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111. 发明申请

WO2006130310A1 PROCESS FOR TRANSITIONING A REACTOR FROM A ZIEGLER-NATTA CATALYZED POLYMERIZATION TO A POLYMERIZATION CATALYZED BY ANOTHER TYPE OF CATALYST SYSTEM 审中-公开
标题翻译：将反应器从ZIEGLER-NATTA催化聚合过渡到由其他类型的催化剂体系催化的聚合反应的方法
公开(公告)号：WO2006130310A1
公开(公告)日：2006-12-07
申请号：PCT/US2006/017497
申请日：2006-05-05
申请人： UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION , TURNER, Michael, D. , LEAL, Guadalupe, G.
发明人： TURNER, Michael, D. , LEAL, Guadalupe, G.
IPC分类号： C08F2/34 , C08F2/42
CPC分类号： C08F10/00 , C08F10/02 , C08F210/16 , C08F4/6543 , C08F4/22 , C08F4/24 , C08F2/34 , C08F2/42 , C08F210/14 , C08F2500/07 , C08F2500/12
摘要： A process for transitioning a continuous olefin polymerization reaction, catalyzed by a Ziegler-type catalyst, to a polymerization reaction catalyzed by another type of catalyst system. In this process, the introduction of the transition metal halide component of the Ziegler-type catalyst and the electron donor of the Ziegler-type catalyst into the reactor are discontinued, and the level of each of these components is reduced, using a catalyst inventory reduction step or steps, before and/or after the discontinuation of the catalyst components. The catalyst inventory reduction is eventually followed by the introduction of at least one reversible poison, such as CO 2 , and/or at least one irreversible poison into the reactor, and the circulation of the poison(s) within the reactor. The reactor is purged with an inert gas. Following this process, another catalyst system (or second catalyst system) is introduced into the reactor, and polymerization initiated.
摘要翻译：将由齐格勒型催化剂催化的连续烯烃聚合反应转化为由另一种催化剂体系催化的聚合反应的方法。在该方法中，将齐格勒型催化剂的过渡金属卤化物组分和齐格勒型催化剂的电子给体引入反应器中停止，并且使用催化剂存量减少来降低这些组分的水平步骤或步骤，在催化剂组分中止之前和/或之后。催化剂库存减少最终是在反应器中引入至少一种可逆毒物，例如CO 2和/或至少一种不可逆的毒物，并且毒药的循环，在反应堆内。反应器用惰性气体吹扫。在该方法之后，将另一催化剂体系（或第二催化剂体系）引入反应器中，并开始聚合。

112. 发明申请

WO2005123791A1 CATALYST COMPRISING CHROMIUM AND ZINC FOR OLEFIN POLYMERIZATION AND PROCESS FOR PREPARING IT 审中-公开
标题翻译：包含铬和锌的催化剂用于烯烃聚合及其制备方法
公开(公告)号：WO2005123791A1
公开(公告)日：2005-12-29
申请号：PCT/EP2005/052672
申请日：2005-06-09
申请人： BASELL POLYOLEFINE GMBH , SCHNEIDER, Martin , GÖHRE, Jan , KARER, Rainer , ROHDE, Wolfgang , BOLD, Anke , LUX, Martin , FISCHER, Ernst , KIENER, Christoph
发明人： SCHNEIDER, Martin , GÖHRE, Jan , KARER, Rainer , ROHDE, Wolfgang , BOLD, Anke , LUX, Martin , FISCHER, Ernst , KIENER, Christoph
IPC分类号： C08F10/02
CPC分类号： B01J23/26 , C08F10/00 , C08F110/02 , C08F210/16 , C08F2410/01 , C08F2410/02 , Y10T428/139 , C08F4/10 , C08F4/24 , C08F4/22 , C08F4/025 , C08F2500/12 , C08F2500/24 , C08F2500/13 , C08F2500/04 , C08F210/14 , C08F2500/18
摘要： Catalyst for the polymerization and/or copolymerization of olefins which has a chromium content of from 0.01 to 5% by weight, based on the element in the finished catalyst, is supported on a finely divided inorganic support and is obtainable by concluding calcination at temperatures of from 350 to 1050°C and has a zinc content of from 0.01 to 10% by weight, based on the element in the finished catalyst.
摘要翻译：用于烯烃的聚合和/或共聚的催化剂负载在精细分散的无机载体上，铬含量为0.01-5重量％，基于成品催化剂中的元素，可通过在基于成品催化剂中的元素，从350至1050℃，锌含量为0.01至10重量％。

113. 发明申请

WO2005108439A2 CATALYST SYSTEMS FOR PRODUCING POLYMERS HAVING BROAD MOLECULAR WEIGHT DISTRIBUTIONS AND METHODS OF MAKING THE SAME 审中-公开
标题翻译：用于生产具有广泛分子量分布的聚合物的催化剂体系及其制备方法
公开(公告)号：WO2005108439A2
公开(公告)日：2005-11-17
申请号：PCT/US2005/009669
申请日：2005-03-24
申请人： CHEVRON PHILLIPS CHEMICAL COMPANY LP , MCDANIEL, Max, P. , BENHAM, Elizabeth, A. , SECORA, Steven, J. , JENSEN, Michael, D. , COLLINS, Kathy, S.
发明人： MCDANIEL, Max, P. , BENHAM, Elizabeth, A. , SECORA, Steven, J. , JENSEN, Michael, D. , COLLINS, Kathy, S.
IPC分类号： C08F10/00
CPC分类号： C08F10/00 , C08F210/16 , C08F4/623 , C08F4/24 , C08F4/69 , C08F210/14 , C08F2500/04 , C08F2500/07 , C08F2500/13 , C08F2500/12
摘要： Catalyst systems for polymerizing olefins include a catalyst comprising chromium and a cocatalyst comprising a substituted or unsubstituted non-transition metal cyclopentadienyl (Cp) compound. The catalyst also comprises an inorganic oxide support. Methods of preparing a catalyst comprise contacting a support with chromium and with a non-transition metal Cp compound. The support can be contacted with a solution comprising the non-transition metal Cp compound prior to entry into a reaction zone. Methods of polymerizing at least one olefin include contacting the olefin with a catalyst comprising chromium and with a cocatalyst comprising a non-transition metal Cp. The polymerization can be performed in the presence of hydrogen. Using the cocatalyst in conjunction with the catalyst increases several properties of the polymers produced by this method. Polymer compositions produced by such methods have various unique properties, including a PDI greater than 30.
摘要翻译：用于聚合烯烃的催化剂体系包括含铬的催化剂和包含取代或未取代的非过渡金属环戊二烯基（Cp）化合物的助催化剂。催化剂还包含无机氧化物载体。制备催化剂的方法包括使载体与铬和非过渡金属Cp化合物接触。在进入反应区之前，载体可以与包含非过渡金属Cp化合物的溶液接触。聚合至少一种烯烃的方法包括使烯烃与包含铬的催化剂和包含非过渡金属Cp的助催化剂接触。聚合可以在氢的存在下进行。使用助催化剂与催化剂结合增加了通过该方法生产的聚合物的几种性质。通过这种方法制备的聚合物组合物具有各种独特的性质，包括大于30的PDI。

114. 发明申请

WO2005052012A1 HIGH MOLECULAR WEIGHT HDPE RESINS 审中-公开
标题翻译：高分子量HDPE树脂
公开(公告)号：WO2005052012A1
公开(公告)日：2005-06-09
申请号：PCT/US2003/034679
申请日：2003-10-31
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , ROGER, Scott, T. , TOWLES, Thomas, W. , SPECA, Anthony, N. , KATZEN, Stanley, J.
发明人： ROGER, Scott, T. , TOWLES, Thomas, W. , SPECA, Anthony, N. , KATZEN, Stanley, J.
IPC分类号： C08F10/02
CPC分类号： C08F210/16 , C08F4/24 , C08F4/16 , C08F210/14 , C08F2500/07 , C08F2500/12 , C08F2500/13 , C08F2500/01 , C08F2500/26
摘要： This invention is related to a polyethylene resin particularly suitable for large parts by blow molding and/or sheet extrusion/thermoforming procedures, wherein the resin is made by a process using an activated chromium and titanium-based catalyst.
摘要翻译：本发明涉及通过吹塑和/或片材挤出/热成型方法特别适用于大型部件的聚乙烯树脂，其中树脂通过使用活性铬和钛基催化剂的方法制备。

115. 发明申请

WO2005049665A1 POLYMER OF ETHYLENE 审中-公开
标题翻译：乙烯聚合物
公开(公告)号：WO2005049665A1
公开(公告)日：2005-06-02
申请号：PCT/EP2004/012745
申请日：2004-11-05
申请人： SOLVAY POLYOLEFINS EUROPE-BELGIUM (S.A.) , GROSJEAN, Abel , SANDSTRUM, Steven Don , ZIMMERMAN, John, Mark
发明人： GROSJEAN, Abel , SANDSTRUM, Steven Don , ZIMMERMAN, John, Mark
IPC分类号： C08F10/02
CPC分类号： C08F10/00 , C08F110/02 , C08F210/16 , C08F4/24 , C08F2500/12 , C08F2500/04 , C08F2500/19 , C08F210/14
摘要： The invention relates to a polymer of ethylene which has a μ 0 /μ 2 ratio of at least 13; and a high load melt index HLMI lower than 8 g / 10 min, and a value of tan δ at ω/ωc = 0.01 of less than 1.3, where δ is G"/G', ω is the frequency at which G" and G' are measured and we is the frequency at which G" = G', and Gand G" are respectively the elastic modulus and viscous modulus, both measured in Pa at 190°C; a process for making the polymer using a catalyst comprising chromium supported on a silica-titania support is also described.
摘要翻译：本发明涉及一种具有至少13的mu0 / mu2比的乙烯聚合物; 和高负荷熔体指数HLMI低于8g / 10min，ω/ωgac= 0.01处的tanδ值小于1.3，其中δ是G“/ G'，ω是G”和G“ G'测量，我们是G“= G'的频率，Gand G”分别是在190℃下以Pa计的弹性模量和粘度模量; 还描述了使用包含负载在二氧化硅 - 二氧化钛载体上的铬的催化剂制备聚合物的方法。

116. 发明申请

WO02040556A1 PROCESS FOR THE CONTINUOUS GAS-PHASE (CO-) POLYMERISATION OF OLEFINS IN A FLUIDISED BED REACTOR 审中-公开
标题翻译：烯烃在流化床反应器中的连续气相（CO）聚合方法
公开(公告)号：WO02040556A1
公开(公告)日：2002-05-23
申请号：PCT/GB2001/005078
申请日：2001-11-16
IPC分类号： C08F2/34 , C08F2/40 , C08F4/24 , C08F10/02 , C08F210/16
CPC分类号： C08F10/02 , C08F210/16 , Y10S526/901 , C08F4/24 , C08F2/40 , C08F210/08 , C08F2500/12 , C08F2500/14 , C08F2500/07
摘要： The present invention relates to a process for the gas-phase (co-)polymerisation of olefins in a fluidised bed reactor using a chromium oxide catalyst characterised in that the polymerisation is performed in the presence of a polymer structure modifier.
摘要翻译：本发明涉及使用铬氧化物催化剂在流化床反应器中使烯烃气相（共）聚合的方法，其特征在于聚合在聚合物结构改性剂存在下进行。

117. 发明申请

WO01090204A1 POLYMERIZATION CATALYST USED FOR PRODUCING POLYOLEFINS THAT HAVE EXCELLENT COMBINED PROPERTIES 审中-公开
标题翻译：用于制造具有突出的特征组合的聚烯烃聚合催化剂
公开(公告)号：WO01090204A1
公开(公告)日：2001-11-29
申请号：PCT/EP2001/005452
申请日：2001-05-14
IPC分类号： C08F4/02 , C08F4/24 , C08F10/00 , C08F10/02
CPC分类号： C08F10/02 , C08F4/24
摘要： The invention relates to a method for producing a catalyst used for polymerizing olefins. The inventive method comprises the following steps: a) producing a finely divided silica xerogel, b) loading said xerogel, starting from a solution of chromium trioxide or a chromium compound that is converted to chromium trioxide under the conditions of step c), with chromium, and c) activating the resulting product in a water-free gas flow that contains oxygen in a concentration of more than 10 % by volume at a temperature of from 400 to 1100 DEG C, and doping the product in step b) or in step c) with a fluorinating agent. The invention further relates to a catalyst used for polymerizing olefins that is obtained according to the inventive method and to a method for polymerizing olefins according to which an olefin or an olefinic mixture is polymerized in the presence of a catalyst, using an inventive catalyst.
摘要翻译：本发明涉及一种用于制备催化剂用于烯烃包括聚合：A）制备细分散的二氧化硅干凝胶; b）由三氧化铬或步骤c的合并与铬三氧化铬的铬化合物出来的条件）下的溶液的干凝胶的加载，以及c）在无水氧所得到的产物的激活在含有约10体积的浓度.-％在温度的气流400到1100℃，其中，在阶段a氟化物掺杂与氟化剂b进行）或在步骤c）。本发明还涉及一种用于烯烃聚合的，通过本发明的方法和用于烯烃在烯烃或在催化剂的存在下烯烃的聚合聚合的方法获得，其特征在于，使用本发明的催化剂的催化剂。

118. 发明申请

WO00058375A1 PRODUCTION OF POLYETHYLENE 审中-公开
标题翻译：聚乙烯的生产
公开(公告)号：WO00058375A1
公开(公告)日：2000-10-05
申请号：PCT/EP2000/002279
申请日：2000-03-14
IPC分类号： C08F4/02 , C08F4/22 , C08F4/24 , C08F4/69 , C08F10/02 , C08F210/16
CPC分类号： C08F10/02 , C08F4/24 , C08F210/16 , C08F4/69 , C08F210/14 , C08F2500/12 , C08F2500/07 , C08F2500/04 , C08F4/025
摘要： A process for producing a polyethylene resin having a monomodal molecular weight distribution in a single polymerisation reactor using a chromium-based catalyst system, by copolymerising ethylene and an alpha-olefinic-comonomer having from 3 to 8 carbon atoms, the polyethylene resin comprising a blend of a higher molecular weight fraction polymerised by a first chromium-based catalyst of the system and a lower molecular weight fraction polymerised by a second chromium-based catalyst of the system, wherein the comonomer incorporation in the higher molecular weight fraction is greater than the comonomer incorporation in the lower molecular weight fraction is greater than the comonomer incorporation in the lower molecular weight fraction whereby the higher and lower molecular weight fractions differ in density by from 0.01 to 0.03g/cc.
摘要翻译：一种使用铬基催化剂体系在单一聚合反应器中制备具有单峰分子量分布的聚乙烯树脂的方法，该方法是通过共聚合乙烯和具有3-8个碳原子的α-烯烃共聚单体，所述聚乙烯树脂包含共混物由系统的第一铬基催化剂聚合的较高分子量馏分和由该体系的第二铬基催化剂聚合的较低分子量馏分，其中较高分子量馏分中的共聚单体引入大于共聚单体较低分子量级分中的引入大于较低分子量级分中的共聚单体引入，由此较高分子量分数和较低分子量级分的密度在0.01至0.03g / cc之间。

119. 发明申请

WO00035970A1 MULTISTEP PROCESS FOR PREPARING POLYOLEFINS HAVING HIGH MELT STRENGTH 审中-公开
标题翻译：用于制备具有高熔体强度的聚烯烃的多步法
公开(公告)号：WO00035970A1
公开(公告)日：2000-06-22
申请号：PCT/GB1999/004273
申请日：1999-12-16
IPC分类号： C08F2/00 , C08F4/02 , C08F4/606 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F297/08
CPC分类号： C08F297/08 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F297/083 , Y10S526/905 , C08F4/24 , C08F4/63904 , C08F2/001 , C08F2500/12 , C08F2500/17 , C08F2500/07 , C08F2500/03 , C08F2500/04 , C08F210/14 , C08F4/63922 , C08F4/69
摘要： A process for the preparation of an olefin polymer wherein olefin plymerization is effected in a plurality of polymerization stages (optionally in a plurality of polymerization reactors) in the presence of hydrogen and an olefin polymerization multisite catalyst, preferably a dualsite catalyst, having at least catalytic sites A and B, site A capable of yielding polymers of different molecular weights and differing MFR2 or MFR21 depending on the concentration of hydrogen in the polymerization reactor and site B capable of yielding polymers of certain molecular weight and MFR2 or MFR21 depending on the concentration of hydrogen in the polymerization reactor wherein the ratio between MFR2 OR MFR21 of polymers produced by site B at two different selected hydrogen concentrations is less than 10 and the ratio between MFR2 or MFR21 of polymers produced by site A at the same hydrogen concentrations is more than 50.
摘要翻译：一种烯烃聚合物的制备方法，其中烯烃聚合在多个聚合阶段（任选地在多个聚合反应器中）在氢气和烯烃聚合多位点催化剂，优选双重位点催化剂的存在下进行，所述催化剂至少具有催化作用位点A和B，A能够产生不同分子量和不同MFR 2或MFR 21的聚合物，取决于聚合反应器中的氢浓度和能产生某种分子量的MFR 2或MFR 21的聚合反应器B的位点，这取决于浓度在聚合反应器中的氢气，其中由两个不同选择的氢气浓度下由位点B产生的聚合物的MFR 2 OR MFR 21之间的比率小于10，并且在相同氢气浓度下由位点A产生的聚合物的MFR 2或MFR 21之间的比率大于50 。

120. 发明申请

WO99031143A1 START-UP POLYMERIZATION PROCESS 审中-公开
标题翻译：启动聚合过程
公开(公告)号：WO99031143A1
公开(公告)日：1999-06-24
申请号：PCT/GB1998/003738
申请日：1998-12-14
IPC分类号： B01J8/24 , C08F2/34 , C08F4/24 , C08F10/00 , C08F210/16
CPC分类号： B01J8/1809 , B01J2208/00256 , B01J2208/00274 , B01J2208/00716 , C08F10/00 , C08F210/16 , Y10S526/901 , Y10S526/922 , Y10S585/951 , C08F2/34 , C08F4/24 , C08F210/08
摘要： The present invention relates to a process for starting up a reaciton for the polymerization of an olefin in the gas phase carried out using a catalyst based on chromium oxide in a fluidized bed reactor through which moves a reaction gas mixture containing the olefin, characterized in that in the start-up of the reaction the olefin is introduced into the reactor until the desired production of polymer is reached by means of a two-stage process, during the first stage of which the introduction of the olefin is carried out so as to maintain a constant partial pressure of olefin inthe reactor and during the second stage, the introduction of olefin is regulated at a constant flow rate.
摘要翻译：本发明涉及使用在流化床反应器中使用基于氧化铬的催化剂进行的气相中的烯烃聚合反应的方法，通过该方法移动含有烯烃的反应气体混合物，其特征在于在反应开始时，将烯烃引入反应器中，直到通过两阶段方法达到所需的聚合物生产，在其第一阶段中进行烯烃的引入以维持在反应器中的烯烃的恒定分压，并且在第二阶段期间，以恒定流速调节烯烃的引入。

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