用于获得有机硅烷的改进方法包括：式（1）（R）a（H）bSiCl 4-ab的氯化有机氢硅烷与式（2）的有机取代的和任选氯化的硅烷（R'）c SiCl 4 -c之间的再分布反应其中：a = 1或2; b = 1或2; a + b = 3; c = 1,2,3或4; 符号R和R'相同或不同，表示烷基和芳基; 在足量的由式（3）M（X）d的路易斯酸组成的催化剂存在下进行分配反应，其中：M表示选自Ti，Fe，Cu，Ag，Zn，Cd ，Hg，Al，Ga，In，B，Sn，Pb，Sb和Bi; X表示卤原子; d表示金属M的化合价; 并通过再分配产生的氯化有机氢硅烷进行蒸馏分离; 所述方法的特征在于，在再分配之后，使用至少一种满足以下定义的再分布催化剂抑制化合物：其选自粘度在25℃不超过5000mPa.s的流体聚有机硅氧烷（POS）; 以比例r =由催化剂给出的金属M的数量/抑制剂给出的氧原子数不超过0.9的比例使用。

9. 发明申请

WO1997045380A1 NEW PHOSPHOMAGNESIUM CEMENT COMPOUND COMPRISING A POLYMER IN PARTICLE FORM 审中-公开
标题翻译：包含聚合物颗粒形式的新型磷酸钙水泥化合物
公开(公告)号：WO1997045380A1
公开(公告)日：1997-12-04
申请号：PCT/FR1997000904
申请日：1997-05-23
申请人： RHONE-POULENC CHIMIE , LEMOS, Dominique , ORANGE, Gilles , COLOMBET, Jean-François
发明人： RHONE-POULENC CHIMIE
IPC分类号： C04B28/34
CPC分类号： C04B28/34 , C04B14/06 , C04B14/304 , C04B24/2641 , C04B24/42 , C04B2103/50
摘要： The invention discloses a new phosphomagnesium cement that can be obtained by contacting at least one phosphorus compound and at least one magnesium compound based binder phase, with at least one polymer in water insoluble particle form, and water. The polymer can be selected among those derived from the polymerisation of at least one ethylenically unsaturated monomer and at least one monomer selected among monomers with carboxylic function and acrylamide or methacrylamide. The phosphomagnesium cement can also comprise an aminoalkylsilane, preferably an aminoalkyl(alkoxysilane).
摘要翻译：本发明公开了一种新的磷酸镁水泥，其可以通过使至少一种磷化合物和至少一种镁化合物基粘合剂相与至少一种水不溶性颗粒形式的聚合物和水接触而获得。聚合物可以选自衍生自至少一种烯键式不饱和单体和至少一种选自具有羧酸官能团的单体和丙烯酰胺或甲基丙烯酰胺的单体的聚合。磷酸镁水泥还可以包含氨基烷基硅烷，优选氨基烷基（烷氧基硅烷）。

10. 发明申请

WO1997040935A1 POLYGON-SHAPED CATALYST OR CATALYST SUPPORT 审中-公开
标题翻译：聚合形式的催化剂或催化剂支持
公开(公告)号：WO1997040935A1
公开(公告)日：1997-11-06
申请号：PCT/FR1997000701
申请日：1997-04-18
申请人： RHONE-POULENC CHIMIE , BORTZMEYER, Denis
发明人： RHONE-POULENC CHIMIE
IPC分类号： B01J35/02
CPC分类号： B01J21/063 , B01J21/06 , B01J35/026
摘要： The invention relates to new catalysts or catalyst supports with a transversal polygon-shaped cross-section. The mechanical properties of these new catalysts or catalyst supports are improved.
摘要翻译：本发明涉及具有横截面多边形横截面的新催化剂或催化剂载体。这些新催化剂或催化剂载体的机械性能得到改善。

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