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1. 发明申请

WO2003070370A1 PROCESS FOR THE CARBONYLATION OF AN ETHYLENICALLY UNSATURATED COMPOUND AND CATALYST THEREFORE 审中-公开
标题翻译：乙烯化合物和催化剂的羰化方法
公开(公告)号：WO2003070370A1
公开(公告)日：2003-08-28
申请号：PCT/EP2003/001688
申请日：2003-02-18
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DRENT, Eit , VAN DER MADE, Renata, Helena , PRINGLE, Paul, Gerard , PUGH, Robert, Ian
发明人： DRENT, Eit , VAN DER MADE, Renata, Helena , PRINGLE, Paul, Gerard , PUGH, Robert, Ian
IPC分类号： B01J31/24
CPC分类号： B01J31/2485 , B01J31/28 , B01J2231/321 , B01J2531/80 , B01J2531/822 , B01J2531/824 , B01J2531/828 , B01J2531/847 , C07C51/14 , C07F9/65683 , C07C53/122
摘要： Process for the carbonylation of an ethylenically unsaturated compound with carbon monoxide and a coreactant. The carbonylation reaction is carried out in the presence of a novel catalyst comprising: a) a source of a group VIII metal; b) a bidentate diphosphine of formula (I), wherein R?1¿ represents a bivalent radical that together with the phosphorus atom to which it is attached is an optionally substituted 2-phospha-tricyclo[3.3.1.1{3,7}]-decyl group or a derivative thereof in which one or more of the carbon atoms are replaced by heteroatoms ("2-PA" group); wherein R?2¿ and R?3¿ independently represent univalent radicals of up to 20 atoms or jointly form a bivalent radical of up to 20 atoms; and wherein A?1¿ and A?2¿ independently represent optionally substituted alkylene groups and R represents an optionally substituted aromatic group; and c) a source of anions.
摘要翻译：用一氧化碳和共反应物羰基化烯属不饱和化合物的方法。羰基化反应在新型催化剂存在下进行，该催化剂包括：式Ⅰ的Ⅷ族金属二齿二膦的源，其中R 1表示与连接的磷原子一起的二价基团是任选取代的2-磷杂三环[3.3.1.1 {3,7}] - 癸基或其衍生物，其中一个或多个碳原子被杂原子“2-PA”基团取代，其中R 2和 R 3独立地表示至多20个原子的一价基团或共同形成至多20个原子的二价基团，其中A 1和A 2独立地表示任选取代的亚烷基，R表示任选取代的芳族基团，阴离子的来源。

2. 发明申请

WO2003040159A3 BIDENTATE LIGANDS FOR THE CARBONYLATION OF UNSATURATED COMPOUNDS 审中-公开
公开(公告)号：WO2003040159A3
公开(公告)日：2003-05-15
申请号：PCT/EP2002/012380
申请日：2002-11-05
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DRENT, Eit , VAN GINKEL, Roelof , VAN DER MADE, Renata, Helena
发明人： DRENT, Eit , VAN GINKEL, Roelof , VAN DER MADE, Renata, Helena
IPC分类号： C07F9/50
摘要： Bidentate ligand of formula (I), R 1 R 2 M 1 -R-M 2 R 3 R 4 wherein M 1 and M 2 each indenpendently represent P, As or Sb; R 1 , R 2 , R 3 and R 4 each independently represent the same or a different optionally substituted organic group and at least one of R 1 , R 2 , R 3 and R 4 contains a tertiary carbon atom through which the group is linked to M 1 or M 2 ; and R represents a bridging group based on a trimethylene group connecting M 1 and M 2 of which the middle carbon atom is double bonded to a non-metal element chosen from group 14, 15 or 16 of the periodic table of elements. Catalyst comprising this bidentate ligand and carbonylation process n which this catalyst is used.

3. 发明申请

WO2003040065A3 BIDENTATE LIGAND FOR THE TELOMERIZATION OF DIENES 审中-公开
公开(公告)号：WO2003040065A3
公开(公告)日：2003-05-15
申请号：PCT/EP2002/012381
申请日：2002-11-05
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DRENT, Eit , EBERHARD, Michael, Rolf , VAN DER MADE, Renata, Helena , PRINGLE, Paul, Gerard
发明人： DRENT, Eit , EBERHARD, Michael, Rolf , VAN DER MADE, Renata, Helena , PRINGLE, Paul, Gerard
IPC分类号： C07B37/02
摘要： Process for the telomerization of a conjugated diene, wherein the conjugated diene is reacted with a compound containing an active hydrogen atom and having a formula R-H in the presence of a telomerization catalyst based on: (a) a source of group VIII metal, (b) a bidentate ligand wherein the bidentate ligand has the general Formula (I): R 1 R 2 M 1 -R-M 2 R 3 R 4 wherein M 1 and M 2 are independently P, As or Sb; R 1 , R 2 , R 3 and R 4 independently represent a monovalent aliphatic group; or R 1 , R 2 and M 1 together and/or R 3 , R 4 and M 2 together independently represent an optionally substituted aliphatic cyclic group with at least 5 ring atoms, of which one is the M 1 or M 2 atom, respectively; R represents a bivalent organic bridging group; and novel bidentate diphosphines which can be used in this process.

4. 发明申请

WO2003040065A2 PROCESS FOR THE TELOMERIZATION OF A CONJUGATED DIENE, CATALYST AND BIDENTATE LIGAND USEFUL THEREIN 审中-公开
标题翻译：连接的二烯，催化剂和二氯甲烷配位体的有机合成方法
公开(公告)号：WO2003040065A2
公开(公告)日：2003-05-15
申请号：PCT/EP2002/012381
申请日：2002-11-05
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DRENT, Eit , EBERHARD, Michael, Rolf , VAN DER MADE, Renata, Helena , PRINGLE, Paul, Gerard
发明人： DRENT, Eit , EBERHARD, Michael, Rolf , VAN DER MADE, Renata, Helena , PRINGLE, Paul, Gerard
IPC分类号： C07B37/02
CPC分类号： B01J31/248 , B01J23/44 , B01J31/1895 , B01J31/24 , B01J2231/20 , B01J2531/80 , B01J2531/824 , C07C2/36 , C07C2/406 , C07C41/06 , C07C253/30 , C07C2531/24 , C07C2531/28 , C07D201/08 , C07F9/5027 , C07F9/65683 , C07C255/19 , C07C11/12 , C07C43/15
摘要： Process for the telomerization of a conjugated diene, wherein the conjugated diene is reacted with a compound containing an active hydrogen atom and having a formula R-H in the presence of a telomerization catalyst based on: (a) a source of group VIII metal, (b) a bidentate ligand wherein the bidentate ligand has the general Formula (I): R 1 R 2 M 1 -R-M 2 R 3 R 4 wherein M 1 and M 2 are independently P, As or Sb; R 1 , R 2 , R 3 and R 4 independently represent a monovalent aliphatic group; or R 1 , R 2 and M 1 together and/or R 3 , R 4 and M 2 together independently represent an optionally substituted aliphatic cyclic group with at least 5 ring atoms, of which one is the M 1 or M 2 atom, respectively; R represents a bivalent organic bridging group; and novel bidentate diphosphines which can be used in this process.
摘要翻译：共轭二烯的调聚方法，其中共轭二烯在调聚催化剂存在下，与含有活性氢原子并具有式RH的化合物反应：（a）VIII族金属源，（b ）双齿配体，其中二齿配体具有通式（I）：R 1 R 2 M 1 -R M 2 R 3 R 4其中M 1和M 2 >独立为P，As或Sb; R 1，R 2，R 3和R 4独立地表示一价脂族基团; 或R 1，R 2和M 1一起和/或R 3，R 4和M 2一起独立地表示任选取代的具有至少5个环原子的脂族环基团分别是M 1或M 2原子; R表示二价有机桥基; 和可用于该方法的新型二齿二膦。

5. 发明申请

WO03040159A8 NEW BIDENTATE LIGANDS, CATALYST COMPRISING SUCH BIDENTATE LIGANDSAND PROCESS FOR THE CARBONYLATION OF ETHYLENCALLY OR ACETYLENICALLY UNSATURATED COMPOUNDS USING SUCH A CATALYST 审中-公开
标题翻译：新的双重配体，包含这种双酸性配体的催化剂，用于使用这种催化剂乙烯化或乙烯化的不饱和化合物的羰基化方法
公开(公告)号：WO03040159A8
公开(公告)日：2003-07-31
申请号：PCT/EP0212380
申请日：2002-11-05
申请人： SHELL INT RESEARCH , DRENT EIT , VAN GINKEL ROELOF , VAN DER MADE RENATA HELENA
发明人： DRENT EIT , VAN GINKEL ROELOF , VAN DER MADE RENATA HELENA
IPC分类号： B01J23/44 , B01J31/24 , C07B41/12 , C07B61/00 , C07C2/40 , C07C41/06 , C07C67/22 , C07C67/38 , C07C69/24 , C07C69/44 , C07C253/30 , C07C255/19 , C07D201/08 , C07F9/50 , C08G69/02 , C08G69/16 , C08G69/26 , C08G69/28
CPC分类号： B01J31/1895 , B01J23/44 , B01J31/24 , B01J31/2414 , B01J2231/321 , B01J2531/80 , B01J2531/824 , C07C2/406 , C07C67/38 , C07C253/30 , C07C2531/24 , C07C2531/28 , C07D201/08 , C07F9/5027 , C07C255/19 , C07C69/24
摘要： Bidentate ligand of formula (I), R R M -R-M R R wherein M and M each indenpendently represent P, As or Sb; R , R , R and R each independently represent the same or a different optionally substituted organic group and at least one of R , R , R and R contains a tertiary carbon atom through which the group is linked to M or M ; and R represents a bridging group based on a trimethylene group connecting M and M of which the middle carbon atom is double bonded to a non-metal element chosen from group 14, 15 or 16 of the periodic table of elements. Catalyst comprising this bidentate ligand and carbonylation process n which this catalyst is used.
摘要翻译：式（I）的二齿配体，R 1 R 2 M 1 -R M 2 R 3，其中M 1和M 2各自独立地表示P，As或锑; R 1，R 2，R 3和R 4各自独立地表示相同或不同的任选取代的有机基团，并且R 1，R 2，R 3，并且R 4含有叔碳原子，该基团通过该叔碳原子与M 1或M 2连接; 并且R表示基于连接M 1和M 2的三亚甲基的桥连基团，其中中碳原子与选自元素周期表第14,15或16族的非金属元素双键键合。包含该二齿配体和使用该催化剂的羰基化方法n的催化剂。

6. 发明申请

WO03040159A2 NEW BIDENTATE LIGANDS, CATALYST COMPRISING SUCH BIDENTATE LIGANDSAND PROCESS FOR THE CARBONYLATION OF ETHYLENCIALLY OR ACETYLENICALLY UNSATURATED COMPOUNDS USING SUCH A CATALYST 审中-公开
标题翻译：新的双重配体，包含这种二元配体的催化剂，用于使用这种催化剂的乙烯或乙烯基不饱和化合物的羰基化方法
公开(公告)号：WO03040159A2
公开(公告)日：2003-05-15
申请号：PCT/EP0212380
申请日：2002-11-05
申请人： SHELL INT RESEARCH , DRENT EIT , VAN GINKEL ROELOF , VAN DER MADE RENATA HELENA
发明人： DRENT EIT , VAN GINKEL ROELOF , VAN DER MADE RENATA HELENA
IPC分类号： B01J23/44 , B01J31/24 , C07B41/12 , C07B61/00 , C07C2/40 , C07C41/06 , C07C67/22 , C07C67/38 , C07C69/24 , C07C69/44 , C07C253/30 , C07C255/19 , C07D201/08 , C07F9/50 , C08G69/02 , C08G69/16 , C08G69/26 , C08G69/28
CPC分类号： B01J31/1895 , B01J23/44 , B01J31/24 , B01J31/2414 , B01J2231/321 , B01J2531/80 , B01J2531/824 , C07C2/406 , C07C67/38 , C07C253/30 , C07C2531/24 , C07C2531/28 , C07D201/08 , C07F9/5027 , C07C255/19 , C07C69/24
摘要： Bidentate ligand of formula (I), R R M -R-M R R wherein M and M each indenpendently represent P, As or Sb; R , R , R and R each independently represent the same or a different optionally substituted organic group and at least one of R , R , R and R contains a tertiary carbon atom through which the group is linked to M or M ; and R represents a bridging group based on a trimethylene group connecting M and M of which the middle carbon atom is double bonded to a non-metal element chosen from group 14, 15 or 16 of the periodic table of elements. Catalyst comprising this bidentate ligand and carbonylation process n which this catalyst is used.
摘要翻译：式（I）的二齿配体，R 1 R 2 M 1 -R M 2 R 3，其中M 1和M 2各自独立地表示P，As或锑; R 1，R 2，R 3和R 4各自独立地表示相同或不同的任选取代的有机基团，并且R 1，R 2，R 3，并且R 4含有叔碳原子，该基团通过该叔碳原子与M 1或M 2连接; 并且R表示基于连接M 1和M 2的三亚甲基的桥连基团，其中中碳原子与选自元素周期表第14,15或16族的非金属元素双键键合。包含该二齿配体和使用该催化剂的羰基化方法n的催化剂。

7. 发明申请

WO2002083747A2 PROCESS FOR THE PREPARATION OF A POLYMER-AMINE 审中-公开
标题翻译：制备聚合物胺的方法
公开(公告)号：WO2002083747A2
公开(公告)日：2002-10-24
申请号：PCT/EP2002/003487
申请日：2002-03-26
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DRENT, Eit , VAN DER MADE, Renata, Helena
发明人： DRENT, Eit , VAN DER MADE, Renata, Helena
IPC分类号： C08F8/32
CPC分类号： C10L1/2383 , B01J31/1845 , C08F8/32 , C08F2810/40 , C08F8/04 , C08F8/00 , C08F110/06
摘要： Process for the preparation of a polymer-amine comprising:_a) reacting an ethylenically unsaturated polymer with carbon monoxide and hydrogen in the presence of a hydroformylation catalyst, yielding a polymer-aldehyde;_b) reacting the polymer-aldehyde of step a) in a carbon monoxide depleted environment with a nitrogen-containing compound and hydrogen in the presence of an amination catalyst yielding a polymer-amine; wherein step b) is carried out in the presence of the hydroformylation catalyst used in step a)._Atactic polymer-amine, having in the range from 10 to 40 "mm" triads; in the range from 20 to 80 "mr" or "rm" triads; and in the range from 10 to 40 "rr" triads. Fuel composition or lubricating oilcomposition comprising such an atactic polymer-amine.
摘要翻译：制备聚合物胺的方法包括：a）在加氢甲酰化催化剂存在下使烯属不饱和聚合物与一氧化碳和氢反应，得到聚合物醛; b）使步骤a）的聚合物醛与在含胺化催化剂的存在下，用含氮化合物和氢气消耗一氧化碳的环境，得到聚合物 - 胺; 其中步骤b）在步骤a）中使用的加氢甲酰化催化剂的存在下进行。 - 具有10至40“mm”三元组范围内的无规立构聚合物 - 胺; 在20至80“mr”或“rm”三元组范围内; 在10到40个“rr”三合一的范围内。燃料组合物或包含这种无规立构聚合物 - 胺的润滑油组合物。

8. 发明申请

WO2010049465A1 PROCESS FOR THE PREPARATION OF ACYLATED SECONDARY ALCOHOL ALKOXYLATES AND SECONDARY ALCOHOL ALKOXYLATES 审中-公开
标题翻译：制备二级醇酸二烷基酯和次级醇酸烷基酯的方法
公开(公告)号：WO2010049465A1
公开(公告)日：2010-05-06
申请号：PCT/EP2009/064241
申请日：2009-10-28
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VAN DER HEIJDEN, Harry , VAN DER MADE, Renata, Helena , MEURS, Jan, Hermen, Hendrik , ON, Quoc An , VAN ZON, Arie
发明人： VAN DER HEIJDEN, Harry , VAN DER MADE, Renata, Helena , MEURS, Jan, Hermen, Hendrik , ON, Quoc An , VAN ZON, Arie
IPC分类号： C07C67/26 , C07C67/04 , C07C69/24 , C07C41/26 , C07C43/11 , C07C303/24 , C07C303/10 , C08G65/26
CPC分类号： C07C67/04 , C07C41/26 , C07C67/26 , C07C303/24 , C08G65/2615 , C08G65/2648 , C08G65/2675 , C08G65/2678 , C08G65/269 , C07C305/10 , C07C69/14 , C07C43/11
摘要： A process for the preparation of acylated secondary alcohol alkoxylates, said process comprising : (i) reaction of one or more internal olefins with one or more carboxylic acids in the presence of a catalyst composition in order to form one or more carboxylic acid esters; (ii) reaction of one or more carboxylic acid esters from step (i) with one or more alkylene oxide reactants, in the presence of a catalytically effective amount of a catalyst composition comprising: (a) one or more alkaline earth metal salts of carboxylic and/or hydroxycarboxylic acids and/or hydrates of the former; (b) an oxy-acid selected from sulphuric acid and ortho-phosphoric acid; (c) an alcohol and/or an ester; and/or products of the reciprocal reactions of (a), (b) and/or (c) in order to form one or more acylated secondary alcohol alkoxylates; and optionally (iii) hydrolysis or transesterification of one or more acylated secondary alcohol alkoxylates from step (ii) in order to form one or more secondary alcohol alkoxylates; and a process for making secondary alcohol alkoxy sulphates comprising the steps of: preparing secondary alcohol alkoxylates by the afore-mentioned process; and sulphating the secondary alcohol alkoxylates.
摘要翻译：一种制备酰化仲醇烷氧基化物的方法，所述方法包括：（i）在催化剂组合物存在下使一种或多种内烯烃与一种或多种羧酸反应以形成一种或多种羧酸酯; （ii）在催化有效量的催化剂组合物的存在下，将一种或多种来自步骤（i）的羧酸酯与一种或多种烯化氧反应物反应，所述催化剂组合物包含：（a）一种或多种羧酸碱土金属盐和/或前者的羟基羧酸和/或水合物; （b）选自硫酸和正磷酸的氧酸; （c）醇和/或酯; 和/或（a），（b）和/或（c）的相互反应的产物，以便形成一种或多种酰化的仲醇烷氧基化物; 和任选地（iii）来自步骤（ii）的一种或多种酰化仲醇烷氧基化物的水解或酯交换以形成一种或多种仲醇烷氧基化物; 以及制备仲醇烷氧基硫酸盐的方法，包括以下步骤：通过上述方法制备仲醇烷氧基化物; 并使仲醇烷氧基化物硫酸化。

9. 发明申请

WO2004029014A1 PROCESS FOR THE PRODUCTION OF PRIMARY ALCOHOLS 审中-公开
标题翻译：生产初级酒精的方法
公开(公告)号：WO2004029014A1
公开(公告)日：2004-04-08
申请号：PCT/EP2003/050650
申请日：2003-09-24
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DRENT, Eit , VAN DER MADE, Renata Helena
发明人： DRENT, Eit , VAN DER MADE, Renata Helena
IPC分类号： C07C29/16
CPC分类号： C07C29/16 , B01J31/0215 , B01J31/24 , C07C31/125
摘要： A process for producing primary alcohols from secondary alcohols and/or tertiary alcohols and/or ketones, wherein the process comprises reacting a compound selected from a secondary alcohol, a tertiary alcohol, a ketone, or mixtures thereof, with carbon monoxide and hydrogen in the presence of a catalyst based on: i) a source of Group VIII metal, ii)a bidentate ligand having the general formula (I): R 1 -R 2 M 1 -R-M 2 R 3 R 4 wherein M 1 and M 2 are independently P, As or Sb; R 1 and R 2 together represent a bivalent substituted or unsubstituted cyclic group whereby the two free valencies are linked to M l ; R 3 and R 4 independently represent a substituted or unsubstituted hydrocarbyl group, or together represent a bivalent or non-substituted cyclic group whereby the two free valencies are linked to M 2 ; and R represents a bivalent aliphatic bridging group; and iii) an acid having a pK a of 3 or less which is in excess over the Group VIII metal.
摘要翻译：由仲醇和/或叔醇和/或酮生产伯醇的方法，其中该方法包括使选自仲醇，叔醇，酮或其混合物的化合物与一氧化碳和氢气在基于以下的催化剂的存在：i）VIII族金属源，ii）具有通式（I）的二齿配体：R 1 -R 2 M 1 -R M 2 R 3 其中M 1和M 2独立地是P，As或Sb; R 1和R 2一起表示二价取代或未取代的环状基团，其中两个自由价与M 1连接; R 3和R 4独立地表示取代或未取代的烃基，或一起表示二价或未取代的环状基团，由此两种自由价与M 2连接; R表示二价脂肪族桥基; 和iii）pKa为3以下的酸，其超过VIII族金属。

10. 发明申请

WO2003070679A1 PROCESSES FOR THE PREPARATION OF A CAROBXYLIC ANHYDRIDE AND USE OF THE CARBOXYLIC ANHYDRIDE AS AN ACYLATION AGENT 审中-公开
标题翻译：制备碳氢化合物的方法和用作酰化剂的羧酸酐的用途
公开(公告)号：WO2003070679A1
公开(公告)日：2003-08-28
申请号：PCT/EP2003/001689
申请日：2003-02-18
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DRENT, Eit , VAN DER MADE, Renata, Helena , PUGH, Robert, Ian
发明人： DRENT, Eit , VAN DER MADE, Renata, Helena , PUGH, Robert, Ian
IPC分类号： C07C51/14
CPC分类号： C07C67/08 , C07C51/56 , C07C67/38 , C07C53/122 , C07C69/017 , C07C69/24
摘要： Process for the preparation of an carboxylic anhydride by reaction of an ethylenically unsaturated compound with carbon monoxide and an carboxylic acid in the presence of a catalyst comprising: a) a source of a group VIII metal, b) a bidentate diphosphine of formula (I), wherein R 1 represents a bivalent radical that together with the phosphorus atom to which it is attached is an optionally substituted 2-phospha-tricyclo [3.3.1.1{3,7}]-decyl group or a derivative thereof in which one or more of the carbon atoms are replaced by heteroatoms ("2-PA" group); wherein R 2 and R 3 independently represent univalent radicals of up to 20 atoms or jointly form a bivalent radical of up to 20 atoms; wherein R represents a bivalent organic bridging group; and c) a complexing anion; wherein the complexing anion is the anion of the carboxylic acid. Process wherein the carboxylic acid is prepared in-situ and use of the carboxylic anhydride as an acylation agent.
摘要翻译：通过烯属不饱和化合物与一氧化碳和羧酸在催化剂存在下反应来制备羧酸酐的方法，该催化剂包含：Ⅷ族金属的源，其中R1代表二价的二齿二膦与其所连接的磷原子一起是与其中一个或多个碳原子被一个或多个碳原子取代的任选取代的2-磷杂三环[3.3.1.1 {3,7}] - 癸基或其衍生物杂原子“2-PA”基团，其中R2和R3独立地表示至多20个原子的一价基团或共同形成至多20个原子的二价基团，其中R表示二价有机桥连基团和ca络合阴离子，其中络合阴离子是阴离子的羧酸。其中羧酸原位制备并使用羧酸酐作为酰化剂的方法。

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