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    • 24. 发明申请
    • ETCHING OF SOLAR CELL MATERIALS
    • 太阳能电池材料的蚀刻
    • WO2005013321A3
    • 2006-02-02
    • PCT/US2004023198
    • 2004-07-19
    • SUNPOWER CORPROSE DOUGLAS HURALWONG PONGSTHORNSMITH DAVID D
    • ROSE DOUGLAS HURALWONG PONGSTHORNSMITH DAVID D
    • H01L20060101H01L31/00H01L31/18C23F1/00C23F1/18C23F1/20C23F1/34C23F1/36
    • H01L31/022425H01L31/02008H01L31/18
    • A solar cell is fabricated by etching one or more of its layers without substantially etching another layer of the solar cell. In one embodiment, a copper layer in the solar cell is etched (506) without substantially etching a topmost metallic layer comprising tin. For example, an etchant comprising sulfuric acid and hydrogen peroxide may be employed to etch the copper layer selective to the tin layer. A particular example of the aforementioned etchant is a Co-Bra Etch® etchant modified to comprise about 1% by volume of sulfuric acid, about 4% by volume of phosphoric acid, and about 2% by volume of stabilized hydrogen peroxide. In one embodiment, an aluminum layer in the solar cell is etched (514) without substantially etching the tin layer. For example, an etchant comprising potassium hydroxide may be employed to etch the aluminum layer without substantially etching the tin layer.
    • 通过蚀刻其一个或多个层而不基本上蚀刻太阳能电池的另一层来制造太阳能电池。 在一个实施例中,在基本上蚀刻包含锡的最顶层的金属层的同时蚀刻太阳能电池中的铜层(506)。 例如,可以使用包含硫酸和过氧化氢的蚀刻剂来蚀刻对锡层有选择性的铜层。 上述蚀刻剂的一个具体实例是改性为包含约1体积%的硫酸,约4体积%的磷酸和约2体积%的稳定的过氧化氢的Co-Bra Etch蚀刻剂。 在一个实施例中,蚀刻(514)太阳能电池中的铝层而基本上不蚀刻锡层。 例如,可以使用包含氢氧化钾的蚀刻剂来蚀刻铝层而基本上不蚀刻锡层。
    • 25. 发明申请
    • ETCHING COMPOSITION AND USE THEREOF WITH FEEDBACK CONTROL OF HF IN BEOL CLEAN
    • 清洁环境中的HF反馈控制​​组合物及其使用方法
    • WO0210480A3
    • 2002-10-31
    • PCT/US0123905
    • 2001-07-30
    • INFINEON TECHNOLOGIES CORP
    • RAMACHANDRAN RAVIKUMARPENNER KLAUSNICHTERWITZ MARIONNITSCHKE CHRISTIANEKRAUSE HOLGE
    • C09K13/08C23F1/18C23F1/20G03F7/42H01L21/02H01L21/306H01L21/3213C23G1/00G01N1/00
    • H01L21/02071C09K13/08C11D3/3942C11D3/3947C11D7/08C11D11/0047C23F1/00C23F1/18C23F1/20G03F7/423G03F7/426H01L21/02052H01L21/02063
    • A process for providing an aqueous back-end-of-line (BEOL) clean with feed-back control to monitor the active component of HF in the clean, for a wiring/interconnect of a reactive ion etched semiconductor device, comprising: subjecting the reactive ion etched semiconductor device to a post metal RIE clean using an etchant composition comprising about 0.01 to about 15 percent by weight of sulfuric acid; about 0.1 to about 100 ppm of a fluoride containing compound; and a member selected from the group consisting of about 0.01 to about 20 percent by weight of hydrogen peroxide or about 1 to about 30 ppm of ozone, comprising: a) mixing water, sulfuric acid and hydrogen peroxide in a mixing tank; b) mixing HF directly into the mixing tank or adding HF into a separate vessel for wafer processing, either before, during or after the mixture water, sulfuric acid and hydrogen peroxide as a mixture is transported to the separate tank for wafer processing; c) taking a sample comprising HR from the mixing tank or HF from the wafer processing tank and sending the sample through a feedback loop; d) comprising the sample to a standard dilute solution of HF to obtain a value of HF concentration in the sample; e) inputting the value to a tank tool recipe control to cause any needed adjustment in concentration of HF to a predetermined range, either in the mixing tank or the wafer processing vessel; and f) subjecting the wiring/interconnect of the semiconductor device to etching by the etchant composition to remove sidewall polymer, polymer rails and via residue without etching conductive materials during removal of sidewall polymer, polymer rails, and via residue.
    • 一种用于反馈控制以提供水性生产线后端(BEOL)清洁的方法,用于监视清洁过程中HF的活性成分,用于反应离子蚀刻半导体器件的布线/互连,包括:使所述 使用包含约0.01重量%至约15重量%的硫酸的蚀刻剂组合物对所述反应离子蚀刻的半导体器件进行后金属RIE清洁; 约0.1至约100ppm的含氟化合物; 和选自约0.01至约20重量%的过氧化氢或约1至约30ppm的臭氧的成员,包括:a)在混合罐中混合水,硫酸和过氧化氢; b)将HF直接混入混合罐或将HF加入单独的容器中用于晶片处理,或者在混合物水之前,之中或之后,将硫酸和过氧化氢混合物输送到单独的罐中进行晶片处理; c)从混合罐中取出包含HR的样品或从晶片处理罐取出HF,并通过反馈回路发送样品; d)将样品包含在HF的标准稀释溶液中以获得样品中HF浓度的值; e)将该值输入到罐工具配方控制中,以在混合罐或晶圆处理容器中引起HF浓度到预定范围的任何需要的调整; 以及f)在除去侧壁聚合物,聚合物轨道和通孔残留物期间,不蚀刻导电材料,通过蚀刻剂组合物对半导体器件的布线/互连进行蚀刻以去除侧壁聚合物,聚合物轨道和通孔残余物。
    • 27. 发明申请
    • LOW ETCH ALKALINE ZINCATE COMPOSITION AND PROCESS FOR ZINCATING ALUMINUM
    • 低含量碱性锌酸盐组合物和铝锌合金工艺
    • WO99058256A1
    • 1999-11-18
    • PCT/US1999/007453
    • 1999-04-05
    • B32B15/01C23C18/18C23C18/22C23C18/31C23F1/20C25D5/44G11B5/84B05D5/04B32B15/00
    • C25D5/44C23C18/1651C23C18/1844C23C18/31C23C18/54C23F1/20
    • A method is provided for zincating aluminum substrates for metal plating thereon wherein the plated aluminum product has smoothness, dimensional integrity and increased production yield of the plated products. The substrates also have enhanced paramagnetic thermal stability of ENP coatings used on memory disk products. A zincate bath contains as additives Fe and NaNO3, and a chelator to chelate the iron, with a preferred iron chelator being Rochelle Salt and with the amount of Fe being controlled at a preferred concentration of 0.2 to 0.3 g/l. A preferred zincating method employs an etchant composition comprising HNO3, H2SO4 and H3PO4 to etch the aluminum substrate prior to zincating. Use of this etchant composition, either alone or with the zincate bath of the invention, is particularly effective for aluminum substrates which have been ground to a smoothness of less than 100 ANGSTROM . The etchant is non-aggressive and removes metal oxides formed by the grinding and annealing process to form the aluminum substrates used to fabricate the memory disks. The etchant also preserves the dimensional integrity of the substrate and prepares the surface for zincate deposition. It is highly preferred to use the etchant and zincate bath of the invention in the same metal plating process to provide an enhanced process and metal plated product. The etchant or zincating bath may also be used alone in other plating processes requiring these type substrate treatments.
    • 提供了一种用于镀锌铝基板以进行金属镀覆的方法,其中镀铝产品具有平滑度,尺寸完整性和提高的镀覆产品的生产成本。 基板还具有增强的记忆盘产品上使用的ENP涂层的顺磁性热稳定性。 锌酸盐浴包含添加剂Fe +和NaNO 3,螯合剂螯合铁,优选的铁螯合剂为罗谢尔盐,Fe 2+的量控制在0.2至0.3的优选浓度 克/升。 优选的锌化方法使用包含HNO 3,H 2 SO 4和H 3 PO 4的蚀刻剂组合物在锌化之前蚀刻铝基材。 单独使用或与本发明的锌酸盐浴的这种蚀刻剂组合物的使用对于已被研磨成小于100安培的平滑度的铝基材特别有效。 蚀刻剂是非侵蚀性的,并且去除通过研磨和退火工艺形成的金属氧化物以形成用于制造存储盘的铝基板。 蚀刻剂还保留了基材的尺寸完整性,并为锌酸盐沉积制备了表面。 在相同的金属电镀工艺中,非常优选使用本发明的蚀刻剂和锌酸盐浴来提供增强的工艺和金属镀覆的产品。 蚀刻剂或锌化浴也可以单独用于需要这种类型的底物处理的其它电镀工艺中。