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21. 发明申请

WO2003040159A3 BIDENTATE LIGANDS FOR THE CARBONYLATION OF UNSATURATED COMPOUNDS 审中-公开
公开(公告)号：WO2003040159A3
公开(公告)日：2003-05-15
申请号：PCT/EP2002/012380
申请日：2002-11-05
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DRENT, Eit , VAN GINKEL, Roelof , VAN DER MADE, Renata, Helena
发明人： DRENT, Eit , VAN GINKEL, Roelof , VAN DER MADE, Renata, Helena
IPC分类号： C07F9/50
摘要： Bidentate ligand of formula (I), R 1 R 2 M 1 -R-M 2 R 3 R 4 wherein M 1 and M 2 each indenpendently represent P, As or Sb; R 1 , R 2 , R 3 and R 4 each independently represent the same or a different optionally substituted organic group and at least one of R 1 , R 2 , R 3 and R 4 contains a tertiary carbon atom through which the group is linked to M 1 or M 2 ; and R represents a bridging group based on a trimethylene group connecting M 1 and M 2 of which the middle carbon atom is double bonded to a non-metal element chosen from group 14, 15 or 16 of the periodic table of elements. Catalyst comprising this bidentate ligand and carbonylation process n which this catalyst is used.

22. 发明申请

WO2002083747A2 PROCESS FOR THE PREPARATION OF A POLYMER-AMINE 审中-公开
标题翻译：制备聚合物胺的方法
公开(公告)号：WO2002083747A2
公开(公告)日：2002-10-24
申请号：PCT/EP2002/003487
申请日：2002-03-26
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DRENT, Eit , VAN DER MADE, Renata, Helena
发明人： DRENT, Eit , VAN DER MADE, Renata, Helena
IPC分类号： C08F8/32
CPC分类号： C10L1/2383 , B01J31/1845 , C08F8/32 , C08F2810/40 , C08F8/04 , C08F8/00 , C08F110/06
摘要： Process for the preparation of a polymer-amine comprising:_a) reacting an ethylenically unsaturated polymer with carbon monoxide and hydrogen in the presence of a hydroformylation catalyst, yielding a polymer-aldehyde;_b) reacting the polymer-aldehyde of step a) in a carbon monoxide depleted environment with a nitrogen-containing compound and hydrogen in the presence of an amination catalyst yielding a polymer-amine; wherein step b) is carried out in the presence of the hydroformylation catalyst used in step a)._Atactic polymer-amine, having in the range from 10 to 40 "mm" triads; in the range from 20 to 80 "mr" or "rm" triads; and in the range from 10 to 40 "rr" triads. Fuel composition or lubricating oilcomposition comprising such an atactic polymer-amine.
摘要翻译：制备聚合物胺的方法包括：a）在加氢甲酰化催化剂存在下使烯属不饱和聚合物与一氧化碳和氢反应，得到聚合物醛; b）使步骤a）的聚合物醛与在含胺化催化剂的存在下，用含氮化合物和氢气消耗一氧化碳的环境，得到聚合物 - 胺; 其中步骤b）在步骤a）中使用的加氢甲酰化催化剂的存在下进行。 - 具有10至40“mm”三元组范围内的无规立构聚合物 - 胺; 在20至80“mr”或“rm”三元组范围内; 在10到40个“rr”三合一的范围内。燃料组合物或包含这种无规立构聚合物 - 胺的润滑油组合物。

23. 发明申请

WO2004054946A1 HYDROFORMYLATION PROCESS FOR THE CONVERSION OF AN ETHYLENICALLY UNSATURATED COMPOUND TO AN ALCOHOL 审中-公开
标题翻译：将乙烯基化合物转化成醇的氢化方法
公开(公告)号：WO2004054946A1
公开(公告)日：2004-07-01
申请号：PCT/EP2003/051027
申请日：2003-12-16
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DRENT, Eit , SUYKERBUYK, Jacoba Catherina Lucia Johanna
发明人： DRENT, Eit , SUYKERBUYK, Jacoba Catherina Lucia Johanna
IPC分类号： C07C29/16
CPC分类号： C07C29/16 , B01J23/75 , B01J31/189 , B01J2231/321 , B01J2531/845 , C07C31/125
摘要： The invention pertains to a hydroformylation process for the conversion of an ethylenically unsaturated compound to an alcohol comprising a first step of reacting at an elevated temperature in a reactor the ethylenically unsaturated compound, carbon monoxide, hydrogen, and a phosphine-containing cobalt hydroformylation catalyst, which are dissolved in a solvent, followed by a second step of separating a mixture comprising the alcohol and heavy ends from a solution comprising the catalyst and the solvent, followed by a third step of recycling the solution to the reactor.
摘要翻译：本发明涉及用于将烯键式不饱和化合物转化为醇的加氢甲酰化方法，该方法包括在高温下在反应器中使烯键式不饱和化合物，一氧化碳，氢气和含膦的羰基氢化羰基化催化剂反应的第一步骤，其溶解在溶剂中，随后是第二步，从包含催化剂和溶剂的溶液中分离包含醇和重馏分的混合物，随后将溶液再循环到反应器中的第三步骤。

24. 发明申请

WO2004029014A1 PROCESS FOR THE PRODUCTION OF PRIMARY ALCOHOLS 审中-公开
标题翻译：生产初级酒精的方法
公开(公告)号：WO2004029014A1
公开(公告)日：2004-04-08
申请号：PCT/EP2003/050650
申请日：2003-09-24
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DRENT, Eit , VAN DER MADE, Renata Helena
发明人： DRENT, Eit , VAN DER MADE, Renata Helena
IPC分类号： C07C29/16
CPC分类号： C07C29/16 , B01J31/0215 , B01J31/24 , C07C31/125
摘要： A process for producing primary alcohols from secondary alcohols and/or tertiary alcohols and/or ketones, wherein the process comprises reacting a compound selected from a secondary alcohol, a tertiary alcohol, a ketone, or mixtures thereof, with carbon monoxide and hydrogen in the presence of a catalyst based on: i) a source of Group VIII metal, ii)a bidentate ligand having the general formula (I): R 1 -R 2 M 1 -R-M 2 R 3 R 4 wherein M 1 and M 2 are independently P, As or Sb; R 1 and R 2 together represent a bivalent substituted or unsubstituted cyclic group whereby the two free valencies are linked to M l ; R 3 and R 4 independently represent a substituted or unsubstituted hydrocarbyl group, or together represent a bivalent or non-substituted cyclic group whereby the two free valencies are linked to M 2 ; and R represents a bivalent aliphatic bridging group; and iii) an acid having a pK a of 3 or less which is in excess over the Group VIII metal.
摘要翻译：由仲醇和/或叔醇和/或酮生产伯醇的方法，其中该方法包括使选自仲醇，叔醇，酮或其混合物的化合物与一氧化碳和氢气在基于以下的催化剂的存在：i）VIII族金属源，ii）具有通式（I）的二齿配体：R 1 -R 2 M 1 -R M 2 R 3 其中M 1和M 2独立地是P，As或Sb; R 1和R 2一起表示二价取代或未取代的环状基团，其中两个自由价与M 1连接; R 3和R 4独立地表示取代或未取代的烃基，或一起表示二价或未取代的环状基团，由此两种自由价与M 2连接; R表示二价脂肪族桥基; 和iii）pKa为3以下的酸，其超过VIII族金属。

25. 发明申请

WO2002064250A2 PROCESS FOR THE CARBONYLATION OF ETHYLENICALLY UNSATURATED COMPOUNDS, BIDENTATE DIPHOSPHINE COMPOSITION USED IN THIS PROCESS AND PROCESSES FOR PREPARATION OF THIS BIDENTATE DIPHOSPHINE COMPOSITION 审中-公开
标题翻译：亚乙基不饱和化合物的羰基化方法，本方法中使用的双歧酚二磷酸酯组合物及其制备方法本发明涉及双歧杆菌组合物
公开(公告)号：WO2002064250A2
公开(公告)日：2002-08-22
申请号：PCT/EP2002/001036
申请日：2002-01-31
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , ARNOLDY, Peter , BOLINGER, Cornelius, Mark , DRENT, Eit , EBERHARD, Michael, Rolf , HEERES, Hero, Jan , VAN DER LINDEN, Adrianus, Johannes , MUL, Wilhelmus, Petrus , PRINGLE, Paul, Gerard , SUYKERBUYK, Jacoba, Catherina, Lucia, Johanna , TAU, Kwoliang, David
发明人： ARNOLDY, Peter , BOLINGER, Cornelius, Mark , DRENT, Eit , EBERHARD, Michael, Rolf , HEERES, Hero, Jan , VAN DER LINDEN, Adrianus, Johannes , MUL, Wilhelmus, Petrus , PRINGLE, Paul, Gerard , SUYKERBUYK, Jacoba, Catherina, Lucia, Johanna , TAU, Kwoliang, David
IPC分类号： B01J31/24
CPC分类号： B01J31/248 , B01J23/42 , B01J2231/321 , B01J2531/82 , B01J2531/828 , C07C45/49 , C07C45/50 , C07F9/5072 , C07F9/5095 , C07F9/65683 , C07C47/02
摘要： Process for the carbonylation of optionally substituted ethylenically unsaturated compounds by reaction with carbon monoxide and a coreactant in the presence of a catalyst system. The catalyst system includes (a) a source of Pt group metal cations, (b) a bidentate diphosphine composition. More than 60% w/w of bidentate diphosphine present in the bidentate diphosphine composition has the general formula (II) X 1 -R-X 2 wherein X 1 and X?2 ¿independently represent an optionally substituted symmetrical phosphabicycloalkyl group, having at least 5 ring atoms; and R represents a bivalent organic bridging group, connecting both phosphorus atoms. Bidentate diphosphine composition wherein more than 60% w/w of bidentate diphosphine present has the general formula (II) ) X 1 -R-X?2 ¿ wherein X 1 and X?2 ¿independently represent an optionally substituted symmetrical phosphabicycloalkyl group, having at least 5 ring atoms; and R represents a bivalent organic bridging group, connecting both phosphorus atoms, with the proviso that the bidentate diphosphine is not 1,3-PP'bis(9-phosphabicyclo[3.3.1]nonyl)propane. In addition methods to prepare such a bidentate diphosphine composition are described.
摘要翻译：在催化剂体系存在下通过与一氧化碳和共反应物反应来羰基化任选取代的烯属不饱和化合物的方法。催化剂体系包括（a）Pt族金属阳离子源，（b）二齿二膦组合物。存在于双齿二膦组合物中的二价二膦的60％重量以上具有通式（II）X 1 -RX 2，其中X 1和X 2独立地表示任选取代的对称磷杂双环烷基具有至少5个环原子; R表示连接两个磷原子的二价有机桥基。其中多于60％w / w的二齿二膦存在的二齿二膦组合物具有通式（II））X 1 -RX 2其中X 1和X 2独立地表示任选取代的对称磷杂双环烷基具有至少5个环原子; 并且R表示连接两个磷原子的二价有机桥连基团，条件是二齿二膦不是1,3-PP'-双（9-磷杂双环[3.3.1]壬基）丙烷。另外还描述了制备这种二齿二膦组合物的方法。

26. 发明申请

WO1997003943A1 PROCESS FOR THE CONTINUOUS CARBONYLATION OF OLEFINS 审中-公开
标题翻译：烯烃连续加成方法
公开(公告)号：WO1997003943A1
公开(公告)日：1997-02-06
申请号：PCT/EP1996003170
申请日：1996-07-16
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , SHELL CANADA LIMITED
发明人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , SHELL CANADA LIMITED , DRENT, Eit , HASSELAAR, Melis
IPC分类号： C07C67/38
CPC分类号： C07C67/38 , C07C69/24
摘要： The invention relates to a process for the continuous carbonylation of olefins whereby an olefin is reacted with carbon monoxide and a nucleophilic compound in the presence of a catalyst system based on: (a) a source of a Group VIII metal cations, (b) a source of an aliphatic diphosphine, and (c) a carboxylic acid which is the hydrocarboxylation product of the olefin, whereby during the process the carboxylic acid is either added continuously or intermittently or is prepared in-situ by continuous or intermittent addition of water.
摘要翻译：本发明涉及烯烃的连续羰基化方法，其中烯烃在催化剂体系的存在下与一氧化碳和亲核化合物反应，其基于：（a）VIII族金属阳离子源，（b）脂肪族二膦的来源，和（c）作为烯烃的加氢羧化产物的羧酸，由此在该过程中，羧酸连续地或间歇地加入，或通过连续或间歇加入水原位制备。

27. 发明申请

WO1997027160A1 PROCESS FOR THE PREPARATION OF PROPYNE 审中-公开
标题翻译：制备丙烯的方法
公开(公告)号：WO1997027160A1
公开(公告)日：1997-07-31
申请号：PCT/EP1997000388
申请日：1997-01-23
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.
发明人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , BLANK, Peter, Bastiaan , DRENT, Eit , VAN DER EIJK, Johan, Meindert , HOVING, Johan, Mettinus , SIMONS, Theodoor, Johan, Leonard, Wenceslaus
IPC分类号： C07C11/22
CPC分类号： C07C5/23 , C07C11/22 , C07C67/38 , C07C2527/24 , C07C2531/02 , C07C69/54
摘要： The invention relates to a process for the preparation of propyne by contacting a propadiene-containing feed with an isomerization catalyst comprising a strong base dissolved in an amide solvent.
摘要翻译：本发明涉及通过使含丙二烯的进料与包含溶解在酰胺溶剂中的强碱的异构化催化剂接触来制备丙炔的方法。

28. 发明申请

WO1995005354A1 HYDROFORMYLATION PROCESS 审中-公开
标题翻译：氢化工艺
公开(公告)号：WO1995005354A1
公开(公告)日：1995-02-23
申请号：PCT/EP1994002762
申请日：1994-08-18
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , SHELL CANADA LIMITED
发明人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , SHELL CANADA LIMITED , DRENT, Eit , PELLO, Dennis, Humphrey, Louis , SUYKERBUYK, Jacoba, Catherina, Lucia, Johanna , VAN GOGH, Johan
IPC分类号： C07C29/16
CPC分类号： C07C51/14 , C07C29/16 , C07C45/50 , C07C67/293 , C07C47/347 , C07C47/12 , C07C69/14 , C07C31/125 , C07C31/12 , C07C31/20
摘要： Process for the hydroformylation of ethylenically unsaturated compounds, by reaction with carbon monoxide and hydrogen in the presence of a catalyst based on a metal of the platinum group, a source of anions other than halide anions and a bidentate ligand of the formula R R M RM R R wherein M and M are phosphorus, arsenic or antimony, R is a bivalent organic bridging group with 1 to 4 atoms in the bridge, R and R together represent a bivalent cyclic group and R and R independently represent an optionally substituted hydrocarbyl group or together represent a bivalent substituted or non-substituted cyclic group whereby the two free valencies are linked to M .
摘要翻译：在基于铂族金属的催化剂存在下，与一氧化碳和氢气反应的烯属不饱和化合物的加氢甲酰化方法，除卤化物阴离子之外的阴离子源和式R 1的二齿配体， R 2 M 1 R 2 R 3 R 4其中M 1和M 2是磷，砷或锑，R是具有1至4个原子的二价有机桥连基团桥，R 1和R 2一起表示二价环状基团，R 3和R 4独立地表示任选取代的烃基或一起代表二价取代或未取代的环状基团，由此两者自由价格与M 2相关。

29. 发明申请

WO1997038964A1 PROCESS FOR THE CARBONYLATION OF ETHYLENICALLY UNSATURATED COMPOUNDS 审中-公开
标题翻译：乙烯化不饱和化合物的羰基化方法
公开(公告)号：WO1997038964A1
公开(公告)日：1997-10-23
申请号：PCT/EP1997001905
申请日：1997-04-15
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.
发明人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DRENT, Eit , DE CASTRO LOUREIRO BARRETO ROSA, Maria, Manuel , GIILESPIE, Harold, Moncrieff , SAVAGE, Paul, David , VAN HELDEN, Arend, Kuindert , MCKENNA, Eugene, Gerard
IPC分类号： C07C67/38
CPC分类号： C10M111/00 , C07C67/38 , C07C69/017 , C10M105/34 , C10M2205/028 , C10M2207/027 , C10M2207/144 , C10M2207/146 , C10M2207/262 , C10M2207/281 , C10M2207/2815 , C10M2207/282 , C10M2207/283 , C10M2207/284 , C10M2207/2845 , C10M2207/285 , C10M2207/286 , C10M2207/289 , C10M2215/04 , C10M2215/086 , C10M2215/26 , C10M2215/28 , C10M2217/046 , C10M2217/06 , C10M2219/044 , C10M2223/045 , C10N2210/02 , C07C69/24
摘要： The invention provides a process for the carbonylation of ethylenically unsaturated compounds by reaction thereof with carbon monoxide and a coreactant in the presence of a catalyst system obtainable by combining (a) a source of a Group VIII metal cation, (b) a phosphine, arsine or stibine compound acting as a ligand; and (c) a source of anions, other than halide anions, carried out in the presence of substoichiometric amounts of halide anions and/or - in case of a coreactant other than an aromatic alcohol - in the presence of a phenolic promoter. It also provides novel alkylphenol esters that find use as synthetic lubricant.
摘要翻译：本发明提供了一种烯属不饱和化合物的羰基化方法，其通过与一氧化碳和共反应物在存在催化剂体系的情况下进行羰基化，所述催化剂体系可通过将（a）第Ⅷ族金属阳离子源，（b）膦，胂或作为配体的酪蛋白化合物; 和（c）在亚化学计量的卤化物阴离子存在下和/或 - 在酚类助催化剂存在下的共反应物的情况下，除卤化物阴离子以外的阴离子源。它还提供可用作合成润滑剂的新型烷基酚酯。

30. 发明申请

WO1997000127A2 CATALYST COMPOSITION AND PROCESS FOR THE PREPARATION OF COPOLYMERS OF CARBON MONOXIDE AND AN OLEFINICALLY UNSATURATED COMPOUND 审中-公开
标题翻译：催化剂组合物和制备一氧化碳和烯烃不饱和化合物的共聚物的方法
公开(公告)号：WO1997000127A2
公开(公告)日：1997-01-03
申请号：PCT/EP1996002537
申请日：1996-06-11
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.
发明人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DRENT, Eit , DE KOCK, Mirjam, Catharina, Theodora
IPC分类号： B01J00/00
CPC分类号： C08G67/02
摘要： A catalyst composition which is based upon (a) a source of nickel cations, and (b) a bidentate ligand of the general formula (I): R R M -R-M R R wherein M and M represent independently phosphorus, nitrogen, arsenic or antimony, R , R , R and R represent independently optionally substituted hydrocarbyl groups on the understanding that at least one of R , R , R and R represent a substituted aryl group, and R represents a bivalent bridging group of which the bridge consists of at most two bridging atoms, and a process for the preparation of copolymers of carbon monoxide and an olefinically unsaturated compound comprising contacting the monomers in the presence of the said catalyst composition.
摘要翻译：一种催化剂组合物，其基于（a）镍阳离子源，和（b）通式（I）的二齿配体：R 1 R 2 M 1 -R M 2 R 其中M 1和M 2独立地表示磷，氮，砷或锑，R 1，R 2，R 3和R 4独立地表示任选取代的烃基理解为R 1，R 2，R 3和R 4中的至少一个表示取代的芳基，R表示二价桥连基团，其桥由至多两个桥连原子，以及制备一氧化碳和烯属不饱和化合物的共聚物的方法，包括在所述催化剂组合物存在下使单体接触。

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