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11. 发明申请

WO1995021156A1 PHENYLTHIO ACETIC ACID DERIVATIVES, PROCESS AND INTERMEDIATE PRODUCTS FOR THEIR PRODUCTION AND AGENTS CONTAINING THEM 审中-公开
标题翻译： PHENYLTHIOESSIGSÄUREDERIVATE，工艺以及它们和代理人含相同的中间产品
公开(公告)号：WO1995021156A1
公开(公告)日：1995-08-10
申请号：PCT/EP1995000014
申请日：1995-01-03
申请人： BASF AKTIENGESELLSCHAFT , BAYER, Herbert , SAUTER, Hubert , MÜLLER, Ruth , GRAMMENOS, Wassilios , HARREUS, Albrecht , KIRSTGEN, Reinhard , RÖHL, Franz , AMMERMANN, Eberhard , LORENZ, Gisela
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07C327/04
CPC分类号： A01N37/50 , C07C327/22
摘要： Phenylthio acetic acid derivatives of formula (I) in which the components and index have the following meanings: R is hydrogen and alkyl; R is cyano, nitro, trifluoro methyl, halogen, alkyl and alkoxy; m is 0, 1 or 2, in which the radicals R may be different if m is 2; R is hydrogen, cyano, nitro, hydroxy, amino, halogen, alkyl, halogen alkyl, alkoxy, halogen alkoxy, alkylthio, alkylamino or dialkylamino; R is hydrogen, cyano, nitro, hydroxy, amino, halogen, possibly substituted alkyl, alkoxy, alkylthio, alkylamino, dialkylamino, alkenyl, alkenyloxy, alkenylthio, alkenylamino, N-alkenyl-N-alkylamino, alkinyl, alkinyloxy, alkinylthio, alkinylamino, N-alkinyl-N-alkylamino, possibly substituted cycloalkyl, cycloalkyloxy, cycloalkylthio, cycloalkylamino, N-cycloalkyl-N-alkylamino, cycloalkenyl, cycloalkenyloxy, cycloalkenylthio, cycloalkenylamino, N-cycloalkenyl-N-alkylamino, heterocyclyl, heterocyclyloxy, heterocyclylthio, heterocyclylamino, N-heterocyclyl-N-alkylamino, aryl, aryloxy, arylthio, arylamino, N-aryl-N-alkylamino, hetaryl, hetaryloxy, hetarylthio, hetarylamino, N-hetaryl-N-alkylamino; R is hydrogen, possibly substituted alkyl, cycloalkyl, alkenyl, alkinyl, alkyl carbonyl, alkenyl carbonyl, alkinyl carbonyl or alkyl sulphonyl, possibly substituted aryl, aryl carbonyl, aryl sulphonyl, hetaryl, hetaryl carbonyl or hetaryl sulphonyl. The invention also concern their salts, the process and intermediate products for their production and their use.
摘要翻译：式（I），其中取代基和指数具有以下含义的苯乙酸衍生物：R t <1>是氢和烷基; [R <2>氰基，硝基，三氟甲基，卤素，烷基和烷氧基; m是0，1或2，其中基团可以是与R <2>中，当m是2不同; [R <3>是氢，氰基，硝基，羟基，氨基，卤素，烷基，卤代烷基，烷氧基，卤代烷氧基，烷硫基，烷基氨基或二烷基氨基; [R <4>为氢，氰基，硝基，羟基，氨基，卤素，未取代或取代的。烷基，烷氧基，烷硫基，烷基氨基，二烷基氨基，烯基，烯氧基，烯硫基，链烯基，N-链烯基 - N-烷基氨基，炔基，炔氧基，炔硫基，炔基氨基，N-炔基 - N-烷基氨基; 未取代的或取代的。环烷基，环烷氧基，环烷硫基，环烷基氨基，N-环烷基-N-烷基氨基，环烯基，环烯氧基，环烯硫基，cycloalkenylamino，N-环烯基-N-烷基氨基，杂环基，杂环氧基，杂环硫基，杂环基氨基，N-杂环基 - N-烷基氨基，芳基，芳氧基，芳硫基，芳基氨基，N-芳基-N-烷基氨基，杂芳基，杂芳氧基，杂芳硫基，Hetarylamino，N-杂芳基的N-烷基氨基; [R <5>氢，未取代或取代的。烷基，环烷基，烯基，炔基，烷基羰基，烯基羰基，炔基羰基或烷基磺酰基; 未取代的或取代的。芳基，芳基羰基，芳基磺酰基，杂芳基，或hetarylcarbonyl hetarylsulfonyl; 和它们的盐，过程和它们的制备方法和它们的使用的中间体。

12. 发明申请

WO1993025588A1 DISPERSIONS OR SOLUTIONS CONTAINING HYDROXYLAMINE COMPOUNDS AS CROSS-LINKING AGENTS 审中-公开
标题翻译：分散体或解含羟胺化合物作为交联剂
公开(公告)号：WO1993025588A1
公开(公告)日：1993-12-23
申请号：PCT/EP1993001395
申请日：1993-06-03
申请人： BASF AKTIENGESELLSCHAFT , BAUER, Gerhard , AYDIN, Oral , BOTT, Kaspar , NEUHAUSER, Horst , LEY, Gregor , ZOSEL, Albrecht , WILD, Jochen , HARREUS, Albrecht , WISTUBA, Eckehardt
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08F08/30
CPC分类号： C08K5/32 , C08F8/32 , C08F2800/20 , C08L57/10 , C08F220/14
摘要： The invention concerns dispersions or solutions of a polymerizate, polycondensate or polyadduct formed by a radical reaction and including 0.001 to 20 % by wt. of aldehyde-CHO or ketone-CO-groups, the dispersion or solution containing as a cross-linking agent a compound with at least two H2N-O- groups or oxime ether groups derived therefrom.

13. 发明申请

WO1997024317A1 IMINO OXYPHENYL ACETIC ACID DERIVATIVES, METHODS AND INTERMEDIATES FOR THEIR PREPARATION AND USE THEREOF 审中-公开
标题翻译： IMINOOXYPHENYLESSIGSÄUREDERIVATE，工艺和中间产品和使用
公开(公告)号：WO1997024317A1
公开(公告)日：1997-07-10
申请号：PCT/EP1996005642
申请日：1996-12-16
申请人： BASF AKTIENGESELLSCHAFT , GROTE, Thomas , SAUTER, Hubert , KIRSTGEN, Reinhard , BAYER, Herbert , MÜLLER, Ruth , MÜLLER, Bernd , OBERDORF, Klaus , GRAMMENOS, Wassilios , GÖTZ, Norbert , RACK, Michael , HARREUS, Albrecht , RÖHL, Franz , AMMERMANN, Eberhard , HARRIES, Volker , LORENZ, Gisela , STRATHMANN, Siegfried
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07C251/60
CPC分类号： C07C251/60 , C07C2601/10 , C07C2601/14
摘要： The invention relates to 2-imino oxyphenyl acetic acid derivatives of formula (I) in which the substituents and the index have the following meanings: R is C(CO2CH3)=NOCH3 (Ia), C(CONHCH3)=NOCH3 (Ib), C(CONH2)=NOCH3 (Ic), C(CO2CH3)=CHOCH3 (Id), or C(CO2CH3)=CHCH3 (Ie); R is cyano, nitro, halogen, alkyl, alkyl halide or alkoxy; m is 0,1 or 2; R is hydrogen, cyano, hydroxy, halogen, alkyl, alkyl halide, alkoxy alkyl, alkoxy, alkoxy halide, alkylthio, cyclopropyl, alkenyl, optionally substituted aryloxy alkyl, benzyl or benzyloxy; R is hydrogen, cyano, optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, heterocyclyl, aryl and hetaryl, optionally substituted alkoxy, alkenyloxy, alkinyloxy, cycloalkoxy, heterocyclyloxy, aryloxy and hetaryloxy, optionally substituted arylthio and hetarylthio; -Q-C(R )=N-Y -R or -Q-O-N=CR R ; R and R together with the carbon atom to which they are bound, are an optionally substituted four to eight-membered ring which can contain in addition to carbon atoms one or two oxygen atoms and/or sulphur atoms and/or NH- and/or N(C1-C4-alkyl)groups; wherein R and R are not simultaneously bound via heteroatoms to the carbon atom. The invention also relates to the salts of said derivatives, methods and intermediates for their preparation and use thereof.
摘要翻译：式（I），2-Iminooxyphenylessigsäurederivate其中取代基和指数具有以下含义：R t <1> C（CO 2 CH 3）= NOCH 3（Ia）中，C（CONHCH 3）= NOCH 3（Ib）中，C（CONH 2）= NOCH 3（Ic）中，C（CO2CH3）= CHOCH 3（同上）或C（CO2CH3）= CHCH3（IE）; [R <2>氰基，硝基，卤素，烷基，卤代烷基或烷氧基; m是0，1或2; [R <3>是氢，氰基，羟基，卤素，烷基，卤代烷基，烷氧基烷基，烷氧基，卤代烷氧基，烷硫基，环丙基，链烯基，未取代的或取代的。芳氧基烷基，苄基或苄氧基; [R <4>是氢，氰基，未取代的或取代的。烷基，烯基，炔基，环烷基，杂环基，芳基和杂芳基; 未取代的或取代的。烷氧基，烯氧基，炔氧基，环烷氧基，杂环氧基，芳氧基和杂芳氧基; 未取代的或取代的。芳和杂芳硫基; -Q-C（R <5>）= N-Y <1> -R <6>或-Q-O-N = CR <7> - [R <8>; [R <3>和R <4>的碳原子一起形成它们所连接的未取代或取代的。四到八位元环，其除了碳原子，一个或两个氧和/或硫原子和/或NH和/或N（C1-C4烷基）可以含有基团; 其中R <3>和R <4>不同时经由键合至的碳原子键合的杂原子; 和它们的盐，过程和它们的制备方法和它们的使用的中间体。

14. 发明申请

WO1997018195A1 SUBSTITUTED 1-METHYL-3-PHENYLPYRAZOLES AND THE USE THEREOF AS HERBICIDES AND FOR THE DESICCATION OR DEFOLIATION OF PLANTS 审中-公开
标题翻译：取代的1-甲基-3-苯基吡唑及其作为除草剂和植物的干燥/落叶
公开(公告)号：WO1997018195A1
公开(公告)日：1997-05-22
申请号：PCT/EP1996004819
申请日：1996-11-05
申请人： BASF AKTIENGESELLSCHAFT , ZAGAR, Cyrill , HARREUS, Albrecht , VON DEM BUSSCHE-HÜNNEFELD, Christoph, Sweder , HAMPRECHT, Gerhard , HEISTRACHER, Elisabeth , SCHÄFER, Peter , MENKE, Olaf , WESTPHALEN, Karl-Otto , MISSLITZ, Ulf , WALTER, Helmut
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07D231/20
CPC分类号： A01N43/56 , C07D231/18 , C07D231/20
摘要： The invention relates to substituted 1-methyl-3-phenylpyrazoles (I) and the agriculturally useful acid addition salts thereof, in which R is C1-C4 alkylhalide or C1-C4 alkylthiohalide; R is halogen; R is F or Cl; R is CN, C1-C4 fluoroalkyl, C2-C4 fluoroalkenyl or -C(R ) (X-R ) (Y-R ); R is H or C1-C4 alkyl; X and Y are -O- or -S-; R , R is C1-C4 alkyl, C1-C4 alkylhalide, C3-4 alkenyl, C3-C4 alkenylhalide or C3-C4 alkinyl. It also relates to the use thereof as herbicides and for the desiccation or defoliation of plants.
摘要翻译：式（I）或农业上可接受的酸加成盐，取代的1-甲基-3-苯基吡唑，其中R <1> = C 1 -C 4卤代烷氧基或C1-C4卤代烷硫基; [R <2> =卤素; [R <3> = F或Cl; [R <4> = CN，C1-C4氟烷基，C 2 -C 4氟代或-C（R <5>）（X-R <6>）（Y-R <7>）; [R <5> = H或C1-C4烷基; X和Y = -O-或-S-; [R <6> - [R <7> = C1-C4烷基，C1-C4卤代烷基，C3-C4链烯基，C3-C4卤代链烯基或C 3 -C 4炔基。用途：用作除草剂; 对于植物干燥/落叶。

15. 发明申请

WO1996026192A1 ISOXAZOLYL-BENZOYL DERIVATIVES 审中-公开
标题翻译：异恶唑基苯甲酰
公开(公告)号：WO1996026192A1
公开(公告)日：1996-08-29
申请号：PCT/EP1996000592
申请日：1996-02-13
申请人： BASF AKTIENGESELLSCHAFT , VON DEYN, Wolfgang , HILL, Regina, Luise , KARDORFF, Uwe , ENGEL, Stefan , OTTEN, Martina , VOSSEN, Marcus , PLATH, Peter , RANG, Harald , HARREUS, Albrecht , RÖHL, Franz , WALTER, Helmut , WESTPHALEN, Karl-Otto , MISSLITZ, Ulf
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07D261/08
CPC分类号： C07D413/10 , A01N43/80 , C07D261/08 , C07D417/10
摘要： The invention concerns isoxazol-4-yl-benzoyl derivatives of formula (I) in which the substituents have the following meanings: L and M represent hydrogen, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkinyl, C1-C4 alkoxy (these groups being optionally substituted by one to five halogen atoms or C1-C4 alkoxy), halogen, cyano, nitro, a -(Y)n-S(O)mR or -(Y)n-CO-R group; Z represents a five to six-membered heterocyclic saturated or unsaturated group which contains one to three heteroatoms selected from the group comprising oxygen, sulphur or nitrogen and can optionally be substituted by halogen, cyano, nitro, an -CO-R group, C1-C4 alkyl, C1-C4 alkyl halide, C3-C8 cycloalkyl, C1-C4 alkoxy, C1-C4 alkoxy halide, C1-C4 alkyl thio, C1-C4 alkyl thio halide, di-C1-C4 alkyl amino, phenyl optionally substituted by halogen, cyano, nitro, C1-C4 alkyl or C1-C4 alkyl halide, or an oxo group which can be present in the tautomeric form as a hydroxy group, is substituted or, together with a condensation-bound phenyl ring which is optionally substituted by halogen, cyano, nitro, C1-C4 alkyl or C1-C4 alkyl halide, with a condensation-bound carbocycle or with a condensation-bound second heterocycle which can optionally be substituted by halogen, cyano, nitro, C1-C4 alkyl, di-C1-C4 alkyl amino, C1-C4 alkoxy, C1-C4 alkoxy halide, or a C1-C4 alkyl halide, form a bicyclic system; Y represents O or NR ; n is 0 or 1; m is 0, 1 or 2; R represents C1-C4 alkyl, C1-C4 alkyl halide or NR R ; R represents C1-C4 alkyl, C1-C4 alkyl halide, C1-C4 alkoxy or NR R ; R represents hydrogen or C1-C4 alkyl; R represents C1-C4 alkyl; Q represents an isoxazole ring connected at position 4 and of formula (II) in which R represents hydrogen or -CO2R , R represents hydrogen, C1-C4 alkyl or C3-C6 cycloalkyl which can optionally be substituted by one or more halogen atoms or C1-C4 alkyl, R representing a C1-C4 alkyl; J represents a carbonyl group CO or a -CHR group, R representing an OH group, a hydroxyl group optionally acylated with C2-C4 acyl, or a chlorine atom. The invention also concerns salts of compounds of formula (I) usually utilized in agriculture.
摘要翻译： Fomel（I）的异恶唑-4-基 - 苯甲酰基衍生物，其中取代基具有以下含义：L，M是氢，C1-C6烷基，C2-C6链烯基，C2-C6炔基，C1-C4烷氧基，（Y）N S（O）MR <7>或基团 - - （Y）N-CO-，其基团可被一至五个卤素原子或C1-C4烷氧基，任选，卤素，氰基，硝基，的基团取代 [R <8>; Z是5-或6-元杂环的饱和或不饱和基团含有一个，从组氧，硫或氮的选择三个杂原子，任选被卤素取代，氰基，硝基，基团-CO-R <8> C1-C4烷基，C1-C4卤代烷基，C3-C8环烷基，C1-C4烷氧基，C1-C4卤代烷氧基，C1-C4烷硫基，C1-C4卤代烷硫基，二-C 1 -C 4 - 烷基氨基，任选被卤素，氰基，硝基，C1-C4烷基或C1-C4卤代烷基取代的苯基或氧代基团，其也可以任选地以互变异构形式作为羟基存在，或与稠合的，任选被卤素取代，氰基取代的，硝基，C1-C4烷基或C1-C4卤代烷基取代的苯环，稠合碳环或稠合的，任选地被卤素，氰基，硝基，C1-C4烷基取代，二C1-C4烷基氨基，C1-C4- 烷氧基，C1-C4卤代烷氧基，或C1-C4卤代烷基取代的第二Heterocycl 美国形成双环体系; Y是O，NR <9>; n是0或1; m是零，1或2; [R <7> C1-C4烷基，C1-C4卤代烷基，或NR <9> - [R <10>; [R <8> C1-C4烷基，C1-C4卤代烷基，C1-C4烷氧基，或NR <9> - [R <10>; [R <9>是氢或C1-C4烷基; [R <10> C1-C4烷基; Q在位置相连4式的异恶唑（II）其中R <1>是氢或-CO 2 R <3>; [R <2>为氢，可以被一个或多个卤素原子或C1-C4烷基，R是任选取代的C1-C4烷基或C3-C6环烷基<3>是C1-C4烷基; J是羰基或CO基团-CHR <4>; [R <4>为OH基团，任选地被C 2 -C 4酰基羟基或氯原子酰化; 化合物（I）的和农业上常用盐。

16. 发明申请

WO1996024590A1 NOVEL 3-(4-CYANOPHENYL)URACILS 审中-公开
标题翻译： NEW 3-（4-氰基苯基）尿嘧啶
公开(公告)号：WO1996024590A1
公开(公告)日：1996-08-15
申请号：PCT/EP1996000312
申请日：1996-01-26
申请人： BASF AKTIENGESELLSCHAFT , KLINTZ, Ralf , SCHÄFER, Peter , HAMPRECHT, Gerhard , HEISTRACHER, Elisabeth , VON DEM BUSSCHE-HÜNNEFELD, Christoph-Sweder , GÖTZ, Norbert , HARREUS, Albrecht , WESTPHALEN, Karl-Otto , WALTER, Helmut , MISSLITZ, Ulf
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07D239/54
CPC分类号： C07D239/54 , A01N43/54 , C07C255/60 , C07C275/42
摘要： The invention concerns 3-(4-cyanophenyl)uracils of formula (I), wherein A = H, CH3, NH2; Y = -O-, -S-; R = H, halogen; R = H, halogen, C1-C6-alkyl, C1-C6-alkyl halide, C1-C6-alkylthio, C1-C6-alkylsulphenyl, C1-C6-alkylsulphonyl; R = H, halogen, C1-C6-alkyl; R = H, C1-C6-alkyl halide, C1-C6-alkyl, C3-C8-cycloalkyl, C3-C6-alkenyl, C3-C6-alkinyl, (C1-C6-alkyl)carbonyl, (C3-C6-alkenyl)carbonyl, (C3-C6-alkinyl)carbonyl or alkylsulphonyl, each of the last-mentioned eight groups being able to carry one to three substituents: halogen, nitro, cyano, hydroxy, C3-C8-cycloalkyl, C1-C6-alkoxy, C3-C8-cycloalkoxy, C3-C6-alkenyloxy, C3-C6-alkinyloxy, C1-C6-alkoxy-C1-C6-alkoxy, C1-C6-alkylthio, C1-C6-alkylsulphenyl, C1-C6-alkylsulphonyl, C1-C6-alkylidene aminoxy, optionally substituted phenyl, phenoxy or phenylsulphonyl, an optionally substituted 3 to 7-member heterocyclyl or heterocyclyloxy group with one to three heteroatoms, -CO-XR , -OCO-XR or -N(R )R , wherein X = chemical bond, oxygen, sulphur or -N(R )-; R = H, C1-C6-alkyl, C3-C8-cycloalkyl, C3-C6-alkenyl, C3-C6-alkinyl, C1-C6-alkoxy-C1-C6-alkyl, (C1-C6-alkoxy)carbonyl-C1-C6-alkyl, optionally substituted phenyl or phenyl-C1-C6-alkyl; or X and R together equal a 3 to 7-member heterocyclic ring which is bonded via nitrogen, has one to three heteroatoms and can optionally carry one to three substituents; R = H, OH, C1-C6-alkyl, C3-C8-cycloalkyl or C1-C6-alkoxy, and the salts of I when A = hydrogen. The products are used as herbicides, for desiccating and defoliating plants.
摘要翻译： 3-（4-氰基苯基）尿嘧啶（I），其中A = H，CH 3，NH 2; Y = -O - ， - S-; [R <1> = H，卤素; [R <2> = H，卤素，C1-C6烷基，C1-C6卤代烷基，C1-C6-烷硫基，C1-C6-烷基亚磺酰基，C1-C6-烷基磺酰基; [R <3> = H，卤素，C1-C6烷基; [R <4> = H，C1-C6卤代烷基，C1-C6-烷基，C3-C8环烷基，C3-C6链烯基，C3-C6炔基，（C1-C6烷基）羰基，（C3-C6 链烯基）羰基，（C 3 -C 6炔基）羰基或烷基磺酰基中，每个8最后提及的基团可以被一至三个取代基携带：卤素，硝基，氰基，羟基，C3-C8环烷基，C1-C6-烷氧基，C3 C8环烷氧基，C3-C6链烯氧基，C3-C6炔氧基，C1-C6烷氧基C1-C6烷氧基，C1-C6-烷硫基，C1-C6-烷基亚磺酰基，C1-C6烷基磺酰基，C1-C6 -Alkylidenaminoxy，GEG。SUBST。苯基，苯氧基或苯基磺酰基，任选取代的3-至7-元杂环基或具有一至三个杂原子的杂环基氧基，-CO-XR <5>， - OCO-XR <5>，或-N（R <5>）R <6> X =化学键，氧，硫或-N（R <6>） - ; [R <5> = H，C1-C6烷基，C3-C8环烷基，C3-C6链烯基，C3-C6炔基，C1-C6烷氧基C1-C6烷基，（C1-C6烷氧基）羰基C1-C6烷基，GEG。SUBST。苯基，苯基-C 1 -C 6 - 烷基，或X是或和R <5>合起来为=氮连接的3-至7-元具有一至三个杂原子，其中如果需要的话可以带有1-3个取代基取代的杂环; [R <6> = H，OH，C1-C6-烷基，C3-C8环烷基与A =氢或C1-C6烷氧基，和（Ⅰ）的盐。用途：用作除草剂; 对于植物干燥/落叶。

17. 发明申请

WO1996004237A1 METHOD OF PRODUCING O-(2-HYDROXYALKYL)-OXIMES 审中-公开
标题翻译：用于制备O-（2-羟烷基）肟
公开(公告)号：WO1996004237A1
公开(公告)日：1996-02-15
申请号：PCT/EP1995002932
申请日：1995-07-25
申请人： BASF AKTIENGESELLSCHAFT , HARREUS, Albrecht , GÖTZ, Norbert , RANG, Harald
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07C249/12
CPC分类号： C07C249/12
摘要： A method is disclosed of producing O-(2-hydroxyalkyl)-oximes of formula (I), wherein R and R represent an alkyl, or R and R and the carbon atom which carries them represent a 5- to 7-membered cycloalkyl, by the catalytic hydration of O-(2,3-epoxyalkyl)-oxime of general formula (II) with hydrogen. The products of formula (I) are suitable for use as intermediate products in the production of herbicides.
摘要翻译： O-（2-羟烷基）肟（I）（R <1>，R的制备<2> =烷基或R <1>和R <2>和携带它们的碳原子= 5-至7- 元环烷基）由通式（II）与氢的肟O-（2,3-环氧烷基）催化氢化。该产品（I）是作为中间体除草剂。

18. 发明申请

WO1995030648A1 PROCESS FOR PRODUCING ISOMER MIXTURES FROM O-PHENOXYALKYLHYDROXYL AMINES OR O-PHENOXYALKYLOXIMES 审中-公开
标题翻译：用于生产的异构体混合物ØPHENOXYALKYLHYDROXYLAMINEN或o phenoxyalkyloximes
公开(公告)号：WO1995030648A1
公开(公告)日：1995-11-16
申请号：PCT/EP1995001581
申请日：1995-04-26
申请人： BASF AKTIENGESELLSCHAFT , RANG, Harald , GÖTZ, Norbert , HARREUS, Albrecht , BORCHERS, Dirk , HARTMANN, Horst , MAYWALD, Volker , HEIMANN, Frank , BUSCHULTE, Thomas
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07C239/20
CPC分类号： C07C239/20 , C07C249/12 , C07C309/66
摘要： A process is disclosed for producing isomer mixtures from O-phenoxyalkylhydroxyl amines Ia: H2N-O-CH2-CH(R )-O-Ar and Ib: H2N-O-CH(R )-CH2-O-Ar (wherein R represents alkyl, Ar where appropriate a substituted phenyl) and the corresponding salt mixtures. This process involves the following steps: (a) an isomer mixture of O-(2-hydroxyethyl)-oximes (IIa) and (IIb) (in which R is an alkyl and R is an alkyl or alkoxy, or R and R together with the common C atom form a 5-7 member ring) is converted by reaction with a sulphonyl halogenide of formula (III): Hal-SO2-R (wherein R represents an organic group and Hal is a halogen) in the presence of a base to form the corresponding sulphonate mixture of (IVa) and (IVb); (b) this sulphonate mixture is reacted in the presence of a base with a phenol of formula (V): HO-Ar to produce a mixture of O-phenoxyalkyloximes of general formulae (VIa) and (VIb); (c) the mixture is hydrolysed in the presence of an acid and, if required, (d) the O-phenoxyalkylhydroxyl amines (Ia) and (Ib) are released from the resulting salts using a mineral base. The O-phenoxyalkylhydroxyl amines (Ia/Ib) and their precursors (VIa/VIb) are important intermediate products for plant protective agents and drugs.
摘要翻译：的异构体的混合物的制备O型Phenoxyalkylhydroxylaminen（Ia）中：H 2 N-O-CH2-CH（R <1>） - O-Ar和（Ib）中：H 2 N-O-CH（R <1>） - CH2-O-氩（R <1> =烷基; Ar为SUBST GEG苯基..）以及相应的盐的混合物，通过一）肟的异构体混合物O-（2-羟基乙基）（IIa）和（IIb）的（R <2> = 烷基，并且R <3> =烷基，烷氧基，或R <2>和R <3>使用通用C原子= 5-至7-元环）化合物与式（III）的磺酰卤一起：哈尔-SO 2 -R <4> <4>是且其中R是有机基团，Hal是卤素，在碱存在下的成的（IVa）的磺酸盐的相应的混合物和（IVb）中被转换，b）磺酸酯的混合物在碱的存在下与酚式（V）：HO-氩气，于通式（VIA）和（VIb）的O- phenoxyalkyloximes的混合物反应，c）中将该混合物水解在酸的存在下和，如果需要的话，d）从所述发生的盐，所述O- phenoxyalkylhydroxylamines（Ia）和（Ib）的装置矿工芭 Ë版本。 O型phenoxyalkylhydroxylamines（IA / IB）及其前体（VIA /ⅥB）是作物保护剂和药物的重要中间体。

19. 发明申请

WO1995021153A1 PHENYL ACETIC ACID DERIVATIVES, PROCESS AND INTERMEDIATE PRODUCTS FOR THEIR PRODUCTION AND AGENTS CONTAINING THEM 审中-公开
标题翻译：苯乙酸衍生物，PROCESS和中间产品FOR THEIR和代理CONTAINING THE SAME
公开(公告)号：WO1995021153A1
公开(公告)日：1995-08-10
申请号：PCT/EP1995000013
申请日：1995-01-03
申请人： BASF AKTIENGESELLSCHAFT , BAYER, Herbert , SAUTER, Hubert , MÜLLER, Ruth , GRAMMENOS, Wassilios , HARREUS, Albrecht , KIRSTGEN, Reinhard , RÖHL, Franz , AMMERMANN, Eberhard , LORENZ, Gisela
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07C251/34
CPC分类号： C07D207/333 , A01N37/36 , A01N37/50 , A01N43/08 , A01N43/36 , A01N43/40 , A01N43/54 , A01N43/76 , A01N43/78 , A01N43/80 , A01N43/88 , C07C249/08 , C07C251/38 , C07C251/48 , C07C251/60 , C07C327/58 , C07C2601/02 , C07C2601/04 , C07C2601/08 , C07C2601/14 , C07D213/53 , C07D213/64 , C07D239/34 , C07D239/36 , C07D261/08 , C07D261/10 , C07D263/32 , C07D271/06 , C07D277/24 , C07D307/12
摘要： Phenyl acetic acid derivatives of formula (I) in which the components and index have the following meanings: X is NOCH3, CHOCH3 CHCH3 and CHCH2CH3; R is hydrogen and alkyl; R is cyano, nitro, trifluoro methyl, halogen, alkyl and alkoxy; m is 0, 1 or 2, in which the radicals R may be different if m is 2; R is hydrogen, cyano, nitro, hydroxy, amino, halogen, alkyl, halogen alkyl, alkoxy, halogen alkoxy, alkylthio, alkylamino or dialkylamino; R is hydrogen, cyano, nitro, hydroxy, amino, halogen, possibly substituted alkyl, alkoxy, alkylthio, alkylamino, dialkylamino, alkenyl, alkenyloxy, alkenylthio, alkenylamino, N-alkenyl-N-alkylamino, alkinyl, alkinyloxy, alkinylthio, alkinylamino, N-alkinyl-N-alkylamino, possibly substituted cycloalkyl, cycloalkyloxy, cycloalkylthio, cycloalkylamino, N-cycloalkyl-N-alkylamino, cycloalkenyl, cycloalkenyloxy, cycloalkenylthio, cycloalkenylamino, N-cycloalkenyl-N-alkylamino, heterocyclyl, heterocyclyloxy, heterocyclylthio, heterocyclylamino, N-heterocyclyl-N-alkylamino, aryl, aryloxy, arylthio, arylamino, N-aryl-N-alkylamino, hetaryl, hetaryloxy, hetarylthio, hetarylamino, N-hetaryl-N-alkylamino; R is hydrogen, possibly substituted alkyl, cycloalkyl, alkenyl, alkinyl, alkyl carbonyl, alkenyl carbonyl, alkinyl carbonyl or alkyl sulphonyl; possibly substituted aryl, aryl carbonyl, aryl sulphonyl, hetaryl, hetaryl carbonyl or hetaryl sulphonyl; and their salts, process and intermediate products for their production and their use.
摘要翻译：式（I），其中取代基和指数具有以下含义的苯乙酸衍生物：X是NOCH 3，CHOCH 3，CHCH 3和CHCH 2; [R <1>是氢和烷基; [R <2>氰基，硝基，三氟甲基，卤素，烷基和烷氧基; m是0，1或2，其中基团可以是与R <2>中，当m是2不同; [R <3>是氢，氰基，硝基，羟基，氨基，卤素，烷基，卤代烷基，烷氧基，卤代烷氧基，烷硫基，烷基氨基或二烷基氨基; [R <4>为氢，氰基，硝基，羟基，氨基，卤素，未取代或取代的。烷基，烷氧基，烷硫基，烷基氨基，二烷基氨基，烯基，烯氧基，烯硫基，链烯基，N-链烯基 - N-烷基氨基，炔基，炔氧基，炔硫基，炔基氨基，N-炔基 - N-烷基氨基; 未取代的或取代的。环烷基，环烷氧基，环烷硫基，环烷基氨基，N-环烷基-N-烷基氨基，环烯基，环烯氧基，环烯硫基，cycloalkenylamino，N-环烯基-N-烷基氨基，杂环基，杂环氧基，杂环硫基，杂环基氨基，N-杂环基 - N-烷基氨基，芳基，芳氧基，芳硫基，芳基氨基，N-芳基-N-烷基氨基，杂芳基，杂芳氧基，杂芳硫基，Hetarylamino，N-杂芳基的N-烷基氨基; [R <5>氢，未取代或取代的。烷基，环烷基，烯基，炔基，烷基羰基，烯基羰基，炔基羰基或烷基磺酰基; 未取代的或取代的。芳基，芳基羰基，芳基磺酰基，杂芳基，或hetarylcarbonyl hetarylsulfonyl; 和它们的盐，过程和它们的制备方法和它们的使用的中间体。

20. 发明申请

WO1994022812A1 IMINO-SUBSTITUTED PHENYLACETIC ACID AMIDES, THEIR PREPARATION AND FUNGICIDES CONTAINING THEM 审中-公开
标题翻译：亚胺基取代benzeneacetamides，生产和含有杀菌剂
公开(公告)号：WO1994022812A1
公开(公告)日：1994-10-13
申请号：PCT/EP1994000877
申请日：1994-03-19
申请人： BASF AKTIENGESELLSCHAFT , DOETZER, Reinhard , GRAMMENOS, Wassilios , SAUTER, Hubert , HARREUS, Albrecht , WINGERT, Horst , AMMERMANN, Eberhard , LORENZ, Gisela
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07C251/48
CPC分类号： C07C251/48 , A01N37/50 , C07C251/52 , C07C251/54 , C07C251/56 , C07C251/58 , C07C251/60 , C07C251/86 , C07C255/62 , C07C255/66 , C07C2601/02 , C07C2601/08 , C07C2601/14 , C07C2603/24 , C07D217/24
摘要： Described are compounds of the formula (I) in which Y is oxygen or an NR6 group; Z and Z are hydrogen, halogen, alkyl, alkenyl, alkinyl, alkoxy, alkenyloxy, haloalkyl, haloalkoxy, haloalkenyloxy, cyano or nitro; R is hydrogen, alkyl, haloalkyl or aryl; R is hydrogen, alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, aryl, heteroaryl, arylalkyl, heteroarylalkyl, arylalkenyl, heteroarylalkenyl, aryloxyalkyl, heteroarylalkyl, arylalkenyl, heteroarylalkenyl, aryloxyalkyl, heteroaryloxyalkyl, acyl, arylcarbonyl, heteroarylcarbonyl or alkoxycarbonyl and R , R , R and R are hydrogen or alkyl, whereby R and R can together form a ring. Also described are fungicides containing these compounds.

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