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    • 1. 发明申请
    • IMINO OXYPHENYL ACETIC ACID DERIVATIVES, METHODS AND INTERMEDIATES FOR THEIR PREPARATION AND USE THEREOF
    • IMINOOXYPHENYLESSIGSÄUREDERIVATE,工艺和中间产品和使用
    • WO1997024317A1
    • 1997-07-10
    • PCT/EP1996005642
    • 1996-12-16
    • BASF AKTIENGESELLSCHAFTGROTE, ThomasSAUTER, HubertKIRSTGEN, ReinhardBAYER, HerbertMÜLLER, RuthMÜLLER, BerndOBERDORF, KlausGRAMMENOS, WassiliosGÖTZ, NorbertRACK, MichaelHARREUS, AlbrechtRÖHL, FranzAMMERMANN, EberhardHARRIES, VolkerLORENZ, GiselaSTRATHMANN, Siegfried
    • BASF AKTIENGESELLSCHAFT
    • C07C251/60
    • C07C251/60C07C2601/10C07C2601/14
    • The invention relates to 2-imino oxyphenyl acetic acid derivatives of formula (I) in which the substituents and the index have the following meanings: R is C(CO2CH3)=NOCH3 (Ia), C(CONHCH3)=NOCH3 (Ib), C(CONH2)=NOCH3 (Ic), C(CO2CH3)=CHOCH3 (Id), or C(CO2CH3)=CHCH3 (Ie); R is cyano, nitro, halogen, alkyl, alkyl halide or alkoxy; m is 0,1 or 2; R is hydrogen, cyano, hydroxy, halogen, alkyl, alkyl halide, alkoxy alkyl, alkoxy, alkoxy halide, alkylthio, cyclopropyl, alkenyl, optionally substituted aryloxy alkyl, benzyl or benzyloxy; R is hydrogen, cyano, optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, heterocyclyl, aryl and hetaryl, optionally substituted alkoxy, alkenyloxy, alkinyloxy, cycloalkoxy, heterocyclyloxy, aryloxy and hetaryloxy, optionally substituted arylthio and hetarylthio; -Q-C(R )=N-Y -R or -Q-O-N=CR R ; R and R together with the carbon atom to which they are bound, are an optionally substituted four to eight-membered ring which can contain in addition to carbon atoms one or two oxygen atoms and/or sulphur atoms and/or NH- and/or N(C1-C4-alkyl)groups; wherein R and R are not simultaneously bound via heteroatoms to the carbon atom. The invention also relates to the salts of said derivatives, methods and intermediates for their preparation and use thereof.
    • 式(I),2-Iminooxyphenylessigsäurederivate其中取代基和指数具有以下含义:R t <1> C(CO 2 CH 3)= NOCH 3(Ia)中,C(CONHCH 3)= NOCH 3(Ib)中,C(CONH 2)= NOCH 3(Ic)中,C(CO2CH3)= CHOCH 3(同上)或C(CO2CH3)= CHCH3(IE); [R <2>氰基,硝基,卤素,烷基,卤代烷基或烷氧基; m是0,1或2; [R <3>是氢,氰基,羟基,卤素,烷基,卤代烷基,烷氧基烷基,烷氧基,卤代烷氧基,烷硫基,环丙基,链烯基,未取代的或取代的。 芳氧基烷基,苄基或苄氧基; [R <4>是氢,氰基,未取代的或取代的。 烷基,烯基,炔基,环烷基,杂环基,芳基和杂芳基; 未取代的或取代的。 烷氧基,烯氧基,炔氧基,环烷氧基,杂环氧基,芳氧基和杂芳氧基; 未取代的或取代的。 芳和杂芳硫基; -Q-C(R <5>)= N-Y <1> -R <6>或-Q-O-N = CR <7> - [R <8>; [R <3>和R <4>的碳原子一起形成它们所连接的未取代或取代的。 四到八位元环,其除了碳原子,一个或两个氧和/或硫原子和/或NH和/或N(C1-C4烷基)可以含有基团; 其中R <3>和R <4>不同时经由键合至的碳原子键合的杂原子; 和它们的盐,过程和它们的制备方法和它们的使用的中间体。
    • 4. 发明申请
    • PHENYL ACETIC ACID DERIVATIVES, PROCESS AND INTERMEDIATE PRODUCTS FOR THEIR PRODUCTION AND AGENTS CONTAINING THEM
    • 苯乙酸衍生物,PROCESS和中间产品FOR THEIR和代理CONTAINING THE SAME
    • WO1995021153A1
    • 1995-08-10
    • PCT/EP1995000013
    • 1995-01-03
    • BASF AKTIENGESELLSCHAFTBAYER, HerbertSAUTER, HubertMÜLLER, RuthGRAMMENOS, WassiliosHARREUS, AlbrechtKIRSTGEN, ReinhardRÖHL, FranzAMMERMANN, EberhardLORENZ, Gisela
    • BASF AKTIENGESELLSCHAFT
    • C07C251/34
    • C07D207/333A01N37/36A01N37/50A01N43/08A01N43/36A01N43/40A01N43/54A01N43/76A01N43/78A01N43/80A01N43/88C07C249/08C07C251/38C07C251/48C07C251/60C07C327/58C07C2601/02C07C2601/04C07C2601/08C07C2601/14C07D213/53C07D213/64C07D239/34C07D239/36C07D261/08C07D261/10C07D263/32C07D271/06C07D277/24C07D307/12
    • Phenyl acetic acid derivatives of formula (I) in which the components and index have the following meanings: X is NOCH3, CHOCH3 CHCH3 and CHCH2CH3; R is hydrogen and alkyl; R is cyano, nitro, trifluoro methyl, halogen, alkyl and alkoxy; m is 0, 1 or 2, in which the radicals R may be different if m is 2; R is hydrogen, cyano, nitro, hydroxy, amino, halogen, alkyl, halogen alkyl, alkoxy, halogen alkoxy, alkylthio, alkylamino or dialkylamino; R is hydrogen, cyano, nitro, hydroxy, amino, halogen, possibly substituted alkyl, alkoxy, alkylthio, alkylamino, dialkylamino, alkenyl, alkenyloxy, alkenylthio, alkenylamino, N-alkenyl-N-alkylamino, alkinyl, alkinyloxy, alkinylthio, alkinylamino, N-alkinyl-N-alkylamino, possibly substituted cycloalkyl, cycloalkyloxy, cycloalkylthio, cycloalkylamino, N-cycloalkyl-N-alkylamino, cycloalkenyl, cycloalkenyloxy, cycloalkenylthio, cycloalkenylamino, N-cycloalkenyl-N-alkylamino, heterocyclyl, heterocyclyloxy, heterocyclylthio, heterocyclylamino, N-heterocyclyl-N-alkylamino, aryl, aryloxy, arylthio, arylamino, N-aryl-N-alkylamino, hetaryl, hetaryloxy, hetarylthio, hetarylamino, N-hetaryl-N-alkylamino; R is hydrogen, possibly substituted alkyl, cycloalkyl, alkenyl, alkinyl, alkyl carbonyl, alkenyl carbonyl, alkinyl carbonyl or alkyl sulphonyl; possibly substituted aryl, aryl carbonyl, aryl sulphonyl, hetaryl, hetaryl carbonyl or hetaryl sulphonyl; and their salts, process and intermediate products for their production and their use.
    • 式(I),其中取代基和指数具有以下含义的苯乙酸衍生物:X是NOCH 3,CHOCH 3,CHCH 3和CHCH 2; [R <1>是氢和烷基; [R <2>氰基,硝基,三氟甲基,卤素,烷基和烷氧基; m是0,1或2,其中基团可以是与R <2>中,当m是2不同; [R <3>是氢,氰基,硝基,羟基,氨基,卤素,烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基,烷基氨基或二烷基氨基; [R <4>为氢,氰基,硝基,羟基,氨基,卤素,未取代或取代的。 烷基,烷氧基,烷硫基,烷基氨基,二烷基氨基,烯基,烯氧基,烯硫基,链烯基,N-链烯基 - N-烷基氨基,炔基,炔氧基,炔硫基,炔基氨基,N-炔基 - N-烷基氨基; 未取代的或取代的。 环烷基,环烷氧基,环烷硫基,环烷基氨基,N-环烷基-N-烷基氨基,环烯基,环烯氧基,环烯硫基,cycloalkenylamino,N-环烯基-N-烷基氨基,杂环基,杂环氧基,杂环硫基,杂环基氨基,N-杂环基 - N-烷基氨基,芳基, 芳氧基,芳硫基,芳基氨基,N-芳基-N-烷基氨基,杂芳基,杂芳氧基,杂芳硫基,Hetarylamino,N-杂芳基的N-烷基氨基; [R <5>氢,未取代或取代的。 烷基,环烷基,烯基,炔基,烷基羰基,烯基羰基,炔基羰基或烷基磺酰基; 未取代的或取代的。 芳基,芳基羰基,芳基磺酰基,杂芳基,或hetarylcarbonyl hetarylsulfonyl; 和它们的盐,过程和它们的制备方法和它们的使用的中间体。